Corrosion is one of the most expensive failures in industries that used metal components and other construction materials. In fact, corrosion is responsible for hundreds of billions-dollar loss in the US alone each year. In general, corrosion occurs when metal surfaces are exposed to water, oxygen, acids, bases, or salts. Therefore, metal substrates must be protected by using materials that act as barriers to avoid destructive corrosion attack. Aluminum is one of the most common metals used in the industry; and it is used in many places such as refining and petroleum production equipment, pipelines, and fossil fuel power plants. Aluminum is known to have corrosion resistance due to the forming of an oxide layer that can be reformed rapidly if the surface gets damaged. However, in the long-term the oxide layer cannot protect the aluminum surface from corrosion because it is stable only in neutral mediums and it is soluble in acidic and basic environments. Barrier protection is one of the most effective methods that prevent aluminum surfaces from being exposed to corrosive environments. These barriers can be organic or inorganic coatings that can limit the electron transport or the cathodic and the anodic reactions between aluminum alloys and …

Since the adoption of neoliberalism, many cities have taken to integrating nature with capital accumulation to create a sense of place. This has been closely tied to urban greening, or green "revitalization." As part of curating this desired character, city governments are working to roll out plans to restore and renew neighborhoods using their natural landscapes through methods such as reforestation, the creation of parks, and commercial development. These cities, deemed Entrepreneurial cities, are increasingly incorporating natural or green spaces into their development of character as part of their branding schemes. This research focuses on the role of nature as the site of economic development and community revitalization within Dallas, Texas. This research examines how the City of Dallas uses nature to attract capital, and how the narratives of development relate to residents' visions for development in the historically neglected Joppa neighborhood in the Trinity River Corridor. Development near Joppa could be an example of how the natural landscape is being used to not only attract developers but also to bring a different ‘class' of resident into the area. By exploring this intersection of nature and capital in Dallas, we can better understand the nuanced ways through which the neoliberalization …

The purpose of the study was two-fold. First, the study explored how self-identified Afrocentrist professors in higher education utilized Afrocentric pedagogy and andragogy to address the learning needs of students, specifically Black women students. Second, the study explored the ways in which Black women students experienced that learning in the higher education classroom. The purpose was advanced through an in-depth analysis of Afrocentric teaching and learning in the higher education. A sample of five self-identified Afrocentric faculty members - three females and two males - and five Black women students who studied with those professors was identified. Participants were interviewed individually in-person and by telephone. Data analysis resulted in the themes of the importance of living an Afrocentric life in which the African body is centered and elevated, rejection of European dominance and universalism, re-routing history, and introducing Afrocentricity as a methodology from which to analyze human life. These themes presented core values, approaches, practices and characteristics utilized in Afrocentric teaching. Findings also showed that the Black women student participants received multiple benefits from receiving an Afrocentric education that assisted them in their journeys through higher education. Study findings provided a foundation for the guidebook "Teach Me, Toward Me Kuongoza, …

Has years of citizen-based nutrient sampling and baseline water quality monitoring efforts only had a "trivial" impact on natural resource management decisions? This thesis will explore this and other findings from a qualitative evaluation of the Rock River Coalition (RRC) citizen-based stream monitoring project in Dane County, Wisconsin, USA. These findings are the culmination of 47 semi-structured interviews with decision-makers from seven client-identified categories and participant observations of board meetings and other watershed groups. Interview questions focused on current strategies of data design and dissemination with the goal of constructing a clearer picture of existing data usage by Dane County decision-makers. In the wider picture of citizen science and community-based research, this case study aims to highlight barriers to data use and potential solutions. The results of this case study were understood through four key frames: (1) Bourdieu's concept of symbolic capital, (2) Barzilai‐Nahon's theory of network gatekeeping, (3) Newman et al.'s framework for leveraging the power of place, and (4) a Foucauldian approach to the production of scientific knowledge. The findings of this study highlight the presence of gatekeeping mechanisms within the scientific field as well as government institutions, problematize the practice of placemaking, assert there is untapped symbolic …

There is currently an increasing trend among the American working population to voluntarily join the gig economy. New terms like the gig economy, sharing economy, internet freelancing, and eLancing have been created to understand this emerging trend among today's workforce. There is a small, yet highly relevant, body of scholarly literature in human resource management that is focused specifically on the eLancing economy as a subset of the gig economy. The purpose of this research is to acknowledge and contribute to this timely literature, which has adequately recognized the enormous potential of this new trend of working. Grounded in the psychology of working theory, a theoretical typology of eLancers is proposed based on the workers' level of volition to be able to choose eLancing as their employment. Further, various predictors such as demographics and personality characteristics were explored on the basis of which eLancers can be classified into types. The study also proposes that different types of eLancers differ in their attitudinal and behavioral work and life outcomes. Prior research has shown that career decisions made by individuals with high work volition relate to higher levels of overall well-being. Hence, classifying eLancers on the basis of their varying levels of …

Daytime cognitive performance and sleep/wake cycles are strongly interrelated, and cognitive dysfunction has been extensively investigated in relation to insomnia. However, methods and outcomes vary widely by study, making comparison difficult without more systematic evaluation. Review of the literature reveals discrepant findings for the relationship between both subjective and objective measures of cognitive performance and insomnia. The current meta-analysis included 42 studies investigating the relationship between insomnia and cognitive performance. Results confirmed the discrepant nature of previous findings and suggest that type of cognitive performance (e.g., simple attention, procedural memory, verbal functions) is important to consider when discussing the impact of insomnia. Mixed-effect meta-analysis of aggregate effect sizes suggest impairments in working memory, complex attention, and episodic memory are significantly associated with insomnia. Analysis of the grouped subjective cognitive performance effect size revealed no significant impact of insomnia. Average age and gender makeup of the sample, study quality, and type of insomnia measure (i.e., clinical or diagnostic criteria, validated scale, or single unvalidated item) did not consistently moderate findings. These results confirm the equivocal nature of the relationship between insomnia and cognitive performance. Overall, about 44% of the studies included in the analysis failed to use DSM or ICSD criteria …

The rising rate of the autism spectrum disorders (ASD) has resulted in challenges for teachers in public schools, concerning the delivery of evidence-based practices for superior outcomes. Thus, school districts are in need of professional learning options that can be efficiently and effectively delivered to improve the procedural fidelity of interventions. The purpose of this study is to demonstrate the effectiveness of using telepractice to teach autism teachers how to contrive motivating operations to teach manding to students with ASD. By utilizing multiple baselines across participants design, four autism teachers in public schools received intervention support through an online module along with video models as well as direct performance feedback from autism specialists via video-conferencing. The primary dependent variable was the percentage of correct responses from the instructional procedures of task analysis, and the secondary measure was the subsequent rate of student mands. Data were analyzed both visually (i.e., through the study of behavioral patterns) and statistically (i.e., analysis of effect size). Results indicate that telepractice increased accuracy of both teacher and student target responses.

Repetitive verbal patterns of speech are a trait associated with high-functioning autism (HFA). For some, this higher-order restricted, repetitive behavior impedes learning, social opportunities, and access to work environments. Despite emerging motivation for establishing social relationships, some individuals with HFA lack the behavioral prerequisites to establish meaningful relationships. The purpose of this study is to demonstrate the effectiveness of teaching interaction to decrease higher-order verbal restricted and repetitive behaviors (RRBs) for four adults with HFA. Through a multiple baseline design across participants, individuals were exposed to a function-based intervention (i.e., teaching interaction) that systematically taught and reinforced alternative communicative behaviors while interrupting repetitive speech with specific feedback. Teaching interaction effectively reduced RRBs and increased alternative conversation for all four participants. Three of the four participants elected to participate in post-intervention maintenance sessions that occurred in individualized naturalistic settings. Their conversation behaviors maintained with one participant receiving one booster session.

This work investigates the Fresnel-lens-based solar concentrator-receiver system in a multi-perspective manner to design, test and fabricate this concentrator with high-efficiency photon and heat outputs and a minimized effect of chromatic aberrations. First, a MATLAB®-incorporated algorithm optimizes both the flat-spot and the curved lens designs via a statistical ray-tracing methodology of the incident light, considering all of its incidence parameters. The target is to maximize the solar ray intensity on the receiver's aperture, and therefore, achieve the highest possible focal flux. The algorithm outputs prismatic and dimensional geometries of the Fresnel-lens concentrator, which are simulated by COMSOL® Multiphysics to validate the design. For the second part, a novel genetically-themed hierarchical algorithm (GTHA) has been investigated to design Fresnel-lens solar concentrators that match with the distinct energy input and spatial geometry of various thermal applications. Basic heat transfer analysis of each application decides its solar energy requirement. The GTHA incorporated in MATLAB® optimizes the concentrator characteristics to secure this energy demand, balancing a minimized geometry and a maximized efficiency. Two experimental applications were selected from literature to validate the optimization process, a solar welding system for H13 steel plates and a solar Stirling engine with an aluminum-cavity receiver attached to the …

Running From My Youth: Essays is a collection of nonfiction essays that explore important moments and experiences from the narrator's youth, and how he has addressed and remembered them in the years since. Some of the essays explore the narrator's time as a distance-runner, while others explore the awkwardness and discomfort onset by religion and nudity.

Photophysical properties of an array of various polyaromatic hydrocarbons were benchmarked with B3LYP, M06 and B97D methods coupled with Pople and CEP-31G(d) basis sets. Results from the benchmark show the importance of diffuse basis sets when modeling the electronic properties of highly conjugated systems and provide qualitative reliable accuracy with certain levels of theory. B97D and M06 are applied to modeling pyrene adducts governed by non-covalent interactions in both gaseous and condensed states to reproduce experimental spectra. DFT calculations with both B97D and M06 functionals show qualitatively and quantitatively that pyrene dimer is a stronger π–base as compared to its monomer. Binding energies coupled with MEP, PCA and Qzz results show that the difference in π-basicity of the monomer and dimer impacts the supramolecular chemistry involved in adducts formed with super π-acidic silver cyclometallic trimer (CTC). Non-covalent interactions between coinage metal CTCs and ammonia/phosphine substrates is reported. Interactions between these substrates and the facial plane of the π-rich gold CTC reveal a novel interaction, where the typical Lewis acid/base roles are reversed for the substrates. Adducts formed through this type of interaction define typical Lewis bases like ammonia and phosphine as Lewis acids, wherein the partially positive hydrogens coordinate to …

William Gillock, a 20th-century American composer and pedagogue, composed numerous works in the styles of different periods for early intermediate-level piano students. The purpose of this dissertation is to introduce Gillock's pieces to teachers of early intermediate students and illustrate how they can be used as a bridge to the study of similar music from Baroque, Classical, and Romantic periods. Gillock's Little Suite in Baroque Style is compared with Handel's Suite in E Major, HWV 430; his Accent on Analytical Sonatinas (Classical) is compared with Clementi's Piano Sonatinas, Op. 36, No. 3, 5, 6; and his Lyric Preludes in Romantic Style (Romantic) is compared with Chopin's 24 Preludes, Op. 28, No. 3, 6, 9, 16, 18, and 24. Each work is examined to reveal its compositional and technical elements along with pedagogical concepts.

In 1873, a financial crisis plunged the United States into a deep economic depression that exacerbated a number of post-war economic issues. By the late 1870s, political dissent centered primarily on financial issues merged into the Greenback movement, which represented a loose coalition of reformers calling for economic relief based on the expanded use of greenbacks (paper currency issued by the United States Treasury during the Civil War). The Greenback Party emerged as a direct response to federal financial policies, but in Texas, it also provided a broad political platform for those opposed to the policies of "Redeemer/Bourbon" Democrats. The Greenback Party of Texas brought together a wide range of dissenters, including disgruntled Democrats, ousted Republicans, and many different economic and social reformers. From 1876, when the first Greenback clubs appeared in Texas, to the Greenback Party's virtual disappearance after the election of 1884, the Texas Greenbackers reached across boundaries of section, race, class, and sometimes gender; brought together farmers, workers, and professionals; Southerners and Northerners, white and black; former Confederates and former Unionists; native-born Americans and immigrants; and received sizable support from multiple counties in the northern, eastern, and central part of the state. In spite of its short …

The goal of the current study was to evaluate the ways in which religious behaviors and perceived social support are associated with the relationship between depressive symptoms and health-related quality of life for this group. We hypothesized (1) that religious behaviors moderate the relationship between depressive symptoms and health-related quality of life, (2) perceived social support mediates the relationship between depressive symptoms and health-related quality of life and (3) that religious behaviors moderate the mediational indirect effect of perceived social support in the depression and health-related quality of life relationship. Findings from a sample of 244 HIV-positive individuals provided evidence to support direct, conditional, and indirect effects on the depressive symptoms and health-related quality of life relationship. A discussion of the findings, implications for future research and clinical practice are provided.

This study focuses on dark-skinned, Black women's representation in Black sitcoms. Through a mixed-methods use of a comparative textual analysis and focus group, the content and context of episodes from A Different World and Dear White People are explored to illustrate portrayals of dark-skinned, Black women and how these portrayals affect dark-skinned, Black women's self-esteem. Its findings contribute to colorism research by exploring colorism in Black sitcoms. Because this topic is largely unexplored, this study seeks to begin a conversation about dark skinned, Black women's representation in Black sitcoms. The main objective is to ultimately improve their depictions and roles in Black sitcoms and hold Black creatives responsible for the role they play in promoting colorism and its ultimate effect on Black women's self esteem.

This two-part mixed-methods study analyzed the Twitter activity of two regional magazines – D Magazine and Texas Monthly – and how social media editors implement strategies to maintain journalistic integrity (news values, topics, and ethical standards) while increasing engagement.

Cognitive Radio (CR) technology creates the opportunity for unlicensed users to make use of the spectral band provided it does not interfere with any licensed user. It is a prominent tool with spectrum sensing functionality to identify idle channels and let the unlicensed users avail them. Thus, the CR technology provides the consumers access to a very large spectrum, quality spectral utilization, and energy efficiency due to spectral load balancing. However, the full potential of the CR technology can be realized only with CRs equipped with accurate mechanisms to predict/sense the spectral holes and vacant spectral bands without any prior knowledge about the characteristics of traffic in a real-time environment. Multi-layered perception (MLP), the popular neural network trained with the back-propagation (BP) learning algorithm, is a keen tool for classification of the spectral bands into "busy" or "idle" states without any a priori knowledge about the user system features. In this dissertation, we proposed the use of an evolutionary algorithm, Bacterial Foraging Optimization Algorithm (BFOA), for the training of the MLP NN. We have compared the performance of the proposed system with the traditional algorithm and with the Hybrid GA-PSO method. With the results of a simulation experiment that this …

This dissertation emphasizes the security aspects of real-time media. The problems of existing real-time media protections are identified in this research, and viable solutions are proposed. First, the security of real-time media depends on the Secure Real-time Transport Protocol (SRTP) mechanism. We identified drawbacks of the existing SRTP Systems, which use symmetric key encryption schemes, which can be exploited by attackers. Elliptic Curve Cryptography (ECC), an asymmetric key cryptography scheme, is proposed to resolve these problems. Second, the ECC encryption scheme is based on elliptic curves. This dissertation explores the weaknesses of a widely used elliptic curve in terms of security and describes a more secure elliptic curve suitable for real-time media protection. Eighteen elliptic curves had been tested in a real-time video transmission system, and fifteen elliptic curves had been tested in a real-time audio transmission system. Based on the performance, X9.62 standard 256-bit prime curve, NIST-recommended 256-bit prime curves, and Brainpool 256-bit prime curves were found to be suitable for real-time audio encryption. Again, X9.62 standard 256-bit prime and 272-bit binary curves, and NIST-recommended 256-bit prime curves were found to be suitable for real-time video encryption.The weaknesses of NIST-recommended elliptic curves are discussed and a more secure new …

The performance of electrical and optical devices based on two-dimensional semiconductors (2D) such as molybdenum disulfide is critically influenced due to very poor light absorption in the atomically thin layers. In this study, the phonon mediated optical absorption and emission properties in single atomic layers of MoS2 have been investigated. The electronic transitions in MoS2 due to near-field optical interaction and the influence of interface phonons due to the dielectric substrate GaN on the relaxation of optically generated carriers will be described. The near-field interaction can be induced in the presence of metal plasmons deposited on the surface of MoS2 monolayers. A hybrid metal-semiconductor system was realized by the deposition of silver (Ag) NPs on MoS2 layer and the localized plasmon modes were selectively chosen to interact with quasiparticles such as excitons and phonons. These quasiparticles are confined within the single atomic layer of MoS2 and are stable at room temperatures due to high binding energy. The lattice vibrational modes in MoS2 can be optically excited with the pulses from a femtosecond laser. These phonon modes can be optically dressed due to near-field interaction in the hybrid Ag-MoS2 system under an optical excitation resonant to localized plasmon modes. The coherent …

Adolphe Gouhenant tells the story of artist, revolutionary, and early North Texas resident Francois Ignace (Adolphe) Gouhenant (1804-1871). Gouhenant was selected by well-known Icarian communist Etienne Cabet to lead an advance guard from France to settle a utopian colony in North Texas. The community, beset by hardships, ultimately scapegoated Gouhenant, accused him of being a French agent, and expelled him. He then journeyed first to Fort Worth to teach the federal soldiers French and art, and next to Dallas, where he founded the town’s first arts establishment in the 1850s. Gouhenant set up shop as a daguerreotypist and photographed the town’s early residents. His Arts Saloon was the scene of many exhibitions and dances but ultimately became the high stake in a nasty battle among Dallas’s leading citizens, setting legal precedent for Texas homestead law.

Wyatt Earp is one of the most legendary figures of the nineteenth-century American West, notable for his role in the gunfight at the O.K. Corral in Tombstone, Arizona. Some see him as a hero lawman of the Wild West, whereas others see him as yet another outlaw, a pimp, and failed lawman. Roy B. Young, Gary L. Roberts, and Casey Tefertiller, all notable experts on Earp and the Wild West, present in A Wyatt Earp Anthology an authoritative account of his life, successes, and failures. The editors have curated an anthology of the very best work on Earp—more than sixty articles and excerpts from books—from a wide array of authors, selecting only the best written and factually documented pieces and omitting those full of suppositions or false material. Earp’s life is presented in chronological fashion, from his early years to Dodge City, Kansas; triumph and tragedy in Tombstone; and his later years throughout the West. Important figures in Earp’s life, such as Bat Masterson, the Clantons, the McLaurys, Doc Holliday, and John Ringo, are also covered. Wyatt Earp’s image in film and the myths surrounding his life, as well as controversies over interpretations and presentations of his life by various …

This anthology collects the eleven winners of the 2018 Best American Newspaper Narrative Writing Contest at the Mayborn Literary Nonfiction Conference, an event hosted by the Frank W. Mayborn Graduate Institute of Journalism at the University of North Texas. First place winner: Kale Williams, “The Loneliest Polar Bear” (The Oregonian), relates the tale of Nora, a baby polar bear raised by humans in a zoo after being abandoned by her mother. Second place: Patricia Callahan, “Doomed by Delay” (Chicago Tribune), reveals the experiences of Illinois families with children diagnosed with Krabbe—a deadly disease that healthcare professionals could have screened for at birth, and ultimately treated, if it weren’t for government bureaucracy. Third place: Christopher Goffard, “Dirty John” (Los Angeles Times), is an investigative story that explores the dynamics of domestic violence with a nuanced, psychologically complex narrative of family and survival. Runners-up include John Woodrow Cox, “Twelve Seconds of Gunfire” (The Washington Post); Tom Hallman Jr., “His Heart, Her Hands” (The Oregonian); Jenna Russell, “The Last Refugee” (The Boston Globe); Lisa Gartner and Zachary T. Sampson, “Wrong Way” (Tampa Bay Times); Casey Parks, “About a Boy” (The Oregonian); Jennifer Emily, “Hope for the Rest of Us” (The Dallas Morning News); …

This method book is designed to help intermediate to advanced jazz students incorporate classic jazz vocabulary into their original improvisations.

In this dissertation, I apply Gadamerian philosophical hermeneutics to examine interpretations of the food-drug relationship within the contexts of health and medicine. Assumptions regarding the relationship between these categories undergird a substantial academic discourse and function as key components in worldviews beyond the academy. Despite this, little work has been done in foregrounding them to allow for critique and consideration of alternative perspectives. Unearthing philosophical assumptions within various fields, epistemic systems, and regulatory bodies, I classify food-drug interpretations into two main categories: dichotomous interpretations of the categories of "food" and "drugs" as ontologically distinct, and continuum-based interpretations where these categories overlap. Rather than arguing for a single appropriate way of understanding the food-drug relationship, my project aims to disclose the complexities of both sets of interpretations, illustrating their virtues and vices, and underscoring the need for people to call their own interpretations into question while taking seriously those of others. The dialogical structure of philosophical hermeneutics provides a useful foundation for dialogue within and between dichotomous and continuum-based interpretations. We do not have unmediated access to a mind-independent reality, the terms "food" and "drugs" do not necessarily refer to natural kinds, and all interpretations likely have different degrees of strengths …