Butanol is a fuel that has been proposed as a bio-derived alternative to conventional petroleum derived fuels. The structural isomer in traditional 'bio-butanol' fuel is n-butanol, but newer conversion technologies produce iso-butanol as a fuel. In order to better understand the combustion chemistry of bio-butanol, this study presents a comprehensive chemical kinetic model for all the four isomers of butanol (e.g., 1-, 2-, iso- and tert-butanol). The proposed model includes detailed high temperature and low temperature reaction pathways. In this study, the primary experimental validation target for the model is premixed flat low-pressure flame species profiles obtained using molecular beam mass spectrometry (MBMS). The model is also validated against previously published data for premixed flame velocity and n-butanol rapid compression machine and shock tube ignition delay. The agreement with these data sets is reasonably good. The dominant reaction pathways at the various pressures and temperatures studied are elucidated. At low temperature conditions, we found that the reaction of alphahydroxybutyl with O{sub 2} was important in controlling the reactivity of the system, and for correctly predicting C{sub 4} aldehyde profiles in low pressure premixed flames. Enol-keto isomerization reactions assisted by HO{sub 2} were also found to be important in converting enols …

Algebraic Multigrid (AMG) solvers are an essential component of many large-scale scientific simulation codes. Their continued numerical scalability and efficient implementation is critical for preparing these codes for exascale. Our experiences on modern multi-core machines show that significant challenges must be addressed for AMG to perform well on such machines. We discuss our experiences and describe the techniques we have used to overcome scalability challenges for AMG on hybrid architectures in preparation for exascale.

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Training Manual updated for United Negro College Fund Special Programs Corporation/National Library of Medicine - HBCU ACCESS Project for Alcorn State University, Natchez, Mississippi, November 12, 2010

The IBRD Operational Decision Framework in this document is an expansion of an emerging general risk management framework under development by an interagency working group. It provides the level of detail necessary to develop a general Consequence Management Guidance Document for biological contamination remediation and restoration. It is the intent of this document to support both wide area and individual site remediation and restoration activities. This product was initiated as a portion of the IBRD Task 1 Systems Analysis to aid in identification of wide area remediation and restoration shortcomings and gaps. The draft interagency general risk management framework was used as the basis for the analysis. The initial Task 1 analysis document expanded the draft interagency framework to a higher level of resolution, building on both the logic structure and the accompanying text explanations. It was then employed in a qualitative manner to identify responsible agencies, data requirements, tool requirements, and current capabilities for each decision and task. This resulted in identifying shortcomings and gaps needing resolution. Several meetings of a joint LLNL/SNL working group reviewed and approved the initial content of this analysis. At the conclusion of Task 1, work continued on the expanded framework to generate this …

The purpose of this work is to develop a technical basis for both estimating the dose of a worker exposed to respirable tritiated LaNi{sub 4.25}Al{sub 0.75} (LANA) and implementing hazard appropriate controls. Savannah River National Laboratory (SRNL) has agreed to provide Lovelace Respiratory Research Institute (LRRI) with a tritiated LANA sample. LRRI will determine the particle size distribution (PSD) as well as perform dissolution rate studies on the sample in serum ultrafiltrate (SUF), a simulated lung fluid. The rate of tritium release from the sample will be measured over a three month period. Tritium release rate information will be used to calculate a DCF for respirable tritiated LANA.

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This report summarizes the first year research and development effort leading to development of high-temperature sensors for enhanced geothermal systems. It covers evaluation of ultrasonic and electromagnetic (EM) techniques applied to temperature measurement and flow characterization. On temperature measurement, we have evaluated both microwave radiometry and ultrasonic techniques for temperature gradient and profile measurements. Different antenna designs are evaluated and array loop antenna design is selected for further development. We have also evaluated ultrasonic techniques for total flow characterization, which includes using speed of sound to determine flow temperature, measuring acoustic impedance to estimate fluid density, and using cross-correlation technique to determine the mass flow rate. Method to estimate the flow enthalpy is briefly discussed. At end, the need and proposed techniques to characterize the porosity and permeability of a hot dry rock resource are presented.

This report gives an overview of diagnostic techniques of "Alphabet Soup".

Laser angle resolved photoelectron spectroscopy (ARPES) provides unique information about angle and energy distribution of photoelectrons. Laser ARPES gives unique insight into how NEA materials work. ARPES combined with some ancillary measurements gives a very complete picture of system electronic physics. For H:C[100] there is now a clear program for engineering as well as development analogous systems. ARPES well suited for identifying 'ideal' photocathodes with intrinsically low emittance and high QE.

A model is presented for calculating the environmental burdens of the part manufacturing and vehicle assembly (VMA) stage of the vehicle life cycle. The approach is bottom-up, with a special focus on energy consumption and CO{sub 2} emissions. The model is applied to both conventional and advanced vehicles, the latter of which include aluminum-intensive, hybrid electric, plug-in hybrid electric and all-electric vehicles. An important component of the model, a weight-based distribution function of materials and associated transformation processes (casting, stamping, etc.), is developed from the United States Council for Automotive Research Generic Vehicle Life Cycle Inventory Study. As the approach is bottom-up, numerous transformation process data and plant operational data were extracted from the literature for use in representing the many operations included in the model. When the model was applied to conventional vehicles, reliable estimates of cumulative energy consumption (34 GJ/vehicle) and CO{sub 2} emission (2 tonnes/vehicle) were computed for the VMA life-cycle stage. The numerous data sets taken from the literature permitted the development of some statistics on model results. Because the model explicitly includes a greater coverage of relevant manufacturing processes than many earlier studies, our energy estimates are on the higher end of previously published values. …

A simple device has been developed to deposit elemental lithium onto plasma facing components in the National Spherical Torus Experiment. Deposition is accomplished by dropping lithium powder into the plasma column. Once introduced, lithium particles quickly become entrained in scrape-off layer flow as an evaporating aerosol. Particles are delivered through a small central aperture in a computer-controlled resonating piezoelectric disk on which the powder is supported. The device has been used to deposit lithium both during discharges as well as prior to plasma breakdown. Clear improvements to plasma performance have been demonstrated. The use of this apparatus provides flexibility in the amount and timing of lithium deposition and, therefore, may benefit future fusion research devices.

Quantum confinement of electronic wavefunctions in semiconductor quantum dots (QDs) yields discrete atom-like and tunable electronic levels, thereby allowing the engineering of excitation and emission spectra. Metal nanoparticles, on the other hand, display strong resonant interactions with light from localized surface plasmon resonance (LSPR) oscillations of free carriers, resulting in enhanced and geometrically tunable absorption and scattering resonances. The complementary attributes of these nanostructures lends strong interest toward integration into hybrid nanostructures to explore enhanced properties or the emergence of unique attributes arising from their interaction. However, the physicochemical interface between the two components can be limiting for energy transfer and synergistic coupling within such a hybrid nanostructure. Therefore, it is advantageous to realize both attributes, i.e., LSPRs and quantum confinement within the same nanostructure. Here, we describe well-defined LSPRs arising from p-type carriers in vacancy-doped semiconductor quantum dots. This opens up possibilities for light harvesting, non-linear optics, optical sensing and manipulation of solid-state processes in single nanocrystals.

Following is a brief summary of the assumptions that are pertinent to the radioactive isotope transport in the GoldSim Performance Assessment model of the Area 5 Radioactive Waste Management Site, with special emphasis on the water-phase reactive transport of uranium, which includes depleted uranium products.

The Hanford Site has 28 double-shell tanks (DSTs) and 149 single-shell tanks (SSTs) containing radioactive wastes that are complex mixes of radioactive and chemical products. The mission of the Department of Energy’s River Protection Project is to retrieve and treat the Hanford tank waste for disposal and close the tank farms. A key aspect of the mission is to retrieve and transfer waste from the SSTs, which are at greater risk for leaking, into DSTs for interim storage until the waste is transferred to and treated in the Waste Treatment and Immobilization Plant. There is, however, limited space in the existing DSTs to accept waste transfers from the SSTs, and approaches to overcoming the limited DST space will benefit the overall mission. The purpose of this study is to summarize and analyze the key previous experiment that forms the basis for the relaxed controls and to summarize initial progress and results on new experiments focused on understanding the conditions that result in low gas retention. The work is ongoing; this report provides a summary of the initial findings. The previous large-scale test used about 50 m3 of sediment, which would be unwieldy for doing multiple parametric experiments. Accordingly, experiments will …

This document provides an overview to the five-month RACORO Campaign. There are many details in such an extensive program that this document cannot capture; therefore, it should be thought of as a guide for acquainting yourself with the program and you are encouraged to contact the members involved. In particular, users of the data are strongly urged to contact instrument principal investigators (PIs) about use of the data. Further, it is highly recommended that studies using the data be done in collaboration with the instrument PIs, since they are in the best position to provide insights and or caveats associated with the data that should be considered.

This presentation addresses the current state of wind energy technology in the United States.

The EBIS based preinjector for both the Relativistic Heavy Ion Collider (RHIC) and NASA Space Radiation Laboratory (NSRL) is now being commissioned at Brookhaven National Laboratory (BNL). In 2008, the RFQ for the project was delivered and commissioned using Test EBIS, which was built to demonstrate the high current EBIS's performance. A dedicated beamline after the RFQ was assembled to confirm the RFQ's performance, and the beam energy was measured by a bending dipole magnet. In November 2009, the RFQ was moved to the final location and the vanes were realigned. The beam commissioning with the RHIC-EBIS was started again during March 2010. The RFQ accelerates ions from 17 keV/u to 300 keV/u and operates at 100.625 MHz. It is followed by a short Medium Energy Beam Transport (MEBT), which consists of four quadrupoles and one buncher cavity. Some temporary diagnostics for this commissioning include an emittance probe, TOF system, fast Faraday cup, and beam current measurement units. As of September 2010, the RFQ and the MEBT show expected performance with He{sup +}, Au{sup 32+} and Fe{sup 20+} beams. Further commissioning for higher intensity beams is in progress.

The status is presented of the commissioning of a new heavy ion preinjector at Brookhaven National Laboratory. This preinjector uses an Electron Beam Ion Source (EBIS), and an RFQ and IH Linac, both operating at 100.625 MHz, to produce 2 MeV/u ions of any species for use, after further acceleration, at the Relativistic Heavy Ion Collider (RHIC) and the NASA Space Radiation Laboratory (NSRL). Among the increased capabilities provided by this preinjector are the ability to produce ions of any species, and the ability to switch between multiple species in 1 second, to simultaneously meet the needs of both science programs. For initial setup, helium beam from EBIS was injected and circulated in the Booster synchrotron. Following this, accelerated Au{sup 32+} and Fe{sup 20+} beams were transported to the Booster injection point, fulfilling DOE requirements for project completion.

The US Department of Energy Facility for Rare Isotope Beams (FRIB) at Michigan State University includes a heavy ion superconducting linac capable of accelerating all ions up to uranium with energies higher than 200 MeV/u and beam power up to 400 kW. To achieve these goals with present ion source performance it is necessary to accelerate simultaneously two charge states of uranium from the ion source in the first section of the linac. At an energy of approximately 16.5 MeV/u it is planned to strip the uranium beam to reduce the voltage needed in the rest of the linac to achieve the final energy. Up to five different charge states are planned to be accelerated simultaneously after the stripper. The design of the stripper is a challenging problem due to the high power deposited (approximately 0.7 kW) in the stripper media by the beam in a small spot. To assure success of the project we have established a research and development program that includes several options: carbon or diamond foils, liquid lithium films, gas strippers and plasma strippers. We present in this paper the status of the different options.

In Brookhaven National Laboratory (BNL), a 750 keV medium energy beam transport line between the 201 MHz 750 keV proton RFQ and the 200 MeV Alvarez DTL is being modified to get a better transmission of the beam. Within a tight space, high field gradient quadrupoles (65 Tm) and newly designed steering magnets (6.5 mm in length) will be installed considering the cross-talk effects. Also a new half wave length 200 MHz buncher is being prepared. The beam commissioning will be done in this year. To enhance the performance of the proton linacs, the MEBT is being modified. New quadrupole magnets, steering magnets and a half wave length buncher as shown in Figure 7 will be installed and be commissioned soon.

The National Library of Medicine (NLM) is sponsoring this course to increase awareness of the availability and value of NLM’s online environmental health and toxicology information resources that provide invaluable tools to address these issues—for professionals and consumers alike. Participants will receive hands-on practice with selected NLM resources, and demonstrations of other valuable resources will be provided.

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Seven water-soluble, tetradentate bis(3-hydroxy-N-methyl-pyridin-2-one) (bis-Me-3,2-HOPO) ligands were synthesized that vary only in linker geometry and rigidity. Solution phase thermodynamic measurements were conducted between pH 1.6 and pH 9.0 to determine the effects of these variations on proton and uranyl cation affinity. Proton affinity decreases by introduction of the solubilizing triethylene glycol group as compared to un-substituted reference ligands. Uranyl affinity was found to follow no discernable trends with incremental geometric modification. The butyl-linked 4Li-Me-3,2-HOPO ligand exhibited the highest uranyl affinity, consistent with prior in vivo decorporation results. Of the rigidly-linked ligands, the o-phenylene linker imparted the best uranyl affinity to the bis-Me-3,2-HOPO ligand platform.