This paper presents a circuit model and an electrostatic field analysis with an approximate model of the SDM170HK MOS turn-off thyristor (MTO) fabricated by Silicon Power Corporation. The circuit model consists of five cells, each containing two bipolar junction transistors and three resistors. The turn-off feature of the MTO was simulated by inserting an array of 21 Fairchild FDS6670A MOSFET importable sub-circuit components between the cathode and the turn-on gate. The model was then used to create a four-terminal sub-circuit component representing the MTO that can be readily imported into computer-aided circuit design programs such as PSPICE and Micro-Cap. The generated static I-V characteristics and simulated switching waveforms are shown. The electrostatic field analysis was done for the maximum operating voltage of 4.5 kV using the Ansoft Maxwell 3D field simulator. Electrostatic field magnitudes that exceed the nominal air breakdown threshold of 30 kV/cm were observed surrounding the simulated turn-off gate wire, the turn-off gate ring contact, and the cathode ring contact. The resulting areas of high fields are a concern, as arc track marks have been found on the inner surface of the ceramic insulator near the internal gate connections of a failed device.

A fundamental problem in providing high-quality surveillance images recorded over long horizontal or slant paths is the blurring caused by atmospheric turbulence, which reduces both the resolution and contrast. The objective of the work reported here is to develop a capability for long-range imaging through the atmosphere that is not limited by the atmosphere but only by the fundamental diffraction limit of the optics. This paper describes our recent horizontal and slant-path imaging experiments of point targets and extended scenes as well as simulations of point targets in comparison to experiment. We show the near-diffraction limited resolution results obtained using bispectral speckle-imaging techniques. The experiments were performed with an 8-inch diameter telescope placed either in a field, on a rooftop, or on a hillside and cover ranges of interest from 100 meters up to 10 km. The scenery includes resolution targets, people, vehicles, and other structures.

The objective of this report is to discuss the degree of sorption and desorption of {sup 137}Cs and {sup 60}Co that may be associated with the granite bedrock and the ''popcorn'' cement drain system that underlie the Maine Yankee Containment Foundation. The purpose is to estimate how much retardation of these two radionuclides takes place in groundwater that flows in the near-field of the Containment Foundation, specifically with respect to contamination originating at the PAB Test Pit. Specific concerns revolve around the potential for the contamination originating near the PAB to create a radioactive dose to a hypothetical ''resident farmer'' using a well intercepting this water to exceed 4 millirems/yr.

The Scaled Thermal Explosion Experiment (STEX) has been developed to quantify the violence of thermal explosion under well defined and carefully controlled initial and boundary conditions. Here we present results with HMX-based explosives (LX-04 and PBX-9501) and with Composition B. Samples are 2 inches (50 mm) in diameter and 8 inches (200 mm) in length, under confinement of 7,500-30,000 psi (50-200 MPa), with heating rates of 1-3 C/hr. We quantify reaction violence by measuring the wall velocity in the ensuing thermal explosion, and relate the measured velocity to that expected from a detonation. Results with HMX-based explosives (LX-04 and PBX-9501) have shown the importance of confinement and HMX solid phase, with reaction violence ranging from mild pressure bursts to near detonations. By contrast, Composition B has shown very violent reactions over a wide range of conditions.

The space science community has identified a need for ultra-light weight, large aperture optical systems that are capable of producing high-resolution images of low contrast. Current mirror technologies are limited due either to not being scalable to larger sizes at reasonable masses, or to lack of surface finish, dimensional stability in a space environment or long fabrication times. This paper will discuss the development of thin-shell, nano-laminate mirror substrates that are capable of being electro-actively figured. This technology has the potential to substantially reduce the cost of space based optics by allowing replication of ultra-lightweight primary mirrors from a master precision tool. Precision master tools have been shown to be used multiple times with repeatable surface quality results with less than one week fabrication times for the primary optical mirror substrate. Current development has developed a series of 0.25 and 0.5 meter spherical nanolaminate mirrors that are less than 0.5 kg/m{sup 2} areal density before electroactive components are mounted, and a target of less than 2.0 kg/m with control elements. This paper will provide an overview of nanolaminate materials for optical mirrors, modeling of their behavior under figure control and experiments conducted to validate precision control.

We present equation of state results from impulsively stimulated light scattering (ISLS) experiments conducted in diamond anvil cells on pure supercritical fluids. We have made measurements on fluid H{sub 2}O (water), and CH{sub 3}OH (methanol). Sound speeds measured through ISLS have allowed us to refine existing potential models used in the exponential-6 (EXP-6) detonation product library [Fried, L. E., and Howard, W. M., J. Chem. Phys. 109 (17): 7338-7348 (1998).]. The refined models allow us to more accurately assess the chemical composition at the Chapman-Jouget (C-J) state of common energetic materials. We predict that water is present in appreciable quantities at the C-J state of energetic materials HMX, RDX, and nitro methane.

A Working Group Meeting on Heavy Vehicle Aerodynamic Drag was held at Lawrence Livermore National Laboratory on April 3 and 4, 2002. The purpose of the meeting was to present and discuss technical details on the experimental and computational work in progress and future project plans. Representatives from the Department of Energy (DOE) Office of Transportation Technology Office of Heavy Vehicle Technology (OHVT), Lawrence Livermore National Laboratory (LLNL), Sandia National Laboratories (SNL), NASA Ames Research Center, University of Southern California (USC), and California Institute of Technology (Caltech), Georgia Tech Research Institute (GTRI), and Argonne National Laboratory (ANL), Volvo Trucks, and Freightliner Trucks presented and participated in discussions. This report contains the technical presentations (viewgraphs) delivered at the Meeting, briefly summarizes the comments and conclusions, and outlines the future action items.

New algorithms that efficiently calculate the volume of a closed chamber are presented in this paper. The current pressure in the enclosed chamber can then be computed, based on the user-specified gas law, from the updated volume and the initial volume and pressure of the chamber. This pressure load function is very useful in modeling common features, such as air pocket, airbag, piston, and gun barrel, in structural analyses.

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Extensive plastic deformation during wire drawing is commonly used to produce steel wires with very high strengths. Typically these steels are eutectoid and hypereutectoid steels and drawing strains up to 4 are used during processing. The resulting materials can have tensile strengths in excess of 4000 MPa. The evolution of microstructure and the strengthening mechanisms resulting from wire drawing have been studied for eutectoid and hypereutectoid steels. Strength has been shown to be a function of pearlite colony size, interlamellar spacing and the size of the stable dislocation cells that are produced during wire drawing. The results have been used to model the evolution of strength during wire drawing. Model predictions for the evolution of tensile strength with drawing strain show excellent agreement with data derived from a number of eutectoid and hyperectectoid steels as a function of drawing strain.

In this report, we review the results of Reimus et al. (2000a; 2000b) regarding matrix diffusion and colloid-facilitated transport in fractured rock and evaluate the implications of these results on modeling fracture flow at the Nevada Test Site (NTS). In particular, we examine these data in the context of the recent Cheshire hydrologic source term (HST) model results (Pawloski et al., 2001). This report is divided into several sections. In the first, we evaluate the effective diffusion coefficient (D{sub e}) data reported in Reimus et al. (2000a) for conservative tracer species ({sup 3}H, {sup 14}C, and {sup 99}Tc) and fit a simple effective diffusion model to these data. In the second, we use the fitted effective diffusion model, in conjunction with a surface complexation model, to simulate plutonium-colloid transport and compare model results to data reported in Reimus et al. (2000b). In the third, we evaluate the implications of these data with regards to radionuclide transport through fractures at the field scale and, in particular, with regards to the Cheshire HST model (Pawloski et al., 2001). Finally, we make recommendations regarding future radionuclide transport modeling efforts at the NTS.

Oxides are ubiquitous in much of environmental chemistry. Silica and related glasses are potential vehicles by which radioactive elements may be sequestered and stored. The migration of toxic waste in ground water is largely influenced by interactions at the liquid-solid interface, with several metal oxides making up the bulk of soil. In addition, metal oxides with Bronsted acid or Lewis base functionality are potential replacements for many traditional liquid catalysis that are hazardous to work with and difficult to dispose. In this proposal, we targeted two such areas of oxide chemistry. The long-term behavior of silicate materials slated for use in the entombment of high-level waste (HLW), and the use of solid acid metal oxides as replacements for toxic sulfuric and hydrofluoric acid used in industry (referred to as Green Chemistry). Thus, this project encompassed technology that can be used to both remediate and prevent pollution. These oxide systems were studied using density functional theory (DFT). The comparatively large size and complexity of the systems that will bweree studied made use of high-accuracy electronic structure studies intractable on conventional computers. The 512 node parallel processor housed in the Molecular Science Computing Facility (MSCF) provided the required capability.

Following the same approach as with the W-Re targets [l], we have calculated the damage induced by photon irradiation (22.1 MeV average energy) in titanium targets. Stefan Roesler calculated, using FLUKA [2] the spallation products, neutrons and fission products from the interaction of the photons with the titanium target. Using these initial values of energies and positions, we calculated the number of defects produced per incoming photon. It should be noted that the threshold displacement energy for defect production of Titanium as measured experimentally is between 21 and 30 eV [3]. We used a value of 25eV. This is a much lower value than for the case of W-alloys (90 eV) which implies a larger defect production for the same deposited energy in the case of Titanium. The number of defects for different neutron energies was calculated using SPECTER [4] Figure 1(a) shows the number of defects as a function of energy for the case of Ti as compared to W, in Figure 1(b). The number of defects is much larger in the Ti case due to the low threshold displacement energy as explained.

This report provides the technical background and a guide to characterizing a site for storing natural gas in the Columbia River Basalt

In this paper we discuss methods to obtain high dopant concentrations during processing of Si devices. The possibility of increasing the solubility of B in Si by misfit stress is investigated. The enthalpy of B atoms is calculated, with and without stress, using density functional theory. A second approach, the trapping of excess dopant atoms during deposition of Si, is also considered. For this purpose, the enthalpies of several dopant species in sites near the surface are calculated.

This document describes the Project Plan for the development and manufacture of a Vertical Lift Machine. It is assumed by this project plan that the Vertical Lift Machine will be developed, designed, manufactured, and tested by a qualified vendor. LLNL will retain review and approval authority for each step given in this project plan. The Vertical Lift Machine is a single linear axis positioning device capable of lifting objects vertically at controlled rates and positioning them repeatedly at predetermined heights, in relation to other objects suspended from above, for high neutron multiplication experiments. Operation of the machine during the experiments is done remotely. The lift mechanism shall accommodate various platforms (tables) that support the objects to be raised. A frame will support additional subassemblies from above such that the lower subassembly can be raised close to and/or interface with those above. The structure must be stiff and motion of the table linear such that radial alignment is maintained (e.g. concentricity). The safe position for the Vertical Lift Machine is the lift mechanism fully retracted with the subassemblies fully separated. The machine shall reside in this position when not in use. It must return to this safe condition from any position …

A major challenge in the development of optical glasses for high-power lasers is reducing or eliminating laser-induced damage to the interior (bulk) and the polished surface of the glass. Bulk laser damage in glass generally originates from inclusions. With the development of novel glass melting and forming processes it is now possible to make both fused silica and a suit of meta-phosphate laser glasses in large sizes ({approx}>0.5-lm diameter), free of inclusions and with high optical homogeneity ({approx} 10{sup -6}). Considerable attention also has been focused on improving the laser damage resistance to polished optical glass surfaces. Studies have shown that laser-induced damage to surfaces grows exponentially with the number of shots when illuminated with nano-second pulses at 351-nm above a given fluence threshold. A new approach for reducing and eliminating laser-induced surface damage relies on a series of post-polishing treatment steps. This damage improvement method is briefly reviewed.

We present equation of state results from impulsively stimulated light scattering (ISLS) experiments conducted in diamond anvil cells on pure supercritical fluids, and supercritical fluid mixtures. We have made measurements on fluid H2O (water), CH2O (formaldehyde), and CH3OH (methanol). Sound speeds measured through ISLS have allowed us to refine existing potential models used in the Em6 detonation product library [Fried, L. E., and Howard, W. M., J. Chem. Phys. 109 (17): 7338-7348 (1998).]. The refined models allow us to more accurately assess the chemical composition at the Chapman-Jouget (C-J) state of common explosives. We predict that water and formaldehyde are present in appreciable quantities at the C-J state of HMX, RDX, and NM. Methanol is predicted to be present only in trace quantities at the C-J state. In the case of methanol, chemical decomposition and phase separation was observed at high temperatures. We are developing micro-FTIR and Raman techniques to determine the chemical composition of the phase separated detonation products.

The objective of this work is to investigate various silicon-metal eutectic systems that selectively retain detrimental impurities, such as Ni, Co, Fe, Cr, in the melt so that silicon may be purified. We studied possible interactions in the melt and in the silicon crystal between impurity elements and solvent metals that lead to reduced or enhanced impurity partition relative to the respective silicon-impurity binary systems. Systems such as Al- Si, Cu-Si, and In-Si show promises of reduced impurity incorporations in recrystallized silicon, which are good candidates for further investigation besides Ga-Si, Au-Si, and Ag-Si.

This document will serve as a summary of my work activities as a summer employee for the Lawrence Livermore National Laboratory (LLNL). The intent of this document is to provide an overview of the National Ignition Facility (NIF) project, to explain the role of the department that I am working for, and to discuss my specific assigned tasks and their impact on the NIF project as a whole.

In the Nd-Fe-A1 system, compositions in the range of Nd{sub 60}Fe{sub 30}Al{sub 10} have been reported to be ferromagnetic bulk metallic glasses with high coercivities. Careful examination of both the microstructure and magnetic properties of these materials shows this to be true only in the most general sense. The materials are shown to be nanocomposites, in the strictest sense, with characteristic structural length scales on the order of 1.2 nm. Magnetically, the materials are also composites exhibiting a number of magnetic transitions as a function of temperature. The temperature dependence of the magnetic properties will be discussed in terms of strongly-interacting superparamagnetic clusters residing in a paramagnetic matrix. The clusters exhibit a frequency-dependent blocking temperature as determined from AC susceptibility, that is inconsistent with simple superparamagnetic behavior but is consistent with a spin glass-type ordering of the clusters to form a cluster glass. For a temperature region extending approximately 100 K below the cluster glass ordering temperature, the materials exhibit low coercivity. Below this temperature regime significant coercivities develop. The energy barrier to magnetic reversal provided by the product of the cluster volume multiplied by the anisotropy energy is inconsistent with the values required to fit the superparamagnetic behavior above …

Quantitative analysis or numeric simulation on a cross-section of silicon devices offers many insights into understanding material problems and their effects on device performances as well as device structure optimizations. Such two-dimensional simulations on semiconductor devices are standard design practices and are routinely done with expensive software packages. The availability of less expensive software tools nowadays, such as MicroTec(R) for 2D modeling of semiconductor devices, affords us a more detailed examination of polycrystalline thin-silicon materials and solar cells.

Direct writing of solar cell components is an attractive processing approach. We have fabricated a 6.8% Si solar cell using silver ink based electrodes. Ohmic contact through the antireflection (AR) coating was obtained with pure Ag electrodes at 850 0C. We also report on highly conductive silver metallizations and initial results on direct-write TCO demonstrating a 100-micron spatial resolution produced by inkjet printing.

The understanding of the physical mechanisms by which important biological inhibitors control the nucleation, growth, aggregation, and phase transformation of calcium oxalate crystals at fundamental level is of importance not only to the advances in biomineralization but also to the development of stone disease therapy. Of the three phases of calcium oxalate crystalline, calcium oxalate monohydrate (COM) and dehydrate (COD) are found in the majority of stones formed in the urinary system. Only COM, a major inorganic component of kidney stones, produces adverse physiological effects to human, however. Although a great deal of research has been carried out on the modulation of nucleation, growth, aggregation, and phase transformation of calcium oxalates by biological molecules, the basic mechanism has not yet been determined due to inherent limitations of those techniques that have been utilized The invention of atomic force microscopy (AFM) has opened a new avenue for the study of the crystal growth in general. One can now probe the growth kinetics and dynamics, and morphology of crystal surfaces down to molecular levels as a typical AFM has a lateral resolution of nanometers. In this study, in situ AFM was used to monitor the COM surface under controlled growth conditions. The …