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4-D XRD for strain in many grains using triangulation (open access)

4-D XRD for strain in many grains using triangulation

Determination of the strains in a polycrystalline materialusing 4-D XRD reveals sub-grain and grain-to-grain behavior as a functionof stress. Here 4-D XRD involves an experimental procedure usingpolychromatic micro-beam X-radiation (micro-Laue) to characterizepolycrystalline materials in spatial location as well as with increasingstress. The in-situ tensile loading experiment measured strain in a modelaluminum-sapphire metal matrix composite using the Advanced Light Source,Beam-line 7.3.3. Micro-Laue resolves individual grains in thepolycrystalline matrix. Results obtained from a list of grains sorted bycrystallographic orientation depict the strain states within and amongindividual grains. Locating the grain positions in the planeperpendicular to the incident beam is trivial. However, determining theexact location of grains within a 3-D space is challenging. Determiningthe depth of the grains within the matrix (along the beam direction)involved a triangulation method tracing individual rays that producespots on the CCD back to the point of origin. Triangulation wasexperimentally implemented by simulating a 3-D detector capturingmultiple diffraction images while increasing the camera to sampledistance. Hence by observing the intersection of rays from multiple spotsbelonging to the corresponding grain, depth is calculated. Depthresolution is a function of the number of images collected, grain to beamsize ratio, and the pixel resolution of the CCD. The 4DXRD methodprovides grain morphologies, strain …
Date: December 31, 2006
Creator: Bale, Hrishikesh A.; Hanan, Jay C. & Tamura, Nobumichi
Object Type: Article
System: The UNT Digital Library
2003 Climate Change Fuel Cell Buy-Down Program (open access)

2003 Climate Change Fuel Cell Buy-Down Program

The Student Apartments Fuel Cell Island Project consists of three (3) 200 kW phosphoric acid fuel cells located in conjunction with three (3) student apartment buildings, each housing 200 students. The Final Report contains limited data because the fuel cells were started up November 2005 and shutdown March 2006. The price of natural gas, which is the primary fuel for the fuel cells, escalated by 200% following hurricane Katrina in August 2005. This escalation in natural gas price made operation of the fuel cells economically unviable, i.e., the cost to produce electricity with the fuel cells far exceeded the cost to purchase electricity from the utility. The College intends to restart the fuel cells once the cost of natural gas stabilizes. The natural gas futures market is currently overpriced even though fundamentally the physical inventory is a five year high. We believe the natural gas market will eventually correct to the fundamentals and drive the cost down. Once this occurs we will restart the fuel cells.
Date: December 31, 2006
Creator: Winyard, Lori K.
Object Type: Report
System: The UNT Digital Library
The ^2H(e,e'p)n Reaction at High Four-Momentum Transfer (open access)

The ^2H(e,e'p)n Reaction at High Four-Momentum Transfer

This dissertation presents the highest four-momentum transfer, Q^2,quasielastic (x_Bj = 1) results from Experiment E01-020 which systematically explored the 2He(e,e'p)n reaction ("Electro-disintegration" of the deuteron) at three different four-momentum transfers, Q^2 = 0.8, 2.1, and 3.5 GeV^2 and missing momenta, P_miss = 0, 100, 200, 300, 400, and 500 GeV including separations of the longitudinal-transverse interference response function, R_LT, and extractoin of the longitudinal-transverse asymmetry, A_LT. This systematic approach will help to understand the reaction mechanism and the deuteron structure down to the short range part of the nucleon-nucleon interaction which is one of the fundamental missions of nuclear physics. By studying the very short distance structure of the deuteron, one may also determine whether or to what extent the description of nuclei in terms of nucleon/meson degrees of freedom must be supplemented by inclusion of explicit quark effects. The unique combination of energy, current, duty factor, and control of systematics for Hall A at Jefferson Lab made Jefferson Lab the only facility in the world where these systematic studies of the deuteron can be undertaken. This is especially true when we want to understand the short range structure of the deuteron where high energies and high luminosity/duty factor are …
Date: December 31, 2006
Creator: Ibrahim, Hassan
Object Type: Thesis or Dissertation
System: The UNT Digital Library
Achieving New Source Performance Standards (NSPS) Emission Standards Through Integration of Low-NOx Burners with an Optimization Plan for Boiler Combustion (open access)

Achieving New Source Performance Standards (NSPS) Emission Standards Through Integration of Low-NOx Burners with an Optimization Plan for Boiler Combustion

The objective of this project was to demonstrate the use of an Integrated Combustion Optimization System to achieve NO{sub X} emission levels in the range of 0.15 to 0.22 lb/MMBtu while simultaneously enabling increased power output. The project plan consisted of the integration of low-NO{sub X} burners and advanced overfire air technology with various process measurement and control devices on the Holcomb Station Unit 1 boiler. The plan included the use of sophisticated neural networks or other artificial intelligence technologies and complex software to optimize several operating parameters, including NO{sub X} emissions, boiler efficiency, and CO emissions. The program was set up in three phases. In Phase I, the boiler was equipped with sensors that can be used to monitor furnace conditions and coal flow to permit improvements in boiler operation. In Phase II, the boiler was equipped with burner modifications designed to reduce NO{sub X} emissions and automated coal flow dampers to permit on-line fuel balancing. In Phase III, the boiler was to be equipped with an overfire air system to permit deep reductions in NO{sub X} emissions. Integration of the overfire air system with the improvements made in Phases I and II would permit optimization of boiler performance, …
Date: December 31, 2006
Creator: Penrod, Wayne
Object Type: Report
System: The UNT Digital Library
Advanced Measurement and Modeling Techniques for Improved SOFC Cathodes (open access)

Advanced Measurement and Modeling Techniques for Improved SOFC Cathodes

The goal of this project was to develop an improved understanding of factors governing performance and degradation of mixed-conducting SOFC cathodes. Two new diagnostic tools were developed to help achieve this goal: (1) microelectrode half-cells for improved isolation of cathode impedance on thin electrolytes, and (2) nonlinear electrochemical impedance spectroscopy (NLEIS), a variant of traditional impedance that allows workers to probe nonlinear rates as a function of frequency. After reporting on the development and efficacy of these tools, this document reports on the use of these and other tools to better understand performance and degradation of cathodes based on the mixed conductor La{sub 1-x}Sr{sub x}CoO{sub 3-{delta}} (LSC) on gadolinia or samaria-doped ceria (GDC or SDC). We describe the use of NLEIS to measure O{sub 2} exchange on thin-film LSC electrodes, and show that O{sub 2} exchange is most likely governed by dissociative adsorption. We also describe parametric studies of porous LSC electrodes using impedance and NLEIS. Our results suggest that O{sub 2} exchange and ion transport co-limit performance under most relevant conditions, but it is O{sub 2} exchange that is most sensitive to processing, and subject to the greatest degradation and sample-to-sample variation. We recommend further work that focuses on …
Date: December 31, 2006
Creator: Adler, Stuart; Dunyushkina, L.; Huff, S.; Lu, Y. & Wilson, J.
Object Type: Report
System: The UNT Digital Library
Advanced Multi-Product Coal Utilization By-Product Processing Plant (open access)

Advanced Multi-Product Coal Utilization By-Product Processing Plant

The objective of the project is to build a multi-product ash beneficiation plant at Kentucky Utilities 2,200-MW Ghent Generating Station, located in Carroll County, Kentucky. This part of the study includes an investigation of the secondary classification characteristics of the ash feedstock excavated from the lower ash pond at Ghent Station. The market study for the products of the processing plant (Subtask 1.6), conducted by Cemex, is reported herein. The study incorporated simplifying assumptions and focused only on pozzolan and ultra fine fly ash (UFFA). It found that the market for pozzolan in the Ghent area was oversupplied, with resultant poor pricing structure. Reachable export markets for the Ghent pozzolan market were mostly locally served with the exception of Florida. It was concluded that a beneficiated material for that market may be at a long term disadvantage. The market for the UFFA was more complex as this material would compete with other beneficiated ash and potential metakaolin and silica fume as well. The study concluded that this market represented about 100,000 tons of sales per year and, although lucrative, represented a widely dispersed niche market.
Date: December 31, 2006
Creator: Jackura, Andrew; Groppo, John & Robl, Thomas
Object Type: Report
System: The UNT Digital Library
The Altus Times (Altus, Okla.), Vol. 108, No. 235, Ed. 1 Sunday, December 31, 2006 (open access)

The Altus Times (Altus, Okla.), Vol. 108, No. 235, Ed. 1 Sunday, December 31, 2006

Daily newspaper from Altus, Oklahoma that includes local, state, and national news along with advertising.
Date: December 31, 2006
Creator: Bush, Michael
Object Type: Newspaper
System: The Gateway to Oklahoma History
Amended Silicated for Mercury Control (open access)

Amended Silicated for Mercury Control

Amended Silicates{trademark}, a powdered, noncarbon mercury-control sorbent, was tested at Duke Energy's Miami Fort Station, Unit 6 during the first quarter of 2006. Unit 6 is a 175-MW boiler with a cold-side electrostatic precipitator (ESP). The plant burns run-of-the-river eastern bituminous coal with typical ash contents ranging from 8-15% and sulfur contents from 1.6-2.6% on an as-received basis. The performance of the Amended Silicates sorbent was compared with that for powdered activated carbon (PAC). The trial began with a period of baseline monitoring during which no sorbent was injected. Sampling during this and subsequent periods indicated mercury capture by the native fly ash was less than 10%. After the baseline period, Amended Silicates sorbent was injected at several different ratios, followed by a 30-day trial at a fixed injection ratio of 5-6 lb/MMACF. After this period, PAC was injected to provide a comparison. Approximately 40% mercury control was achieved for both the Amended Silicates sorbent and PAC at injection ratios of 5-6 lbs/MMACF. Higher injection ratios did not achieve significantly increased removal. Similar removal efficiencies have been reported for PAC injection trials at other plants with cold-side ESPs, most notably for plants using medium to high sulfur coal. Sorbent injection …
Date: December 31, 2006
Creator: Butz, James; Broderick, Thomas & Turchi, Craig
Object Type: Report
System: The UNT Digital Library
Application and Development of Appropriate Tools and Technologies for Cost-Effective Carbon Sequestration (open access)

Application and Development of Appropriate Tools and Technologies for Cost-Effective Carbon Sequestration

The Nature Conservancy is participating in a Cooperative Agreement with the Department of Energy (DOE) National Energy Technology Laboratory (NETL) to explore the compatibility of carbon sequestration in terrestrial ecosystems and the conservation of biodiversity. The title of the research project is ''Application and Development of Appropriate Tools and Technologies for Cost-Effective Carbon Sequestration''. The objectives of the project are to: (1) improve carbon offset estimates produced in both the planning and implementation phases of projects; (2) build valid and standardized approaches to estimate project carbon benefits at a reasonable cost; and (3) lay the groundwork for implementing cost-effective projects, providing new testing ground for biodiversity protection and restoration projects that store additional atmospheric carbon. This Technical Progress Report discusses preliminary results of the six specific tasks that The Nature Conservancy is undertaking to answer research needs while facilitating the development of real projects with measurable greenhouse gas reductions. The research described in this report occurred between October 1st and December 31st 2006. The specific tasks discussed include: Task 1: carbon inventory advancements; Task 2: emerging technologies for remote sensing of terrestrial carbon; Task 3: baseline method development; Task 4: third-party technical advisory panel meetings; Task 5: new project feasibility …
Date: December 31, 2006
Creator: Stanley, Bill; Brown, Sandra; Gonzalez, Patrick; Sohngen, Brent; Sampson, Neil; Anderson, Mark et al.
Object Type: Report
System: The UNT Digital Library
Basin Analysis and Petroleum System Characterization and Modeling, Interior Salt Basins, Central and Eastern Gulf of Mexico (open access)

Basin Analysis and Petroleum System Characterization and Modeling, Interior Salt Basins, Central and Eastern Gulf of Mexico

The principal research effort for Year 1 of Phase 2 (Concept Demonstration) of the project is Smackover petroleum system characterization and modeling. The necessary software applications have been acquired to accomplish this work. No major problems have been encountered to date, and the project is on schedule.
Date: December 31, 2006
Creator: Mancini, Ernest A.
Object Type: Report
System: The UNT Digital Library
The Baytown Sun (Baytown, Tex.), Vol. 86, No. 35, Ed. 1 Sunday, December 31, 2006 (open access)

The Baytown Sun (Baytown, Tex.), Vol. 86, No. 35, Ed. 1 Sunday, December 31, 2006

Daily newspaper from Baytown, Texas that includes local, state, and national news along with advertising.
Date: December 31, 2006
Creator: Clements, Clifford E.
Object Type: Newspaper
System: The Portal to Texas History
Beam Intensity Expectations for a 200 Mev/U 400 KW Radioactive Beam Driver Accelerator. (open access)

Beam Intensity Expectations for a 200 Mev/U 400 KW Radioactive Beam Driver Accelerator.

The expected radioactive ion production rate for a 200 MeV/u 400 kW driver linac using four different production methods is discussed. For each isotope the optimum method is identified and the rate is calculated based on different model assumptions, empirical observation and extrapolations. The results are compared to the rates expected for a 550 MeV proton driver machine with a beam power of 50 kW, as well as the full RIA facility with a 400 MeV/u 400 kW production linac.
Date: December 31, 2006
Creator: Back, B. B.; Jiang, C. L. & Physics
Object Type: Report
System: The UNT Digital Library
China-U.S. Relations in the 109th Congress (open access)

China-U.S. Relations in the 109th Congress

This report discusses the U.S. concern about China that appeared driven by security calculation at the Pentagon and in congress. It also points out key issues, Hong Kong Governance and Major Legislation.
Date: December 31, 2006
Creator: Dumbaugh, Kerry
Object Type: Report
System: The UNT Digital Library
CO2 Capture by Absorption with Potassium Carbonate (open access)

CO2 Capture by Absorption with Potassium Carbonate

The objective of this work is to improve the process for CO{sub 2} capture by alkanolamine absorption/stripping by developing an alternative solvent, aqueous K{sub 2}CO{sub 3} promoted by piperazine. The best solvent and process configuration, matrix with MDEA/PZ, offers 22% and 15% energy savings over the baseline and improved baseline, respectively, with stripping and compression to 10 MPa. The energy requirement for stripping and compression to 10 MPa is about 20% of the power output from a 500 MW power plant with 90% CO{sub 2} removal. The stripper rate model shows that a ''short and fat'' stripper requires 7 to 15% less equivalent work than a ''tall and skinny'' one. The stripper model was validated with data obtained from pilot plant experiments at the University of Texas with 5m K{sup +}/2.5m PZ and 6.4m K{sup +}/1.6m PZ under normal pressure and vacuum conditions using Flexipac AQ Style 20 structured packing. Experiments with oxidative degradation at low gas rates confirm the effects of Cu{sup +2} catalysis; in MEA/PZ solutions more formate and acetate is produced in the presence of Cu{sup +2}. At 150 C, the half life of 30% MEA with 0.4 moles CO{sub 2}/mole amine is about 2 weeks. At …
Date: December 31, 2006
Creator: Rochelle, Gary T.; Chen, Eric; Oyenekan, Babatunde; Sexton, Andrew; Davis, Jason; Hiilliard, Marus et al.
Object Type: Report
System: The UNT Digital Library
Commercial Demonstration of the Manufactured Aggregate Processing Technology Utilizing Spray Dryer Ash (open access)

Commercial Demonstration of the Manufactured Aggregate Processing Technology Utilizing Spray Dryer Ash

Universal Aggregates LLC (UA) was awarded a cost sharing Co-operative Agreement from the Department of Energy (DOE) through the Power Plant Improvement Initiative Program (PPII) to design, construct and operate a lightweight aggregate manufacturing plant at the Birchwood Power Facility in King George, Virginia in October 2001. The Agreement was signed in November 2002. The installation and start-up expenses for the Birchwood Aggregate Facility are $19.5 million. The DOE share is $7.2 million (37%) and the UA share is $12.3 million (63%). The original project team consists of UA, SynAggs, LLC, CONSOL Energy Inc. and P. J. Dick, Inc. Using 115,000 ton per year of spray dryer ash (SDA), a dry FGD by-product from the power station, UA will produce 167,000 tons of manufactured lightweight aggregate for use in production of concrete masonry units (CMU). Manufacturing aggregate from FGD by-products can provide an economical high-volume use and substantially expand market for FGD by-products. Most of the FGD by-products are currently disposed of in landfills. Construction of the Birchwood Aggregate Facility was completed in March 2004. Operation startup was begun in April 2004. Plant Integration was initiated in December 2004. Integration includes mixing, extrusion, curing, crushing and screening. Lightweight aggregates with …
Date: December 31, 2006
Creator: Wu, Milton & Yuran, Paul
Object Type: Report
System: The UNT Digital Library
CONCEPTUAL DESIGN REPORT (open access)

CONCEPTUAL DESIGN REPORT

Brookhaven National Laboratory has prepared a conceptual design for a world class user facility for scientific research using synchrotron radiation. This facility, called the ''National Synchrotron Light Source II'' (NSLS-II), will provide ultra high brightness and flux and exceptional beam stability. It will also provide advanced insertion devices, optics, detectors, and robotics, and a suite of scientific instruments designed to maximize the scientific output of the facility. Together these will enable the study of material properties and functions with a spatial resolution of {approx}1 nm, an energy resolution of {approx}0.1 meV, and the ultra high sensitivity required to perform spectroscopy on a single atom. The overall objective of the NSLS-II project is to deliver a research facility to advance fundamental science and have the capability to characterize and understand physical properties at the nanoscale, the processes by which nanomaterials can be manipulated and assembled into more complex hierarchical structures, and the new phenomena resulting from such assemblages. It will also be a user facility made available to researchers engaged in a broad spectrum of disciplines from universities, industries, and other laboratories.
Date: December 31, 2006
Creator: ROBINSON,K.
Object Type: Report
System: The UNT Digital Library
Consortium for Petroleum & Natural Gas Stripper Wells (open access)

Consortium for Petroleum & Natural Gas Stripper Wells

The Pennsylvania State University, under contract to the U.S. Department of Energy (DOE), National Energy Technology Laboratory (NETL), established a national industry-driven Stripper Well Consortium (SWC) that is focused on improving the production performance of domestic petroleum and/or natural gas stripper wells. The SWC represents a partnership between U.S. petroleum and natural gas producers, trade associations, state funding agencies, academia, and the NETL. This document serves as the eleventh quarterly technical progress report for the SWC. Key activities for this reporting period included: (1) Organizing and hosting the Fall SWC Technology Transfer Workshop for the northeastern U.S., in Pittsburgh, PA, on November 9, 2006, and organizing and identifying projects to exhibit during the SWC/Gas Storage Technology Consortium (GSTC) joint reception on November 8, 2006; (2) Distributing a paper copy of the Texas Tech 2004 Final Report and a revised, complete compact disc of all 2004 final reports; (3) Invoicing current and potential members for FY2007; (4) Soliciting nominations for the 2007-2008 Executive Council seats; and (5) Communications and outreach.
Date: December 31, 2006
Creator: Morrison, Joel L. & Elder, Sharon L.
Object Type: Report
System: The UNT Digital Library
Cost-Effective Method for Producing Self Supported Palladium Alloy Membranes for Use in Efficient Production of Coal Derived Hydrogen (open access)

Cost-Effective Method for Producing Self Supported Palladium Alloy Membranes for Use in Efficient Production of Coal Derived Hydrogen

In the past quarter, no technical work has been completed and two ''no cost'' time extensions have been requested and granted to allow Idatech time to complete Task 5 relating to the testing of prototype membrane modules. The scheduled completion date of April 7, 2007 has been confirmed by Idatech.
Date: December 31, 2006
Creator: Coulter, K.
Object Type: Report
System: The UNT Digital Library
Cost-Effective Reciprocating Engine Emissions Control and Monitoring for E&P Field and Gathering Engines (open access)

Cost-Effective Reciprocating Engine Emissions Control and Monitoring for E&P Field and Gathering Engines

This report highlights work done on a project intended to lower the cost of environmental compliance and expedite project permitting for Exploration and Production (E&P) operators by identifying, developing, testing, and commercializing emissions control and monitoring technologies. Promising technologies have already been identified and developed. Current work focuses on testing these promising technologies. Specifically, several technologies are being tested in the laboratory for application to lean-burn engines or fully characterized on-site for use with rich-burn engines. Upon completion of these tests, the most cost-effective and robust technologies will be tested in the field and commercialization will ensue. During this quarter, progress in laboratory testing for lean-burn engines was limited by maintenance issues on the KSU Ajax DP-115. The difficulties that required maintenance to be performed will likely require that the 180 psig prototype valve be tested in the future, if possible. The maintenance was performed, and it is expected that the Ajax will be available for testing in the coming quarter. Although laboratory testing was slowed as a result of maintenance issues, progress in experimental characterization of technologies has been significant. NSCR systems will be characterized as applied to rich-burn engines on-site. This characterization will ensure high-quality data in final …
Date: December 31, 2006
Creator: Chapman, Kirby S. & Nuss-Warren, Sarah R.
Object Type: Report
System: The UNT Digital Library
Development of a Novel Oxygen Supply Process and its Integration with an Oxy-Fuel Coal-Fired Boiler (open access)

Development of a Novel Oxygen Supply Process and its Integration with an Oxy-Fuel Coal-Fired Boiler

BOC, the world's second largest industrial gas company, has developed a novel high temperature sorption based technology referred to as CAR (Cyclic Autothermal Recovery) for oxygen production and supply to oxy-fuel boilers with flue gas recycle. This technology is based on sorption and storage of oxygen in a fixed bed containing mixed ionic and electronic conductor materials. The objective of the proposed work was to construct a CAR PDU that was capable of producing 10-scfm of oxygen, using steam or recycled flue gas as the sweep gas, and install it in the Combustion Test Facility. The unit was designed and fabricated at BOC/The Linde Group, Murray Hill, New Jersey. The unit was then shipped to WRI where the site had been prepared for the unit by installation of air, carbon dioxide, natural gas, nitrogen, computer, electrical and infrastructure systems. Initial experiments with the PDU consisted of flowing air into both sides of the absorption systems and using the air heaters to ramp up the bed temperatures. The two beds were tested individually to operational temperatures up to 900 C in air. The cycling process was tested where gases are flowed alternatively from the top then bottom of the beds. The …
Date: December 31, 2006
Creator: unknown
Object Type: Report
System: The UNT Digital Library
Development of All-Solid-State Sensors for Measurement of Nitric Oxide and Ammonia Concentrations by Optical Absorption in Particle-Laden Combustion Exhaust Streams (open access)

Development of All-Solid-State Sensors for Measurement of Nitric Oxide and Ammonia Concentrations by Optical Absorption in Particle-Laden Combustion Exhaust Streams

An all-solid-state continuous-wave (cw) laser system for ultraviolet absorption measurements of the nitric oxide (NO) molecule has been developed and demonstrated. For the NO sensor, 250 nW of tunable cw ultraviolet radiation is produced by sum-frequency-mixing of 532-nm radiation from a diode-pumped Nd:YAG laser and tunable 395-nm radiation from an external cavity diode laser (ECDL). The sum-frequency-mixing process occurs in a beta-barium borate crystal. The nitric oxide absorption measurements are performed by tuning the ECDL and scanning the sum-frequency-mixed radiation over strong nitric oxide absorption lines near 226 nm. In Year 1 of the research, the nitric oxide sensor was used for measurements in the exhaust of a coal-fired laboratory combustion facility. The Texas A&M University boiler burner facility is a 30 kW (100,000 Btu/hr) downward-fired furnace with a steel shell encasing ceramic insulation. Measurements of nitric oxide concentration in the exhaust stream were performed after modification of the facility for laser based NOx diagnostics. The diode-laser-based ultraviolet absorption measurements were successful even when the beam was severely attenuated by particulate in the exhaust stream and window fouling. Single-laser-sweep measurements were demonstrated with an effective time resolution of 100 msec, limited at this time by the scan rate of our …
Date: December 31, 2006
Creator: Caton, Jerald A.; Annamalai, Kalyan & Lucht, Robert P.
Object Type: Report
System: The UNT Digital Library
Development of Continuous Solvent Extraction Processes for Coal Derived Carbon Products (open access)

Development of Continuous Solvent Extraction Processes for Coal Derived Carbon Products

This DOE NETL-sponsored effort seeks to develop continuous processes for producing carbon products from solvent-extracted coal. A key process step is removal of solids from liquefied coal. Three different processes were compared: gravity separation, centrifugation using a decanter-type Sharples Pennwalt centrifuge, and a Spinner-II centrifuge. The data suggest that extracts can be cleaned to as low as 0.5% ash level and probably lower using a combination of these techniques.
Date: December 31, 2006
Creator: Kennel, Elliot B.
Object Type: Report
System: The UNT Digital Library
Development of Sensors Using Evanescent Wave Interactions in Sapphire Optical Fibers (open access)

Development of Sensors Using Evanescent Wave Interactions in Sapphire Optical Fibers

The development of tunable diode laser absorption sensors for measurements in industrial boilers, both through direct absorption and evanescent wave absorption have been performed in the work presented here. These sensors use both direct and indirect absorption through the use of evanescent interactions within a coal firing combustion environment. For the direct absorption sensor, wavelength modulation absorption spectroscopy with second-harmonic detection was implemented within a physical probe designed to be placed with the flue stack of a power plant. Measurements were taken of carbon dioxide and water vapor concentration during operation at a local industrial facility. The design of this sensor probe overcomes problems of beam steering and permits a reference gas measurement. Extracted concentration data and design elements from the direct absorption measurements are presented. In addition, development of a sapphire fiber-based sensor using evanescent wave absorption along the outside of the fiber is presented. Evanescent absorption allows for the laser transmission to be maintained in the fiber at all times and may alleviate problems of background emission, beam steering, and especially scattering of the laser beam from solid particles experienced through free path direct absorption measurements in particulated flows. Laboratory measurements using evanescent fiber detection are presented.
Date: December 31, 2006
Creator: Renfro, Michael W. & Jordan, Eric H.
Object Type: Report
System: The UNT Digital Library
Diffusion Coatings for Corrosion-Resistant Components in Coal Gasification Systems (open access)

Diffusion Coatings for Corrosion-Resistant Components in Coal Gasification Systems

Heat-exchangers, particle filters, turbines, and other components in integrated coal gasification combined cycle system must withstand the highly sulfiding conditions of the high-temperature coal gas over an extended period of time. The performance of components degrades significantly with time unless expensive high alloy materials are used. Deposition of a suitable coating on a low-cost alloy may improve its resistance to such sulfidation attack, and decrease capital and operating costs. The alloys used in the gasifier service include austenitic and ferritic stainless steels, nickel-chromium-iron alloys, and expensive nickel-cobalt alloys. During this period, we analyzed several coated and exposed samples of 409 steel by scanning electron microscopy (SEM) and energy-dispersive X-ray (EDX), and report on the findings of four samples: (1) Analysis of two porous coupons after exposure to the porous metal particulate filter of the coal gasification power plant at 370 C for 2140 hours revealed that corrosion takes place in the bulk of the sample while the most external zone surface survived the test. (2) Coating and characterization of several porous 409 steel coupons after being coated with nitrides of Ti, Al and/or Si showed that adjusting experimental conditions results in thicker coatings in the bulk of the sample. (3) …
Date: December 31, 2006
Creator: Krishnan, Gopala N.; Malhotra, Ripudaman; Alvarez, Esperanza; Lau, Kai-Hung; Perez-Mariano, Jordi & Sanjurjo, Angel
Object Type: Report
System: The UNT Digital Library