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Rheology Modifiers Applied to Kaolin-Bentonite Slurries for SRNL WTP Pulse Jets Tank Pilot Work in Support of RPP at Hanford (open access)

Rheology Modifiers Applied to Kaolin-Bentonite Slurries for SRNL WTP Pulse Jets Tank Pilot Work in Support of RPP at Hanford

Savannah River National Laboratory (SRNL) was tasked to find and characterize the impact of rheological modifiers to a clay (Kaolin-Bentonite) slurry having 23.1 total wt percent solids, 1.165 g/ml, and Bingham Plastic yield stress of 13 Pa and plastic viscosity of 24 mPa-sec. The primary objective was to find rheological modifiers when blended with this clay slurry that would provide a vane yield stress of 300 Pa when the slurry was undisturbed for 24 hours. A secondary objective was to find a modifier that after shearing would produce a Bingham Plastic yield stress of 30 Pa and plastic viscosity of 30 mPa-sec. Two parallel paths were chosen with one examining a variety of organic/inorganic modifiers and another using just the inorganic modifier Laponite (R). The addition of organic modifiers hydroxyethylcellulose, hydroxypropylmethylcellulose, and hydroxypropylcellulose at a target 0.50 wt percent dramatically increased the vane yield stress over the range 311 - 724 Pa, and also increased the Bingham plastic yield stress and plastic viscosities over the range 33-112 Pa and 27-166 mPa-sec, respectively. The organic modifiers also showed elastic behavior, yielding a very unpredictable up flow curve. The 0.50 wt percent addition of inorganic modifiers magnesium aluminum silicate and hydrate magnesium …
Date: February 9, 2005
Creator: William, Daniel
System: The UNT Digital Library
Direct Photon Measurement at RHIC-PHENIX. (open access)

Direct Photon Measurement at RHIC-PHENIX.

Results on direct photon measurements from the PHENIX experiment at RHIC are presented. The results suggest that the photons observed are emitted from the initial stage of hard scattering. Comparisons with several theoretical calculations are also presented.
Date: February 5, 2005
Creator: Sakaguchi, T.
System: The UNT Digital Library
Anodic polymerization of vinyl ethylene carbonate in Li-Ion battery electrolyte (open access)

Anodic polymerization of vinyl ethylene carbonate in Li-Ion battery electrolyte

A study of the anodic oxidation of vinyl ethylene carbonate (VEC) was conducted with post-mortem analysis of reaction products by ATR-FTIR and gel permeation chromatography (GPC). The half-wave potential (E1/2) for oxidation of VEC is ca. 3.6 V producing a resistive film on the electrode surface. GPC analysis of the film on a gold electrode produced by anodization of a commercial Li-ion battery electrolyte containing 2 percent VEC at 4.1 V showed the presence of a high molecular weight polymer. IR analysis indicated polycarbonate with alkyl carbonate rings linked by aliphatic methylene and methyl branches.
Date: February 28, 2005
Creator: Chen, Guoying; Zhuang, Guorong V.; Richardson, Thomas J.; Gao, Liu & Ross Jr., Philip N.
System: The UNT Digital Library
Lessons Learned from an External Review of the Savannah River Site Saltstone Performance Assessment Program (open access)

Lessons Learned from an External Review of the Savannah River Site Saltstone Performance Assessment Program

None
Date: February 15, 2005
Creator: Cook, James R.
System: The UNT Digital Library
Domain-specific Web Service Discovery with Service Class Descriptions (open access)

Domain-specific Web Service Discovery with Service Class Descriptions

This paper presents DynaBot, a domain-specific web service discovery system. The core idea of the DynaBot service discovery system is to use domain-specific service class descriptions powered by an intelligent Deep Web crawler. In contrast to current registry-based service discovery systems--like the several available UDDI registries--DynaBot promotes focused crawling of the Deep Web of services and discovers candidate services that are relevant to the domain of interest. It uses intelligent filtering algorithms to match services found by focused crawling with the domain-specific service class descriptions. We demonstrate the capability of DynaBot through the BLAST service discovery scenario and describe our initial experience with DynaBot.
Date: February 14, 2005
Creator: Rocco, Daniel; Caverlee, James; Liu, Ling & Critchlow, Terence J.
System: The UNT Digital Library
Measurement of the alpha asymmetry parameter for the Omega- ---> Lambda K- decay (open access)

Measurement of the alpha asymmetry parameter for the Omega- ---> Lambda K- decay

None
Date: February 1, 2005
Creator: Chen, Y. C.; /Taiwan, Inst. Phys.; Burnstein, R. A.; Chakravorty, A.; Chan, A.; Choong, W. S. et al.
System: The UNT Digital Library
Heavy-ion-induced production and preseparation of short-livedisotopes for chemistry experiments (open access)

Heavy-ion-induced production and preseparation of short-livedisotopes for chemistry experiments

Physical separation of short-lived isotopes produced inheavy-ion-induced fusion reactions is a powerful and well know method andoften applied in investigations of the heaviest elements, called thetransactinides (Z>=104). By extracting these isotopes from a recoilseparator, they can be made available for transport to setups locatedoutside the heavily shielded irradiation position such as chemistrysetups. This physical preseparation technique overcomes many limitationscurrently faced in the chemical investigation of transactinides. Here wedescribe the basic principle using relatively short-lived isotopes of thelighter group 4 elements zirconium (Zr) and hafnium (Hf) that are used asanalogs of the lightest transactinide element, rutherfordium (Rf, element104). The Zr and Hf isotopes were produced at the LBNL 88-Inch Cyclotronusing a cocktail of 18O and 50Ti beams and the appropriate targets.Subsequently, the isotopes were physically separated in the BerkeleyGas-filled Separator (BGS) and guided to a Recoil Transfer Chamber (RTC)to transfer them to chemistry setups. The magnetic rigidities of thereaction products in low-pressure helium gas were measured and theiridentities determined with gamma-pectroscopy. Using preseparated isotopeshas the advantages of low background and beam plasma free environment forchemistry experiments. The new possibilities that open up for chemicalinvestigations of transactinide elements are descr ibed. The method canreadily be applied to homologous elements within other groups …
Date: February 24, 2005
Creator: Dullmann, Christoph E.; Folden, Charles M., III; Gregorich, Kenneth E.; Hoffman, Darleane C.; Leitner, Daniela; Pang, Gregory K. et al.
System: The UNT Digital Library
The Journey to Fielded BioInstrumentation (open access)

The Journey to Fielded BioInstrumentation

Over the last ten years, a team at Lawrence Livermore National Laboratory created fieldable instruments that performed identification/quantification via bioassays. These instruments have been based on molecular surface-recognition assays, such as immunoassays, and on nucleic-acid-based assays, such as the polymerase chain reaction. In 1996, we participated in the Joint Field Trials 3, employing both immunoassays as well as the polymerase chair reaction. In 1998, we participated in the Joint Field Trials 4, using only the real-time polymerase chain reaction, as implemented on a 10-chamber instrument. Our hand-held, real-time PCR instrument, known as HANAA has been commercialized as the Bioseeq{reg_sign}, by Smiths Detection. More recently, teams from LLNL have built and fielded an autonomous pathogen detection system (APDS).
Date: February 24, 2005
Creator: Mariella, R., Jr.
System: The UNT Digital Library