The IceTop air shower array now under construction at the South Pole as the surface component of the IceCube neutrino telescope (Achterberg et al. 2006) detected an unusual near-solar-minimum Ground Level Enhancement (GLE) after a solar flare on 13 December 2006. Beginning at 0220 UT, the 4B class flare occurred at solar coordinates S06 W24, accompanied by strong (X3.4) X-ray emission and type II and IV radio bursts. The LASCO coronagraph on the SOHO spacecraft observed a halo CME launch from the Sun at {approx} 0225 UT with speed estimated to be {approx} 1770 km/s. We have begun (Bieber et al. 2007) a comprehensive analysis of the propagation of solar energetic particles in this event. However the focus of this Letter is the new and unique ability of IceTop to derive the energy spectrum of these particles in the multi-GeV regime from a single detector with a well defined viewing direction. When completed, IceTop will have approximately 500 square meters of ice Cherenkov collecting area arranged in an array of 80 stations on a 125 m triangular grid to detect air showers from one PeV to one EeV. Each station consists of two, two meter diameter tanks filled with ice …