SMALL-SCALE TESTING OF PLUTONIUM (IV) OXALATE PRECIPITATION AND CALCINATION TO PLUTONIUM OXIDE TO SUPPORT THE MOX FEED MISSION (open access)

SMALL-SCALE TESTING OF PLUTONIUM (IV) OXALATE PRECIPITATION AND CALCINATION TO PLUTONIUM OXIDE TO SUPPORT THE MOX FEED MISSION

The H-Canyon facility will be used to dissolve Pu metal for subsequent purification and conversion to plutonium dioxide (PuO{sub 2}) using Phase II of HB-Line. To support the new mission, SRNL conducted a series of experiments to produce calcined plutonium (Pu) oxide and measure the physical properties and water adsorption of that material. This data will help define the process operating conditions and material handling steps for HB-Line. An anion exchange column experiment produced 1.4 L of a purified 52.6 g/L Pu solution. Over the next nine weeks, seven Pu(IV) oxalate precipitations were performed using the same stock Pu solution, with precipitator feed acidities ranging from 0.77 M to 3.0 M nitric acid and digestion times ranging from 5 to 30 minutes. Analysis of precipitator filtrate solutions showed Pu losses below 1% for all precipitations. The four larger precipitation batches matched the target oxalic acid addition time of 44 minutes within 4 minutes. The three smaller precipitation batches focused on evaluation of digestion time and the oxalic acid addition step ranged from 25-34 minutes because of pump limitations in the low flow range. Following the precipitations, 22 calcinations were performed in the range of 610-690 C, with the largest number …
Date: June 25, 2012
Creator: Crowder, M.; Pierce, R.; Scogin, J.; Daniel, G. & King, W.
Object Type: Report
System: The UNT Digital Library
Manganese-Based Magnets (open access)

Manganese-Based Magnets

Advanced Research Projects Agency-Energy project sheet summarizing general information about the Rare Earth Alternatives in Critical Technologies (REACT) program including critical needs, innovation and advantages, impacts, and contact information. This sheet discusses a new type of magnet for wind turbines as part of the "Manganese-Based Permanent Magnet with 40 MGOe at 200°C" project.
Date: May 25, 2012
Creator: Pacific Northwest National Laboratory (U.S.)
Object Type: Text
System: The UNT Digital Library
Iron-Nitride Alloy Magnets (open access)

Iron-Nitride Alloy Magnets

Advanced Research Projects Agency-Energy project sheet summarizing general information about the Rare Earth Alternatives in Critical Technologies (REACT) program including critical needs, innovation and advantages, impacts, and contact information. This sheet discusses the development of a magnetic iron-nitride alloy as part of the "Transformation Enabled Nitride Magnets Absent Rare Earths (TEN Mare)" project.
Date: May 25, 2012
Creator: Case Western Reserve University
Object Type: Text
System: The UNT Digital Library
Asian Summer Monsoon Diagnostics for CAM5.1 (open access)

Asian Summer Monsoon Diagnostics for CAM5.1

None
Date: October 25, 2012
Creator: Sperber, K R & Wehner, M F
Object Type: Report
System: The UNT Digital Library
Efficient Heat Storage Materials (open access)

Efficient Heat Storage Materials

Advanced Research Projects Agency-Energy project sheet summarizing general information about the High Energy Advanced Thermal Storage (HEATS) program including critical needs, innovation and advantages, impacts, and contact information. This sheet discusses the development of new materials to store heat in solar and nuclear power plants as part of the "Metallic Composites Phase-Change Materials for High-Temperature Thermal Energy Storage" project.
Date: May 25, 2012
Creator: Massachusetts Institute of Technology
Object Type: Text
System: The UNT Digital Library
What Coexists with the Ferromagnetic Metallic Phase in Manganites? (open access)

What Coexists with the Ferromagnetic Metallic Phase in Manganites?

Colossal magnetoresistance, whereby the application of a magnetic field reduces the resistivity of a manganite by orders of magnitude, is generally believed to occur because of coexisting phases. Development of a complete theory to explain the phenomenon requires that the exact nature of these phases be known. We used resonant elastic soft x-ray scattering to examine the superlattice order that exists in La{sub 0.35}Pr{sub 0.275}Ca{sub 0.375}MnO{sub 3} above and below the Curie temperature. By measuring the resonance profile of the scattered x-rays at different values of q, we disentangle the contributions of orbital order and antiferromagnetism to the scattering signal above the Curie temperature. Below the Curie temperature, we see no signal from orbital order, and only antiferromagnetism coexists with the dominant ferromagnetic metallic phase.
Date: July 25, 2012
Creator: Burkhardt, Mark H.; Hossain, M.A.; Sarkar, S.; Achkar, A.J.; Hawthorn, D.G.; Sutarto, R. et al.
Object Type: Article
System: The UNT Digital Library
COMMENTS ON RESIDENT FARMER DCGLs FOR SITE SOILS AT THE CURTISS-WRIGHT SITE IN CHESWICK, PENNSYLVANIA DCN: 5000-TR-04-0 (open access)

COMMENTS ON RESIDENT FARMER DCGLs FOR SITE SOILS AT THE CURTISS-WRIGHT SITE IN CHESWICK, PENNSYLVANIA DCN: 5000-TR-04-0

Oak Ridge Associated Universities (ORAU), via the Oak Ridge Institute for Science and Education contract, evaluated the Enercon Services, Inc. report on site soils derived concentration guideline levels (DCGLs). The RESRAD code Version 6.5 was used in deterministic mode to consider a range of radionuclides and potential future receptors. A standard sensitivity analysis was also included, along with a probabilistic analysis to select conservative input values for the most sensitive physical parameters.
Date: April 25, 2012
Creator: DAVID KING, CHP
Object Type: Report
System: The UNT Digital Library
Gelled Ionic Liquid-Based Membranes (open access)

Gelled Ionic Liquid-Based Membranes

Advanced Research Projects Agency-Energy project sheet summarizing general information about the Innovative Materials and Processes for Advanced Carbon Capture Technologies (IMPACCT) program including critical needs, innovation and advantages, impacts, and contact information. This sheet discusses the development of gelled membranes as part of the "Achieving a 10,000 GPU Permeance for Post-Combustion Carbon Capture with Gelled Ionic Liquid-Based Membranes" project.
Date: May 25, 2012
Creator: University of Colorado Boulder
Object Type: Text
System: The UNT Digital Library
National Biodiesel Infrastructure Development Initiative Final Program Report (open access)

National Biodiesel Infrastructure Development Initiative Final Program Report

Initiative to increase acceptance of biodiesel in petroleum pipelines
Date: July 25, 2012
Creator: Hamilton, Jill N.; Miller, R. Lynn & Howell, Steve
Object Type: Report
System: The UNT Digital Library