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THE AFFECTS OF HALIDE MODIFIERS ON THE SORPTION KINETICS OF THE LI-MG-N-H SYSTEM (open access)

THE AFFECTS OF HALIDE MODIFIERS ON THE SORPTION KINETICS OF THE LI-MG-N-H SYSTEM

In this present work, the affects of different transition metal halides (TiCl{sub 3}, VCl{sub 3}, ScCl{sub 3} and NiCl{sub 2}) on the sorption properties of the 1:1 molar ratio of LiNH{sub 2} to MgH{sub 2} are investigated. The modified mixtures were found to contain LiNH{sub 2}, MgH{sub 2} and LiCl. TGA results showed that the hydrogen desorption temperature was reduced with the modifier addition in this order: TiCl{sub 3}>ScCl{sub 3}>VCl{sub 3}>NiCl{sub 2}. Ammonia release was not significantly reduced resulting in a weight loss greater than the theoretical hydrogen storage capacity of the material. The isothermal sorption kinetics of the modified systems showed little improvement after the first dehydrogenation cycle over the unmodified system but showed drastic improvement in rehydrogenation cycles. XRD and Raman spectroscopy identified the cycled material to be composed of LiH, MgH{sub 2}, Mg(NH{sub 2}){sub 2} and Mg{sub 3}N{sub 2}.
Date: December 16, 2010
Creator: Erdy, C.; Gray, J.; Lascola, R. & Anton, D.
System: The UNT Digital Library
Charmed Hadron Physics at BABAR (open access)

Charmed Hadron Physics at BABAR

We present a study of the D{sup +}{pi}{sup -}, D{sup 0}{pi}{sup +}, and D*{sup +}{pi}{sup -} systems in inclusive e{sup +}e{sup -} {yields} c{bar c} interactions in a search for new excited D meson states. We use a dataset, consisting of {approx}454 fb{sup -1}, collected at center-of-mass energies near 10.58 GeV by the BABAR detector at the SLAC PEP-II asymmetric-energy collider. We observe, for the first time, candidates for the radial excitations of the D{sup 0}, D*{sup 0}, and D*{sup +}, as well as the L = 2 excited states of the D{sup 0} and D{sup +}, where L is the orbital angular momentum of the quarks.
Date: December 16, 2010
Creator: Benitez, Jose
System: The UNT Digital Library
Counts-in-Cylinders in the Sloan Digital Sky Survey with Comparisons to N-Body (open access)

Counts-in-Cylinders in the Sloan Digital Sky Survey with Comparisons to N-Body

Environmental statistics provide a necessary means of comparing the properties of galaxies in different environments and a vital test of models of galaxy formation within the prevailing, hierarchical cosmological model. We explore counts-in-cylinders, a common statistic defined as the number of companions of a particular galaxy found within a given projected radius and redshift interval. Galaxy distributions with the same two-point correlation functions do not necessarily have the same companion count distributions. We use this statistic to examine the environments of galaxies in the Sloan Digital Sky Survey, Data Release 4. We also make preliminary comparisons to four models for the spatial distributions of galaxies, based on N-body simulations, and data from SDSS DR4 to study the utility of the counts-in-cylinders statistic. There is a very large scatter between the number of companions a galaxy has and the mass of its parent dark matter halo and the halo occupation, limiting the utility of this statistic for certain kinds of environmental studies. We also show that prevalent, empirical models of galaxy clustering that match observed two- and three-point clustering statistics well fail to reproduce some aspects of the observed distribution of counts-in-cylinders on 1, 3 and 6-h{sup -1}Mpc scales. All models …
Date: December 16, 2010
Creator: Berrier, Heather D.; Barton, Elizabeth J.; /UC, Irvine; Berrier, Joel C.; U., /Arkansas; Bullock, James S. et al.
System: The UNT Digital Library
EFFECT OF IMPURITIES ON THE PERFORMANCE OF A Pd-Ag DIFFUSER (open access)

EFFECT OF IMPURITIES ON THE PERFORMANCE OF A Pd-Ag DIFFUSER

A commercially fabricated diffuser purchased from Johnson-Matthey, Inc. was evaluated for performance characterization testing at the Savannah River National Laboratory (SRNL). Different impurities are often present in the feed streams of the process diffusers, but the effect of these impurities on the diffuser performance is currently unknown. Various impurities were introduced into the feed stream of the diffuser at various levels ranging from 0.5% to 10% of the total flow in order to determine the effect that these impurities have on the permeation of hydrogen through the palladium-silver membrane. The introduction of various impurities into the feed stream of the diffuser had a minimal effect on the overall permeation of hydrogen through the Pd-Ag membrane. Of the four impurities introduced into the feed stream, carbon monoxide (CO) was the only impurity that showed any evidence of causing a reduction in the amount of hydrogen permeating through the Pd-Ag membrane. The hydrogen permeation returned to its baseline level after the CO was removed from the feed stream. There were no lasting effects of the CO exposure on the ability of the membrane to effectively separate hydrogen from the non-hydrogen species in the gas stream under the conditions tested.
Date: December 16, 2010
Creator: Morgan, G.
System: The UNT Digital Library
Gauge theories from D7-branes over vanishing 4-cycles (open access)

Gauge theories from D7-branes over vanishing 4-cycles

We study quiver gauge theories on D7-branes wrapped over vanishing holomorphic 4-cycles. We investigate how to incorporate O7-planes and/or flavor D7-branes, which are necessary to cancel anomalies. These theories are chiral, preserve four supercharges and exhibit very rich infrared dynamics. Geometric transitions and duality in the presence of O-planes are analyzed. We study the Higgs branch of these quiver theories, showing the emergence of fuzzy internal dimensions. This branch is related to noncommutative instantons on the divisor wrapped by the seven-branes. Our results have a natural application to the recently introduced F(uzz) limit of F-theory.
Date: December 16, 2010
Creator: Franco, Sebastian; /Santa Barbara, KITP; Torroba, Gonzalo & /SLAC /Stanford U., Phys. Dept.
System: The UNT Digital Library
MaterialsSemicrystallineCopolyamidesBased on the Renewable Monomer, 1,9-Nonane Diamine (open access)

MaterialsSemicrystallineCopolyamidesBased on the Renewable Monomer, 1,9-Nonane Diamine

The conclusions of the presentation are: (1) Confirmed Isomorphism; (2) Reproduced Sigmoidal Relationship Between Melting Temperature and Composition; (3) Tg Increased with Increasing 9T Content; (4) Thermal Stability Increased with Increasing 9T Content; (5) Crystallization Rate Increased Dramatically at 9T Contents Above 50 Mole %; and (6) Copolymers Possessing a 9T Content Exceeding 50 Mole % 9T Possess Very Desirable Thermal Properties That Rival Nylon 6,6.
Date: December 16, 2010
Creator: Kugal, Alex; He, Jie; Bahr, James; Nasrullah, Mohammed & Chisholm, Bret
System: The UNT Digital Library
Measurement of the B -> D(*)D(*)K Branching Fractions (open access)

Measurement of the B -> D(*)D(*)K Branching Fractions

The authors present a measurement of the branching fractions of the 22 decay channels of the B{sup 0} and B{sup +} mesons to {bar D}{sup (*)}D{sup (*)}K, where the D{sup (*)} and {bar D}{sup (*)} mesons are fully reconstructed. Summing the 10 neutral modes and the 12 charged modes, the branching fractions are found to be {Beta}(B{sup 0} {yields} {bar D}{sup (*)}D{sup (*)}K) = (3.68 {+-} 0.10 {+-} 0.24)% and {Beta}(B{sup +} {yields} {bar D}{sup (*)}D{sup (*)}K) = (4.05 {+-} 0.11 {+-} 0.28)%, where the first uncertainties are statistical and the second systematic. The results are based on 429 fb{sup -1} of data containing 471 x 10{sup 6} B{bar B} pairs collected at the {Upsilon}(4S) resonance with the BABAR detector at the SLAC National Accelerator Laboratory.
Date: December 16, 2010
Creator: Sanchez, P.del Amo
System: The UNT Digital Library
PLANTS AS BIO-MONITORS FOR 137CS, 238PU, 239, 240PU AND 40K AT THE SAVANNAH RIVER SITE (open access)

PLANTS AS BIO-MONITORS FOR 137CS, 238PU, 239, 240PU AND 40K AT THE SAVANNAH RIVER SITE

The nuclear fuel cycle generates a considerable amount of radioactive waste, which often includes nuclear fission products, such as strontium-90 ({sup 90}Sr) and cesium-137 ({sup 137}Cs), and actinides such as uranium (U) and plutonium (Pu). When released into the environment, large quantities of these radionuclides can present considerable problems to man and biota due to their radioactive nature and, in some cases as with the actinides, their chemical toxicity. Radionuclides are expected to decay at a known rate. Yet, research has shown the rate of elimination from an ecosystem to differ from the decay rate due to physical, chemical and biological processes that remove the contaminant or reduce its biological availability. Knowledge regarding the rate by which a contaminant is eliminated from an ecosystem (ecological half-life) is important for evaluating the duration and potential severity of risk. To better understand a contaminants impact on an environment, consideration should be given to plants. As primary producers, they represent an important mode of contamination transfer from sediments and soils into the food chain. Contaminants that are chemically and/or physically sequestered in a media are less likely to be bio-available to plants and therefore an ecosystem.
Date: December 16, 2010
Creator: Caldwell, E.; Duff, M. & Ferguson, C.
System: The UNT Digital Library
Radiation multigroup diffusion for refractive, lossy media in ALE3D (U) (open access)

Radiation multigroup diffusion for refractive, lossy media in ALE3D (U)

None
Date: December 16, 2010
Creator: Shestakov, A I
System: The UNT Digital Library
A three wavelength scheme to optimize hohlraum coupling on the National Ignition Facility (open access)

A three wavelength scheme to optimize hohlraum coupling on the National Ignition Facility

By using three tunable wavelengths on different cones of laser beams on the National Ignition Facility, numerical simulations show that the energy transfer between beams can be tuned to redistribute the energy within the cones of beams most prone to backscatter instabilities. These radiative hydrodynamics and laser-plasma interaction simulations have been tested against large scale hohlraum experiments with two tunable wavelengths, and reproduce the hohlraum energetics and symmetry. Using a third wavelength provides a greater level of control of the laser energy distribution and coupling in the hohlraum, and could significantly reduce stimulated Raman scattering losses and increase the hohlraum radiation drive while maintaining a good implosion symmetry.
Date: December 16, 2010
Creator: Michel, P; Divol, L; Town, R & Rosen, M
System: The UNT Digital Library