A high resolution grating spectrometer (HRGS) with 2400 line/mm variable line spacing grating for the 10-50 {angstrom} wavelength range has been designed for laser-produced plasma experiments at the Lawrence Livermore National Laboratory (LLNL). The spectrometer has a large radius of curvature, R=44.3 m, is operated at a 2{sup o} grazing angle and can record high signal-to-noise spectra when used with a low-noise, cooled, charge-coupled device detector. The instrument can be operated with a 10-25 {micro}m wide slit to achieve the best spectral resolving power on laser plasma sources, approaching 2000, or in slitless mode with a small symmetrical emission source. Results will be presented for the spectral response of the spectrometer cross-calibrated at the LLNL Electron Beam Ion Trap facility using the broadband x-ray energy EBIT Calorimeter Spectrometer (ECS).

The electric field dependence of charge carrier transport and the effect of carrier heating in disordered conjugated polymers were investigated. A parameter-free multiscale methodology consisting of classical molecular dynamics simulation for the generation of the atomic structure, large system electronic structure and electron-phonon coupling constants calculations and the procedure for extracting the bulk polymer mobility, was used. The results suggested that the mobility of a fully disordered poly(3-hexylthiophene) (P3HT) polymer increases with electric field which is consistent with the experimental results on samples of regiorandom P3HT and different from the results on more ordered regioregular P3HT polymers, where the opposite trend is often observed at low electric fields. We calculated the electric field dependence of the effective carrier temperature and showed however that the effective temperature cannot be used to replace the joint effect of temperature and electric field, in contrast to previous theoretical results from phenomenological models. Such a difference was traced to originate from the use of simplified Miller-Abrahams hopping rates in phenomenological models in contrast to our considerations that explicitly take into account the electronic state wave functions and the interaction with all phonon modes.

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This paper outlines the characterization of voids and Microstructure in TATB-based Explosives over several orders of magnitude, from sizes on the order of 10 nm to about 1 cm. This is accomplished using ultra small angle x-ray scattering to investigate voids from a few nm to a few microns, ultra small angle neutron scattering for voids from 100 nm to 10 microns, and x-ray computed microtomography to investigate microstructure from a few microns to a few centimeters. The void distributions of LX-17 are outlined, and the microstructure of LX-17 is presented. Temperature cycling and compressive creep cause drastically different damage to the microstructure. Temperature cycling leads to a volume expansion (ratchet growth) in TATB-based explosives, and x-ray scattering techniques that are sensitive to sizes up to a few microns indicated changes to the void volume distribution that had previously accounted for most, but not all of the change in density. This paper presents the microstructural damage larger than a few microns caused by ratchet growth. Temperature cycling leads to void creation in the binder poor regions associated with the interior portion of formulated prills. Conversely, compressive creep causes characteristically different changes to microstructure; fissures form at binder-rich prill boundaries prior …

We present an empirical model that describes the experimentally observed laser-induced bulk damage and conditioning behavior in deuterated Potassium dihydrogen Phosphate (DKDP) crystals in a self-consistent way. The model expands on an existing nanoabsorber precursor model and the multi-step absorption mechanism to include two populations of absorbing defects, one with linear absorption and another with nonlinear absorption. We show that this model connects previously uncorrelated small-beam damage initiation probability data to large-beam damage density measurements over a range of ns pulse widths relevant to ICF lasers such as the National Ignition Facility (NIF). In addition, this work predicts the damage behavior of laser-conditioned DKDP and explains the upper limit to the laser conditioning effect. The ADM model has been successfully used during the commissioning and early operation of the NIF.

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Washington River Protection Solutions, LLC (WRPS) has faced significant project management challenges in managing Davis-Bacon construction work that meets contractually required small business goals. The unique challenge is to provide contracting opportunities to multiple small business constructioin subcontractors while performing high hazard work in a safe and productive manner. Previous to the WRPS contract, construction work at the Hanford Tank Farms was contracted to large companies, while current Department of Energy (DOE) Contracts typically emphasize small business awards. As an integral part of Nuclear Project Management at Hanford Tank Farms, construction involves removal of old equipment and structures and installation of new infrastructure to support waste retrieval and waste feed delivery to the Waste Treatment Plant. Utilizing the optimum construction approach ensures that the contractors responsible for this work are successful in meeting safety, quality, cost and schedule objectives while working in a very hazardous environment. This paper descirbes the successful transition from a traditional project delivery method that utilized a large business general contractor and subcontractors to a new project construction management model that is more oriented to small businesses. Construction has selected the Agency Construction Management Method (John E Schaufelberger, Len Holm, "Management of Construction Projects, A Constructor's …

Employment of cyanobacteria in biomineralization of carbon dioxide by calcium carbonate precipitation offers novel and self-sustaining strategies for point-source carbon capture and sequestration. Although details of this process remain to be elucidated, a carbon-concentrating mechanism, and chemical reactions in exopolysaccharide or proteinaceous surface layers are assumed to be of crucial importance. Cyanobacteria can utilize solar energy through photosynthesis to convert carbon dioxide to recalcitrant calcium carbonate. Calcium can be derived from sources such as gypsum or industrial brine. A better understanding of the biochemical and genetic mechanisms that carry out and regulate cynaobacterial biomineralization should put us in a position where we can further optimize these steps by exploiting the powerful techniques of genetic engineering, directed evolution, and biomimetics.

The Total Carbon Column Observing Network (TCCON) produces precise measurements of the column average dry-air mole fractions of CO{sub 2}, CO, CH{sub 4}, N{sub 2}O and H{sub 2}O at a variety of sites worldwide. These observations rely on spectroscopic parameters that are not known with sufficient accuracy to compute total columns that can be used in combination with in situ measure ments. The TCCON must therefore be calibrated to World Meteorological Organization (WMO) in situ trace gas measurement scales. We present a calibration of TCCON data using WMO-scale instrumentation aboard aircraft that measured profiles over four TCCON stations during 2008 and 2009. The aircraft campaigns are the Stratosphere-Troposphere Analyses of Regional Transport 2008 (START-08), which included a profile over the Park Falls site, the HIAPER Pole-to-Pole Observations (HIPPO-1) campaign, which included profiles over the Lamont and Lauder sites, a series of Learjet profiles over the Lamont site, and a Beechcraft King Air profile over the Tsukuba site. These calibrations are compared with similar observations made during the INTEX-NA (2004), COBRA-ME (2004) and TWP-ICE (2006) campaigns. A single, global calibration factor for each gas accurately captures the TCCON total column data within error.

The problem of Network Traffic Classification (NTC) has attracted significant amount of interest in the research community, offering a wide range of solutions at various levels. The core challenge is in addressing high amounts of traffic diversity found in today's networks. The problem becomes more challenging if a quick detection is required as in the case of identifying malicious network behavior or new applications like peer-to-peer traffic that have potential to quickly throttle the network bandwidth or cause significant damage. Recently, Traffic Dispersion Graphs (TDGs) have been introduced as a viable candidate for NTC. The TDGs work by forming a network wide communication graphs that embed characteristic patterns of underlying network applications. However, these patterns need to be quickly evaluated for mounting real-time response against them. This paper addresses these concerns and presents a novel solution for real-time analysis of Traffic Dispersion Metrics (TDMs) in the TDGs. We evaluate the dispersion metrics of interest and present a dedicated solution on an FPGA for their analysis. We also present analytical measures and empirically evaluate operating effectiveness of our design. The mapped design on Virtex-5 device can process 7.4 million packets/second for a TDG comprising of 10k flows at very high accuracies …

Although they are but a small fraction of the mass ejected in core-collapse supernovae, neutrino-driven winds (NDWs) from nascent proto-neutron stars (PNSs) have the potential to contribute significantly to supernova nucleosynthesis. In previous works, the NDW has been implicated as a possible source of r-process and light p-process isotopes. In this paper we present time-dependent hydrodynamic calculations of nucleosynthesis in the NDW which include accurate weak interaction physics coupled to a full nuclear reaction network. Using two published models of PNS neutrino luminosities, we predict the contribution of the NDW to the integrated nucleosynthetic yield of the entire supernova. For the neutrino luminosity histories considered, no true r-process occurs in the most basic scenario. The wind driven from an older 1.4M{sub {circle_dot}} model for a PNS is moderately neutron-rich at late times however, and produces {sup 87}Rb, {sup 88}Sr, {sup 89}Y, and {sup 90}Zr in near solar proportions relative to oxygen. The wind from a more recently studied 1.27M{sub {circle_dot}} PNS is proton-rich throughout its entire evolution and does not contribute significantly to the abundance of any element. It thus seems very unlikely that the simplest model of the NDW can produce the r-process. At most, it contributes to the …

Diffuse reflectance near infrared hyperspectral imaging is an important analytical tool for a wide variety of industries, including agriculture consumer products, chemical and pharmaceutical development and production. Using this technique as a method for the standoff detection of explosive particles is presented and discussed. The detection of the particles is based on the diffuse reflectance of light from the particle in the near infrared wavelength range where CH, NH, OH vibrational overtones and combination bands are prominent. The imaging system is a NIR focal plane array camera with a tunable OPO/laser system as the illumination source. The OPO is programmed to scan over a wide spectral range in the NIR and the camera is synchronized to record the light reflected from the target for each wavelength. The spectral resolution of this system is significantly higher than that of hyperspectral systems that incorporate filters or dispersive elements. The data acquisition is very fast and the entire hyperspectral cube can be collected in seconds. A comparison of data collected with the OPO system to data obtained with a broadband light source with LCTF filters is presented.

Time sequence x-ray imaging was utilized to determine the response of aluminum spheres embedded in a detonating high-explosive cylinder. The size of these spheres ranged from 3/8-inch to 1/32-inch in diameter. These experiments directly observed the response of the spheres as a function of time after interaction with the detonation wave. As the spheres are entrained in the post-detonation flow field, they are accelerating and their velocity profile is complicated, but can be determined from the radiography. Using the aluminum spheres as tracers, radial velocities of order 1.6 mm/us and horizontal velocities of order 0.08 mm/us were measured at early times post detonation. In terms of response, these data show that the largest sphere deforms and fractures post detonation. The intermediate size spheres suffer negligible deformation, but appear to ablate post detonation. Post detonation, the smallest spheres either react, mechanically disintegrate, atomize as a liquid or some combination of these.

This paper examines the attractiveness of material mixtures containing special nuclear materials (SNM) associated with reprocessing and the thorium-based LWR fuel cycle. This paper expands upon the results from earlier studies that examined the attractiveness of SNM associated with the reprocessing of spent light water reactor (LWR) fuel by various reprocessing schemes and the recycle of plutonium as a mixed oxide (MOX) fuel in LWR. This study shows that {sup 233}U that is produced in thorium-based fuel cycles is very attractive for weapons use. Consistent with other studies, these results also show that all fuel cycles examined to date need to be rigorously safeguarded and provided moderate to high levels of physical protection. These studies were performed at the request of the United States Department of Energy (DOE), and are based on the calculation of 'attractiveness levels' that has been couched in terms chosen for consistency with those normally used for nuclear materials in DOE nuclear facilities. The methodology and key findings will be presented.

While the bulk of the finished microbial genomes sequenced to date are derived from cultured bacterial and archaeal representatives, the vast majority of microorganisms elude current culturing attempts, severely limiting the ability to recover complete or even partial genomes from these environmental species. Single cell genomics is a novel culture-independent approach, which enables access to the genetic material of an individual cell. No single cell genome has to our knowledge been closed and finished to date. Here we report the completed genome from an uncultured single cell of Candidatus Sulcia muelleri DMIN. Digital PCR on single symbiont cells isolated from the bacteriome of the green sharpshooter Draeculacephala minerva bacteriome allowed us to assess that this bacteria is polyploid with genome copies ranging from approximately 200?900 per cell, making it a most suitable target for single cell finishing efforts. For single cell shotgun sequencing, an individual Sulcia cell was isolated and whole genome amplified by multiple displacement amplification (MDA). Sanger-based finishing methods allowed us to close the genome. To verify the correctness of our single cell genome and exclude MDA-derived artifacts, we independently shotgun sequenced and assembled the Sulcia genome from pooled bacteriomes using a metagenomic approach, yielding a nearly identical …

The evaporator recycle streams of nuclear waste tanks may contain waste in a chemistry and temperature regime that exceeds the current corrosion control program, which imposes temperature limits to mitigate caustic stress corrosion cracking (CSCC). A review of the recent service history found that two of these A537 carbon steel tanks were operated in highly concentrated hydroxide solution at high temperature. Visual inspections, experimental testing, and a review of the tank service history have shown that CSCC has occurred in uncooled/un-stress relieved tanks of similar construction. Therefore, it appears that the efficacy of stress relief of welding residual stress is the primary corrosion-limiting mechanism. The objective of this experimental program is to test A537 carbon steel small scale welded U-bend specimens and large welded plates (30.48 x 30.38 x 2.54 cm) in a caustic solution with upper bound chemistry (12 M hydroxide and 1 M each of nitrate, nitrite, and aluminate) and temperature (125 C). These conditions simulate worst-case situations in these nuclear waste tanks. Both as-welded and stress-relieved specimens have been tested. No evidence of stress corrosion cracking was found in the U-bend specimens after 21 days of testing. The large plate test was completed after 12 weeks of …

Scalar fields with a"chameleon" property, in which the effective particle mass is a function of its local environment, are common to many theories beyond the standard model and could be responsible for dark energy. If these fields couple weakly to the photon, they could be detectable through the afterglow effect of photon-chameleon-photon transitions. The ADMX experiment was used in the first chameleon search with a microwave cavity to set a new limit on scalar chameleon-photon coupling beta_gamma excluding values between 2x109 and 5x1014 for effective chameleon masses between 1.9510 and 1:9525 micro eV.

Gribov viewed the axial anomaly as a manifestation of the collective motion of Dirac fermions with arbitrarily high momenta in the vacuum. In the presence of an external magnetic field and a chirality imbalance, this collective motion becomes directly observable in the form of the electric current - this is the chiral magnetic effect (CME). I give an elementary introduction into the physics of CME, and discuss the experimental status and recent developments.

MicroBooNE is a liquid Argon time projection chamber to be built at Fermilab for an accelerator-based neutrino physics experiment and as part of the R&D strategy for a large liquid argon detector at DUSEL. The waveforms of the {approx}9000 sense wires in the chamber are continuously digitized at 2 M samples/s - which results in a large volume of data coming off the TPC. We have developed a lossless data reduction scheme based on Huffman Coding and have tested the scheme on cosmic ray data taken from a small liquid Argon time projection chamber, the BO detector. For sense wire waveforms produced by cosmic ray tracks, the Huffman Coding scheme compresses the data by a factor of approximately 10. The compressed data can be fully recovered back to the original data since the compression is lossless. In addition to accelerator neutrino data, which comes with small duty cycle in sync with the accelerator beam spill, continuous digitized waveforms are to be temporarily stored in the MicroBooNE data-acquisition system for about an hour, long enough for an external alert from possible supernova events. Another scheme, Dynamic Decimation, has been developed to compress further the potential supernova data so that the storage …

We report measurements of the Fermi surface (FS) of the ternary iron-phosphide SrFe{sub 2}P{sub 2} using the de Haas-van Alphen effect. The calculated FS of this compound is very similar to SrFe{sub 2}As{sub 2}, the parent compound of the high temperature superconductors. Our data show that the Fermi surface is composed of two electron and two hole sheets in agreement with bandstructure calculations. Several of the sheets show strong c-axis warping emphasizing the importance of three-dimensionality in the non-magnetic state of the ternary pnictides. We find that the electron and hole pockets have a different topology, implying that this material does not satisfy a ({pi},{pi}) nesting condition.

Almost 40 years ago, Gribov and colleagues at the Leningrad Nuclear Physics Institute developed the ideas that led to the Dokhsitzer-Gribov-Altarelli-Parisi the Baltisky-Fadin-Kuraev-Lipatov equations. These equations describe the evolution of the distributions for quarks and gluon inside a hadron to increased resolution scale of a probe or to smaller values of the fractional momentum of a hadronic constituent. I motivate and discuss the generalization required of these equations needed for high energy processes when the density of constituents is large. This leads to a theory of saturation realized by the Color Glass Condensate

We find a correspondence between semiclassical QCD quantized on the light-front and a dual gravity model in anti-de Sitter (AdS) space, thus providing an initial approximation to QCD in its strongly coupled regime. This correspondence - light-front holography - leads to a light-front Hamiltonian and relativistic bound-state wave equations that are functions of an invariant impact variable {zeta} which measures the separation of the quark and gluonic constituents within hadrons at equal lightfront time. The eigenvalues of the resulting light-front Schrodinger and Dirac equations are consistent with the observed light meson and baryon spectrum, and the eigenmodes provide the light-front wavefunctions, the probability amplitudes describing the dynamics of the hadronic constituents. The light-front equations of motion, which are dual to an effective classical gravity theory, possess remarkable algebraic and integrability properties which are dictated by the underlying conformal properties of the theory. We extend the algebraic construction to include a confining potential while preserving the integrability of the mesonic and baryonic bound-state equations.

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