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Internal Energies of Ion-Sputtered Neutral Tryptophan and Thymine Molecules Determined by Vacuum Ultraviolet Photoionization
Vacuum ultraviolet photoionization coupled to secondary neutral mass spectrometry (VUV-SNMS) of deposited tryptophan and thymine films are performed at the Chemical Dynamics Beamline. The resulting mass spectra show that while the intensity of the VUV-SNMS signal is lower than the corresponding secondary ion mass spectroscopy (SIMS) signal, the mass spectra are significantly simplified in VUV-SNMS. A detailed examination of tryptophan and thymine neutral molecules sputtered by 25 keV Bi3 + indicates that the ion-sputtered parent molecules have ~;;2.5 eV of internal energy. While this internal energy shifts the appearance energy of the photofragment ions for both tryptophan and thymine, it does not change the characteristic photoionizaton efficiency (PIE) curves of thymine versus photon energy. Further analysis of the mass spectral signals indicate that approximately 80 neutral thymine molecules and 400 tryptophan molecules are sputtered per incident Bi3 + ion. The simplified mass spectra and significant characteristic ion contributions to the VUV-SNMS spectra indicate the potential power of the technique for organic molecule surface analysis.
Date:
March 11, 2010
Creator:
Zhou, Jia; Takahashi, Lynelle; Wilson, Kevin R.; Leone, Stephen R. & Ahmed, Musahid
Object Type:
Article
System:
The UNT Digital Library
Cooper Review (Cooper, Tex.), Vol. 130, No. 10, Ed. 1 Thursday, March 11, 2010
Weekly newspaper from Cooper, Texas that includes local, state, and national news along with advertising.
Date:
March 11, 2010
Creator:
Palmer, Roger
Object Type:
Newspaper
System:
The Portal to Texas History
Iceland's Financial Crisis
This report discusses the banking collapse in Iceland. Iceland's banking system had collapsed as a result of a culmination of a series of decisions the banks made that left them highly exposed to disruptions in financial markets. The collapse of the banks raised questions for U.S. leaders and others about supervising banks that operate across national borders, especially as it has become increasingly difficult to distinguish the limits of domestic financial markets.
Date:
March 11, 2010
Creator:
Jackson, James K.
Object Type:
Report
System:
The UNT Digital Library
Moldova: Background and U.S. Policy
This report provides information and analysis on Moldova, including its political and economic situation, foreign policy, and on U.S. policy toward Moldova.
Date:
March 11, 2010
Creator:
Woehrel, Steven
Object Type:
Report
System:
The UNT Digital Library
Universal Service Fund: Background and Options for Reform
This report discusses the idea that all Americans should be able to afford access to the telecommunications network; this is commonly called the "universal service concept" and can trace its origins back to the 1934 Communications Act.
Date:
March 11, 2010
Creator:
Gilroy, Angele A.
Object Type:
Report
System:
The UNT Digital Library
Limiting Central Government Budget Deficits: International Experiences
This report focuses on how major developed and emerging-market country governments, particularly the G-20 and Organization for Economic Cooperation and Development (OECD) countries, limit their fiscal deficits.
Date:
March 11, 2010
Creator:
Jackson, James K.
Object Type:
Report
System:
The UNT Digital Library
Armenia, Azerbaijan, and Georgia: Security Issues and Implications for U.S. Interests
This report discusses the internal and external security concerns of the South Caucasus states and U.S. interests and policy toward the region. The countries of Armenia, Azerbaijan, and Georgia are generally considered as comprising the South Caucasus region, which borders Russia, Turkey, and Iran.
Date:
March 11, 2010
Creator:
Nichol, Jim
Object Type:
Report
System:
The UNT Digital Library
U.S.-Japan Economic Relations: Significance, Prospects, and Policy Options
his report explores the significance and state of U.S.-Japan economic ties; how the ties have changed over time; and what the possible options for managing the relationship might be.
Date:
March 11, 2010
Creator:
Cooper, William H.
Object Type:
Report
System:
The UNT Digital Library
Chile Earthquake: U.S. and International Response
This report discusses the Earthquake in Chile, the current condition, the response from Chilean government, international humanitarian response, as well as the U.S. humanitarian response. The report provides background information on Chile and U.S. relations and policy issues.
Date:
March 11, 2010
Creator:
Beittel, June S.
Object Type:
Report
System:
The UNT Digital Library
Iran: U.S. Concerns and Policy Responses
This report discusses the reasons that Iran is considered a threat to U.S. security, including Iran's nuclear program, involvement with terrorist organizations, and involvement with neighboring countries' local governments. The report also discusses ways which the U.S. hopes to modify Iran's behavior with sanctions, and the effectiveness of these sanctions.
Date:
March 11, 2010
Creator:
Katzman, Kenneth
Object Type:
Report
System:
The UNT Digital Library
The OECD Initiative on Tax Havens
This report examines the Organization for Economic Cooperation and Development (OECD) and its role in changes to U.S. laws related to bribery, tax havens.
Date:
March 11, 2010
Creator:
Jackson, James K.
Object Type:
Report
System:
The UNT Digital Library
Trade Agreements: Impact on the U.S. Economy
This report examines the major features of economic models being used to estimate the effects of trade agreements. It assesses the strengths and weaknesses of the models as an aid in helping Congress evaluate the economic impact of trade agreements on the U.S. economy.
Date:
March 11, 2010
Creator:
Jackson, James K.
Object Type:
Report
System:
The UNT Digital Library
The Sachse News (Sachse, Tex.), Vol. 6, No. 7, Ed. 1 Thursday, March 11, 2010
Weekly newspaper from Sachse, Texas that includes local, state and national news along with advertising.
Date:
March 11, 2010
Creator:
Fisher, Donnita Nesbit
Object Type:
Newspaper
System:
The Portal to Texas History
Views of the March 11, 2010 McKinney Chapter Meeting
Webpage from McKinney TXSSAR website containing photographs from a March 11, 2010 meeting at El Chico Cafe.
Date:
March 11, 2010
Creator:
Texas Society Sons of the American Revolution, McKinney Chapter 63
Object Type:
Website
System:
The UNT Digital Library
The Baytown Sun (Baytown, Tex.), Vol. 90, No. 50, Ed. 1 Thursday, March 11, 2010
Daily newspaper from Baytown, Texas that includes local, state, and national news along with advertising.
Date:
March 11, 2010
Creator:
Halter, Janie
Object Type:
Newspaper
System:
The Portal to Texas History
Archer County News (Archer City, Tex.), No. 10, Ed. 1 Thursday, March 11, 2010
Weekly newspaper from Archer City, Texas that includes local, state, and national news along with advertising.
Date:
March 11, 2010
Creator:
Lewis, Shelley
Object Type:
Newspaper
System:
The Portal to Texas History
Biocultural conservation in Cape Horn: the Magellanic woodpecker as a charismatic species
This book chapter discusses a research project to promote biocultural conservation in Cape Horn, Chile. In an effort to achieve the goal of transdisciplinary integration, the authors used the strategy of identifying a charismatic species, since doing so serves to motivate people towards biodiversity conservation, to communicate ecological concepts, and to integrate both the ecological and social dimensions of sustainability.
Date:
March 11, 2010
Creator:
Arango, Ximena; Rozzi, Ricardo, 1960-; Massardo, Francisca & Ibarra, J. Tomás
Object Type:
Book Chapter
System:
The UNT Digital Library
Sweetwater Reporter (Sweetwater, Tex.), Vol. 112, No. 099, Ed. 1 Thursday, March 11, 2010
Daily newspaper from Sweetwater, Texas that includes local, state, and national news along with advertising.
Date:
March 11, 2010
Creator:
unknown
Object Type:
Newspaper
System:
The Portal to Texas History
Rio Grande Herald (Rio Grande City, Tex.), Vol. 97, No. 10, Ed. 1 Thursday, March 11, 2010
Weekly newspaper from Rio Grande City, Texas that includes local, state and national news along with extensive advertising.
Date:
March 11, 2010
Creator:
Roberts, Kenneth
Object Type:
Newspaper
System:
The Portal to Texas History
The Canadian Record (Canadian, Tex.), Vol. 120, No. 10, Ed. 1 Thursday, March 11, 2010
Weekly newspaper from Canadian, Texas that includes local, state and national news along with some advertising.
Date:
March 11, 2010
Creator:
Brown, Laurie Ezzell
Object Type:
Newspaper
System:
The Portal to Texas History
Everglades Restoration: The Federal Role in Funding
None
Date:
March 11, 2010
Creator:
Stern, Charles V.; Sheikh, Pervaze A. & Carter, Nicole T.
Object Type:
Report
System:
The UNT Digital Library
Freedom of Information Act (FOIA): Issues for the 111th Congress
This report is categorized into six categories: (I) Introduction, (II) FOIA History, (III) The George W. Bush Administration, (IV) 110TH Congress Legislative Reform Efforts, (V) The Obama Administration, and (VI) FOIA and the 111th Congress.
Date:
March 11, 2010
Creator:
Ginsberg, Wendy R.
Object Type:
Report
System:
The UNT Digital Library
Net Hydrogenation of Pt-NHPh Bond Is Catalyzed by Elemental Pt
This article discusses the net hydrogenation of Pt-NHPh bond catalyzed by elemental Pt.
Date:
March 11, 2010
Creator:
Webb, Joanna R.; Pierpont, Aaron W.; Munro-Leighton, Colleen; Gunnoe, T. Brent; Cundari, Thomas R., 1964- & Boyle, Paul D.
Object Type:
Article
System:
The UNT Digital Library
Study of Ether-, Alcohol-, or Cyano-Functionalized Ionic Liquids Using Inverse Gas Chromatography
This article discusses the study of ether-, alcohol, or cyano-functionalized ionic liquids using inverse gas chromatography.
Date:
March 11, 2010
Creator:
Revelli, Anne-Laure; Mutelet, Fabrice; Jaubert, Jean-Noël; Garcia-Martinez, Marina; Sprunger, Laura M.; Acree, William E. (William Eugene) et al.
Object Type:
Article
System:
The UNT Digital Library