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Chemometric Analysis of Two Dimensional Decay Data: Application to {sup 17}O NMR Relaxation Matrices (open access)

Chemometric Analysis of Two Dimensional Decay Data: Application to {sup 17}O NMR Relaxation Matrices

The use of {sup 17}O NMR spectroscopy as a tool to investigate aging in polymer systems has recently been demonstrated. Because the natural abundance of {sup 17}O is extremely low (0.037%), the use of labeled {sup 17}O{sub 2} during the oxidation of polymers produces {sup 17}O NMR spectra whose signals arise entirely from the degradation species (i.e. signals from the bulk or unaged material are not observed). This selective isotopic labeling eliminates the impact of interference from the unaged material, cause (1) above. As discussed by Alam et al. spectral overlap between different degradation species as well as errors in quantification remains a major difficulty in {sup 17}O NMR spectroscopy. As a demonstration of the DECRA and CTBSA methods, relaxation matrices obtained from {sup 17}O NMR for model alcohol systems are evaluated. The benefits and limitations of these newly developed chemometric techniques are discussed.
Date: March 18, 1999
Creator: Alam, M. K. & Alam, T. M.
Object Type: Article
System: The UNT Digital Library
News Bulletin (Castroville, Tex.), Vol. 41, No. 11, Ed. 1 Thursday, March 18, 1999 (open access)

News Bulletin (Castroville, Tex.), Vol. 41, No. 11, Ed. 1 Thursday, March 18, 1999

Weekly newspaper from Castroville, Texas that includes local, state, and national news along with extensive advertising.
Date: March 18, 1999
Creator: Barnes, Thomas
Object Type: Newspaper
System: The Portal to Texas History
Operational Characteristics, parameters, and history of a 13T Nb3Sn dipole (open access)

Operational Characteristics, parameters, and history of a 13T Nb3Sn dipole

The early design and test results have been previously reported. During the subsequent operation of 'D20' the accelerator prototype dipole has provided both additional and more detailed data as to its characteristics and performance. D20's use as a test facility for high field critical current measurements has provided operational experience and history pertammg to accelerator required characteristics. There has been recently obtained data related to field quality, operational reproducibility and reliability, which will be presented. This prototype 'D20' has attained the highest magnetic field of any accelerator prototype dipole constructed and tested to date. The magnet has continued to operate routinely.
Date: March 18, 1999
Creator: Benjegerdes, R.; Bish, P.; Caspi, S.; Chow, K.; Dietderich, D.; Hannaford, R. et al.
Object Type: Article
System: The UNT Digital Library
The Goldthwaite Eagle (Goldthwaite, Tex.), Vol. 105, No. 34, Ed. 1 Thursday, March 18, 1999 (open access)

The Goldthwaite Eagle (Goldthwaite, Tex.), Vol. 105, No. 34, Ed. 1 Thursday, March 18, 1999

Weekly newspaper from Goldthwaite, Texas that includes local, state, and national news along with extensive advertising.
Date: March 18, 1999
Creator: Bridges, G. Frank & Bridges, Georgie
Object Type: Newspaper
System: The Portal to Texas History
Technical Basis for Safe Operations with Pu-239 in NMS and S Facilities (F and H Areas) (open access)

Technical Basis for Safe Operations with Pu-239 in NMS and S Facilities (F and H Areas)

Plutonium-239 is now being processed in HB-Line and H-Canyon as well as FB-Line and F-Canyon. As part of the effort to upgrade the Authorization Basis for H Area facilities relative to nuclear criticality, a literature review of Pu polymer characteristics was conducted to establish a more quantitative vs. qualitative technical basis for safe operations. The results are also applicable to processing in F Area facilities.The chemistry of Pu polymer formation, precipitation, and depolymerization is complex. Establishing limits on acid concentrations of solutions or changing the valence to Pu(III) or Pu(VI) can prevent plutonium polymer formation in tanks in the B lines and canyons. For Pu(IV) solutions of 7 g/L or less, 0.22 M HNO3 prevents polymer formation at ambient temperature. This concentration should remain the minimum acid limit for the canyons and B lines when processing Pu-239 solutions. If the minimum acid concentration is compromised, the solution may need to be sampled and tested for the presence of polymer. If polymer is not detected, processing may proceed. If polymer is detected, adding HNO3 to a final concentration above 4 M is the safest method for handling the solution. The solution could also be heated to speed up the depolymerization process. …
Date: March 18, 1999
Creator: Bronikowski, M.G.
Object Type: Report
System: The UNT Digital Library
Perry Daily Journal (Perry, Okla.), Vol. 106, No. 54, Ed. 1 Thursday, March 18, 1999 (open access)

Perry Daily Journal (Perry, Okla.), Vol. 106, No. 54, Ed. 1 Thursday, March 18, 1999

Daily newspaper from Perry, Oklahoma that includes local, state, and national news along with advertising.
Date: March 18, 1999
Creator: Brown, Gloria
Object Type: Newspaper
System: The Gateway to Oklahoma History
The Express-Star (Chickasha, Okla.), Ed. 1 Thursday, March 18, 1999 (open access)

The Express-Star (Chickasha, Okla.), Ed. 1 Thursday, March 18, 1999

Daily newspaper from Chickasha, Oklahoma that includes local, state, and national news along with advertising.
Date: March 18, 1999
Creator: Bush, Kent
Object Type: Newspaper
System: The Gateway to Oklahoma History
A machining parameter study to select best conditions for SPDT of large single-crystal silicon optics (open access)

A machining parameter study to select best conditions for SPDT of large single-crystal silicon optics

The interdependence of process parameters on diamond turning of single-crystal silicon is poorly understood. An experimental design technique based on methods of statistical analysis permits the determination of a specific parameter's influence and its co-dependence on other factors. This design technique enables the creation of an experimental matrix, considering all input parameters (surface velocity; feed rate; depth of cut; tool radius; tool rake/skew angle; cutting fluid), while substantially decreasing the overall number of experiments. After an initial survey the significant parameters for a subsequent response surface methodology (RSM) study can be selected. From measurements of tool wear, surface finish and sub-surface damage (SSD) the optimum parameter settings for the diamond turning process can then be determined.
Date: March 18, 1999
Creator: Carr, J W; Davis, P J; Haack, J K; Krulewich, D A; McClellan, M R & Zimmermann, M
Object Type: Article
System: The UNT Digital Library
Mechanical design of a high field common coil magnet (open access)

Mechanical design of a high field common coil magnet

A common coil design for high field 2-in-1 accelerator magnets has been previously presented as a 'conductor-friendly' option for high field magnets applicable for a Very Large Hadron Collider. This paper presents the mechanical design for a 14 tesla 2-in-1 dipole based on the common coil design approach. The magnet will use a high current density Nb{sub 3}Sn conductor. The design addresses mechanical issues particular to the common coil geometry: horizontal support against coil edges, vertical preload on coil faces, end loading and support, and coil stresses and strains. The magnet is the second in a series of racetrack coil magnets that will provide experimental verification of the common coil design approach.
Date: March 18, 1999
Creator: Caspi, S.; Chow, K.; Dietderich, D.; Gourlay, S.; Gupta, R.; McInturff, A. et al.
Object Type: Article
System: The UNT Digital Library
De Leon's Monitor (De Leon, Tex.), Vol. 4, No. 37, Ed. 1 Thursday, March 18, 1999 (open access)

De Leon's Monitor (De Leon, Tex.), Vol. 4, No. 37, Ed. 1 Thursday, March 18, 1999

Weekly newspaper from De Leon, Texas that includes local, state, and national news along with advertising.
Date: March 18, 1999
Creator: Chupp, Charles & Chupp Holdman, Tracy
Object Type: Newspaper
System: The Portal to Texas History
Tritium Permeation Estimate from APT and CLWR-TEF Waste Packages (open access)

Tritium Permeation Estimate from APT and CLWR-TEF Waste Packages

The amount of tritium permeating out of waste containers has been estimated for the Accelerator Production of Tritium project (APT) and for the Commercial Light Water Reactor - Tritium Extraction Facility project (CLWR-TEF). The waste packages analyzed include the Aluminum, Window, Tungsten, Lead, and Steel packages for the APT project, and the overpack of extracted Tritium Producing Burnable Absorber Rods (TPBARs) for the CLWR-TEF project. All of the tritium contained in the waste was assumed to be available as a gas in the free volume inside the waste container at the beginning of disposal, and to then permeate the stainless steel waste container. From estimates of the tritium content of each waste form, the void or free volume of the package, disposal temperature and container geometry, the amount of tritium exiting the waste container by permeation was calculated. Two tritium permeation paths were considered separately: through the entire wall surface area and through the weld area only, the weld area having reduced thickness and significantly less surface area compared to the wall area. Permeation out of the five APT waste containers at 50 degrees Celsius is mainly through the welds, and at 100 degrees Celsius is through the permeation out …
Date: March 18, 1999
Creator: Clark, E.A.
Object Type: Report
System: The UNT Digital Library
Altus Times (Altus, Okla.), Vol. 100, No. 4, Ed. 1 Thursday, March 18, 1999 (open access)

Altus Times (Altus, Okla.), Vol. 100, No. 4, Ed. 1 Thursday, March 18, 1999

Daily newspaper from Altus, Oklahoma that includes local, state, and national news along with advertising.
Date: March 18, 1999
Creator: Cole, Carol
Object Type: Newspaper
System: The Gateway to Oklahoma History
Oral History Interview with Warren Klein, March 18, 1999 (open access)

Oral History Interview with Warren Klein, March 18, 1999

Interview with Warren Klein, a rancher from Kerrville, Texas. Mr. Klein discusses his parents' move to the area, his life as a rancher, and several notable events in local history: droughts, the flood of 1932, the establishment of the Divide School building on his family's land, and deadly weather.
Date: March 18, 1999
Creator: Craig, Brenda; Nicholson, Marj & Klein, Warren
Object Type: Text
System: The Portal to Texas History
Oral History Interview with Warren Klein, March 18, 1999, Supplement (open access)

Oral History Interview with Warren Klein, March 18, 1999, Supplement

Supplemental materials to accompany an interview with rancher Warren Klein, including photos of the Divide on the Warren Klein Ranch, cattle he raised, the Divide School building established on the Klein family's land, family photos, newspaper clippings, and article excerpts.
Date: March 18, 1999
Creator: Craig, Brenda; Nicholson, Marj & Klein, Warren
Object Type: Text
System: The Portal to Texas History
A Multi-Attribute Utility Decision Analysis for Treatment Alternatives for the DOE/SR Aluminum-Based Spent Nuclear Fuel (open access)

A Multi-Attribute Utility Decision Analysis for Treatment Alternatives for the DOE/SR Aluminum-Based Spent Nuclear Fuel

A multi-attribute utility analysis is applied to a decision process to select a treatment method for the management of aluminum-based spent nuclear fuel (Al-SNF) owned by the US Department of Energy (DOE). DOE will receive, treat, and temporarily store Al-SNF, most of which is composed of highly enriched uranium, at its Savannah River Site in South Carolina. DOE intends ultimately to send the treated Al-SNF to a geologic repository for permanent disposal. DOE initially considered ten treatment alternatives for the management of Al-SNF, and has narrowed the choice to two of these: the direct disposal and melt and dilute alternatives. The decision analysis presented in this document focuses on a formal decision process used to evaluate these two remaining alternatives.
Date: March 18, 1999
Creator: Davis, F.; Weiner, R.; Wheeler, T.; Sorenson, K. & Kuzio, K.
Object Type: Article
System: The UNT Digital Library
The Baytown Sun (Baytown, Tex.), Vol. 77, No. 119, Ed. 1 Thursday, March 18, 1999 (open access)

The Baytown Sun (Baytown, Tex.), Vol. 77, No. 119, Ed. 1 Thursday, March 18, 1999

Daily newspaper from Baytown, Texas that includes local, state, and national news along with advertising.
Date: March 18, 1999
Creator: Dobbs, Gary
Object Type: Newspaper
System: The Portal to Texas History
Oxidation Effects on the Friction of Lubricants and Self-Lubricating Materials in the Enduring Stockpile (open access)

Oxidation Effects on the Friction of Lubricants and Self-Lubricating Materials in the Enduring Stockpile

Predictive models of solid lubricant performance are needed to determine the dynamic behavior of electromechanical devices after long periods of storage. X-ray photoelectron spectroscopy has been used to determine the kinetics of oxidation and sulfate formation for solid lubricants and self-lubricating materials containing MoS{sub 2}, exposed to a variety of oxidation conditions. The frictional performance of the lubricant has then been determined as a fi.mction of its surface chemistry and the ambient environment in which sliding takes place. Results indicate that surface sulfate formation governs the initial or start-up friction coefficient of MoS{sub 2}-containing films, while the composition of the ambient gas determines the steady-state friction coefficient. The dependence of the steady-state friction coefficient on the environment in which sliding takes place has been examined, and the results show that dynamic oxidation of surfaces having exposed metal has a major impact on friction. Surface oxidation is also shown to influence the frictional behavior of a self-lubricating composite material containing MoS{sub 2}.
Date: March 18, 1999
Creator: Dugger, M. T.; Peebles, D. E.; Ohlhausen, J. A.; Robinson, J. A.; Sorroche, E. H. & Fanska, J.
Object Type: Article
System: The UNT Digital Library
The Canadian Record (Canadian, Tex.), Vol. 109, No. 62, Ed. 1 Thursday, March 18, 1999 (open access)

The Canadian Record (Canadian, Tex.), Vol. 109, No. 62, Ed. 1 Thursday, March 18, 1999

Weekly newspaper from Canadian, Texas that includes local, state and national news along with extensive advertising.
Date: March 18, 1999
Creator: Ezzell, Nancy & Brown, Laurie Ezzell
Object Type: Newspaper
System: The Portal to Texas History
Controlling the Expansion of Laser-Fusion Plasma to Minimize Impact Damage (open access)

Controlling the Expansion of Laser-Fusion Plasma to Minimize Impact Damage

I propose to analytically model the rapid, nonequilibrium expansion of laser-fusion plasma from an initial diameter of 1 mm to a final diameter of 10 m. The aim is to devise a counterforce that minimizes the impact damage on optics by laser-plasma debris. This flow model is the basis of an idea for a dynamic target that efficiently converts laser energy to x-rays while minimizing the total mass propelled as debris. Also, the flow model is the basis of an idea to magnetically deflect material away from the optic ports in the vacuum chamber wall. The model combines results for supersonic one-dimensional gas flow of cylindrical-hemispherical symmetry, with a transition from thermal to nonequilibrium (''frozen'') plasma flow, which is set differently along each characteristic line (the ''Bray criterion'' as a Riemann invariant). The model shows how density, pressure, velocity, ionization fraction, electron temperature, and electrical conductivity vary over space and time, given an impulsively-heated source mass. The model is analytical, and examples are calculated on a desktop computer. This ease-of-use makes it possible to iterate quickly when refining ideas, such as a dynamic metal-vapor target that propels minimal debris, and a magnetohydrodynamic generator as a brake on the flow speed …
Date: March 18, 1999
Creator: Garcia, M.
Object Type: Report
System: The UNT Digital Library
Today Cedar Hill (Duncanville, Tex.), Vol. 33, No. 52, Ed. 1 Thursday, March 18, 1999 (open access)

Today Cedar Hill (Duncanville, Tex.), Vol. 33, No. 52, Ed. 1 Thursday, March 18, 1999

Weekly newspaper published in Duncanville, Texas that includes local Cedar Hill, state, and national news along with advertising.
Date: March 18, 1999
Creator: Gooch, Robin
Object Type: Newspaper
System: The Portal to Texas History
Bent Superconducting Solenoids for the Muon Cooling Experiment (open access)

Bent Superconducting Solenoids for the Muon Cooling Experiment

This report describes some solenoid design work done for the cooling experiment for the muon collider collaboration. This report describes an analysis section of superconducting solenoids that have a center line induction of 3.0 T. The section is bent in the shape of an S. Each bend in the S bends the muon beam one radian (57.3 degrees). The warm bore diameter of the solenoid bent solenoid is 300 to 320 mm. The radius of the bend at the solenoid center line is 1000 mm. This report shows the results of three dimensional field calculations and presents a solenoid design that will include four TPC detectors that are 240 mm in diameter and 550 mm long as well as a 1300 mm long section of 1300 MHz RF cavities. The TPC sections need a solenoid wann bore diameter of about 300 320 mm while RF cavities require a warm bore diameter of 440 mm. The superconducting solenoid design must take into account the varying warm bore diameter requirements for the magnet string yet meet the stringent solenoidal field uniformity requirements within the active volume of the four TPCs.
Date: March 18, 1999
Creator: Green, M. A.; Eyssa, Y.; Kenney, S.; Miller, J. R.; Prestemon, S. & Wang, S. T.
Object Type: Article
System: The UNT Digital Library
Sanger Courier (Sanger, Tex.), Vol. 100, No. 21, Ed. 1 Thursday, March 18, 1999 (open access)

Sanger Courier (Sanger, Tex.), Vol. 100, No. 21, Ed. 1 Thursday, March 18, 1999

Weekly newspaper from Sanger, Texas that includes local, state, and national news along with extensive advertising.
Date: March 18, 1999
Creator: Hardy, Lisa
Object Type: Newspaper
System: The Portal to Texas History
Garber Billings News (Garber, Okla.), Vol. 99, No. 23, Ed. 1 Thursday, March 18, 1999 (open access)

Garber Billings News (Garber, Okla.), Vol. 99, No. 23, Ed. 1 Thursday, March 18, 1999

Weekly newspaper from Garber, Oklahoma that includes local, state, and national news along with advertising.
Date: March 18, 1999
Creator: Hogan, Vickie Lee
Object Type: Newspaper
System: The Gateway to Oklahoma History
Sapulpa Daily Herald (Sapulpa, Okla.), Vol. 84, No. 159, Ed. 1 Thursday, March 18, 1999 (open access)

Sapulpa Daily Herald (Sapulpa, Okla.), Vol. 84, No. 159, Ed. 1 Thursday, March 18, 1999

Daily newspaper from Sapulpa, Oklahoma that includes local, state, and national news along with advertising.
Date: March 18, 1999
Creator: Horn, Richard A.
Object Type: Newspaper
System: The Gateway to Oklahoma History