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Statistical Simulation of the Performance and Degradation of a PEMFC Membrane Electrode Assembly (open access)

Statistical Simulation of the Performance and Degradation of a PEMFC Membrane Electrode Assembly

A 1-D MEA Performance model was developed that considered transport of liquid water, agglomerate catalyst structure, and the statistical variation of the MEA characteristic parameters. The model was validated against a low surface area carbon supported catalyst across various platinum loadings and operational conditions. The statistical variation was found to play a significant role in creating noise in the validation data and that there was a coupling effect between movement in material properties with liquid water transport. Further, in studying the low platinum loaded catalyst layers it was found that liquid water played a significant role in the increasing the overall transport losses. The model was then further applied to study platinum dissolution via potential cycling accelerated stress tests, in which the platinum was found to dissolve nearest the membrane effectively resulting in reaction distribution shifts within the layer.
Date: July 1, 2012
Creator: Harvey, David; Bellemare-Davis, Alexander; Karan, Kunal; Jayansankar, Barath; Pharoah, Jon; Colbow, Vesna et al.
System: The UNT Digital Library
Hydrogenation of Dislocation-Limited Heteroepitaxial Silicon Solar Cells: Preprint (open access)

Hydrogenation of Dislocation-Limited Heteroepitaxial Silicon Solar Cells: Preprint

Post-deposition hydrogenation by remote plasma significantly improves performance of heteroepitaxial silicon solar cells. Heteroepitaxial deposition of thin crystal silicon on sapphire for photovoltaics (PV) is an excellent model system for the study and improvement of deposition on inexpensive Al2O3-coated (100) biaxially-textured metal foils. Without hydrogenation, PV conversion efficiencies are less than 1% on our model system. Performance is limited by carrier recombination at electrically active dislocations that result from lattice mismatch, and other defects. We find that low-temperature hydrogenation at 350 degrees C is more effective than hydrogenation at 610 degrees C. In this work, we use measurements such as spectral quantum efficiency, secondary ion mass spectrometry (SIMS), and vibrational Si-H spectroscopies to understand the effects of hydrogenation on the materials and devices. Quantum efficiency increases most at red and green wavelengths, indicating hydrogenation is affecting the bulk more than the surface of the cells. SIMS shows there are 100X more hydrogen atoms in our cells than dangling bonds along dislocations. Yet, Raman spectroscopy indicates that only low temperature hydrogenation creates Si-H bonds; trapped hydrogen does not stably passivate dangling-bond recombination sites at high temperatures.
Date: June 1, 2012
Creator: Bolen, M. L.; Grover, S.; Teplin, C. W.; Bobela, D.; Branz, H. M. & Stradins, P.
System: The UNT Digital Library
Emissivity Tuned Emitter for RTPV Power Sources (open access)

Emissivity Tuned Emitter for RTPV Power Sources

Every mission launched by NASA to the outer planets has produced unexpected results. The Voyager I and II, Galileo, and Cassini missions produced images and collected scientific data that totally revolutionized our understanding of the solar system and the formation of the planetary systems. These missions were enabled by the use of nuclear power. Because of the distances from the Sun, electrical power was produced using the radioactive decay of a plutonium isotope. Radioisotopic Thermoelectric Generators (RTGs) used in the past and currently used Multi-Mission RTGs (MMRTGs) provide power for space missions. Unfortunately, RTGs rely on thermocouples to convert heat to electricity and are inherently inefficient ({approx} 3-7% thermal to electric efficiency). A Radioisotope Thermal Photovoltaic (RTPV) power source has the potential to reduce the specific mass of the onboard power supply by increasing the efficiency of thermal to electric conversion. In an RTPV, a radioisotope heats an emitter, which emits light to a photovoltaic (PV) cell, which converts the light into electricity. Developing an emitter tuned to the desired wavelength of the photovoltaic is a key part in increasing overall performance. Researchers at the NASA Glenn Research Center (GRC) have built a Thermal Photovoltaic (TPV) system, that utilizes a …
Date: March 1, 2012
Creator: Stoots, Carl M.; O'Brien, Robert C. & Howe, Troy M.
System: The UNT Digital Library
N*(1535) electroproduction at high Q2 (open access)

N*(1535) electroproduction at high Q2

A covariant spectator quark model is applied to study the {gamma}N {yields} N*(1535) reaction in the large Q{sup 2} region. Starting from the relation between the nucleon and N*(1535) systems, the N*(1535) valence quark wave function is determined without the addition of any parameters. The model is then used to calculate the {gamma}N {yields} N*(1535) transition form factors. A very interesting, useful relation between the A{sub 1/2} and S{sub 1/2} helicity amplitudes for Q{sup 2} > GeV{sup 2}, is also derived.
Date: April 1, 2012
Creator: G. Ramalho, M.T. Pena, K. Tsushima
System: The UNT Digital Library
Thomson scattering diagnostic for the measurement of ion species fraction (open access)

Thomson scattering diagnostic for the measurement of ion species fraction

Simultaneous Thomson scattering measurements of collective electron-plasma and ion-acoustic fluctuations have been utilized to determine ion species fraction from laser produced CH plasmas. The CH{sub 2} foil is heated with 10 laser beams, 500 J per beam, at the Omega Laser facility. Thomson scattering measurements are made 4 mm from the foil surface using a 30 J 2{omega} probe laser with a 1 ns pulse length. Using a series of target shots the plasma evolution is measured from 2.5 ns to 9 ns after the rise of the heater beams. Measuring the electron density and temperature from the electron-plasma fluctuations constrains the fit of the two-ion species theoretical form factor for the ion feature such that the ion temperature, plasma flow velocity and ion species fraction are determined. The ion species fraction is determined to an accuracy of {+-}0.06 in species fraction.
Date: May 1, 2012
Creator: Ross, J. S.; Park, H. S.; Amendt, A.; Divol, L.; Kugland, N. L.; Rozmus, W. et al.
System: The UNT Digital Library
Operation of the DC current transformer intensity monitors at FNAL during run II (open access)

Operation of the DC current transformer intensity monitors at FNAL during run II

Circulating beam intensity measurements at FNAL are provided by five DC current transformers (DCCT), one per machine. With the exception of the DCCT in the Recycler, all DCCT systems were designed and built at FNAL. This paper presents an overview of both DCCT systems, including the sensor, the electronics, and the front-end instrumentation software, as well as their performance during Run II.
Date: January 1, 2012
Creator: Crisp, J.; Fellenz, B.; Heikkinen, D.; Ibrahim, M. A.; Meyer, T. & Vogel, G.
System: The UNT Digital Library
Impact of Transmission on Resource Adequacy in Systems with Wind and Solar Power: Preprint (open access)

Impact of Transmission on Resource Adequacy in Systems with Wind and Solar Power: Preprint

Variable generation is on track to become a significant contributor to electric power systems worldwide. Thus, it is important to analyze the effect that renewables will have on the reliability of systems. In this paper we present a new tool being implemented at the National Renewable Energy Laboratory, which allows the inclusion of variable generation in the power system resource adequacy. The tool is used to quantify the potential contribution of transmission to reliability in highly interconnected systems and an example is provided using the Western Interconnection footprint.
Date: February 1, 2012
Creator: Ibanez, E. & Milligan, M.
System: The UNT Digital Library
Superconducting Solenoid Lens for a High Energy Part of a Proton Linac Front End (open access)

Superconducting Solenoid Lens for a High Energy Part of a Proton Linac Front End

None
Date: October 1, 2012
Creator: DiMarco, E. J.; Orris, D. F.; Tartaglia, M. A.; Terechkine, I. & Khabiboulline, E.
System: The UNT Digital Library
Desiccant Enhanced Evaporative Air Conditioning: Parametric Analysis and Design; Preprint (open access)

Desiccant Enhanced Evaporative Air Conditioning: Parametric Analysis and Design; Preprint

This paper presents a parametric analysis using a numerical model of a new concept in desiccant and evaporative air conditioning. The concept consists of two stages: a liquid desiccant dehumidifier and a dew-point evaporative cooler. Each stage consists of stacked air channel pairs separated by a plastic sheet. In the first stage, a liquid desiccant film removes moisture from the process (supply-side) air through a membrane. An evaporatively-cooled exhaust airstream on the other side of the plastic sheet cools the desiccant. The second-stage indirect evaporative cooler sensibly cools the dried process air. We analyze the tradeoff between device size and energy efficiency. This tradeoff depends strongly on process air channel thicknesses, the ratio of first-stage to second-stage area, and the second-stage exhaust air flow rate. A sensitivity analysis reiterates the importance of the process air boundary layers and suggests a need for increasing airside heat and mass transfer enhancements.
Date: October 1, 2012
Creator: Woods, J. & Kozubal, E.
System: The UNT Digital Library
Effect of Front-Side Silver Metallization on Underlying n+-p Junction in Multicrystalline Silicon Solar Cells: Preprint (open access)

Effect of Front-Side Silver Metallization on Underlying n+-p Junction in Multicrystalline Silicon Solar Cells: Preprint

We report on the effect of front-side Ag metallization on the underlying n+-p junction of multicrystalline Si solar cells. The junction quality beneath the contacts was investigated by characterizing the uniformities of the electrostatic potential and doping concentration across the junction, using scanning Kelvin probe force microscopy and scanning capacitance microscopy. We investigated cells with a commercial Ag paste (DuPont PV159) and fired at furnace setting temperatures of 800 degrees, 840 degrees, and 930 degrees C, which results in actual cell temperatures ~100 degrees C lower than the setting temperature and the three cells being under-, optimal-, and over-fired. We found that the uniformity of the junction beneath the Ag contact was significantly degraded by the over-firing, whereas the junction retained good uniformity with the optimal- and under-fire temperatures. Further, Ag crystallites with widely distributed sizes from <100 nm to several &#956;m were found at the Ag/Si interface of the over-fired cell. Large crystallites were imaged as protrusions into Si deeper than the junction depth. However, the junction was not broken down; instead, it was reformed on the entire front of the crystallite/Si interface. We propose a mechanism of the junction-quality degradation, based on emitter Si melting at the temperature …
Date: June 1, 2012
Creator: Jiang, C. S.; Li, Z. G.; Moutinho, H. R.; Liang, L.; Ionkin, A. & Al-Jassim, M. M.
System: The UNT Digital Library
LANDSCAPE MANAGEMENT FOR SUSTAINABLE SUPPLIES OF BIOENERGY FEEDSTOCK AND ENHANCED SOIL QUALITY (open access)

LANDSCAPE MANAGEMENT FOR SUSTAINABLE SUPPLIES OF BIOENERGY FEEDSTOCK AND ENHANCED SOIL QUALITY

Agriculture can simultaneously address global food, feed, fiber, and energy challenges provided our soil, water, and air resources are not compromised in doing so. As we embark on the 19th Triennial Conference of the International Soil and Tillage Research Organization (ISTRO), I am pleased to proclaim that our members are well poised to lead these endeavors because of our comprehensive understanding of soil, water, agricultural and bio-systems engineering processes. The concept of landscape management, as an approach for integrating multiple bioenergy feedstock sources, including biomass residuals, into current crop production systems, is used as the focal point to show how these ever-increasing global challenges can be met in a sustainable manner. Starting with the 2005 Billion Ton Study (BTS) goals, research and technology transfer activities leading to the 2011 U.S. Department of Energy (DOE) Revised Billion Ton Study (BT2) and development of a residue management tool to guide sustainable crop residue harvest will be reviewed. Multi-location USDA-Agricultural Research Service (ARS) Renewable Energy Assessment Project (REAP) team research and on-going partnerships between public and private sector groups will be shared to show the development of landscape management strategies that can simultaneously address the multiple factors that must be balanced to meet …
Date: September 1, 2012
Creator: Karlen, Douglas L. & David J. Muth, Jr.
System: The UNT Digital Library
MCRENGINE: A Scalable Checkpointing System using Data-Aware Aggregation and Compression (open access)

MCRENGINE: A Scalable Checkpointing System using Data-Aware Aggregation and Compression

None
Date: May 1, 2012
Creator: Islam, T; Mohror, K; Bagchi, S; Moody, A; de Supinski, B & Eigenmann, R
System: The UNT Digital Library
Passive Measurement of Organic-Scintillator Neutron Signatures for Nuclear Safeguards Applications (open access)

Passive Measurement of Organic-Scintillator Neutron Signatures for Nuclear Safeguards Applications

At nuclear facilities, domestically and internationally, most measurement systems used for nuclear materials’ control and accountability rely on He-3 detectors. Due to resource shortages, alternatives to He-3 systems are needed. This paper presents preliminary simulation and experimental efforts to develop a fast-neutron-multiplicity counter based on liquid organic scintillators. This mission also provides the opportunity to broaden the capabilities of such safeguards measurement systems to improve current neutron-multiplicity techniques and expand the scope to encompass advanced nuclear fuels.
Date: October 1, 2012
Creator: Dolan, Jennfier L.; Miller, Eric C.; Kaplan, Alexis C.; Enqvist, Andreas; Flaska, Marek; Tomanin, Alice et al.
System: The UNT Digital Library
Extremely Low-Energy Design for Army Buildings: Tactical Equipment Maintenance Facility; Preprint (open access)

Extremely Low-Energy Design for Army Buildings: Tactical Equipment Maintenance Facility; Preprint

This paper describes the integrated energy optimization process for buildings and building clusters and demonstrates this process for new construction projects and building retrofits. An explanation is given of how mission critical building loads affect possible site and source energy use reduction in Army buildings.
Date: March 1, 2012
Creator: Langner, R.; Deru, M.; Zhivov, A.; Liesen, R. & Herron, D.
System: The UNT Digital Library
P50/P90 Analysis for Solar Energy Systems Using the System Advisor Model: Preprint (open access)

P50/P90 Analysis for Solar Energy Systems Using the System Advisor Model: Preprint

To secure competitive financing for a solar energy generation project, the economic risk associated with interannual solar resource variability must be quantified. One way to quantify this risk is to calculate exceedance probabilities representing the amount of energy expected to be produced by a plant. Many years of solar radiation and metereological data are required to determine these values, often called P50 or P90 values for the level of certainty they represent. This paper describes the two methods implemented in the National Renewable Energy Laboratory's System Advisor Model (SAM) to calculate P50 and P90 exceedance probabilities for solar energy projects. The methodology and supporting data sets are applicable to photovoltaic, solar water heating, and concentrating solar power (CSP) systems.
Date: June 1, 2012
Creator: Dobos, A. P.; Gilman, P. & Kasberg, M.
System: The UNT Digital Library
Field-Programmable Gate Array (FPGA) Firmware for the Fermilab E906 (SeaQuest) Trigger (open access)

Field-Programmable Gate Array (FPGA) Firmware for the Fermilab E906 (SeaQuest) Trigger

None
Date: January 1, 2012
Creator: Wu, Jinyuan & Shiu, Shiuan-Hal
System: The UNT Digital Library
Advanced Test Reactor National Scientific User Facility Progress (open access)

Advanced Test Reactor National Scientific User Facility Progress

The Advanced Test Reactor (ATR) at the Idaho National Laboratory (INL) is one of the world’s premier test reactors for studying the effects of intense neutron radiation on reactor materials and fuels. The ATR began operation in 1967, and has operated continuously since then, averaging approximately 250 operating days per year. The combination of high flux, large test volumes, and multiple experiment configuration options provide unique testing opportunities for nuclear fuels and material researchers. The ATR is a pressurized, light-water moderated and cooled, beryllium-reflected highly-enriched uranium fueled, reactor with a maximum operating power of 250 MWth. The ATR peak thermal flux can reach 1.0 x1015 n/cm2-sec, and the core configuration creates five main reactor power lobes (regions) that can be operated at different powers during the same operating cycle. In addition to these nine flux traps there are 68 irradiation positions in the reactor core reflector tank. The test positions range from 0.5” to 5.0” in diameter and are all 48” in length, the active length of the fuel. The INL also has several hot cells and other laboratories in which irradiated material can be examined to study material radiation effects. In 2007 the US Department of Energy (DOE) designated …
Date: October 1, 2012
Creator: Marshall, Frances M.; Allen, Todd R.; Cole, James I.; Benson, Jeff B. & Thelen, Mary Catherine
System: The UNT Digital Library
NUCLEAR ENERGY SYSTEM COST MODELING (open access)

NUCLEAR ENERGY SYSTEM COST MODELING

The U.S. Department of Energy’s Fuel Cycle Technologies (FCT) Program is preparing to perform an evaluation of the full range of possible Nuclear Energy Systems (NES) in 2013. These include all practical combinations of fuels and transmuters (reactors and sub-critical systems) in single and multi-tier combinations of burners and breeders with no, partial, and full recycle. As part of this evaluation, Levelized Cost of Electricity at Equilibrium (LCAE) ranges for each representative system will be calculated. To facilitate the cost analyses, the 2009 Advanced Fuel Cycle Cost Basis Report is being amended to provide up-to-date cost data for each step in the fuel cycle, and a new analysis tool, NE-COST, has been developed. This paper explains the innovative “Island” approach used by NE-COST to streamline and simplify the economic analysis effort and provides examples of LCAE costs generated. The Island approach treats each transmuter (or target burner) and the associated fuel cycle facilities as a separate analysis module, allowing reuse of modules that appear frequently in the NES options list. For example, a number of options to be screened will include a once-through uranium oxide (UOX) fueled light water reactor (LWR). The UOX LWR may be standalone, or may be …
Date: September 1, 2012
Creator: Ganda, Francesco & Dixon, Brent
System: The UNT Digital Library
Solar Radiation Research Laboratory (Poster) (open access)

Solar Radiation Research Laboratory (Poster)

SunShot Initiative awardee posters describing the different technologies within the four subprograms of the DOE Solar Program (Photovoltaics, Concentrating Solar Power, Soft Costs, and Systems Integration).
Date: July 1, 2012
Creator: Stoffel, T.; Andreas, A.; Reda, I.; Dooraghi, M.; Habte, A.; Kutchenreiter, M. et al.
System: The UNT Digital Library
Case Studies Comparing System Advisor Model (SAM) Results to Real Performance Data: Preprint (open access)

Case Studies Comparing System Advisor Model (SAM) Results to Real Performance Data: Preprint

NREL has completed a series of detailed case studies comparing the simulations of the System Advisor Model (SAM) and measured performance data or published performance expectations. These case studies compare PV measured performance data with simulated performance data using appropriate weather data. The measured data sets were primarily taken from NREL onsite PV systems and weather monitoring stations.
Date: June 1, 2012
Creator: Blair, N.; Dobos, A. & Sather, N.
System: The UNT Digital Library
Absorber Alignment Measurement Tool for Solar Parabolic Trough Collectors: Preprint (open access)

Absorber Alignment Measurement Tool for Solar Parabolic Trough Collectors: Preprint

As we pursue efforts to lower the capital and installation costs of parabolic trough solar collectors, it is essential to maintain high optical performance. While there are many optical tools available to measure the reflector slope errors of parabolic trough solar collectors, there are few tools to measure the absorber alignment. A new method is presented here to measure the absorber alignment in two dimensions to within 0.5 cm. The absorber alignment is measured using a digital camera and four photogrammetric targets. Physical contact with the receiver absorber or glass is not necessary. The alignment of the absorber is measured along its full length so that sagging of the absorber can be quantified with this technique. The resulting absorber alignment measurement provides critical information required to accurately determine the intercept factor of a collector.
Date: April 1, 2012
Creator: Stynes, J. K. & Ihas, B.
System: The UNT Digital Library
Deeply Virtual Compton Scattering and Meson Production at Jlab/CLAS (open access)

Deeply Virtual Compton Scattering and Meson Production at Jlab/CLAS

This report reviews the recent experimental results from the CLAS collaboration (Hall B of Jefferson Lab, or JLab) on Deeply Virtual Compton Scattering (DVCS) and Deeply Virtual Meson Production (DVMP) and discusses their interpretation in the framework of Generalized Parton Distributions (GPDs). The impact of the experimental data on the applicability of the GPD mechanism to these exclusive reactions is discussed. Initial results obtained from JLab 6 GeV data indicate that DVCS might already be interpretable in this framework while GPD models fail to describe the exclusive meson production (DVMP) data with the GPD parameterizations presently used. An exception is the {phi} meson production for which the GPD mechanism appears to apply. The recent global analyses aiming to extract GPDs from fitting DVCS CLAS and world data are discussed. The GPD experimental program at CLAS12, planned with the upcoming 12 GeV upgrade of JLab, is briefly presented.
Date: April 1, 2012
Creator: Jo, Hyon-Suk
System: The UNT Digital Library
Radionuclides in the Cooling Water Systems for the NuMi Beamline and the Antiproton Production Target Station at Fermilab (open access)

Radionuclides in the Cooling Water Systems for the NuMi Beamline and the Antiproton Production Target Station at Fermilab

None
Date: December 1, 2012
Creator: Matsumura, Hiroshi; Toyoda, Akihiro; Bessho, Kotaro; Sekimoto, Shun; Yashima, Hiroshi; Kasugai, Yoshimi et al.
System: The UNT Digital Library
Marine Hydrokinetic Turbine Power-Take-Off Design for Optimal Performance and Low Impact on Cost-of-Energy: Preprint (open access)

Marine Hydrokinetic Turbine Power-Take-Off Design for Optimal Performance and Low Impact on Cost-of-Energy: Preprint

Marine hydrokinetic devices are becoming a popular method for generating marine renewable energy worldwide. These devices generate electricity by converting the kinetic energy of moving water, wave motion or currents, into electrical energy through the use of a Power-Take-Off (PTO) system. Most PTO systems incorporate a mechanical or hydraulic drive train, power generator and electric control/conditioning system to deliver the generated electric power to the grid at the required state. Like wind turbine applications, the PTO system must be designed for high reliability, good efficiency, and long service life with reasonable maintenance requirements, low cost and an appropriate mechanical design for anticipated applied steady and unsteady loads. The ultimate goal of a PTO design is high efficiency, low maintenance and cost with a low impact on the device Cost-of-Energy (CoE).
Date: April 1, 2012
Creator: Beam, M.; Kline, B.; Elbing, B.; Straka, W.; Fontaine, A.; Lawson, M. et al.
System: The UNT Digital Library