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The status of open heavy flavor production at RHIC (open access)

The status of open heavy flavor production at RHIC

We discuss the calculation of open heavy flavor cross sections at RHIC and describe how the semileptonic decays of charm and bottom quarks can be separated.
Date: December 21, 2010
Creator: Vogt, R
System: The UNT Digital Library
2010 GRC VIBRATIONAL SPECTROSCOPY AUGUST 1 - AUGUST 6, 2010 (open access)

2010 GRC VIBRATIONAL SPECTROSCOPY AUGUST 1 - AUGUST 6, 2010

The Vibrational Spectroscopy conference focuses on using vibrational spectroscopy to probe structure and dynamics of molecules in gases, liquids, and at interfaces. The conference explores the wide range of state-of-the-art techniques based on vibrational motion. These techniques span the fields of time-domain, high-resolution frequency-domain, spatially-resolved, nonlinear and multidimensional spectroscopies. The conference highlights the application of these techniques in chemistry, materials, biology, and medicine. The theory of molecular vibrational motion and its connection to spectroscopic signatures and chemical reaction dynamics is the third major theme of the meeting. The goal is to bring together a collection of researchers who share common interests and who will gain from discussing work at the forefront of several connected areas. The intent is to emphasize the insights and understanding that studies of vibrations provide about a variety of molecular systems ranging from small polyatomic molecules to large biomolecules and nanomaterials.
Date: August 6, 2010
Creator: Pate, Brooks
System: The UNT Digital Library
2010 Thin Film & Small Scale Mechanical Behavior Gordon Research Conference (open access)

2010 Thin Film & Small Scale Mechanical Behavior Gordon Research Conference

Over the past decades, it has been well established that the mechanical behavior of materials changes when they are confined geometrically at least in one dimension to small scale. It is the aim of the 2010 Gordon Conference on 'Thin Film and Small Scale Mechanical Behavior' to discuss cutting-edge research on elastic, plastic and time-dependent deformation as well as degradation mechanisms like fracture, fatigue and wear at small scales. As in the past, the conference will benefit from contributions from fundamental studies of physical mechanisms linked to material science and engineering reaching towards application in modern applications ranging from optical and microelectronic devices and nano- or micro-electrical mechanical systems to devices for energy production and storage. The conference will feature entirely new testing methodologies and in situ measurements as well as recent progress in atomistic and micromechanical modeling. Particularly, emerging topics in the area of energy conversion and storage, such as material for batteries will be highlighted. The study of small-scale mechanical phenomena in systems related to energy production, conversion or storage offer an enticing opportunity to materials scientists, who can provide new insight and investigate these phenomena with methods that have not previously been exploited.
Date: July 30, 2010
Creator: Balk, Dr. Thomas
System: The UNT Digital Library
Direct Comparison of the X-Ray Emission and Absorption of Cerium Oxide (open access)

Direct Comparison of the X-Ray Emission and Absorption of Cerium Oxide

Bremstrahlung Isochromat Spectroscopy (BIS). The XES spectra were collected using a Specs electron gun for the excitation and the XES 350 grating monochromator and channel plate system from Scienta as the photon detection. Spectra were collected in 'normal mode,' where the electron gun kinetic energy (KE) and the energy position of the center of the channel plate were both fixed and the energy distribution in the photon (hv) spectrum was derived from the intensities distributed across the channel plate detector in the energy dispersal direction. The polycrystalline Ce sample was oxidized by exposure to air at ambient pressures. After introduction to the ultra-high vacuum system, the oxidized sample was bombarded with Ar, to clean the topmost surface region and stabilize the surface and near surface regions. Although CeO{sub 2} would be the thermodynamically preferred composition in an oxygen rich environment, the combination of a vacuum environment and ion etching may have driven the near surface region into a Ce{sub 2}O{sub 3} stoichiometry. XES data collection occurred with the sample at or near room temperature. The base pressure of the system was 3 x 10{sup -10} torr, but the pressure changed depending the energy and current of the electron gun. For …
Date: November 24, 2010
Creator: Tobin, J G; Yu, S W; Chung, B W; Waddill, G D & Denlinger, J D
System: The UNT Digital Library
Planning Guide for Vaccinating Pediatric Patients Against H1N1 Influenza in Private Healthcare Settings (open access)

Planning Guide for Vaccinating Pediatric Patients Against H1N1 Influenza in Private Healthcare Settings

The purpose of this document is to provide guidance for planning and conducting 2009 H1N1 Influenza vaccination of pediatric patients in private healthcare settings.
Date: January 1, 2010
Creator: CHE, HCTT
System: The UNT Digital Library
Latest results from the MINOS experiment (open access)

Latest results from the MINOS experiment

The MINOS experiment utilizes the NuMI neutrino beam to study the phenomenon of neutrino oscillations. Muon neutrinos are sent over a baseline of 735 km, with a detector near the production point at Fermilab and one at the Soudan underground laboratory in northern Minnesota. By observing the {nu}{sub {mu}} disappearance characteristic of oscillations, MINOS can measure the oscillation parameters. MINOS has previously made the best measurement of the atmospheric-regime mass splitting to date. New results are presented in which the data-set is doubled. Further analysis improvements, and the inclusion of additional event samples, further improve the sensitivity to the oscillation parameters. The mixing angle {theta}{sub 13} is currently not measured to differ from zero. By searching for {nu}{sub e} appearance in the {nu}{sub {mu}} beam, MINOS is able to set new limits on the value of {theta}{sub 13}. An observation of the neutral current interaction rate at the far detector allows limits to be placed on the existence of sterile neutrinos. From September 2009 to March 2010, MINOS has taken data with a dedicated {bar {nu}}{sub {mu}} beam, allowing the first direct precision measurement of the antineutrino oscillation parameters in the atmospheric regime.
Date: January 1, 2010
Creator: Evans, Justin & London, /University Coll.
System: The UNT Digital Library
Standard model high mass Higgs search at CDF (open access)

Standard model high mass Higgs search at CDF

The CDF collaboration has analyzed almost 6 f b{sup -1} of data collected at the Tevatron Collider at {radical}{ovr s} = 1.96 TeV to search for Standard Model Higgs boson through the decay into W{sup +}W{sup -}*. Starting from events with two leptons, advanced analysis techniques are applied to better discriminate signal from background. The Higgs sensitivity is maximized combining together analysis that exploit different event topologies. No significant excess over the expected background is observed and data is used to set a limit in units of Standard Model expectations. The limit plays a fundamental role in the Higgs search excluding the existence of this particle with mass between 158 and 175 GeV/c{sup 2} when combined with D0, the other Tevatron experiment.
Date: January 1, 2010
Creator: Lucchesi, Donatella
System: The UNT Digital Library
500 MW X-BAND RF SYSTEM OF A 0.25 GEV ELECTRON LINAC FOR ADVANCED COMPTON SCATTERING SOURCE APPLICATION (open access)

500 MW X-BAND RF SYSTEM OF A 0.25 GEV ELECTRON LINAC FOR ADVANCED COMPTON SCATTERING SOURCE APPLICATION

A Mono-Energetic Gamma-Ray (MEGa-Ray) Compton scattering light source is being developed at LLNL in collaboration with SLAC National Accelerator Laboratory. The electron beam for the Compton scattering interaction will be generated by a X-band RF gun and a X-band LINAC at the frequency of 11.424 GHz. High power RF in excess of 500 MW is needed to accelerate the electrons to energy of 250 MeV or greater for the interaction. Two high power klystron amplifiers, each capable of generating 50 MW, 1.5 msec pulses, will be the main high power RF sources for the system. These klystrons will be powered by state of the art solid-state high voltage modulators. A RF pulse compressor, similar to the SLED II pulse compressor, will compress the klystron output pulse with a power gain factor of five. For compactness consideration, we are looking at a folded waveguide setup. This will give us 500 MW at output of the compressor. The compressed pulse will then be distributed to the RF gun and to six traveling wave accelerator sections. Phase and amplitude control are located at the RF gun input and additional control points along the LINAC to allow for parameter control during operation. This high …
Date: May 12, 2010
Creator: Chu, T S; Anderson, S G; Gibson, D J; Hartemann, F V; Marsh, R A; Siders, C et al.
System: The UNT Digital Library
Nodal Diffusion Burnable Poison Treatment for Prismatic Reactor Cores (open access)

Nodal Diffusion Burnable Poison Treatment for Prismatic Reactor Cores

The prismatic block version of the High Temperature Reactor (HTR) considered as a candidate Very High Temperature Reactor (VHTR)design may use burnable poison pins in locations at some corners of the fuel blocks (i.e., assembly equivalent structures). The presence of any highly absorbing materials, such as these burnable poisons, within fuel blocks for hexagonal geometry, graphite-moderated High Temperature Reactors (HTRs) causes a local inter-block flux depression that most nodal diffusion-based method have failed to properly model or otherwise represent. The location of these burnable poisons near vertices results in an asymmetry in the morphology of the assemblies (or blocks). Hence the resulting inadequacy of traditional homogenization methods, as these “spread” the actually local effect of the burnable poisons throughout the assembly. Furthermore, the actual effect of the burnable poison is primarily local with influence in its immediate vicinity, which happens to include a small region within the same assembly as well as similar regions in the adjacent assemblies. Traditional homogenization methods miss this artifact entirely. This paper presents a novel method for treating the local effect of the burnable poison explicitly in the context of a modern nodal method.
Date: October 1, 2010
Creator: Ougouag, A. M. & Ferrer, R. M.
System: The UNT Digital Library
Progress of Bep Treatments on Nb at JLAB (open access)

Progress of Bep Treatments on Nb at JLAB

Recent experimental results have indicated that Buffered Electropolishing (BEP) is a promising candidate for the next generation of surface treatment technique for Nb superconducting radio frequency (SRF) cavities to be used in particle accelerators. In order to lay the foundation for using BEP as the next generation surface treatment technique for Nb SRF cavities, some fundamental aspects of BEP treatments for Nb have to be investigated. In this report, recent progress on BEP study at JLab is shown. Improvements on the existing vertical BEP are made to allow water cooling from outside of a Nb single cell cavity in addition to cooling provided by acid circulation so that the temperature of the cavity can be stable during processing. Some investigation on the electrolyte mixture was performed to check the aging effect of the electrolyte. It is shown that good polishing results can still be obtained on Nb at a current density of 171 mA/cm when the BEP electrolyte was at the stationary condition and was more than 1.5 years old.
Date: May 1, 2010
Creator: A.T. Wu, S. Jin, R.A. Rimmer,X.Y. Lu, K. Zhao
System: The UNT Digital Library
ESTABLISHING FINAL END STATE FOR A RETIRED NUCLEAR WEAPONS PRODUCTION REACTOR; COLLABORATION BETWEEN STAKEHOLDERS, REGULATORS, AND THE FEDERAL GOVERNMENT - 11052 (open access)

ESTABLISHING FINAL END STATE FOR A RETIRED NUCLEAR WEAPONS PRODUCTION REACTOR; COLLABORATION BETWEEN STAKEHOLDERS, REGULATORS, AND THE FEDERAL GOVERNMENT - 11052

The Savannah River Site (SRS) is a 310-square-mile United States Department of Energy nuclear facility located along the Savannah River (SRS) near Aiken, South Carolina. Nuclear weapons material production began in the early 1950s, utilizing five production reactors. In the early 1990s all SRS production reactor operations were terminated. The first reactor closure end state declaration was recently institutionalized in a Comprehensive Environmental Response and Compensation and Liability Act (CERCLA) Early Action Record of Decision. The decision for the final closure of the 318,000 square foot 105-P Reactor was determined to be in situ decommissioning (ISD). ISD is an acceptable and cost effective alternative to off-site disposal for the reactor building, which will allow for consolidation of remedial action wastes generated from other cleanup activities within the P Area. ISD is considered protective by the regulators, U. S. Environmental Protection Agency (US EPA) and the South Carolina Department of Health and Environmental Control (SCDHEC), public and stakeholders as waste materials are stabilized/immobilized, and radioactivity is allowed to naturally decay, thus preventing future exposure to the environment. Stakeholder buy-in was critical in the upfront planning in order to achieve this monumental final decision. Numerous public meetings and workshops were held in …
Date: November 17, 2010
Creator: Bergren, C.; Flora, M. & Belencan, H.
System: The UNT Digital Library
Optical Sideband Generation: a Longitudinal Electron Beam Diagnostic Beyond the Laser Bandwidth Resolution Limit (open access)

Optical Sideband Generation: a Longitudinal Electron Beam Diagnostic Beyond the Laser Bandwidth Resolution Limit

Electro-optic sampling (EOS) is widely used as a technique to measure THz-domain electric field pulses such asthe self-fields of femtosecond electron beams. We present an EOS-based approach for single-shot spectral measurement that excels in simplicity (compatible with fiber integration) and bandwidth coverage (overcomes the laser bandwidth limitation), allowing few-fs electron beams or single-cycle THz pulses to be characterized with conventional picosecond probes. It is shown that the EOS-induced optical sidebands on the narrow-bandwidth optical probe are spectrally-shifted replicas of the THz pulse. An experimental demonstration on a 0-3 THz source is presented.
Date: June 1, 2010
Creator: Laboratory, Lawrence Berkeley National; Tilborg, J. van; Matlis, N. H.; Plateau, G. R. & Leemans, W. P.
System: The UNT Digital Library
Recent Developments on ALICE (Accelerators and Lasers In Combined Experiments) at Daresbury Laboratory (open access)

Recent Developments on ALICE (Accelerators and Lasers In Combined Experiments) at Daresbury Laboratory

Progress made in ALICE (Accelerators and Lasers In Combined Experiments) commissioning and a summary of the latest experimental results are presented in this paper. After an extensive work on beam loading effects in SC RF linac (booster) and linac cavities conditioning, ALICE can now operate in full energy recovery mode at the bunch charge of 40pC, the beam energy of 30MeV and train lengths of up to 100us. This improved operation of the machine resulted in generation of coherently enhanced broadband THz radiation with the energy of several tens of uJ per pulse and in successful demonstration of the Compton Backscattering x-ray source experiment. The next steps in the ALICE scientific programme are commissioning of the IR FEL and start of the research on the first non-scaling FFAG accelerator EMMA. Results from both projects will be also reported.
Date: May 1, 2010
Creator: Saveliev, Y. M.; Buckley, R. K.; Buckley, S. R.; Clarke, J. A.; Corlett, P. A.; Dunning, D. J. et al.
System: The UNT Digital Library
A luminescent nanocrystal stress gauge (open access)

A luminescent nanocrystal stress gauge

Microscale mechanical forces can determine important outcomes ranging from the site of material fracture to stem cell fate. However, local stresses in a vast majority of systems cannot be measured due to the limitations of current techniques. In this work, we present the design and implementation of the CdSe/CdS core/shell tetrapod nanocrystal, a local stress sensor with bright luminescence readout. We calibrate the tetrapod luminescence response to stress, and use the luminescence signal to report the spatial distribution of local stresses in single polyester fibers under uniaxial strain. The bright stress-dependent emission of the tetrapod, its nanoscale size, and its colloidal nature provide a unique tool that may be incorporated into a variety of micromechanical systems including materials and biological samples to quantify local stresses with high spatial resolution.
Date: October 25, 2010
Creator: Choi, Charina; Koski, Kristie; Olson, Andrew & Alivisatos, Paul
System: The UNT Digital Library
Post-Shot Radiation Environment Following Low-Yield Shots Inside the National Ignition Facility (open access)

Post-Shot Radiation Environment Following Low-Yield Shots Inside the National Ignition Facility

A detailed model of the Target Bay (TB) at the National Ignition Facility (NIF) has been developed to estimate the post-shot radiation environment inside the facility. The model includes large number of structures and diagnostic instruments present inside the TB. These structures and instruments are activated by the few nanosecond pulse of neutrons generated during a shot and the resultant gamma dose rates are estimated at various decay times following the shot. The results presented in this paper are based on a low-yield D-T shot of 10{sup 16} neutrons. General environment dose rates drop to below 3 mrem/h within three hours following a shot with higher dose rates observed at contact with some of the components. Dose rate maps of the different TB levels were generated to aid in estimating worker stay-out times following a shot before entry is permitted into the TB.
Date: October 29, 2010
Creator: Sitaraman, S.; Brereton, S.; Dauffy, L.; Hall, J.; Hansen, L.; Khater, H. et al.
System: The UNT Digital Library
Analysis of biostimulated microbial communities from two field experiments reveals temporal and spatial differences in proteome profiles (open access)

Analysis of biostimulated microbial communities from two field experiments reveals temporal and spatial differences in proteome profiles

Stimulated by an acetate-amendment field experiment conducted in 2007, anaerobic microbial populations in the aquifer at the Rifle Integrated Field Research Challenge site in Colorado reduced mobile U(VI) to insoluble U(IV). During this experiment, planktonic biomass was sampled at various time points to quantitatively evaluate proteomes. In 2008, an acetate-amended field experiment was again conducted in a similar manner to the 2007 experiment. As there was no comprehensive metagenome sequence available for use in proteomics analysis, we systematically evaluated 12 different organism genome sequences to generate sets of aggregate genomes, or “pseudo-metagenomes”, for supplying relative quantitative peptide and protein identifications. Proteomics results support previous observations of the dominance of Geobacteraceae during biostimulation using acetate as sole electron donor, and revealed a shift from an early stage of iron reduction to a late stage of iron reduction. Additionally, a shift from iron reduction to sulfate reduction was indicated by changes in the contribution of proteome information contributed by different organism genome sequences within the aggregate set. In addition, the comparison of proteome measurements made between the 2007 field experiment and 2008 field experiment revealed differences in proteome profiles. These differences may be the result of alterations in abundance and population structure …
Date: July 15, 2010
Creator: Callister, S. J.; Wilkins, M. J.; Nicora, C. D.; Williams, K. H.; Banfield, J. F.; VerBerkmoes, N. C. et al.
System: The UNT Digital Library
Dynamics of microbial community composition and function during in-situ bioremediation of a uranium-contaminated aquifer (open access)

Dynamics of microbial community composition and function during in-situ bioremediation of a uranium-contaminated aquifer

A pilot-scale system was established to examine the feasibility of in situ U(VI) immobilization at a highly contaminated aquifer (U.S. DOE Integrated Field Research Challenge site, Oak Ridge, TN). Ethanol was injected intermittently as an electron donor to stimulate microbial U(VI) reduction, and U(VI) concentrations fell to below the Environmental Protection Agency drinking water standard (0.03 mg liter{sup -1}). Microbial communities from three monitoring wells were examined during active U(VI) reduction and maintenance phases with GeoChip, a high-density, comprehensive functional gene array. The overall microbial community structure exhibited a considerable shift over the remediation phases examined. GeoChip-based analysis revealed that Fe(III)-reducing bacterial (FeRB), nitrate-reducing bacterial (NRB), and sulfate-reducing bacterial (SRB) functional populations reached their highest levels during the active U(VI) reduction phase (days 137 to 370), in which denitrification and Fe(III) and sulfate reduction occurred sequentially. A gradual decrease in these functional populations occurred when reduction reactions stabilized, suggesting that these functional populations could play an important role in both active U(VI) reduction and maintenance of the stability of reduced U(IV). These results suggest that addition of electron donors stimulated the microbial community to create biogeochemical conditions favorable to U(VI) reduction and prevent the reduced U(IV) from reoxidation and that …
Date: August 15, 2010
Creator: Van Nostrand, J. D.; Wu, L.; Wu, W. M.; Huang, A.; Gentry, T. J.; Deng, Y. et al.
System: The UNT Digital Library
Sources and transport systems for low energy extreme of ion implantation (open access)

Sources and transport systems for low energy extreme of ion implantation

For the past seven years a joint research and development effort focusing on the design of steady state, intense ion sources has been in progress with the ultimate goal being to meet the two, energy extreme range needs of mega-electron-volt and 100's of electron-volt ion implanters. However, since the last Fortier is low energy ion implantation, focus of the endeavor has shifted to low energy ion implantation. For boron cluster source development, we started with molecular ions of decaborane (B{sub 10}H{sub 14}), octadecaborane (B{sub 18}H{sub 22}), and presently our focus is on carborane (C{sub 2}B{sub 10}H{sub 12}) ions developing methods for mitigating graphite deposition. Simultaneously, we are developing a pure boron ion source (without a working gas) that can form the basis for a novel, more efficient, plasma immersion source. Our Calutron-Berna ion source was converted into a universal source capable of switching between generating molecular phosphorous P{sub 4}{sup +}, high charge state ions, as well as other types of ions. Additionally, we have developed transport systems capable of transporting a very large variety of ion species, and simulations of a novel gasless/plasmaless ion beam deceleration method were also performed.
Date: June 6, 2010
Creator: Hershcovitch, A.; Batalin, V. A.; Bugaev, A. S.; Gushenets, V. I.; Alexeyenko, O.; Gurkova, E. et al.
System: The UNT Digital Library
Hydrogen Bonding Under High-Pressure (open access)

Hydrogen Bonding Under High-Pressure

None
Date: March 12, 2010
Creator: Manaa, M R & Fried, L E
System: The UNT Digital Library
Speciation of Heptavalent Technetium in Sulfuric Acid: Structural and Spectroscopic Studies. (open access)

Speciation of Heptavalent Technetium in Sulfuric Acid: Structural and Spectroscopic Studies.

The speciation of Tc(VII) in 12 M sulfuric acid was studied by NMR, UV-visible and XAFS spectroscopy, experimental results were supported by DFT calculation and were in agreement with the formation of TcO{sub 3}OH(H{sub 2}O){sub 2}. In summary, the speciation of heptvalent technetium has been investigated in sulfuric acid. In 12 M H{sub 2}SO{sub 4}, a yellow solution is observed, and its {sup 99}Tc NMR spectrum is consistent with a heptavalent complex. The yellow solution was further characterized by EXAFS spectroscopy, and results are consistent with the formation of TcO{sub 3}(OH)(H{sub 2}O){sub 2}. No technetium heptoxide or sulfato- complexes were detected in these conditions. The molecular structure of TcO{sub 3}(OH)(H{sub 2}O){sub 2} has been optimized by DFT techniques, and the structural parameters are well in accordance with those found by XAFS spectroscopy. The experimental electronic spectra exhibit ligand-to-metal charge transfer transitions that have been assigned using TDDFT methods. Calculations demonstrate the theoretical electronic spectrum of TcO{sub 3}(OH)(H{sub 2}O){sub 2} to be in very good agreement with the experimental one. Recent experiments in 12 M H{sub 2}SO{sub 4} show the yellow solution to be very reactive in presence of reducing agents presumably forming low valent Tc species. Current spectroscopic works focus …
Date: June 10, 2010
Creator: Poineau, Frederic; Weck, Philippe F.; German, Konstantin; Maruk, Alesya; Kirakosyan, Gayane; Lukens, Wayne et al.
System: The UNT Digital Library
High Power Picosecond Laser Pulse Recirculation (open access)

High Power Picosecond Laser Pulse Recirculation

We demonstrate a nonlinear crystal-based short pulse recirculation cavity for trapping the second harmonic of an incident high power laser pulse. This scheme aims to increase the efficiency and flux of Compton-scattering based light sources. We demonstrate up to 36x average power enhancement of frequency doubled sub-millijoule picosecond pulses, and 17x average power enhancement of 177 mJ, 10 ps, 10 Hz pulses.
Date: April 12, 2010
Creator: Shverdin, M Y; Jovanovic, I; Semenov, V A; Betts, S M; Brown, C; Gibson, D J et al.
System: The UNT Digital Library
Validation of two ribosomal RNA removal methods for microbial metatranscriptomics (open access)

Validation of two ribosomal RNA removal methods for microbial metatranscriptomics

The predominance of rRNAs in the transcriptome is a major technical challenge in sequence-based analysis of cDNAs from microbial isolates and communities. Several approaches have been applied to deplete rRNAs from (meta)transcriptomes, but no systematic investigation of potential biases introduced by any of these approaches has been reported. Here we validated the effectiveness and fidelity of the two most commonly used approaches, subtractive hybridization and exonuclease digestion, as well as combinations of these treatments, on two synthetic five-microorganism metatranscriptomes using massively parallel sequencing. We found that the effectiveness of rRNA removal was a function of community composition and RNA integrity for these treatments. Subtractive hybridization alone introduced the least bias in relative transcript abundance, whereas exonuclease and in particular combined treatments greatly compromised mRNA abundance fidelity. Illumina sequencing itself also can compromise quantitative data analysis by introducing a G+C bias between runs.
Date: October 1, 2010
Creator: He, Shaomei; Wurtzel, Omri; Singh, Kanwar; Froula, Jeff L; Yilmaz, Suzan; Tringe, Susannah G et al.
System: The UNT Digital Library
Mechanism of Thermal Reversal of the (Fulvalene)tetracarbonyldiruthenium Photoisomerization: Toward Molecular Solar-Thermal Energy Storage (open access)

Mechanism of Thermal Reversal of the (Fulvalene)tetracarbonyldiruthenium Photoisomerization: Toward Molecular Solar-Thermal Energy Storage

In the currently intensifying quest to harness solar energy for the powering of our planet, most efforts are centered around photoinduced generic charge separation, such as in photovoltaics, water splitting, other small molecule activation, and biologically inspired photosynthetic systems. In contrast, direct collection of heat from sunlight has received much less diversified attention, its bulk devoted to the development of concentrating solar thermal power plants, in which mirrors are used to focus the sun beam on an appropriate heat transfer material. An attractive alternative strategy would be to trap solar energy in the form of chemical bonds, ideally through the photoconversion of a suitable molecule to a higher energy isomer, which, in turn, would release the stored energy by thermal reversal. Such a system would encompass the essential elements of a rechargeable heat battery, with its inherent advantages of storage, transportability, and use on demand. The underlying concept has been explored extensively with organic molecules (such as the norbornadiene-quadricyclane cycle), often in the context of developing photoswitches. On the other hand, organometallic complexes have remained relatively obscure in this capacity, despite a number of advantages, including expanded structural tunability and generally favorable electronic absorption regimes. A highly promising organometallic system …
Date: February 18, 2010
Creator: Kanai, Y; Srinivasan, V; Meier, S K; Vollhardt, K P & Grossman, J C
System: The UNT Digital Library
Integrated Chamber Design for the Laser Inertial Fusion Energy (LIFE) Engine (open access)

Integrated Chamber Design for the Laser Inertial Fusion Energy (LIFE) Engine

The Laser Inertial Fusion Energy (LIFE) concept is being designed to operate as either a pure fusion or hybrid fusion-fission system. A key component of a LIFE engine is the fusion chamber subsystem. The present work details the chamber design for the pure fusion option. The fusion chamber consists of the first wall and blanket. This integrated system must absorb the fusion energy, produce fusion fuel to replace that burned in previous targets, and enable both target and laser beam transport to the ignition point. The chamber system also must mitigate target emissions, including ions, x-rays and neutrons and reset itself to enable operation at 10-15 Hz. Finally, the chamber must offer a high level of availability, which implies both a reasonable lifetime and the ability to rapidly replace damaged components. An integrated LIFE design that meets all of these requirements is described herein.
Date: December 7, 2010
Creator: Latkowski, J. F.; Kramer, K. J.; Abbott, R. P.; Morris, K. R.; DeMuth, J.; Divol, L. et al.
System: The UNT Digital Library