In this contribution we will describe a technology path to very high quality coatings fabricated in the vacuum of space. To accomplish the ambitious goals set out in NASA's Lunar-Mars proposal, advanced thin-film deposition technology will be required. The ability to deposit thin-film coatings in the vacuum of lunar-space could be extremely valuable for executing this new space mission. Developing lightweight space-based deposition technology (goal:<300 g, including power supply) will enable the future fabrication and repair of flexible large-area space antennae and fixed telescope mirrors for lunar-station observatories. Filtered Cathodic Arc (FCA) is a proven terrestrial energetic thin-film deposition technology that does not need any processing gas but is well suited for ultra-high vacuum operation. Recently, miniaturized cathodic arcs have already been developed and considered for space propulsion. It is proposed to combine miniaturized pulsed FCA technology and robotics to create a robust, enabling space-based deposition system for the fabrication, improvement, and repair of thin films, especially of silver and aluminum, on telescope mirrors and eventually on large area flexible substrates. Using miniature power supplies with inductive storage, the typical low-voltage supply systems used in space are adequate. It is shown that high-value, small area coatings are within the reach …

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This paper investigates the impact of proposed repositorythermal-loading on mountain-scale flow and heat transfer in theunsaturated fractured rock of Yucca Mountain, Nevada. In this context, amodel has been developed to study the coupled thermal-hydrological (TH)processes at the scale of the entire Yucca Mountain. This mountain-scaleTH model implements the current geological framework and hydrogeologicalconceptual models, and incorporates the latest rock thermal andhydrological properties. The TH model consists of a two-dimensionalnorth-south vertical cross section across the entire unsaturated zonemodel domain and uses refined meshes near and around the proposedrepository block, based on the current repository design, drift layout,thermal loading scenario, and estimated current and future climaticconditions. The model simulations provide insights into thermallyaffected liquid saturation, gas- and liquid-phase fluxes, and elevatedwater and rock temperature, which in turn allow modelers to predict thechanges in water flux driven by evaporation/condensation processes, anddrainage between drifts.

Magnetic reconnection in the spheromak changes magnetic topology by conversion of injected toroidal flux into poloidal flux and by magnetic surface closure (or opening) in a slowly decaying spheromak. Results from the Sustained Spheromak Physics Experiment, SSPX, are compared with resistive MHD simulations using the NIMROD code. Voltage spikes on the SSPX gun during spheromak formation are interpreted as reconnection across a negative-current layer close to the mean-field x-point. Field lines are chaotic during these events, resulting in rapid electron energy loss to the walls and the low T{sub e} < 50 eV seen in experiment and simulation during strong helicity injection. Closure of flux surfaces (and high T{sub e}) can occur between voltage spikes if they are sufficiently far apart in time; these topology changes are not reflected in the impedance of the axisymmetric gun. Possible future experimental scenarios in SSPX are examined in the presence of the constraints imposed by reconnection physics.

Cadmium (Cd{sup 2+}), nickel (Ni{sup 2+}) and cobalt (Co{sup 2+}) are human and/or animal carcinogens. Zinc (Zn{sup 2+}) is not categorized as a carcinogen, and rather an essential element to humans. Metals were recently shown to inhibit DNA repair proteins that use metals for their function and/or structure. Here we report that the divalent ions Cd{sup 2+}, Ni{sup 2+}, and Zn{sup 2+} can inhibit the activity of a recombinant human N-methylpurine-DNA glycosylase (MPG) toward a deoxyoligonucleotide with ethenoadenine (var epsilonA). MPG removes a variety of toxic/mutagenic alkylated bases and does not require metal for its catalytic activity or structural integrity. At concentrations starting from 50 to 1000 {micro}M, both Cd{sup 2+} and Zn{sup 2+} showed metal-dependent inhibition of the MPG catalytic activity. Ni{sup 2+} also inhibited MPG, but to a lesser extent. Such an effect can be reversed with EDTA addition. In contrast, Co{sup 2+} and Mg{sup 2+} did not inhibit the MPG activity in the same dose range. Experiments using HeLa cell-free extracts demonstrated similar patterns of inactivation of the var epsilonA excision activity by the same metals. Binding of MPG to the substrate was not significantly affected by Cd{sup 2+}, Zn{sup 2+}, and Ni{sup 2+} at concentrations that …

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The injection and storage of anthropogenic CO2 in deepgeologic formations is a potentially feasible strategy to reduce CO2emissions and atmospheric concentrations. While the purpose of geologiccarbon storage is to trap CO2 underground, CO2 could migrate away fromthe storage site into the shallow subsurface and atmosphere if permeablepathways such as well bores or faults are present. Large-magnitudereleases of CO2 have occurred naturally from geologic reservoirs innumerous volcanic, geothermal, and sedimentary basin settings. Carbondioxide and natural gas have also been released from geologic CO2reservoirs and natural gas storage facilities, respectively, due toinfluences such as well defects and injection/withdrawal processes. Thesesystems serve as natural and industrial analogues for the potentialrelease of CO2 from geologic storage reservoirs and provide importantinformation about the key features, events, and processes (FEPs) that areassociated with releases, as well as the health, safety, andenvironmental consequences of releases and mitigation efforts that can beapplied. We describe a range of natural releases of CO2 and industrialreleases of CO2 and natural gas in the context of these characteristics.Based on this analysis, several key conclusions can be drawn, and lessonscan be learned for geologic carbon storage. First, CO2 can bothaccumulate beneath, and be released from, primary and secondaryreservoirs with capping units located at …

A simple replication of developed country applianceefficiency labels and standards is unlikely to be feasible in Ghana andmany other countries in Africa. Yet by creatively modifying the developedcountry appliance efficiency market transformation model, it should bepossible to achieve dramatic energy use reductions. As was true indeveloped countries in the previous two decades, refrigeration efficiencyimprovements provide the greatest energy savings potential in theresidential electricity sector in Ghana. Although Ghana, like manyAfrican countries may impose standards on imports since Ghana does nothave manufacturing facilities for appliances in country. This approachmay hurt some consumers who patronize a very diverse market of usedappliances imported from Europe. We discuss how meeting the challenges ofthe Ghanaian market will require modification of the usual energyefficiency labeling and standards paradigm. But once a refrigeratormarket transformation is accomplished in Ghana, we estimate an averageenergy savings potential of 550 kWh/refrigerator/year, and a monetarysavings of more than $35/refrigerator/year. We discuss how this modifiedrefrigerator efficiency market transformation may occur in the Ghanaiancontext. If successful, this market transformation is likely to be anexample for many other African countries.

Starting from an accurate inter-atomic potential we develop a simple scheme of generating an ''on-lattice'' molecular potential of short range, which is then incorporated into a lattice Monte Carlo code for simulating size and shape evolution of nanocrystallites. As a specific example, we test such a procedure on the morphological evolution of a molecular crystal of interest to us, e.g., Pentaerythritol Tetranitrate, or PETN, and obtain realistic facetted structures in excellent agreement with experimental morphologies. We investigate several interesting effects including, the evolution of the initial shape of a ''seed'' to an equilibrium configuration, and the variation of growth morphology as a function of the rate of particle addition relative to diffusion.

Using Chandra HETG data we present light curves for individual spectral lines of Mg XI and Mg XII for EX Hydrae, an intermediate-polar type cataclysmic variable. The Mg XI light curve, folded on the white dwarf spin period, shows two spikes that are not seen in the Mg XII or broad-band light curves. Occultation of the accretion column by the body of the white dwarf would produce such spikes for an angle between the rotation axis and the accretion columns of {alpha} = 18{sup o} and a height of the Mg XI emission above the white dwarf surface of {approx}< 0.0004 white dwarf radii or {approx}< 4 km. The absence of spikes in the Mg XII and broad-band light curves could then be explained if the bulk of its emission forms at much larger height, > 0.004 white dwarf radii or > 40 km, above the white dwarf surface. The technique described in this letter demonstrates that high signal-to-noise ratio and high spectral resolution X-ray spectra can be used to map the temperature and density structure of accretion flows in magnetic cataclysmic variables. The Mg XI and Mg XII light curves are not consistent with the temperature and density structure …

We present new measurements of time-dependent CP-violation parameters in hadronic penguin decays: B{sup 0} {yields} K{sup +}K{sup -}K{sub L}{sup 0}, K{sub S}{sup 0}{pi}{sup 0}{pi}{sup 0}, K{sub S}{sup 0}K{sub S}{sup 0}K{sub S}{sup 0}, {omega}K{sub L}{sup 0}, and a radiative penguin decay B{sup 0} {yields} K{sub S}{sup 0}{pi}{sup 0}{gamma} in a dataset of around 230 {center_dot} 10{sup 6} B{bar B} pairs collected by the BABAR detector at the asymmetric B Factory at SLAC. These CP asymmetry measurements probe for amplitudes beyond the Standard Model in loop-dominated decays of neutral B mesons. While we find a puzzling deviation of CP-asymmetry parameters from predicted values, a full confirmation still awaits more data.

Characterization of the epistemic uncertainty and aleatory variability of ground motion, as part of the Yucca Mountain nuclear waste repository PSHA (Stepp et al., 2001), results in ground motion values that increase without bound as lower and lower annual probabilities of exceedance are considered. For probabilities of exceedance less than about 10{sup -6} (yr{sup -1}), use of these results as input to the site response model leads to ground motion values for the repository that most engineering seismologists feel are not credible. To provide a defensible technical basis to develop credible emplacement level motions for extreme events, the undeformed nature of the 12.8 million year old lithophysal tuff units at Yucca Mountain provide strong constraints on the level of strain (stress) not experienced by the site since deposition of the tuff. Uniaxial unconfined compressive tests (the only tests available to the project) of the lithophysal tuff indicate axial strains of about 0.3% at fracture, which converts to approximately 0.2% shear-strain. This shear-strain limit (fracture strain), which has not occurred, is used with standard equivalent-linear (and nonlinear) point-source site response analyses to develop corresponding response spectra assuming a controlling earthquake of M 6.5 at a distance of 5 km, based on …

The aim of this paper is to demonstrate the integration of safety methodology, quality tools, leadership, and teamwork at Hanford and their significant positive impact on safe performance of work. Dashboards, Leading Indicators, Control charts, Pareto Charts, Dr. W. Edward Deming's Red Bead Experiment, and Dr. Deming's System of Profound Knowledge have been the principal tools and theory of an integrated management system. Coupled with involved leadership and teamwork, they have led to significant improvements in worker safety and protection, and environmental restoration at one of the nation's largest nuclear cleanup sites.

The development of a high-energy (10Mev) neutron imaging system at Lawrence Livermore National Laboratory (LLNL) depends on a precision engineered rotating aperture and vacuum system for generating neutrons that are used for imaging dense objects. This subsystem is part of a larger system which includes a linear accelerator that creates a deuteron beam, a scintillator detector, imaging optics and a high resolution CCD camera. The rotating aperture vacuum system has been successfully simulated and tested. Results show the feasibility of the design and point toward ways to improve the design by minimizing the rotating aperture gap.

We have studied the spin relaxation in diluted spin ice Ho{sub 2-x} Y{sub x} Ti{sub 2}O{sub 7} by means of neutron spin echo spectroscopy. Remarkably, the geometrical frustration is not relieved by doping with non-magnetic Y, and the dynamics of the freezing is unaltered in the spin echo time window up to x {approx_equal} 1.6. At higher doping with non-magnetic Y (x {ge} 1.6) a new relaxation process at relatively high temperature (up to at least T {approx_equal} 55 K) appears which is more than 10 times faster than the thermally activated main relaxation process. We find evidence that over the whole range of composition all Ho spins participate in the dynamics. These results are compared to a.c. susceptibility measurements of the diluted Ho and Dy spin ice systems. X-ray absorption fine structure (EXAFS) spectra and x-ray diffraction show that the samples are structurally well ordered.

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This paper outlines rock mechanics investigations associated with mechanical degradation of planned emplacement drifts at Yucca Mountain, which is the designated site for a US high-level nuclear waste repository. The factors leading to drift degradation include stresses from the overburden, stresses induced by the heat released from the emplaced waste, stresses due to seismically related ground motions, and time-dependent strength degradation. The welded tuff emplacement horizon consists of two groups of rock with distinct engineering properties: nonlithophysal units and lithophysal units, based on the relative proportion of lithophysal cavities. Part I of the paper concentrates on the generally hard, strong, and fractured nonlithophysal rock. The degradation behavior of the tunnels in the nonlithophysal rock is controlled by the occurrence of keyblocks. A statistically equivalent fracture model was generated based on extensive underground fracture mapping data from the Exploratory Studies Facility at Yucca Mountain. Three-dimensional distinct block analyses, generated with the fracture patterns randomly selected from the fracture model, were developed with the consideration of in situ, thermal, seismic loads. In this study, field data, laboratory data, and numerical analyses are well integrated to provide a solution for the unique problem of modeling drift degradation throughout the regulatory period for repository …

The GaAsP/GaAs strained superlattice photocathode structure has proven to be a significant advance for polarized electron sources operating with high peak currents per microbunch and relatively low duty factor. This is the characteristic type of operation for SLAC and is also planned for the ILC. This superlattice structure was studied at SLAC [1], and an optimum variation was chosen for the final stage of E-158, a high-energy parity violating experiment at SLAC. Following E-158, the polarized source was maintained on standby with the cathode being re-cesiated about once a week while a thermionic gun, which is installed in parallel with the polarized gun, supplied the linac electron beams. However, in the summer of 2005, while the thermionic gun was disabled, the polarized electron source was again used to provide electron beams for the linac. The performance of the photocathode 24 months after its only activation is described and factors making this possible are discussed.

It is shown that the transient expansion of plutonium-gallium alloys observed both in the lattice parameter as well as in the dimension of a sample held at ambient temperature can be explained by assuming incipient precipitation of Pu{sub 3}Ga. However, this ordered {zeta}-phase is also subject to radiation-induced disordering. As a result, the gallium-stabilized {delta}-phase, being metastable at ambient temperature, is driven towards thermodynamic equilibrium by radiation-enhanced diffusion of gallium and at the same time reverted back to its metastable state by radiation-induced disordering. A steady state is reached in which only a modest fraction of the gallium present is arranged in ordered {zeta}-phase regions.

Denitrification can effectively mitigate the problem of high nitrate concentrations in groundwater under dairy operations by reducing nitrate to N{sub 2} gas, at sites where biogeochemical conditions are favorable. We present results from field studies at central California dairies that document the occurrence of saturated-zone denitrification in shallow groundwater using biomolecular indicators, stable isotope compositions of nitrate, and measurements of dissolved excess N{sub 2} gas. Excess N{sub 2} concentrations provide a measure of the extent to which nitrate in groundwater has been partially or completely denitrified. Abundant excess N{sub 2} and young {sup 3}H/{sup 3}He apparent groundwater ages indicate high denitrification rates near manure lagoons where multiple lines of evidence indicate seepage of lagoon water into the groundwater system. Natural tracers of lagoon water include high chloride and dissolved organic carbon concentrations, distinctive trace organic compounds, and high groundwater {delta}{sup 18}O values (relative to other recharge sources). Proximal to the lagoons, NH{sub 4}{sup +} may be present in groundwater, but is strongly adsorbed on to sediment particles. Bubble formation in the lagoons causes the exsolution of other gases (N{sub 2}, Ar, Ne, He, etc.), which partition into the gas phase and strip the lagoon water of its dissolved gas load, …

A unique electronics system has been built and tested for reading signals from the silicon-strip detectors of the Gamma-ray Large Area Space Telescope mission. The system amplifies and processes signals from 884,736 36-cm strips using only 160 W of power, and it achieves close to 100% detection efficiency with noise occupancy sufficiently low to allow it to self trigger. The design of the readout system is described, and results are presented from ground-based testing of the completed detector system.

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This report talks about Anodic Kinetics of NiCriMo Alloys during Localized Corrosion

Yucca Mountain, Nevada is the designated site for the first long-term geologic repository to safely dispose spent nuclear fuel and high-level nuclear waste in the U.S. Yucca Mountain consists of stacked layers of welded and non-welded volcanic tuffs. Site characterization studies are being performed to assess its future performance as a permanent geologic repository. These studies include the characterization of the shear-wave velocity (Vs) structure of the repository block and the surface facilities area. The Vs data are an input in the calculations of ground motions for the preclosure seismic design and for postclosure performance assessment and therefore their accurate estimation is needed. Three techniques have been employed: 24 downhole surveys, 15 suspension seismic logging surveys and 95 spectral-analysis-of-surface-waves (SASW) surveys have been performed to date at the site. The three data sets were compared with one another and with Vs profiles developed from vertical seismic profiling data collected by the Lawrence Berkeley National Laboratory and with Vs profiles developed independently by the University of Nevada, Reno using the refraction microtremor technique. Based on these data, base case Vs profiles have been developed and used in site response analyses. Since the question of adequate sampling arises in site characterization programs …