An Electron Fixed Target Experiment to Search for a New Vector Boson A' Decaying to e+e- (open access)

An Electron Fixed Target Experiment to Search for a New Vector Boson A' Decaying to e+e-

We describe an experiment to search for a new vector boson A' with weak coupling {alpha}' {approx}> 6 x 10{sup -8} {alpha} to electrons ({alpha} = e{sup 2}/4{pi}) in the mass range 65 MeV < m{sub A'} < 550 MeV. New vector bosons with such small couplings arise naturally from a small kinetic mixing of the 'dark photon' A' with the photon - one of the very few ways in which new forces can couple to the Standard Model - and have received considerable attention as an explanation of various dark matter related anomalies. A' bosons are produced by radiation off an electron beam, and could appear as narrow resonances with small production cross-section in the trident e{sup +}e{sup -} spectrum. We summarize the experimental approach described in a proposal submitted to Jefferson Laboratory's PAC35, PR-10-009. This experiment, the A' Experiment (APEX), uses the electron beam of the Continuous Electron Beam Accelerator Facility at Jefferson Laboratory (CEBAF) at energies of {approx} 1-4 GeV incident on 0.5-10% radiation length Tungsten wire mesh targets, and measures the resulting e{sup +}e{sup -} pairs to search for the A' using the High Resolution Spectrometer and the septum magnet in Hall A. With a {approx} …
Date: June 11, 2010
Creator: Essig, Rouven; Schuster, Philip; Toro, Natalia & Wojtsekhowski, Bogdan
Object Type: Article
System: The UNT Digital Library
Technology Summary Advancing Tank Waste Retrieval and Processing (open access)

Technology Summary Advancing Tank Waste Retrieval and Processing

This technology overview provides a high-level summary of technologies being investigated and developed by Washington River Protection Solutions (WRPS) to advance Hanford Site tank waste retrieval and processing. Technology solutions are outlined, along with processes and priorities for selecting and developing them.
Date: August 11, 2010
Creator: Sams, T. L. & Mendoza, R. E.
Object Type: Report
System: The UNT Digital Library
Studies of Limits on Uncontrolled Heavy Ion Beam Losses for Allowing Hands-On Maintenance (open access)

Studies of Limits on Uncontrolled Heavy Ion Beam Losses for Allowing Hands-On Maintenance

Dose rates from accelerator components activated by 1 W/m beam losses are obtained semiempirically for a 1 GeV proton beam and by use of Monte Carlo transport codes for the proton beam and for 777 MeV/u 3He, 500 MeV/u 48Ca, 86Kr, 136Xe, and 400 MeV/u 238U ions. The dose rate obtained by the semi-empirical method, 0.99 mSv/h (99 mrem/h) at 30 cm, 4 h after 100 d irradiation by a 1-GeV proton beam, is consistent with studies at several accelerator facilities and with adopted hands-on maintenance dose rate limits. Monte Carlo simulations verify this result for protons and extend studies to heavy ion beam losses in drift-tube linac and superconducting linac accelerating structures. The studies indicate that the 1 W/m limit imposed on uncontrolled beam losses for high-energy proton beams might be relaxed for heavy ion beams. These studies further suggest that using the ratio of neutrons produced by a heavy ion beam to neutrons produced by a proton beam along with the dose rate from the proton beam (for thin-target scenarios) should allow an estimate of the dose rates expected from heavy ion beam losses.
Date: September 11, 2010
Creator: Ronningen, Reginald M. & Remec, Igor
Object Type: Report
System: The UNT Digital Library
Report on Electrochemical Corrosion Testing for Tank 241-AN-106 Using 2009 Sampling Campaign Grab Samples (open access)

Report on Electrochemical Corrosion Testing for Tank 241-AN-106 Using 2009 Sampling Campaign Grab Samples

Based on an ENRAF waste surface measurement taken February 1, 2009, double-shell tank (DST) 24l-AN-l06 (AN-106) contained approximately 278.98 inches (793 kgal) of waste. A zip cord measurement from the tank on February 1, 2009, indicated a settled solids layer of 9l.7 inches in height (280 kgal). The supernatant layer in February 2009, by difference, was approximately 187 inches deep (514 kgal). Laboratory results from AN-l06 February 1, 2009 (see Table 2) grab samples indicated the supernatant was below the chemistry limit that applied at the time as identified in HNF-SD-WM-TSR-006, 'Tank Farms Technical Safety Requirements', Administrative Control (AC) 5.16, 'Corrosion Mitigation Controls.' The limits have since been removed from the Technical Safety Requirements (TSR) and are captured in OSD-T-15l-00007, 'Operating Specifications for the Double-Shell Storage Tanks.' Problem evaluation request WRPS-PER-2009-0218 was submitted February 9,2009, to document the finding that the supernatant chemistry for grab samples taken from the middle and upper regions of the supernatant was noncompliant with the chemistry control limits. The lab results for the samples taken from the bottom region of the supernatant met AC 5.16 limits.
Date: May 11, 2010
Creator: Wyrwas, R. B.
Object Type: Report
System: The UNT Digital Library
Nanoheterostructure Cation Exchange: Anionic Framework Conservation (open access)

Nanoheterostructure Cation Exchange: Anionic Framework Conservation

In ionic nanocrystals the cationic sub-lattice can be replaced with a different metal ion via a fast, simple, and reversible place-exchange, allowing post-synthetic modification of the composition of the nanocrystal, while preserving its size and shape. Here, we demonstrate for the first time that during such an exchange, the anionic framework of the crystal is preserved. When applied to nanoheterostructures, this phenomenon ensures that compositional interfaces within the heterostructure are conserved throughout the transformation. For instance, a morphology composed of a CdSe nanocrystal embedded in a CdS rod (CdSe/CdS) was exchanged to a PbSe/PbS nanorod via a Cu2Se/Cu2S structure. During every exchange cycle, the seed size and position within the nanorod were preserved, as evident by excitonic features, Z-contrast imaging, and elemental line-scans. Anionic framework conservation extends the domain of cation exchange to the design of more complex and unique nanostructures.
Date: May 11, 2010
Creator: Jain, Prashant K.; Amirav, Lilac; Aloni, Shaul & Alivisatos, A. Paul
Object Type: Article
System: The UNT Digital Library
Modulation compression for short wavelength harmonic generation (open access)

Modulation compression for short wavelength harmonic generation

Laser modulator is used to seed free electron lasers. In this paper, we propose a scheme to compress the initial laser modulation in the longitudinal phase space by using two opposite sign bunch compressors and two opposite sign energy chirpers. This scheme could potentially reduce the initial modulation wavelength by a factor of C and increase the energy modulation amplitude by a factor of C, where C is the compression factor of the first bunch compressor. Such a compressed energy modulation can be directly used to generate short wavelength current modulation with a large bunching factor.
Date: January 11, 2010
Creator: Qiang, J.
Object Type: Article
System: The UNT Digital Library
Analysis of Failed and Nickel-coated 3093 Beam Clamp Components at the East Tennessee Technology Park (ettp) (open access)

Analysis of Failed and Nickel-coated 3093 Beam Clamp Components at the East Tennessee Technology Park (ettp)

The U.S. Department of Energy and its contractor, Bechtel Jacobs Company (BJC), are undertaking a major effort to clean up the former gaseous diffusion facility (K-25) located in Oak Ridge, TN. The decontamination and decommissioning activities require systematic removal of contaminated equipment and machinery followed by demolition of the buildings. As part of the cleanup activities, a beam clamp, used for horizontal life lines (HLLs) for fall protection, was discovered to be fractured during routine inspection. The beam clamp (yoke and D-ring) was a component in the HLL system purchased from Reliance Industries LLC. Specifically, the U-shaped stainless steel yoke of the beam clamp failed in a brittle mode at under less than 10% of the rated design capacity of 14,500 lb. The beam clamp had been in service for approximately 16 months. Bechtel Jacobs approached Argonne National Laboratory to assist in identifying the root cause of the failure of the beam clamp. The objectives of this study were to (1) review the prior reports and documents on the subject, (2) understand the possible failure mechanism(s) that resulted in the failed beam clamp components, (3) recommend approaches to mitigate the failure mechanism(s), and (4) evaluate the modified beam clamp assemblies. …
Date: October 11, 2010
Creator: Singh, D.; Pappacena, K.; Gaviria, J.; Burtsteva, T. & Division, Nuclear Engineering
Object Type: Report
System: The UNT Digital Library
Small Steps Towards a Grand Unification and the Electron/Positron Excesses in Cosmic-Ray Experiments (open access)

Small Steps Towards a Grand Unification and the Electron/Positron Excesses in Cosmic-Ray Experiments

We consider a small extension of the standard model by adding two Majorana fermions; those are adjoint representations of the SU(2){sub L} and SU(3){sub c} gauge groups of the standard model. In this extension, the gauge coupling unification at an energy scale higher than 10{sup 15} GeV is realized when the masses of the triplet and the octet fermions are smaller than 10{sup 4} GeV and 10{sup 12} GeV, respectively. We also show that an appropriate symmetry ensures a long lifetime of the neutral component of the triplet fermion whose thermal relic density naturally explains the observed dark matter density. The electron/positron excesses observed in recent cosmic-ray experiments can be also explained by the decay of the triplet fermion.
Date: June 11, 2010
Creator: Ibe, Masahiro
Object Type: Article
System: The UNT Digital Library
Single Ion Implantation and Deterministic Doping (open access)

Single Ion Implantation and Deterministic Doping

The presence of single atoms, e.g. dopant atoms, in sub-100 nm scale electronic devices can affect the device characteristics, such as the threshold voltage of transistors, or the sub-threshold currents. Fluctuations of the number of dopant atoms thus poses a complication for transistor scaling. In a complementary view, new opportunities emerge when novel functionality can be implemented in devices deterministically doped with single atoms. The grand price of the latter might be a large scale quantum computer, where quantum bits (qubits) are encoded e.g. in the spin states of electrons and nuclei of single dopant atoms in silicon, or in color centers in diamond. Both the possible detrimental effects of dopant fluctuations and single atom device ideas motivate the development of reliable single atom doping techniques which are the subject of this chapter. Single atom doping can be approached with top down and bottom up techniques. Top down refers to the placement of dopant atoms into a more or less structured matrix environment, like a transistor in silicon. Bottom up refers to approaches to introduce single dopant atoms during the growth of the host matrix e.g. by directed self-assembly and scanning probe assisted lithography. Bottom up approaches are discussed in …
Date: June 11, 2010
Creator: Schenkel, Thomas
Object Type: Book
System: The UNT Digital Library
PROBING STRESS EFFECTS IN SINGLE CRYSTAL ORGANIC TRANSISTORS BY SCANNING KELVIN PROBE MICROSCOPY (open access)

PROBING STRESS EFFECTS IN SINGLE CRYSTAL ORGANIC TRANSISTORS BY SCANNING KELVIN PROBE MICROSCOPY

We report scanning Kelvin probe microscopy (SKPM) of single crystal difluoro bis(triethylsilylethynyl) anthradithiophene (diF-TESADT) organic transistors. SKPM provides a direct measurement of the intrinsic charge transport in the crystals independent of contact effects and reveals that degradation of device performance occurs over a time period of minutes as the diF-TESADT crystal becomes charged.
Date: June 11, 2010
Creator: Teague, L.
Object Type: Article
System: The UNT Digital Library
Autoignition behavior of unsaturated hydrocarbons in the low and high temperature regions (open access)

Autoignition behavior of unsaturated hydrocarbons in the low and high temperature regions

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Date: January 11, 2010
Creator: Mehl, M; Pitz, W J; Westbrook, C K; Yasunaga, K & Curran, H J
Object Type: Article
System: The UNT Digital Library
New Fixed-Target Experiments to Search for Dark Gauge Forces (open access)

New Fixed-Target Experiments to Search for Dark Gauge Forces

Fixed-target experiments are ideally suited for discovering new MeV-GeV mass U(1) gauge bosons through their kinetic mixing with the photon. In this paper, we identify the production and decay properties of new light gauge bosons that dictate fixed-target search strategies. We summarize existing limits and suggest five new experimental approaches that we anticipate can cover most of the natural parameter space, using currently operating GeV-energy beams and well-established detection methods. Such experiments are particularly timely in light of recent terrestrial and astrophysical anomalies (PAMELA, FERMI, DAMA/LIBRA, etc.) consistent with dark matter charged under a new gauge force.
Date: June 11, 2010
Creator: Bjorken, James D.; Essig, Rouven; Schuster, Philip & Toro, Natalia
Object Type: Article
System: The UNT Digital Library
Lake Granbury and Lake Whitney Assessment Initiative Final Scientific/Technical Report Summary (open access)

Lake Granbury and Lake Whitney Assessment Initiative Final Scientific/Technical Report Summary

A team of Texas AgriLife Research, Baylor University and University of Texas at Arlington researchers studied the biology and ecology of Prymnesium parvum (golden algae) in Texas lakes using a three-fold approach that involved system-wide monitoring, experimentation at the microcosm and mesocosm scales, and mathematical modeling. The following are conclusions, to date, regarding this organism’s ecology and potential strategies for mitigation of blooms by this organism. In-lake monitoring revealed that golden algae are present throughout the year, even in lakes where blooms do not occur. Compilation of our field monitoring data with data collected by Texas Parks and Wildlife and Brazos River Authority (a period spanning a decade) revealed that inflow and salinity variables affect bloom formations. Thresholds for algae populations vary per lake, likely due to adaptations to local conditions, and also to variations in lake-basin morphometry, especially the presence of coves that may serve as hydraulic storage zones for P. parvum populations. More specifically, our in-lake monitoring showed that the highly toxic bloom that occurred in Lake Granbury in the winter of 2006/2007 was eliminated by increased river inflow events. The bloom was flushed from the system. The lower salinities that resulted contributed to golden algae not blooming …
Date: October 11, 2010
Creator: Harris, B.L.; Roelke, Daniel; Brooks, Bryan & Grover, James
Object Type: Report
System: The UNT Digital Library
Studying Gaugino mass in Semi-Direct Gauge Mediation (open access)

Studying Gaugino mass in Semi-Direct Gauge Mediation

We study gaugino mass generation in the context of semi-direct gauge mediation models, where the messengers are charged under both the hidden sector and the standard model gauge groups while they do not play important roles in dynamical supersymmetry breaking. We clarify the cancellation of the leading contributions of the supersymmetry breaking effects to the gaugino mass in this class of models in terms of the macroscopic effective theory of the hidden sector dynamics. We also consider how to retrofit the model so that we obtain the non-vanishing leading contribution to the gaugino mass.
Date: June 11, 2010
Creator: Ibe, M.; Izawa, K. -I. & Nakai, Y.
Object Type: Report
System: The UNT Digital Library

Novel Approach to Advanced Direct Methanol Fuel Cell Anode Catalysts

This presentation is a summary of a Novel Approach to Advanced Direct Methanol Fuel Cell Anode Catalysts.
Date: June 11, 2010
Creator: Dinh, H. & Gennett, T.
Object Type: Presentation
System: The UNT Digital Library
Kinetic Modeling of Gasoline Surrogate Components and Mixtures under Engine Conditions (open access)

Kinetic Modeling of Gasoline Surrogate Components and Mixtures under Engine Conditions

Real fuels are complex mixtures of thousands of hydrocarbon compounds including linear and branched paraffins, naphthenes, olefins and aromatics. It is generally agreed that their behavior can be effectively reproduced by simpler fuel surrogates containing a limited number of components. In this work, an improved version of the kinetic model by the authors is used to analyze the combustion behavior of several components relevant to gasoline surrogate formulation. Particular attention is devoted to linear and branched saturated hydrocarbons (PRF mixtures), olefins (1-hexene) and aromatics (toluene). Model predictions for pure components, binary mixtures and multicomponent gasoline surrogates are compared with recent experimental information collected in rapid compression machine, shock tube and jet stirred reactors covering a wide range of conditions pertinent to internal combustion engines (3-50 atm, 650-1200K, stoichiometric fuel/air mixtures). Simulation results are discussed focusing attention on the mixing effects of the fuel components.
Date: January 11, 2010
Creator: Mehl, M; Pitz, W J; Westbrook, C K & Curran, H J
Object Type: Article
System: The UNT Digital Library
From the LHC to Future Colliders (open access)

From the LHC to Future Colliders

Discoveries at the LHC will soon set the physics agenda for future colliders. This report of a CERN Theory Institute includes the summaries of Working Groups that reviewed the physics goals and prospects of LHC running with 10 to 300 fb{sup -1} of integrated luminosity, of the proposed sLHC luminosity upgrade, of the ILC, of CLIC, of the LHeC and of a muon collider. The four Working Groups considered possible scenarios for the first 10 fb{sup -1} of data at the LHC in which (i) a state with properties that are compatible with a Higgs boson is discovered, (ii) no such state is discovered either because the Higgs properties are such that it is difficult to detect or because no Higgs boson exists, (iii) a missing-energy signal beyond the Standard Model is discovered as in some supersymmetric models, and (iv) some other exotic signature of new physics is discovered. In the contexts of these scenarios, theWorking Groups reviewed the capabilities of the future colliders to study in more detail whatever new physics may be discovered by the LHC. Their reports provide the particle physics community with some tools for reviewing the scientific priorities for future colliders after the LHC produces …
Date: June 11, 2010
Creator: De Roeck, A.; Ellis, J.; Grojean, C.; Heinemeyer, S.; Jakobs, K.; Weiglein, G. et al.
Object Type: Article
System: The UNT Digital Library
Single Particle Difraction at FLASH (open access)

Single Particle Difraction at FLASH

Single-pulse coherent diffraction patterns have been collected from randomly injected single particles with a soft X-ray free-electron laser (FEL). The intense focused FEL pulse gives a high-resolution low-noise coherent diffraction pattern of the object before that object turns into a plasma and explodes. A diffraction pattern of a single particle will only be recorded when the particle arrival into the FEL interaction region coincides with FEL pulse arrival and detector integration. The properties of the experimental apparatus coinciding with these three events set the data acquisition rate. For our single particle FLASH diffraction imaging experiments: (1) an aerodynamic lens stack prepared a particle beam that consisted of particles moving at 150-200 m/s positioned randomly in space and time, (2) the 10 fs long FEL pulses were delivered at a fixed rate, and (3) the detector was set to integrate and readout once every two seconds. The effect of these experimental parameters on the rate of data acquisition using randomly injected particles will be discussed. Overall, the ultrashort FEL pulses do not set the limit of the data acquisition, more important is the effective interaction time of the particle crossing the FEL focus, the pulse sequence structure and the detector readout …
Date: June 11, 2010
Creator: Bogan, M.; Boutet, S.; Starodub, Dmitri; Decorwin-Martin, Philippe; /SLAC; Chapman, H. et al.
Object Type: Article
System: The UNT Digital Library
IMPACT OF REDUCING THE 100 C LIQUIDUS TEMPERATURE OFFSET ON WASTE LOADING TARGETS (open access)

IMPACT OF REDUCING THE 100 C LIQUIDUS TEMPERATURE OFFSET ON WASTE LOADING TARGETS

The objective of this report is to assess the potential impact of reducing conservatism in the implementation of the current liquidus temperature (TL) model in the Product Composition Control System (PCCS) on the ability to target higher waste loadings (WLs) for future sludge batches. No changes to the TL model or the associated uncertainties (model or measurement) are proposed, rather only changes in the magnitude of the offset used between the nominal melt pool temperature (1150 C) and the Property Acceptance Region (PAR) value (1050 C). This strategy is consistent with that outlined and initially assessed by Brown et al. (2001). In that report, the authors stated even a fairly conservative change in this safety factor could have a significant impact on waste loading. The results of this study clearly indicate that the implementation of an 1100 C TL PAR criterion (which translates into a reduction in the TL offset from 100 C to 50 C) can have significantly positive impacts on the ability to gain access to WLs exceeding 45%. This is especially true for those frit and sludge systems that are TL limited using the current 1050 C TL criterion, and are not limited by a second constraint …
Date: November 11, 2010
Creator: Peeler, D. & Edwards, T.
Object Type: Report
System: The UNT Digital Library
Life-Cycle Analysis Results of Geothermal Systems in Comparison to Other Power Systems. (open access)

Life-Cycle Analysis Results of Geothermal Systems in Comparison to Other Power Systems.

A life-cycle energy and greenhouse gas emissions analysis has been conducted with Argonne National Laboratory's expanded Greenhouse Gases, Regulated Emissions, and Energy Use in Transportation (GREET) model for geothermal power-generating technologies, including enhanced geothermal, hydrothermal flash, and hydrothermal binary technologies. As a basis of comparison, a similar analysis has been conducted for other power-generating systems, including coal, natural gas combined cycle, nuclear, hydroelectric, wind, photovoltaic, and biomass by expanding the GREET model to include power plant construction for these latter systems with literature data. In this way, the GREET model has been expanded to include plant construction, as well as the usual fuel production and consumption stages of power plant life cycles. For the plant construction phase, on a per-megawatt (MW) output basis, conventional power plants in general are found to require less steel and concrete than renewable power systems. With the exception of the concrete requirements for gravity dam hydroelectric, enhanced geothermal and hydrothermal binary used more of these materials per MW than other renewable power-generation systems. Energy and greenhouse gas (GHG) ratios for the infrastructure and other life-cycle stages have also been developed in this study per kilowatt-hour (kWh) of electricity output by taking into account both plant …
Date: October 11, 2010
Creator: Sullivan, J. L.; Clark, C. E.; Han, J.; Wang, M. & Systems, Energy
Object Type: Report
System: The UNT Digital Library
An Effective Theory of Dirac Dark Matter (open access)

An Effective Theory of Dirac Dark Matter

A stable Dirac fermion with four-fermion interactions to leptons suppressed by a scale {Lambda} {approx} 1 TeV is shown to provide a viable candidate for dark matter. The thermal relic abundance matches cosmology, while nuclear recoil direct detection bounds are automatically avoided in the absence of (large) couplings to quarks. The annihilation cross section in the early Universe is the same as the annihilation in our galactic neighborhood. This allows Dirac fermion dark matter to naturally explain the positron ratio excess observed by PAMELA with a minimal boost factor, given present astrophysical uncertainties. We use the Galprop program for propagation of signal and background; we discuss in detail the uncertainties resulting from the propagation parameters and, more importantly, the injected spectra. Fermi/GLAST has an opportunity to see a feature in the gamma-ray spectrum at the mass of the Dirac fermion. The excess observed by ATIC/PPB-BETS may also be explained with Dirac dark matter that is heavy. A supersymmetric model with a Dirac bino provides a viable UV model of the effective theory. The dominance of the leptonic operators, and thus the observation of an excess in positrons and not in anti-protons, is naturally explained by the large hypercharge and low …
Date: June 11, 2010
Creator: Harnik, Roni & Kribs, Graham D.
Object Type: Article
System: The UNT Digital Library
A Simple Apparatus for the Injection of Lithium Aerosol into the Scrape-Off Layer of Fusion Research Devices (open access)

A Simple Apparatus for the Injection of Lithium Aerosol into the Scrape-Off Layer of Fusion Research Devices

A simple device has been developed to deposit elemental lithium onto plasma facing components in the National Spherical Torus Experiment. Deposition is accomplished by dropping lithium powder into the plasma column. Once introduced, lithium particles quickly become entrained in scrape-off layer flow as an evaporating aerosol. Particles are delivered through a small central aperture in a computer-controlled resonating piezoelectric disk on which the powder is supported. The device has been used to deposit lithium both during discharges as well as prior to plasma breakdown. Clear improvements to plasma performance have been demonstrated. The use of this apparatus provides flexibility in the amount and timing of lithium deposition and, therefore, may benefit future fusion research devices.
Date: October 11, 2010
Creator: D. K. Mansfield, A.L Roquemore, H. Schneider, J. Timberlake, H. Kugel, M.G. Bell and the NSTX Research Team
Object Type: Report
System: The UNT Digital Library
X-ray absorption and magnetic circular dichroism studies of Co2FeAl in magnetic tunnel junctions (open access)

X-ray absorption and magnetic circular dichroism studies of Co2FeAl in magnetic tunnel junctions

The bulk magnetic moment and the element specific magnetic moment of Co{sub 2}FeAl thin films were examined as a function of annealing temperature by alternating gradient magnetometer (AGM) and X-ray absorption spectroscopy (XAS)/X-ray magnetic circular dichroism (XMCD), respectively. A high magnetic moment can be achieved for all annealing temperatures and the predicted bulk and interface magnetic moment of about 5 {tilde A}{sub B} are reached via heating. We will also present tunnel magnetoresistance (TMR) values of up to 153% at room temperature and 260% at 13 K for MgO based magnetic tunnel junctions (MTJs) with Co{sub 2}FeAl and Co-Fe electrodes.
Date: January 11, 2010
Creator: Ebke, D.; Kugler, Z.; Thomas, P.; Schebaum, O.; Schafers, M.; Nissen, D. et al.
Object Type: Article
System: The UNT Digital Library
Soft X-ray absorption spectra of aqueous salt solutions with highly charged cations in liquid microjets (open access)

Soft X-ray absorption spectra of aqueous salt solutions with highly charged cations in liquid microjets

X-ray absorption spectra of 1M aqueous solutions of indium (III) chloride, yttrium (III) bromide, lanthanum (III) chloride, tin (IV) chloride and chromium (III) chloride have been measured at the oxygen K-edge. Relatively minor changes are observed in the spectra compared to that of pure water. SnCl{sub 4} and CrCl{sub 3} exhibit a new onset feature which is attributed to formation of hydroxide or other complex molecules in the solution. At higher energy, only relatively minor, but salt-specific changes in the spectra occur. The small magnitude of the observed spectral changes is ascribed to offsetting perturbations by the cations and anions.
Date: March 11, 2010
Creator: Schwartz, Craig P.; Uejio, Janel S.; Duffin, Andrew M.; Drisdell, Walter S.; Smith, Jared D. & Saykally, Richard J.
Object Type: Article
System: The UNT Digital Library