In 1873, a financial crisis plunged the United States into a deep economic depression that exacerbated a number of post-war economic issues. By the late 1870s, political dissent centered primarily on financial issues merged into the Greenback movement, which represented a loose coalition of reformers calling for economic relief based on the expanded use of greenbacks (paper currency issued by the United States Treasury during the Civil War). The Greenback Party emerged as a direct response to federal financial policies, but in Texas, it also provided a broad political platform for those opposed to the policies of "Redeemer/Bourbon" Democrats. The Greenback Party of Texas brought together a wide range of dissenters, including disgruntled Democrats, ousted Republicans, and many different economic and social reformers. From 1876, when the first Greenback clubs appeared in Texas, to the Greenback Party's virtual disappearance after the election of 1884, the Texas Greenbackers reached across boundaries of section, race, class, and sometimes gender; brought together farmers, workers, and professionals; Southerners and Northerners, white and black; former Confederates and former Unionists; native-born Americans and immigrants; and received sizable support from multiple counties in the northern, eastern, and central part of the state. In spite of its short …

Semiconducting aromatic-boron carbide composite/alloyed films formed by plasma enhanced chemical vapor deposition from carborane and aromatic precursors have been demonstrated to be excellent detectors for thermal neutrons because of the large 10B cross section. The electronic properties of these films derived from XPS show that the properties of boron carbide can be tuned by co-deposition of aromatic compounds and carborane. Aromatic doping results in narrower indirect band gaps (1.1 - 1.7 eV vs ~3 eV for orthocarborane-derived boron carbide without aromatics) and average charge transport lifetimes (as long as 2.5 ms for benzene-orthocarborane and 1.5 - 2.5 ms for indole-orthocarborane) that are superior to those of boron carbide (35 µs). The films also show enhanced electron-hole separation that is also superior to those of boron carbide where the states at the top of the valence band is made of aromatic components while states at the bottom of the conduction band is a combination of aromatic and carborane moeities. These properties result in greatly enhanced (~850%) charge collection, relative to films without aromatic content, in thermal neutron exposures at zero-bias, and are gamma-blind. Such films are therefore excellent candidates for zero-bias neutron detector applications. These properties also show little variation with …

The goal of the current study was to evaluate the ways in which religious behaviors and perceived social support are associated with the relationship between depressive symptoms and health-related quality of life for this group. We hypothesized (1) that religious behaviors moderate the relationship between depressive symptoms and health-related quality of life, (2) perceived social support mediates the relationship between depressive symptoms and health-related quality of life and (3) that religious behaviors moderate the mediational indirect effect of perceived social support in the depression and health-related quality of life relationship. Findings from a sample of 244 HIV-positive individuals provided evidence to support direct, conditional, and indirect effects on the depressive symptoms and health-related quality of life relationship. A discussion of the findings, implications for future research and clinical practice are provided.

Porphyrins with extended π-electronic networks are promising candidates for a wide range of applications from medicine to nanotechnology owing to their unique optical and electronic properties. This dissertation is focused on synthesis, characterization and application of β-functionalized π-extended porphyrins. This dissertation is comprised of seven chapters. Chapter 1 focuses on the importance and objective of this work. Chapter 2 gives brief introduction to porphyrins and π-extended porphyrins. In chapter 3, a class of β-functionalized linear push-pull zinc dibenzoporphyrins YH1-YH3 were designed, synthesized, and utilized as light harvesters for DSSCs. In chapter 4, in order to further enhance the photovoltaic performance of β-functionalized benzoporphyrin dyes based DSSCs, a new class of push-pull dibenzoporphyrins YH4-YH7 bearing the phenylethynyl bridge was designed, synthesized and utilized as light harvesters for DSSCs. In chapter 5, in order to solve the photodegradation problem associated with YH7, a new series of push-pull dibenzoporphyrins YH8-YH10 bearing different diarylamino push groups was designed and synthesized. This class of push-pull porphyrins shows improved photostability and enhanced DSSC performance. In chapter 6, a new pentacene-fused diporphyrin with high stability and solubility was prepared and characterized. Chapter 7 includes the summary of this dissertation and describes possible future work.

In this thesis I look at the Arkansas Project and more specifically the racial dynamics within the project and the surrounding communities in Arkansas where SNCC engaged to assist the residents fight for their civil rights. In addition, I analyze how the differences in the urban and rural communities were affected by the racial dynamics of the project's leadership. The Arkansas project was led by William Hansen, a white man, which made him and the project unique from not only other SNCC projects, but other civil rights organizations. This distinction made the strategy that had to be implemented with the project staff internally and also externally in the Arkansas communities different because his race had to be taken into consideration for all purposes. Another aspect that came into play in Arkansas was the fact that some of their activities occurred in urban communities and others occurred in rural communities. These difference in communities affected not only how the local blacks received the SNCC volunteers, but also affected how local whites received the SNCC volunteers. Although the fact that the Arkansas Project had a white field director made it unique and the racial dynamics worthy of scholarly investigation, Bill Hansen's racial …

High levels of quality father involvement in childhood are associated with children's socio-emotional, cognitive, and behavioral wellbeing. However, fathers can experience difficulty in building positive relationships with their kids due to work-life balance, lack of relational experience, and other life stressors. The purpose of this study was to assess the effectiveness of child-parent relationship therapy (CPRT) on fathers' parental empathy, parental stress, and child behavior problems. Though an abundance of literature exists to support the efficacy of CPRT, this was the first study to include a randomized controlled design with an all-male sample. This was also the first CPRT study to include both English and Spanish speaking fathers with intervention offered in both languages. Participants were 30 fathers (22 English, 8 Spanish; 53% Latino, 40% Caucasian, 7% Asian) with children between the ages of 3 and 10 (60% male, 40% female; 57% Latino/a, 37% Caucasian, 6% Asian). Fathers were randomly assigned to the experimental group (CPRT) (n = 14) or waitlist control group (n = 16). Results from 2 (Group) by 2 (Time) repeated measures ANOVAs did not yield statistically significant interaction effects on the dependent variables. However, results indicated a statistically significant main effect for time on each dependent …

This study examines African American stereotypes in film. I studied six directors, Kathryn Bigelow, Spike Lee, the Russo Brothers, Ryan Coogler, Tate Taylor, and Dee Rees; and six films Detroit, BlacKkKlansman, Captain America: The Winter Soldier, The Help, and Mudbound. Using the framework of critical race theory and auteur theory, I compared the common themes between the films and directors. The main purpose of my study is to see if White or Black directors predominantly used African American stereotypes. I found that both races of directors rely on stereotypes for different purposes. With Black directors, the stereotype was explained further through character development, while the White directors used the stereotype at face value with no further explanation.

This study focuses on dark-skinned, Black women's representation in Black sitcoms. Through a mixed-methods use of a comparative textual analysis and focus group, the content and context of episodes from A Different World and Dear White People are explored to illustrate portrayals of dark-skinned, Black women and how these portrayals affect dark-skinned, Black women's self-esteem. Its findings contribute to colorism research by exploring colorism in Black sitcoms. Because this topic is largely unexplored, this study seeks to begin a conversation about dark skinned, Black women's representation in Black sitcoms. The main objective is to ultimately improve their depictions and roles in Black sitcoms and hold Black creatives responsible for the role they play in promoting colorism and its ultimate effect on Black women's self esteem.

In recent decades, changes to federal and state accountability policy and related teacher evaluation systems occurred in the United States with minimal input from two of the largest groups of stakeholders impacted: principals and teachers. For this case study, I explored principals' and teachers' perceptions of their experiences with the Texas Teacher Evaluation and Support System (T-TESS), specifically the role of leadership practices and use of the evaluation rubric as a policy tool within an evaluation process. The study took place at one elementary school. Teachers perceived the evaluation process as carrying out its intended purpose of improving instruction through professional growth. Principals and teachers viewed the teacher evaluation system and the teacher evaluation rubric, a policy tool designed to facilitate and inform the processes and practices used to improve instruction in their districts and schools, as effective. Important district-level decisions also impacted how principals and teachers perceived the T-TESS. District-level decisions included policy related to frequency of required observations, methods of including student performance data, decisions related whether to issue a single rating or multiple ratings, and evaluation of specialized teachers. School-based leadership behaviors and practices were also found to influence teachers' perceptions related to the effectiveness of teacher …

Genomic modifications occur slowly across generations, whereas short-term epigenetic transgenerational inheritance of adaptive phenotypes may be immediately beneficial to large numbers of individuals, acting as a bridge for survival when adverse environments occur. In this study we used dietary exposure to crude oil as an example of an environmental stressor to assess its effects from the molecular to the organismal levels in piscine and avian animal models. In addition, we assessed the role of the parental exposures on their offspring F1 generation. The research developed in this dissertation has contributed to several areas of investigation including molecular biology, animal physiology, and evolutionary biology. The quantitative information from these studies may be utilized to supplement information regarding the proximate and ultimate effects of environmental stressors on fish and bird populations. Furthermore, this information may be used as additional support for understanding the conservation of the responses from the molecular to the whole organismal levels across the vertebrate taxa, as well as their implications for population survival and maintenance. Additionally, the zebrafish (Danio rerio), the Siamese fighting fish (Betta splendens) and the king quail (Coturnix chinensis) have proven to be excellent models to start building a strong basis for understanding the effects …

This dissertation examines the impact of city-level characteristics (immigration-friendliness index, unemployment rate, and the percentage of Democrat Party votes) on the psychological resiliency of Latino immigrants. In the light of increased attention on the immigrant issue throughout the world, this study aims to develop our understanding of the factors that have the effect on the resiliency of immigrant populations. This dissertation examines these different characteristics by examining five different cities in Texas: Austin, Dallas, Fort-Worth, Houston, and San Antonio. The survey was distributed through the Amazon Mechanical Turk (MTurk) to those individuals who define themselves Hispanic or Latino. Results suggest that the city characteristics have a significant impact on the resiliency of Latino immigrants suggesting that local governments have a potential capability to increase the resiliency of the immigrant groups in the United States by embracing the notion that immigrants should be integrated into the fabric of the local community.

This study examined professional practice issues in sport psychology such as qualifications, credentialing, graduate training, and the scope of practice in order to address questions about who should be teaching and providing such services. We used frequencies, t-tests, and chi-square analyses to assess trends among licensed psychologists in the subdiscipline of sport psychology. Analyses show that 26.7% (n = 52) reported providing services to individual athletes and 17.9% (n = 35) to teams in which their work focused on directly improving sport performances. Additionally, 58.5% (n = 114) reported providing mental health services to individual athletes and 10.3% (n = 20) to sport teams. These results suggest services provided to individual athletes and groups/teams of athletes seem to emphasize mental health concerns. Regarding supervision, 18.5% (n = 36) indicated they had received supervision related to improving athletes' sport performance and 35.9% (n = 70) for mental health services they had provided. Another 17.5% (n = 34) indicated having provided supervision to other professionals who were working with athletes to improve their sport performance and 40.0% (n = 78) for those who were addressing athletes' mental health. Overall, 26 (13.3%) of the psychologists had published articles concerning sport and performance psychology …

This study argues that the American Relief Administration (ARA) operationally and culturally was defined by the character and experiences of First World War American military veterans. The historiography of the American Relief Administration in the last half-century has painted the ARA as a purely civilian organization greatly detached from the military sphere. By examining the military veterans of the ARA scholars can more accurately assess the image of the ARA, including what motivated their personnel and determined their relief mission conduct. Additionally, this study will properly explain how the ARA as an organization mutually benefited and suffered from its connection to the U.S. military throughout its European missions, in particular, the 1921 Russian famine relief expedition.

This dissertation examines the impact of citizen's perception of community policing on public attitudes toward fear of terrorism, resilience for a future terrorist attack, and satisfaction with the police in the face of new terrorism. In particular, considering the changing nature of terrorism in recent years as a response to the centralized homeland security efforts, this dissertation attempts to develop our understanding about the extent to which community policing could be a strategy in dealing with terrorism fear among citizens, in building up resilience for future terrorist attacks, and to increase citizens' satisfaction with the police in order to enhance the quality of life in the face of new terrorism. Additionally, this dissertation examines the impact of the variation in the level of community policing implementation on public attitudes toward fear of terrorism, resilience for a future terrorist attack, and satisfaction with the police. Data was collected through an online survey conducted in the cities of Arlington and Frisco, Texas. The survey distributed to the citizens through the Amazon Mechanical Turk (MTurk) platform. These cities were selected based on a community policing scale which was created through the help of the Law Enforcement Management and Administrative Statistics (LEMAS) survey. Results …

The purpose of the current study is to evaluate a procedure that can be used to introduce horses to clipping. Negative reinforcement was used in a shaping paradigm. Shaping steps were conducted by the handler, starting with touching the horse with the hand, then touching the horse with the clippers while they are off, culminating with touching the horse with the clippers while they are on. When a horse broke contact with either the hand or the clippers, the hand or the clippers were held at that point until the horse emitted an appropriate response. When the horse emitted an appropriate response, the clippers were removed, and the handler stepped away from the horse. For all eight horses, this shaping plan was effective in enabling the clipping of each horse with minimal inappropriate behavior and without additional restraint. The entire process took under an hour for each horse.

This two-part mixed-methods study analyzed the Twitter activity of two regional magazines – D Magazine and Texas Monthly – and how social media editors implement strategies to maintain journalistic integrity (news values, topics, and ethical standards) while increasing engagement.

Small apparel retailers face extreme competition with larger retailers. Large retailers have the upper hand in resources to stay updated with various trends, specifically social media. Social media has lowered the barriers to enter the retail industry. However, once these small retailers enter, half of them fail because they don't attract and retain customers. Small-medium enterprises (SMEs) greatly impact the economy, so it is important to study various facets of their business to increase performance. The purpose of this study is to investigate customer's development of social capital (i.e. affiliation, responsiveness, shared values, norm of reciprocity) in small apparel retailer's Instagram page that ultimately lead to purchase intentions for the retailer. Perceived benefits (i.e. perceived usefulness, perceived enjoyment) are also investigated in relation to purchase intentions. More specifically, social bonding, brand identification and trust are examined as mediating variables between the perceived level of social capital, perceived benefits and purchase intentions. Over a 3-month period, 200 responses were collected from students at a southern university. The findings reveal that younger customers develop a relationship with retailers on Instagram and it transfers to behavioral outcomes towards the retailer. The theoretical contribution of this study draws from the lack of literature for …

Two groups of students were compared to determine the impact of early intervention at the Early Childhood School on academic outcomes in later elementary school years for both math and reading. Students who were determined to be disadvantaged in some way, either by income, limited English proficiency, or having been identified as needing specialized instruction and who attended an early intervention program, prior to kindergarten, were compared to a similar group who did not attend the intervention program. Scores on district level assessments in math and reading were tracked for both groups of students through the third grade. Scores on high stakes standardized testing of the students in third grade were also analyzed. Results indicated that students in the control group outperformed students in the treatment group on the majority of district level assessments. However, the opposite was true for high stakes testing where the treatment group outperformed the control group on a consistent basis. These results were consistent, regardless of the nature of the disadvantage. Students who attended the prekindergarten program at the Early Childhood School had higher scores on the State of Texas Assessment of Academic Readiness (STAAR) exam than disadvantaged students who did not attend. Since this …

Cognitive Radio (CR) technology creates the opportunity for unlicensed users to make use of the spectral band provided it does not interfere with any licensed user. It is a prominent tool with spectrum sensing functionality to identify idle channels and let the unlicensed users avail them. Thus, the CR technology provides the consumers access to a very large spectrum, quality spectral utilization, and energy efficiency due to spectral load balancing. However, the full potential of the CR technology can be realized only with CRs equipped with accurate mechanisms to predict/sense the spectral holes and vacant spectral bands without any prior knowledge about the characteristics of traffic in a real-time environment. Multi-layered perception (MLP), the popular neural network trained with the back-propagation (BP) learning algorithm, is a keen tool for classification of the spectral bands into "busy" or "idle" states without any a priori knowledge about the user system features. In this dissertation, we proposed the use of an evolutionary algorithm, Bacterial Foraging Optimization Algorithm (BFOA), for the training of the MLP NN. We have compared the performance of the proposed system with the traditional algorithm and with the Hybrid GA-PSO method. With the results of a simulation experiment that this …

Pianists often have trouble in determining where a phrase ends, or in other words, cadence identification. This is especially true of certain cadences that can be considered either as half cadences or authentic cadences. This analytically ambiguous cadential point can result in different performance decisions, so pianists should make informed decisions about what kind of cadence it is. This study aims to investigate such cadential ambiguity shown at points of phrase boundaries by focusing on Chopin's Piano Sonata No. 2 in B-flat minor, Op. 35, first movement. I offer both possibilities (a half cadence or an authentic cadence) at the phrase ending, suggesting a performance-related strategy based on each possibility. My objective is not to support only one cadential status, but to bring up the cadential problem from the analytical perspective and to demonstrate how cadence identification affects performance results. The dissertation is divided into two parts: analysis and performance, so it relies on a combined method of analytical terminologies and performance-related musical elements. In the analysis, the terminology of William Caplin is employed. The performance part refers to several method books written by prestigious piano pedagogues. After an introduction in Chapter 1, Chapter 2 reviews some literature on cadences. …

Energy- and electron-transfer processes in molecular and supramolecular donor-acceptor systems are of current interest in order to develop light-energy harvesting systems through designing covalently linked donor-acceptor systems or utilizing self-assembled donor-acceptor systems. The research presented in this dissertation deals with the electrochemical, anion binding, and photochemical studies of various oxoporphyrinogen (OxPs), porphyrin, corrole, and phenothiazine systems. The first chapter provides a brief introduction to the material discussed in the subsequent chapters. The second chapter discusses the bromination of meso-tetraarylporphyrings and how that affects their electrochemical, catalytic, and other properties. Bromination of these porphyrins and oxoporphyrinogens allow the HOMO-LUMO gap to increase revealing blue-shifted absorption. Brominated OxPs and bis-crown ether OxP self-assembled with anions depending on strength of the anion and size of the binding site. The addition of crown ethers allows a cation binding site which makes a self-assembled donor-acceptor supramolecular system.Chapters 5 and 6 discuss a series of donor-acceptor conjugates based on zinc porphyrin as the electron donor and copper(III) corrole as the electron acceptor. These studies illustrate the importance of copper(III) corrole as a potent electron acceptor for the construction of energy harvesting model compounds, and constitute the first definitive proof of charge separation in ZnP-CuIIIC systems.Chapter 7 …

Paganini's 24th caprice still remains to this day one of the most celebrated themes in classical music history. Many composers have used this theme to create variations and each composer attempted to produce stylistically unique variations on this piece. Hamelin's Variations on a Theme of Paganini stands out because his piece incorporates musical borrowing and many different composers' styles. His variations integrate music from different centuries, using pastiche and musical borrowing from figures such as Beethoven, Liszt, Brahms, Chopin, and Rachmaninoff. More provocatively, Hamelin's variations reach outside of Classical music, even adopting elements from salsa and friska. The spectrum of composers and styles included in this set are so radical and shocking that it creates a parody of not only Paganini's theme, but also the tradition of theme and variation pieces it has inspired. Due to its multiple variations juxtaposing extremely different styles, Hamelin's Variations on a Theme of Paganini presents the listener with a musical puzzle that is designed to invoke surprise. The juxtapositions of extremely different styles in these variations create disjointed variations with polystylism. The polystylism in this work diversifies his variations, while unifying these seemingly unbalanced movements through broad musical references. As such, both performers and …

Several historians have identified North Texas as constituting a unique cultural region in antebellum Texas, due to the more limited cotton and slave economies and greater opposition to secession. Different settlement patterns have been put forward as an explanation for the distinct "character" of North Texas, with North Texas being portrayed as being settled largely by migrants from the Upper South while the rest of the state was primarily settled by Lower Southerners. The argument rests on the assumption of differing economic and political cultures between Upper and Lower Southerners. This study investigates migration into North Texas counties and the economic life and secession vote in those counties. It challenges the simplistic dichotomy between migrants from the Upper and Lower South by demonstrating the similar rates at which these two groups grew cotton and owned slaves. It also illustrates how geographic considerations better explain the apparent distinctions between North Texas and the rest of the state. Transportation limitations are likely the reason for the more limited cultivation of cotton and, consequently, the lowered importance of slavery in North Texas. Concerns about Indian depredations following the removal of federal troops in the case of secession also seem to have promoted Unionist …

Spanish composer María Teresa Prieto (1895-1982) belongs to a group of Spanish exiles who left their country for Mexico as a result of the Spanish Civil War. She arrived in Mexico in 1936 and developed her compositional career in there. Her first composition after her arrival in the new country was the song cycle Seis Melodías, a work that includes six songs with poetry by Ricardo de Alcázar, Juan Ramón Jiménez, Federico García Lorca, and María Teresa Prieto herself. This document analyzes each one of the songs, both musically and poetically, as well as the relationship between music and text. Seis Melodías' structural organization as a cycle is very particular, since Prieto organized the cycle in pairs—namely I and II, III and IV, and V and VI—each group with strong poetic and thematic unity. The songs belonging to this cycle, present the duality of being independent and dependent at the same time, given that each song stands by itself, but together they create a meta-narrative that progresses from hope to desolation, not as a political statement, but as a homage to, as well as a lament, for the Spanish land and freedom. The cyclical nature of this work is accomplished …