Alkali-silica reaction (ASR) in cement is a major contributor to failure of cement structures around the world, causing increased repair costs and possible rebuild expenses. Alkali levels are indicative of the potential for ASR and are therefore measured and quantified. A linear correlation relating cement alkali concentration measured by X-ray fluorescence spectroscopy (XRF) and peak ratio measured by Fourier transform infrared spectroscopy (FTIR) is developed. Regression analysis of plots correlating alkali content measured by FTIR absorption band (750 cm-1/923 cm-1) ratio versus equivalent alkali (Na2O)e (%Na2O + 0.658 % K2O) quantified by XRF show linear correlation coefficient, R2, of 0.97. Results of this investigation are discussed in terms of microstructural disorder coefficient Cd which is a reactivity criterion for ASR-susceptible aggregates proposed by Bachiorrini [31]. XRF is a popular technique for alkali quantification but FTIR is faster, safer, and less expensive technique compared to XRF. Portable instrumentation is available for both techniques but FTIR systems are less expensive.

Currently, ASHRAE has determined the zone method and modified zone method are appropriate calculation methods for materials with a high difference in conductivity, such as cold-formed steel (CFS) walls. Because there is currently no standard U-Factor calculation method for CFS walls, designers and code officials alike tend to resort to the zone method. However, the zone method is restricted to larger span assemblies because the zone factor coefficient is 2.0. This tends to overestimate the amount of surface area influenced by CFS. The modified zone method is restricted to C-shaped stud, clear wall assemblies with framing factors between 9 and 15%. The objective of the research is to narrow the gap of knowledge by re-examining the modified zone method in order to more accurately determine R-Values and U-Factors for CFS wall assemblies with whole wall framing factor percentages of 22% and above.