This paper will focus on the methodology of using a 2D plasma Direct Simulation Monte Carlo technique to simulate the species transport in an inductively coupled, low pressure, chemically reacting plasma system. The pressure in these systems is typically less than 20 mtorr with plasma densities of approximately 10{sup 17} {number_sign}/m{sup 3} and an ionization level of only 0.1%. This low ionization level tightly couples the neutral, ion, and electron chemistries and interactions in a system where the flow is subsonic. We present our strategy and compare simulation results to experimental data for Cl{sub 2} in a Gaseous Electronics Conference (GEC) reference cell modified with an inductive coil.

Science took the front seat as 219 Advanced Light Source (ALS) users and staff gathered on Monday and Tuesday, October 18 and 19 for the twelfth annual users' meeting. The bulk of the meeting was dedicated to reports on science at the ALS. Packed into two busy days were 31 invited oral presentations and 80 submitted poster presentations, as well as time to visit 24 vendor booths. The oral sessions were dedicated to environmental science, chemical dynamics, biosciences, magnetic materials, and atomic and molecular science. In addition, there was an ALS highlights session that emphasized new results and a session comprising highlights from the young scientists who will carry the ALS into the future.

Today's insurance industry strongly emphasizes developing cost-effective hazard mitigation programs, increasing and retaining commercial and residential customers through better service, educating customers on their exposure and vulnerabilities to natural disasters, collaborating with government agencies and emergency management organizations, and exploring the use of new technologies to reduce the financial impact of disasters. In June of 1998, the National Renewable Energy Laboratory (NREL) and the National Association of Independent Insurers (NAII) sponsored a seminar titled, ''Solar Technology and the Insurance Industry.'' Presentations were made by insurance company representatives, insurance trade groups, government and state emergency management organizations, and technology specialists. The meeting was attended by insurers, brokers, emergency managers, and consultants from more than 25 US companies. Leading insurers from the personal line and commercial carriers were shown how solar technology can be used in underwriting, claims, catastrophe response, loss control, and risk management. Attendees requested a follow-up report on solar technology, cost, and applications in disasters, including suggestions on how to collaborate with the utility industry and how to develop educational programs for business and consumers. This report will address these issues, with an emphasis on pre-disaster planning and mitigation alternatives. It will also discuss how energy efficiency and renewable …

A new method of ultrasensitive isotope trace analysis has been developed. This method, based on the technique of laser manipulation of neutral atoms, has been used to count individual {sup 85}Kr and {sup 81}Kr atoms present in a natural krypton gas sample with isotopic abundances in the range of 10{sup {minus}11} and 10{sup {minus}13}, respectively. This method is free of contamination from other isotopes and elements and can be applied to several different isotope tracers for a wide range of applications. The demonstrated detection efficiency is 1 x 10{sup {minus}7}. System improvements could increase the efficiency by many orders of magnitude.

The optical arrangement of the scanning transmission electron microscope (STEM) allows formation of incoherent images by use of a large annular detector. Here we show this capability in the imaging of defects in GaN and the interfacial region of an Au/GaAs ohmic contact. A resolution of around 0.15 nm is attained. Such Z-contrast images show strong atomic number contrast and allow the probe to be positioned accurately at the defect or interface for the purpose of performing high spatial resolution electron energy-loss spectroscopy (EELS).

The Relativistic Heavy Ion Collider RHIC will collide polarized proton beams up to a maximum beam energy of 250 GeV [1]. The invariant spin field in a high energy ring can vary substantially across the beam. This decreases the amount of polarization provided to experiments and makes the polarization strongly dependent on the position in phase space. This paper describes a method to compute the invariant spin field by adiabatically blowing up the beam with an rf dipole. This method will also allow measuring the invariant spin field in RHIC.

We have studied the vortex phase diagram of YBa{sub 2}Cu{sub 3}O{sub 7{minus}{delta}} (YBCO) in very strong magnetic field (0-26 Tesla) by a.c. calorimetry. We describe the anomalies associated with the transitions between the different vortex states (solid, liquid, and glass), with special emphasis on the first order flux lattice melting.

The Silicon Vertex Tracker is the CDF online tracker which will re- construct 2D tracks using hit positions measured by the Silicon Vertex Detector and Central Outer Chamber tracks found by the eXtremely Fast Tracker. The precision measurement of the track impact parameter will allow triggering on events contain- ing B hadrons. This will allow the investigation of several important problems in B physics, like CP violation and B_s mixing, and to search for new heavy particles decaying to b{anti b} .

Comparative studies were done on two new types of boron based anion receptors, tris(pentafluorophenyl) borane (TFPB) and tris(pentafluorophenyl) borate (TFPBO), regarding conductivity enhancement electrochemical and thermal stability when used as additives in composite electrolytes for lithium batteries. Both additives enhance the ionic conductivity of electrolytes of simple lithium salts, LiF, CF{sub 3}CO{sub 2}Li and C{sub 2}F{sub 5}CO{sub 2}Li in several organic solvents. The electrochemical windows of TPFB based electrolytes in ethylene carbonate (EC)-propylene carbonate (PC)-dmethyl carbonate (DMC) (1:1:3, v/v) are up to 5, 4.76 and 4.96 V for LiF, CF{sub 3}CO{sub 2}Li and C{sub 2}F{sub 5}CO{sub 2}Li respectively. TPFBO has lower electrochemical stability compared to TPFB. The thermal stability of pure TFPB is better than TFPBO. The lithium salt complexes have higher thermal stability than these two compounds. TPFB based electrolytes showed high cycling efficiencies and good cycleability when they were tested in Li/LiMn{sub 2}O{sub 4} cells. The capacity retention of the cells using TFPB based electrolytes during multiple cycling is better than those using TFPBO based electrolytes.

Small-angle neutron scattering has been used to study the effect of temperature and pressure on the phase behavior of semidilute solutions of polymers dissolved in organic and supercritical solvents. Above the theta temperature (To), these systems exhibit a ''good solvent'' domain, where the molecules expand beyond the unperturbed dimensions in both organic solvents and in COZ. However, this transition can be made to occur at a critical ''theta pressure'' (PO) in CO2 and this represents a new concept in the physics of polymer-solvent systems. For T < To, and P < Po, the system enters the ''poor solvent'' domain where diverging concentration fluctuations prevent the chains from collapsing and allow them to maintain their unperturbed dimensions.

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Between 1992 to 1996, the CDF and D0 detectors each collected data samples exceeding 100 pb{sup {minus}1} of p{bar p} collisions at {radical}s = 1.8 TeV at the Fermilab Tevatron. These data sets led to a large number of precision measurements of the properties of B hadrons including lifetimes, masses, neutral B meson flavor oscillations, and relative branching fractions, and to the discovery of the B{sub 0} meson. Perhaps the most exciting result was the first look at the CP violation parameter sin ({vert_bar}2{beta}){vert_bar} using the world's largest sample of fully reconstructed B{sup 0}/{bar B}{sup 0} {r_arrow} J/{psi}K{sub s}{sup 0} decays. A summary of this result is presented here. In the year 2000, the Tevatron will recommence p{bar p} collisions with an over order of magnitude expected increased in integrated luminosity (1 fb{sup {minus}1} per year). The CDF and D0 detectors will have undergone substantial upgrades, particularly in the tracking detectors and the triggers. With these enhancements, the Tevatron B physics program includes precision measurements of sin(2{beta}) and B{sub s}{sup 0} flavor oscillations, as well as studies of rare B decays that are sensitive to new physics. The studies of B{sub s}{sup 0} mesons will be particularly interesting as this …

In conclusion, this work shows that for sodium coolant the reactor vessel auxiliary cooling system (RVACS) is an effective passive heat removal system if the reactor power does not exceed about 1600 MW(th). Its effectiveness is limited by the effective radiative heat transfer coefficient in the inner gap. In a lead cooled system, economic considerations may impose a lower limit.

The availability of high-energy, high-flux, collimated synchrotrons radiation has extended the application of deep X-ray lithography (DXRL) to thickness values of the PMMA resist of several millimeters. Some of the most severe limitations come from plastic deformation, stress, and cracks induced in PMMA during exposure and development. We have observed and characterized these phenomena quantitatively. Profilometry measurements revealed that the PMMA is subjected either to local shrinkage or to expansion, while compression and expansion evolve over time. Due to material loss and crosslinking, the material undergoes a shrinkage, while the radiation-induced decomposition generates gases expanding the polymer matrix. The overall dynamics of the material microrelief and stress during and after the exposure depend on the balance between compaction and outgassing. These depend in turn on the exposure conditions (spectrum; dose, dose rate, seaming, temperature), post-exposure storage conditions, PMMA material properties and thickness, and also on the size and geometry of the exposed patterns.

The mechanisms of proton radioactivity from deformed rare earth nuclei are discussed and preliminary results on the fine structure decay of {sup 131}Eu are presented.

Simple linear potentiodynamic cycling measurements have been made on abraded pure Al in borate, chromate, phosphate, sulfate and nitrate solutions. In borate and chromate solutions the currents continued to decrease with each subsequent cycle. In phosphate dissolution of the oxide takes place producing repetitive repeat curves. The current variations in borate and chromate were simulated using a high field conduction oxide growth model. Including oxide dissolution in the model simulated the phosphate behavior. Results in sulfate and nitrate solutions were more complex. The behavior in the sulfate solution was attributed to effects of sulfate the oxide/solution interface.

The longevity of high gain GaAs photoconductive semiconductor switches (PCSS) has been extended to over 100 million pulses. This was achieved by improving the ohmic contacts through the incorporation of a doped layer that is very effective in the suppression of filament formation, alleviating current crowding. Damage-free operation is now possible with virtually infinite expected lifetime at much higher current levels than before. The inherent damage-free current capacity of the bulk GaAs itself depends on the thickness of the doped layers and is at least 100A for a dopant diffusion depth of 4pm. The contact metal has a different damage mechanism and the threshold for damage ({approx}40A) is not further improved beyond a dopant diffusion depth of about 2{micro}m. In a diffusion-doped contact switch, the switching performance is not degraded when contact metal erosion occurs, unlike a switch with conventional contacts. This paper will compare thermal diffusion and epitaxial growth as approaches to doping the contacts. These techniques will be contrasted in terms of the fabrication issues and device characteristics.

A 500-ft length, 6-level, 3-component, vertical geophone array was permanently deployed within the upper 800 ft of Unocal's well GDCF 63-29 during a plug and abandonment operation on April 7, 1998. The downhole array remains operational after a period of 1 year, at a temperature of about 150 C. Continuous monitoring and analysis of shallow seismicity (<4000 ft deep) has been conducted over that same 1-year period. The downhole array was supplemented with 4 surface stations in late-1998 and early-1999 to help constrain locations of shallow seismicity. Locations occurring within about 1 km ({approximately}3000 ft) of the array have been determined for a subset of high-frequency events detected on the downhole and surface stations for the 10-week period January 6 to March 16, 1999. These events are distinct from surface-monitored seismicity at The Geysers in that they occur predominantly above the producing reservoir, at depths ranging from about 1200 to 4000 ft depth (1450 to -1350 ft elevation). The shallow seismicity shows a northeast striking trend, similar to seismicity trends mapped deeper within the reservoir and the strike of the predominant surface lineament observed over the productive field.

Our data suggest a correlation between near-interface strain in SiO{sub 2} and the ratio of fixed vs. mobile positive charge generated at the interface during forming gas annealing. A model based on first-principles quantum mechanical calculations supports this correlation.

The dynamic aperture at collision energy is determined pri-marily by the nonlinear fields of the IR quadrupoles but is also influenced by the beam-beam interactions. We revisit the choice of the crossing angle that maximizes the dynamic aperture with an accurate modeling of the long-range inter-actions and use of the present values of the IR quadrupole field harmonics. A separate but related issue we address is the amplitude growth of particles in the beam halo due to the long-range interactions.

The authors discuss the structure of the ''forward visible'' (FW) parts of double and skewed distributions related to usual distributions through reduction relations. They use factorized models for double distributions (DDs) {tilde f}(x,{alpha}) in which one factor coincides with the usual (forward) parton distribution and another specifies the profile characterizing the spread of the longitudinal momentum transfer. The model DDs are used to construct skewed parton distributions (SPDs). For small skewedness, the FW parts of SPDs H ({tilde x},{xi}) can be obtained by averaging forward parton densities f({tilde x}-{xi}{alpha}) with the weight {rho}({alpha}) coinciding with the profile function of the double distribution {tilde f}(x, {alpha}) at small x. They show that if the x{sup n} moments {tilde f}{sub n}({alpha}) of DDs have the asymptotic (1-{alpha}{sup 2}){sup n+1} profile, then the {alpha}-profile of {tilde f}(x,{alpha}) for small x is completely determined by small-x behavior of the usual parton distribution. They demonstrate that, for small {xi}, the model with asymptotic profiles for {tilde f}{sub n}({alpha}) is equivalent to that proposed recently by Shuvaev et al., in which the Gegenbauer moments of SPDs do not depend on {xi}. They perform a numerical investigation of the evolution patterns of SPDs and give interpretation of …

A number of fluoro-carbonate solvents were evaluated as electrolytes for Li-ion cells. These solvents are fluorine analogs of the conventional electrolyte solvents such as dimethyl carbonate, ethylene carbonate, diethyl carbonate in Li-ion cells. Conductivity of single and mixed fluoro carbonate electrolytes containing 1 M LiPF{sub 6} was measured at different temperatures. These electrolytes did not freeze at -40 C. We are evaluating currently, the irreversible 1st cycle capacity loss in carbon anode in these electrolytes and the capacity loss will be compared to that in the conventional electrolytes. Voltage stability windows of the electrolytes were measured at room temperature and compared with that of the conventional electrolytes. The fluoro-carbon electrolytes appear to be more stable than the conventional electrolytes near Li voltage. Few preliminary electrochemical data of the fluoro-carbonate solvents in full cells are reported in the literature. For example, some of the fluorocarbonate solvents appear to have a wider voltage window than the conventional electrolyte solvents. For example, methyl 2,2,2 trifluoro ethyl carbonate containing 1 M LiPF{sub 6} electrolyte has a decomposition voltage exceeding 6 V vs. Li compared to <5 V for conventional electrolytes. The solvent also appears to be stable in contact with lithium at room temperature.

Modern nuclear materials accounting and safeguards measurement systems are becoming increasingly advanced as they embrace emerging technologies. However, many facilities still rely on human intervention to update materials accounting records. The demand for nuclear materials safeguards information continues to increase while general industry and government down-sizing has resulted in less availability of qualified staff. Future safeguards requirements will necessitate access to information through unattended and/or remote monitoring systems requiring minimal human intervention. Under the auspices of the Department of Energy (DOE), LLNL is providing assistance in the development of standards for minimum raw data file contents, methodology for comparing shipper-receiver values and generation of total propagated measurement uncertainties, as well as the implementation of modern information technology to improve reliability of and accessibility to nuclear materials information. An integrated safeguards and accounting system is described, along with data and methodology standards that ultimately speed access to this information. This system will semi-automate activities such as material balancing, reconciliation of shipper/receiver differences, and report generation. In addition, this system will implement emerging standards that utilize secure direct electronic linkages throughout several phases of safeguards accounting and reporting activities. These linkages will demonstrate integration of equipment in the facility that measures material …

As III-V nitride device structures become more complicated and design rules shrink, well-controlled etch processes are necessary. Due to limited wet chemical etch results for the group-III nitrides, a significant amount of effort has been devoted to the development of dry etch processing. Dry etch development was initially focused on mesa structures where high etch rates, anisotropic profiles, smooth sidewalls, and equi-rate etching of dissimilar materials were required. For example, commercially available LEDs and laser facets for GaN-based laser diodes have been patterned using reactive ion etching (RIE). With the recent interest in high power, high temperature electronic devices, etch characteristics may also require smooth surface morphology, low plasma-induced damage, and selective etching of one layer over another. The principal criteria for any plasma etch process is its utility in the fabrication of a device. In this study, we will report plasma etch results for the group-III nitrides and their application to device structures.