Latin American classical vocal repertoire is vast, but in the United States, we only hear a fairly limited part of this literature. Much of this repertoire blends western European classical music traditions and native folk music traditions. One example of such a Latin American vocal work that is well-known in the United States is Alberto Ginastera's frequently performed song set from 1943, Cinco canciones populares argentinas. However, another lesser-known, earlier work, Cinco canciones argentinas (1923), by fellow Argentine composer Pascual De Rogatis (1880-1980) deserves attention as well. As with Ginastera's set, De Rogatis' songs are based on Argentine folk genres, but contain stylistic features of European classical music of its time. De Rogatis' neglected songs are a significant, overlooked part of Argentine classical music history, and a full understanding of well-known works such as Ginastera's song set and of the genre as a whole, must include attention to De Rogatis' Cinco canciones argentinas. Beyond vocal repertoire, De Rogatis' songs are an important part of the development of Argentine classical music. While Western musical trends change rapidly, folk music remains largely unchanged. Both De Rogatis and Ginastera were proud of their Argentine heritage, and incorporated traditional music into their compositions. I …

David Baldwin has been the trumpet professor at the University of Minnesota since 1974. His most celebrated accomplishment is his recording of the Charlier 36 Etudes de Transcendantes and the Marcel Bitsch Vingt Etudes. In addition to this recording Baldwin has made recordings of etude books by Small, St. Jacome, Arban, Caffarelli, Smith, and the 32 Etudes de Perfectionnement also by Charlier. The quality of performance on all of these makes them excellent reference recordings. The back cover of the Etudes 32 de Perfectionnement reveals that the two-CD album, with a total run time of 115:35, was recorded over a span of four days. Endurance is a topic that all brass players confront. Baldwin wrote an etude book titled Lips of Steel that also contains two previously published articles on the topic of endurance. His ideas on endurance reveal a unique approach. This study analyzes the pedagogical concepts in those articles and in Lips of Steel. In addition to his recording projects, Baldwin has had many successful students. Thomas Rolfs and Lynn Erickson are both members of full-time professional orchestras. Larry Griffin, Scott Hagarty, and many others built their careers as professors of trumpet. An investigation of Baldwin's influence on …

Understanding the fundamental physics in light absorption and perfect light absorption is vital for device applications in detector, sensor, solar energy harvesting and imaging. In this research study, a large area fabrication of Al-doped ZnO/Al2O3/graphene/Al2O3/gold/silicon device was enabled by a spin-processable hydrophilic mono-layer graphene oxide. In contrast to the optical properties of noble metals, which cannot be tuned or changed, the permittivity of transparent metal oxides, such as Al-doped ZnO and indium tin oxide, are tunable. Their optical properties can be adjusted via doping or tuned electrically through carrier accumulation and depletion, providing great advantages for designing tunable photonic devices or realizing perfect absorption. A significant shift of Raman frequency up to 360 cm-1 was observed from graphene in the fabricated device reported in this work. The absorption from the device was tunable with a negative voltage applied on the Al-doped ZnO side. The generated absorption change was sustainable when the voltage was off and erasable when a positive voltage was applied. The reflection change was explained by the Fermi level change in graphene. The sustainability of tuned optical property in graphene can lead to a design of device with less power consumption.

To supplement earnings reported under generally accepted accounting principles (GAAP), public companies often voluntarily report alternative measures of earnings called non-GAAP earnings (NGE). These companies assert that NGE exclude the effect of non-recurring transactions, thereby helping users of financial information to better assess the company's past performance and prospects. Because NGE measures are not well defined, managers can exploit the inherent discretion in calculating NGE to mislead users. Prior studies provide arguments and evidence on the informative as well as opportunistic use of NGE. However, the studies have examined the characteristics and informativeness of NGE with a focus on U.S. companies. The results of studies that consider the NGE disclosure by U.S. companies may not be generalizable to the cross-listed companies because foreign financial reporting standards are different from the U.S. GAAP. Further, prior studies report a difference in earnings quality of U.S. firms and cross-listed firms, which can also result in a difference in the informativeness of their NGE. To fill this gap in literature, I examine whether the informativeness of NGE of cross-listed companies is different from that of U.S. companies. This study contributes to the debate on the informativeness of NGE. It provides evidence that in general, …

Nanoparticles, simple yet groundbreaking objects have led to the discovery of invaluable information due to their physiological, chemical, and physical properties, have become a hot topic in various fields of study including but not limited to chemistry, biology, and physics. In the work presented here, demonstrations of various applications of chemical free nanoparticles are explored, from the determination of a non-invasive method for the study of the exposome via using soft-landing ion mobility (SLIM) deposited nanoparticles as a matrix-assisted laser desorption/ionization (MALDI-MS) matrix replacement, to the direct SLIM-exposure of nanoparticles onto living organisms. While there is plenty of published work in soft-landing at operating pressures of 1 Torr, the work presented here shows how this technology can be operated at the less common ambient pressure. The ease of construction of this instrument allows for various modifications to be performed for a wide array of applications, furthermore the flexibility in metallic sample, operating pressure, and deposition time only open doors to many other future applications. The work presented will also show that our ambient SLIM system is also able to be operated for toxicological studies, as the operation at ambient pressure opens the door to new applications where vacuum conditions are …

There is great expectation that oil development in Ghana will catapult the nation towards prosperity and lead to drastic improvement in the wellbeing of Ghanaians. However, there is also concern that Ghana could fail to achieve these due to the resource curse notwithstanding the fact that scholars of the curse have yet to agree on the inevitability of the curse. Resource curse scholars adduce different reasons for its occurrence or absence. One thing common among the scholars, however, is that none discusses environmental justice in the context of the curse. In this dissertation, I examine Ghana's attempts at avoiding the resource curse through policymaking and implementation using the Guidelines on Environmental Assessment and Management of Ghana's offshore oil sector as a case study. I argue that a strong environmental justice frame is required to avert the curse in Ghana. Specifically, I assess the policy process in Ghana's oil sector, the institutional framework for managing the sector, and analyze the perception of environmental justice for policymaking. The outcome of these assessments show that although the policy process requires broadening for full and effective participation, Ghana has checks and balances policies to avert the resource curse and to deliver environmental justice in …

The Texas Stream Team (TST) is one of an increasing number of citizen science water monitoring programs throughout the US which have been continuously collecting surface water quality data under quality assurance protocols for decades. Volunteer monitoring efforts have generated monitoring datasets that are long-term, continuous, and cover a large geographic area - characteristics shown to be valuable for scientists and professional agencies. However, citizen science data has been of limited use to researchers due to concerns about the accuracy of data collected by volunteers, and the decades of water quality monitoring data collected by TST volunteers is not widely used, if at all. A growing body of studies have attempted to address accuracy concerns by comparing volunteer data to professional data, but this has rarely been done with large-scale, existing datasets like those collected by TST. This study assesses the accuracy of the volunteer water quality data collected across the state of Texas by the TST citizen science program between 1992-2017 by comparing it to professional data from corresponding stations during the same time period, as well as comparing existing and experimental data from a local TST partner agency. The results indicate that even large-scale, existing volunteer and professional …

In Kuwait, an increase in the use of social media by the Kuwait National Assembly (KNA) has allowed it members to reach out to the public and so advance their political agenda. This study examines social media influences on the decision making process; addresses the lack of academic research in relation to KNA members; and seeks to understand the extent to which public political engagement using social media might affect the outcome of their decision making. The proposed social media influence model (SMIM) was used to explore the relationships and relative importance of variables influencing legislator decision making in a social media environment. The second decade of the twenty-first century saw a number of major issues emerging in Kuwait. A core mixed method design known as explanatory sequential was applied to multiple sets of data generated during KNA members' 14th (2013-2016) and 15th (2016-2018) terms. These data included Twitter messages (tweets), the KNA Information Center Parliamentary Information System legislation documents, and the news media articles. The sample was drawn from KNA membership, some of which used Twitter to comment on major events with specific hashtags and the Kuwaiti news media articles related to the same. Study results confirm and support …

This dissertation work is a study of the growth kinematics, synthesis strategies and intrinsic properties of InSb nanowires (NWs). The highlights of this work include a study of the effect of the growth parameters on the composition and crystallinity of NWs. A change in the temperature ramp-up rate as the substrate was heated to reach the NW growth temperature resulted in NWs that were either crystalline or amorphous. The as-grown NWs were found to have very different optical and electrical properties. The growth mechanism for crystalline NWs is the standard vapor-liquid-solid growth mechanism. This work proposes two possible growth mechanisms for amorphous NWs. The amorphous InSb NWs were found to be very sensitive to laser radiation and to heat treatment. Raman spectroscopy measurements on these NWs showed that intense laser light induced localized crystallization, most likely due to radiation induced annealing of defects in the region hit by the laser beam. Electron transport measurements revealed non-linear current-voltage characteristics that could not be explained by a Schottky diode behavior. Analysis of the experimental data showed that electrical conduction in this material is governed by space charge limited current (SCLC) in the high bias-field region and by Ohm's law in the low …

Robbins' problem is an optimal stopping problem where one seeks to minimize the expected rank of their observations among all observations. We examine random walk analogs to Robbins' problem in both discrete and continuous time. In discrete time, we consider full information and relative ranks versions of this problem. For three step walks, we give the optimal stopping rule and the expected rank for both versions. We also give asymptotic upper bounds for the expected rank in discrete time. Finally, we give upper and lower bounds for the expected rank in continuous time, and we show that the expected rank in the continuous time problem is at least as large as the normalized asymptotic expected rank in the full information discrete time version.

The purpose of this study was to ascertain student and teacher perceptions of the environment in which student learning takes place and their perceptions of how it has helped them in the cognitive and social domains. Data collected were through student and teacher perception surveys, student and teacher perception questionnaires, classroom observations, student focus group discussions, and teacher interviews. Themes that emerged from the data sources were student interactions, students' autonomy in personalizing their learning space, teacher perceptions of comfort in the classroom, and student perceptions of comfort in the classroom. The findings of this study point to four recommendations for educational leaders to ensure the effective implementation of new and dynamic learning spaces: (1) consult and support teacher and students, (2) provide professional development, (3) visit campuses and other learning spaces, and (4) add color. In order for real change to take place, teachers need to enquire about and embrace student preferences and allow for the discomfort that will be present when trying something new. Teachers must be willing to relinquish control of the learning experience for the student in order to allow for possibilities in personalized learning on the part of the student. They must risk initial failure …

A plethora of novel scientific phenomena and practical applications, such as solid-state molecular solar cells and other optoelectronic devices for energy harvesting and lighting technologies, have catalyzed us to synthesize novel compounds with tunable properties. Synthetic routes, single crystal structures, and spectral and materials properties are described. Reactions of Ag(I) and Cu(I) precursors with various types of ligands -- including the azolates, diimines, and diiphosphines -- lead to the corresponding complexes in high yield. Varying the metal ions, ligands, synthetic methods, solvents, and/or stoichiometric ratio can change the properties including the molecular geometry or packing structure, reactivity, photophysical and photochemical properties, semiconducting behavior, and/or porosity of the functional coordination polymers obtained. For solar cells purposes, the absorption energy can be extended from the ultraviolet (UV) region, through the entire visible (Vis) region, onto a significant portion of the near-infrared (NIR) portion of the solar spectrum with high absorption coefficients due to the infinite conjugation of Cu(I) with diimine ligands. Twenty-eight crystal structures were obtained by conventional crystal growth methods from organic solvents, whereas their bulk product syntheses also included "green chemistry" approaches that precluded the use of hazardous organic solvents. The resulting products are characterized by powder x-ray diffraction (PXRD), …

The architecture of mobile networks has dramatically evolved in order to fulfill the growing demands on wireless services and data. The radio resources, which are used by the current mobile networks, are limited while the users demands are substantially increasing. In the future, tremendous Internet applications are expected to be served by mobile networks. Therefore, increasing the capacity of mobile networks has become a vital issue. Heterogeneous networks (HetNets) have been considered as a promising paradigm for future mobile networks. Accordingly, the concept of small cell has been introduced in order to increase the capacity of the mobile networks. A femtocell network is a kind of small cell networks. Femtocells are deployed within macrocells coverage. Femtocells cover small areas and operate with low transmission power while providing high capacity. Also, UEs can be offloaded from macrocells to femtocells. Thus, the capacity can be increased. However, this will introduce different technical challenges. The interference has become one of the key challenges for deploying femtocells within a certain macrocells coverage. Undesirable impact of the interference can degrade the performance of the mobile networks. Therefore, radio resource management mechanisms are needed in order to address key challenges of deploying femtocells. The objective of …

Previous studies have shown that fish release alarming substances into the water to alert their kin to escape from danger. In our laboratory, we found that zebrafish produce trypsin and release it from their gills into the environment when they are under stress. By placing the zebrafish larvae in the middle of a small tank and then placing trypsin at one end of the tank, we observed that the larvae moved away from the trypsin zone and almost to the opposite end of the tank. This escape response was significant and did not occur in response to the control substances, bovine serum albumin (BSA), Russell's viper venom (RVV), and collagen. Also, previously, we had shown that the trypsin could act via a protease-activated receptor-2 (PAR2) on the surface of the cells. Therefore, we hypothesized that trypsin would induce a change in neuronal activity in the brain via PAR2-mediated signaling in cells on the surface of the fish body. To investigate whether the trypsin-responsive cells were surface cells, we generated a primary cell culture of zebrafish keratinocytes, confirmed these cells' identity by specific marker expression, and then incubated these cells with the calcium indicator Fluo-4 and exposed them to trypsin. By …

This study was aimed at understanding the use of technology in early childhood school and home settings as well as its impact on students' social and language development, specifically with children aged four to seven from two schools (Kindergarten and elementary) in Kuwait. The study followed a qualitative design in which the interpretative approach was applied. Non-participant observations were conducted to gather data concerning the actual use of technology in the classrooms, they were followed by interviews with teachers and a group of parents from each classroom. The study used Vygotsky's social development theory as a framework for the analysis of data. The analysis showed limitations in the use of technology in the classroom; teachers identified a need for training to increase their knowledge about how to integrate technology into instruction. Also, the limited availability of up-to-date technology was viewed as a challenge. Teachers and parents agreed that the use of technology may foster social and language development for most students, on the condition that their use is supervised and guided by an adult. However, they also perceived that technology could have a negative impact on the development of students' social development, an area that requires further investigation.

In this dissertation we focus on the application of thermodynamic formalism to non-autonomous and random dynamical systems. Specifically we use the thermodynamic formalism to investigate the dimension of various fractal constructions via the, now standard, technique of Bowen which he developed in his 1979 paper on quasi-Fuchsian groups. Bowen showed, roughly speaking, that the dimension of a fractal is equal to the zero of the relevant topological pressure function. We generalize the results of Rempe-Gillen and Urbanski on non-autonomous iterated function systems to the setting of non-autonomous graph directed Markov systems and then show that the Hausdorff dimension of the fractal limit set is equal to the zero of the associated pressure function provided the size of the alphabets at each time step do not grow too quickly. In trying to remove these growth restrictions, we present several other systems for which Bowen's formula holds, most notably ascending systems. We then use these various constructions to investigate the Hausdorff dimension of various subsets of the Julia set for different large classes of transcendental meromorphic functions of finite order which have been perturbed non-autonomously. In particular we find lower and upper bounds for the dimension of the subset of the Julia …

Achievement motivation theory suggests there are two primary approaches to achievement tasks: to appear competent or to develop a skill. These two different approaches to performance yield different affective and behavioral responses. Athletes holding a performance goal orientation tend to respond to challenges with behaviors exemplifying learned helplessness and increased anxiety. Athletes holding a mastery goal orientation tend to respond to challenges with greater effort and experience less sport-related anxiety. Individual athlete factors, such as grit, mindfulness, and achievement orientation may influence how athletes experience their environment and their levels of sport anxiety, and may interact with athletes' achievement motives to influence performance. I used hierarchical multiple regressions to test the main effects of feedback and mindfulness, and feedback and goal orientation, to determine if either mindfulness or goal orientation moderated the effects of feedback on performance. I also used simple regression to determine the relative predictive strength of mindfulness, grit, and goal orientation on athletes' experience of sport anxiety. Mindfulness, but not goal orientation, was a significant moderator of the feedback-shooting performance relationship, but particularly for athletes low in mindfulness; mastery-goal orientation, independently of feedback, was also a significant predictor of task performance. Mindfulness also emerged as the strongest …

The technology for storing and using big data is evolving rapidly and those that can keep pace are likely to garner additional competitive advantages. One approach to uncovering existing practice in a manner that provides insights for building theory is the use of grounded theory. The current research employs qualitative research following a grounded theory approach to explore gap in understanding the relationship between big data (BD) and the supply chain (SC). In this study eight constructs emerged: Organizational and environmental factors, big data and supply chain analytics, alignment, data governance, big data capabilities, cost of quality, risk analysis and supply chain performance. The contribution of this research resulted in a new theoretical framework that provides researchers and practitioners with an ability to visualize the relationship between collection and use of BD and the SC. This framework provides a model for future researchers to test the relationships posited and continue to extend understanding about how BD can benefit SC practice. While it is anticipated that the proposed theoretical framework will evolve as a result of future examination and enhanced understating of the relationships shown the framework presented represents a critical first step for moving the literature and practice forward.

This dissertation attempts to answer how social and economic mechanisms operate in individual, community and state levels to impact volunteering. Both social processes and economic factors significantly impact the amount of volunteering. However, researchers have a tendency to explain volunteering only by one of these factors. As both theories are equally important in explaining volunteerism, the development of a coherent theory is necessary to combine economic and social theories. This dissertation suggested that, when evaluated together, the influences of the economic factors on volunteering diminish as individuals get more connected with the other members of the society. The three-level analysis of the volunteering largely supports the primary hypothesis of the dissertation that economic concerns for volunteering are crowded out when individuals or the society is highly connected. This finding can help practitioners design better strategies to enhance volunteering such as creating opportunities for the members of the society to interact with each other.

Despite the variety of successful reports of the preservation, recovery, and identification of archaeological proteins in general, there are few positive reports regarding mass spectrometry-based identification of ceramic-bound proteins. In large part, this shortage is due to the lack of consideration for the unique taphonomic histories of such residues and, in general, methods development. Further, because negative results are rarely published, there is no baseline to which results can be compared. This paper attempts to address these challenges via a multi-pronged approach that uses mass spectrometry and complementary approaches to evaluate ceramic-bound protein preservation in both controlled, actualistic experiments, and in archaeological artifacts. By comparing the results obtained from protein-spiked, experimentally-aged ceramic to those obtained from both faunal and ceramic archaeological materials, an enhanced perspective on protein preservation and subsequent recovery and identification is revealed. This perspective, focusing on taphonomy, reveals why negative results may be the norm for ceramic artifacts when non-targeted methods are employed, and provides insight into how further method development may improve the likelihood of obtaining positive results.

Imagination and creative self-efficacy are important components of the creative process and outcomes but are rarely investigated together. To explore the relationship between personality factors, imaginative thinking, and creative self-efficacy, survey responses were gathered from university students in a southwestern region in the United States (n = 1,731). Personality was measured using the International Personality Item Pool (IPIP), imagination was measured using the Imaginative Capability Scale (ICS), and creative self-efficacy was measured using items based on reliability in previous studies. Participants were asked to complete the three surveys along with demographic information through an online format. Confirmatory factor analysis (CFA) was conducted first to confirm measurements used. After fit indices confirmed measurement models used, subsequent analyses were conducted using structural equation modeling (SEM). The model of best fit supported creative self-efficacy as a strong predictor of all three factors of imagination. Additionally, the model indicated a strong relationship between conscientiousness and conceiving imagination as well as other notable relationships with personality factors.

Using a phenomenological approach, this qualitative study examined the perspectives of Latino parents and their involvement in the decision of their child to enroll in an advanced mathematics course in sixth grade. Since enrollment in Algebra I in high school is said to be a strong predictor of college attainment and with the growing number of Latino students across the nation, this study has the potential to help district and campus leaders establish whole-school systems for communicating with Latino parents to encourage their children to enroll in advanced mathematics courses at earlier grades. Participants in this study included four sixth-grade students enrolled in an advanced mathematics course, four enrolled in regular mathematics, their mother or father, two mathematics teachers, a school counselor, and two district administrators. Data analyzed included audio recordings of semi-structured interviews of each of the participants. The findings suggested that the district has proactively developed a systematic process of creating that includes six data points to create a student profile of students that will do well in advanced mathematics. This process is helping the district close the gap between total Latino school enrollment and the enrollment of Latino students in advanced mathematics. The findings also suggested that …

As a film composer, Bruce Broughton uses themes, motives, gestures, tropes, and other film composition devices; however, he is also able to develop them into compelling formal structures through the use of film composition techniques in his concert music. Traditional musical form is not necessarily applicable to film music. The film dictates the pacing and structure, whereas concert music allows for the creation of form and more complex musical development. Through his extensive experience composing in the film industry, Broughton instinctively uses his film composition techniques as a means to reach his audience with his concert music. He establishes a common ground through film score vernacular to draw the listener into a more sophisticated musical conversation. This is particularly evident in his extensive wind band catalogue. In this dissertation, I identify Bruce Broughton's film composition techniques and examine how he employs them to create a stand-alone form using those techniques in his wind band music. The film composition techniques that are examined include character association, character interaction, motivic snippets, programmatic associations, and musical tropes. These aspects are demonstrated as they influence form in three of his most frequently performed and highly acclaimed pieces for wind band: In the World of …

Meta-analyses are conducted to synthesize the quantitative results of related studies. The random-effects meta-analysis model is based on the assumption that a distribution of true effects exists in the population. This distribution is often assumed to be normal with a mean and variance. The population variance, also called heterogeneity, can be estimated numerous ways. Accurate estimation of heterogeneity is necessary as a description of the distribution and for determining weights applied in the estimation of the summary effect when using inverse-variance weighting. To evaluate a wide range of estimators, we compared 16 estimators (Bayesian and non-Bayesian) of heterogeneity with regard to bias and mean square error over conditions based on reviews of educational and psychological meta-analyses. Three simulation conditions were varied: (a) sample size per meta-analysis, (b) true heterogeneity, and (c) sample size per effect size within each meta-analysis. Confidence or highest density intervals can be calculated for heterogeneity. The heterogeneity estimators that performed best over the widest range of conditions were paired with heterogeneity interval estimators. Interval estimators were evaluated based on coverage probability, interval width, and coverage of the estimated value. The combination of the Paule Manel estimator and Q-Profile interval method is recommended when synthesizing standardized mean …