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Adhesion, Deformation and Friction for Self-Assembled Monolayers on Au and Si Surfaces (open access)

Adhesion, Deformation and Friction for Self-Assembled Monolayers on Au and Si Surfaces

Using Interracial Force Microscopy (IFM), we investigated the tribological behavior of hexadecanethiol monolayer on Au and films of octadecyltrichlorosilane (ODTS), perfluorodecyltrichlorosilane (PFTS) and dodecane on Si. We observe a strong correlation between hysteresis in a compression cycle (measured via nanoindentation) and friction. Additionally, we suggest that the amount of hysteresis and friction in each film is related to its detailed molecular structure, especially the degree of molecular packing.
Date: July 7, 1999
Creator: Houston, J. E.; Hsung, R. P.; Kiely, J. D.; Mulder, J. A. & Zhu, X. Y.
System: The UNT Digital Library
Comparison of InP/InGaAs HBT and InAlAs/InGaAs HBT for ULP Applications (open access)

Comparison of InP/InGaAs HBT and InAlAs/InGaAs HBT for ULP Applications

The increased demand for portable electronics has lead to the need for higher performance and efficiency. Devices operating at less than 50 {micro}W of power are defined as ultra-low-power (ULP) devices. New progress has been achieved on InP/InGaAs HBT and InAIAs/InGaAs HBT optimized for ULP applications. f{sub T} values of 2.2 GHz, and f{sub MAX} values of 20 GHz have been obtained for HBTs operating at less than 40 {micro}W. Current gain is greater than 45 with the device operating at less than 20 {micro}A on a 2.5 x 5 {micro}m{sup 2} device. These devices have been significantly improved over the previously reported MOCVD grown InP/InGaAs ULP HBT which has f{sub MAX} of 10 GHz operating in the ultra-low-power level. The improvements have been attributed to the reduction of base dopant diffusion associated with Zn doping.
Date: July 7, 1999
Creator: Ashby, C. I. H.; Baca, A. G.; Chang, P. C.; Hafich, M. J.; Hietala, V. M. & Klem, J. F.
System: The UNT Digital Library
Design of the Main Injector extraction beamlines (open access)

Design of the Main Injector extraction beamlines

The Main Injector (MI) supports the Tevatron Fixed Tar- get and Proton-Antiproton Collider modes of operation as well as providing 120 GeV/c resonantly extracted beam for the Main Injector Fixed Target Program. A set of beam transport lines, called Al and Pl, from the Main Injector converge on the injection point of the Tevatron, with the Al being used to transport 150 GeV/c antipro- tons (pbars) to the Tevatron. Pl is used to transport 150 GeV/c protons to the Tevatron, 120 GeV/c protons to the pbar target, and eventually 120 GeV/c resonantly ex- tracted protons to the existing Fixed Target areas. In ad- dition, the Pl line will be used to transport 8.9 GeV/c pbars from the Source back to the MI and recycled 150 GeV/c pbars at the end of Collider stores. In order to ac- complish the second and third function, the Pl beamline is continued beyond the Tevatron injection point in a sec- tion of the decommissioned Main Ring, called the P2 beamline. This transports the protons to a magnetic switch used to select either the modified transport line, used for targeting protons for pbar production, or the transport line which connects to the existing Fixed Target …
Date: July 7, 1999
Creator: Johnson, David E.
System: The UNT Digital Library
Development and Testing of Insulated Drill Pipe (open access)

Development and Testing of Insulated Drill Pipe

This project has comprised design, analysis, laboratory testing, and field testing of insulated drill pipe (IDP). This paper will briefly describe the earlier work, but will focus on results from the recently-completed field test in a geothermal well. Field test results are consistent with earlier analyses and laboratory tests, all of which support the conclusion that insulated drill pipe can have a very significant effect on circulating fluid temperatures. This will enable the use of downhole motors and steering tools in hot wells, and will reduce corrosion, deterioration of drilling fluids, and heat-induced failures in other downhole components.
Date: July 7, 1999
Creator: Champness, T.; Finger, J. & Jacobson, R.
System: The UNT Digital Library
Development of lean premixed low-swirl burner for low NO{sub x} practical application (open access)

Development of lean premixed low-swirl burner for low NO{sub x} practical application

Laboratory experiments have been performed to evaluate the performance of a premixed low-swirl burner (LSB) in configurations that simulate commercial heating appliances. Laser diagnostics were used to investigate changes in flame stabilization mechanism, flowfield, and flame stability when the LSB flame was confined within quartz cylinders of various diameters and end constrictions. The LSB adapted well to enclosures without generating flame oscillations and the stabilization mechanism remained unchanged. The feasibility of using the LSB as a low NO{sub x} commercial burner has also been verified in a laboratory test station that simulates the operation of a water heater. It was determined that the LSB can generate NO{sub x} emissions < 10 ppm (at 3% O{sub 2}) without significant effect on the thermal efficiency of the conventional system. The study has demonstrated that the lean premixed LSB has commercial potential for use as a simple economical and versatile burner for many low emission gas appliances.
Date: July 7, 1999
Creator: Yegian, D. T. & Cheng, R. K.
System: The UNT Digital Library
Dynamic Range of Vertical Cavity Surface Emitting Lasers in Multimode Links (open access)

Dynamic Range of Vertical Cavity Surface Emitting Lasers in Multimode Links

The authors report spurious free dynamic range measurements of 850nm vertical cavity surface emitting lasers in short multimode links for radio frequency communication. For a 27m fiber link, the dynamic range at optimal bias was greater than 95dB-Hz{sup 2/3} for modulation frequencies between 1 and 5.5 GHz, which exceeds the requirements for antenna remoting in microcellular networks. In a free space link, they have measured the highest dynamic range in an 850nm vertical cavity surface emitting laser of 113dB-Hz{sup 2/3} at 900MHz. We have also investigated the effects of modal noise and differential mode delay on the dynamic range for longer lengths of fiber.
Date: July 7, 1999
Creator: Lee, H. L. T.; Dalal, R. V.; Ram, R. J. & Choquette, K. D.
System: The UNT Digital Library
Extreme Ultraviolet Lithography for 0.1 {micro}m Devices (open access)

Extreme Ultraviolet Lithography for 0.1 {micro}m Devices

Extreme Ultraviolet Lithography (EUVL) has emerged as one of the leading successors to optics for 0.1 {micro}m IC fabrication. Its strongest attribute is the potential to scale to much finer resolution at high throughput. As such, this technique could meet the lithography needs for Si ULSI down to fundamental device limits. In the US, Lawrence Livermore, Sandia, and Lawrence Berkeley National Laboratories are participating in an industry funded research effort to evolve EUV technology and build a prototype camera for lithographic exposure. More recently, both Europe and Japan have initiated government/industry sponsored programs in EUVL development. This talk will focus on our program successes to date, and highlight some of the challenges that still lie ahead.
Date: July 7, 1999
Creator: Vaidya, S.; Sweeney, D.W.; Stulen, R. & Attwood, D.
System: The UNT Digital Library
Fabrication of High Performance Microlenses for an Integrated Capillary Channel Electrochromatograph with Fluorescence Detection (open access)

Fabrication of High Performance Microlenses for an Integrated Capillary Channel Electrochromatograph with Fluorescence Detection

We describe the microfabrication of an extremely compact optical system as a key element in an integrated capillary channel electrochromatograph with fluorescence detection. The optical system consists of a vertical cavity surface-emitting laser (VCSEL), two high performance microlenses and a commercial photodetector. The microlenses are multilevel diffractive optics patterned by electron beam lithography and etched by reactive ion etching in fused silica. The design uses substrate-mode propagation within the fused silica substrate. Two generations of optical subsystems are described. The first generation design has a 6 mm optical length and is integrated directly onto the capillary channel-containing substrate. The second generation design separates the optical system onto its own substrate module and the optical path length is further compressed to 3.5 mm. The first generation design has been tested using direct fluorescence detection with a 750 nm VCSEL pumping a 10{sup {minus}4}M solution of CY-7 dye. The observed signal-to-noise ratio of better than 100:1 demonstrates that the background signal from scattered pump light is low despite the compact size of the optical system and is adequate for system sensitivity requirements.
Date: July 7, 1999
Creator: Wendt, J. R.; Warren, M. E.; Sweatt, W. C.; Bailey, C. G.; Matzke, C. M.; Arnold, D. W. et al.
System: The UNT Digital Library
First Observation of Mechanochromism at the Nanometer Scale (open access)

First Observation of Mechanochromism at the Nanometer Scale

A mechanically-induced color transition (''mechanochromism'') in polydiacetylene thin films has been generated at the nanometer scale using the tips of two different scanning probe microscopes. A blue-to-red chromatic transition in polydiacetylene molecular trilayer films, polymerized from 10,12-pentacosadiynoic acid (poly-PCDA), was found to result from shear forces acting between the tip and the poly-PCDA molecules, as independently observed with near-field scanning optical microscopy and atomic force microscopy (AFM). Red domains were identified by a fluorescence emission signature. Transformed regions as small as 30 nm in width were observed with AFM. The irreversibly transformed domains preferentially grow along the polymer backbone direction. Significant rearrangement of poly-PCDA bilayer segments is observed by AFM in transformed regions. The removal of these segments appears to be a characteristic feature of the transition. To our knowledge, this is the first observation of nanometer-scale mechanochromism in any material.
Date: July 7, 1999
Creator: Carpick, R. W.; Sasaki, D. Y. & Burns, A. R.
System: The UNT Digital Library
Geothermal Drilling Organization (open access)

Geothermal Drilling Organization

The Geothermal Drilling Organization (GDO), founded in 1982 as a joint Department of Energy (DOE)-Industry organization, develops and funds near-term technology development projects for reducing geothermal drilling costs. Sandia National Laboratories administers DOE funds to assist industry critical cost-shared projects and provides development support for each project. GDO assistance to industry is vital in developing products and procedures to lower drilling costs, in part, because the geothermal industry is small and represents a limited market.
Date: July 7, 1999
Creator: Sattler, A.R.
System: The UNT Digital Library
Measurement of the triple differential jet cross section at {square root} s = 1800 GeV (open access)

Measurement of the triple differential jet cross section at {square root} s = 1800 GeV

We present a measurement of the triple differential cross section for dijet production in proton-antiproton scattering at a center of mass energy of 1800 GeV. The data were taken with the D0 detector at the Fermilab Tevatron and are compared to next to leading order QCD theoretical predictions with differing parton distribution functions. The data are of sufficient accuracy to rule out or favor parton distribution functions over a wide range in x .
Date: July 7, 1999
Creator: Schellman, H.
System: The UNT Digital Library
MOCVD Growth of AlGaInN for UV Emitters (open access)

MOCVD Growth of AlGaInN for UV Emitters

Issues related to the growth of nitride-based UV emitters are investigated in this work. More than 100 times of improved in the optical efficiency of the GaN active region can be attained with a combination of raising the growth pressure and introducing a small amount of indium. The unique issue in the UV emitter concerning the use of AlGaN for confinement and the associated tensile cracking is also investigated. They showed that the quaternary AlGaInN is potentially capable of providing confinement to GaN and GaN:In active regions while maintaining lattice matching to GaN, unlike the AlGaN ternary system.
Date: July 7, 1999
Creator: Crawford, Mary & Han, Jung
System: The UNT Digital Library
Multispectral Thermal Imager (MTI) Payload Overview (open access)

Multispectral Thermal Imager (MTI) Payload Overview

MTI is a comprehensive research and development project that includes up-front modeling and analysis, satellite system design, fabrication, assembly and testing, on-orbit operations, and experimentation and data analysis. The satellite is designed to collect radiometrically calibrated, medium resolution imagery in 15 spectral bands ranging from 0.45 to 10.70 pm. The payload portion of the satellite includes the imaging system components, associated electronics boxes, and payload support structure. The imaging system includes a three-mirror anastigmatic off-axis telescope, a single cryogenically cooled focal plane assembly, a mechanical cooler, and an onboard calibration system. Payload electronic subsystems include image digitizers, real-time image compressors, a solid state recorder, calibration source drivers, and cooler temperature and vibration controllers. The payload support structure mechanically integrates all payload components and provides a simple four point interface to the spacecraft bus. All payload components have been fabricated and tested, and integrated.
Date: July 7, 1999
Creator: Bender, S. C.; Brock, B. C.; Bullington, D. M.; Byrd, D. A.; Claassen, P. J.; Decker, M. L. et al.
System: The UNT Digital Library
A New User-Friendly Model to Reduce Cost for Headwater Benefits Assessment (open access)

A New User-Friendly Model to Reduce Cost for Headwater Benefits Assessment

Headwater benefits at a downstream hydropower project are energy gains that are derived from the installation of upstream reservoirs. The Federal Energy Regulatory Commission is required by law to assess charges of such energy gains to downstream owners of non-federal hydropower projects. The high costs of determining headwater benefits prohibit the use of a complicated model in basins where the magnitude of the benefits is expected to be small. This paper presents a new user-friendly computer model, EFDAM (Enhanced Flow Duration Analysis Method), that not only improves the accuracy of the standard flow duration method but also reduces costs for determining headwater benefits. The EFDAM model includes a MS Windows-based interface module to provide tools for automating input data file preparation, linking and executing of a generic program, editing/viewing of input/output files, and application guidance. The EDFAM was applied to various river basins. An example was given to illustrate the main features of EFDAM application for creating input files and assessing headwater benefits at the Tulloch Hydropower Plant on the Stanislaus River Basin, California.
Date: July 7, 1999
Creator: Bao, Y.S.; Cover, C.K.; Perlack, R.D.; Sale, M.J. & Sarma, V.
System: The UNT Digital Library
On the Theory of Critical Currents and Flux Flow in Superconductors by the Mechanism of Plastic Deformation of the Flux-Line Lattice. (open access)

On the Theory of Critical Currents and Flux Flow in Superconductors by the Mechanism of Plastic Deformation of the Flux-Line Lattice.

In this paper I will discuss how the nature of the stress state in the flux-line lattice (FLL) of superconductors arises from the distribution, density, geometry, and strength of pinning centers. Under certain conditions this stress causes the onset of plastic deformation in the FLL for values of the current density below that required for flux-flow by general depinning. I will describe an analytic framework, based on a theory of plasticity of the FLL, which describes the flux-flow characteristics, including the possibility of thermally-activated flow and flux creep.
Date: July 7, 1999
Creator: Welch, D. O.
System: The UNT Digital Library
Optimization of Blazed Quantum Grid Infrared Photodetectors (open access)

Optimization of Blazed Quantum Grid Infrared Photodetectors

In a quantum grid infrared photodetector (QGIP), the active multiple quantum well material is patterned into a grid structure. The purposes of the grid are on the one hand to create additional lateral electron confinement and on the other to convert part of the incident light into parallel propagation. With these two unique functions, a QGIP allows intersubband transition to occur in all directions. In this work, we focused on improving the effectiveness of a QGIP in redirecting the propagation of light using a blazed structure. The optimization of the grid parameters in terms of the blaze angle and the periodicity was performed by numerical simulation using the modal transmission-line theory and verified by experiment. With a blazed structure, the sensitivity of a QGIP can be improved by a factor of 1.8 compared with a regular QGIP with rectangular profiles.
Date: July 7, 1999
Creator: Chen, C. J.; Choi, K. K.; Jiang, M.; Rokhinson, L. P.; Tamir, T.; Tsui, D. C. et al.
System: The UNT Digital Library
Oxygen-Induced Restructuring of Rutile TiO(2)(110): Formation Mechanism, Atomic Models, and Influence on Surface Chemistry (open access)

Oxygen-Induced Restructuring of Rutile TiO(2)(110): Formation Mechanism, Atomic Models, and Influence on Surface Chemistry

The rutile TiO{sub 2} (110) (1x1) surface is considered the prototypical ''well-defined'' system in the surface science of metal oxides. Its popularity results partly from two experimental advantages: bulk-reduced single crystals do not exhibit charging, and stoichiometric surfaces--as judged by electron spectroscopes--can be prepared reproducibly by sputtering and annealing in oxygen. We present results that show that this commonly-applied preparation procedure may result in a surface structure that is by far more complex than generally anticipated. Flat, (1x1) terminated surfaces are obtained by sputtering and annealing in ultrahigh vacuum. When re-annealed in oxygen at moderate temperatures (470 K to 660 K), irregular networks of partially-connected, pseudohexagonal rosettes (6.5 x 6 {angstrom} wide), one-unit cell wide strands, and small ({approximately} tens of {angstrom}) (1x1) islands appear. This new surface phase is formed through reaction of oxygen gas with interstitial Ti from the reduced bulk. Because it consists of an incomplete, kinetically-limited (1x1) layer, this phenomenon has been termed restructuring. We report a combined experimental and theoretical study that systematically explores this restructuring process. The influence of several parameters (annealing time, temperature, pressure, sample history, gas) on the surface morphology is investigated using STM. The surface coverage of the added phase as …
Date: July 7, 1999
Creator: Li, Min; Hebenstreit, Wilhelm; Diebold, Ulrike; Henderson, Michael A. & Jennison, Dwight R.
System: The UNT Digital Library
Photorefractivity in liquid crystals doped with a soluble conjugated polymer. (open access)

Photorefractivity in liquid crystals doped with a soluble conjugated polymer.

Photoconductive polymers are doped into liquid crystals to create a new mechanism for space-charge field formation in photorefractive liquid crystal composites. The composites contain poly(2,5-bis(2{prime}-ethylhexyloxy)-1,4-phenylenevinylene) (BEH-PPV) and the electron acceptor N,N{prime}-dioctyl-1,4:5,8-naphthalenediimide, NI. Using asymmetric energy transfer (beam coupling) measurements that are diagnostic for the photorefractive effect, the direction of beam coupling as a function of grating fringe spacing inverts at a spacing of 5.5 {micro}m. We show that the inversion is due to a change in the dominant mechanism for space-charge field formation. At small fringe spacings, the space-charge field is formed by ion diffusion in which the photogenerated anion is the more mobile species. At larger fringe spacings, the polarity of the space charge field inverts due to dominance of a charge transport mechanism in which photogenerated holes are the most mobile species due to hole migration along the BEH-PPV chains coupled with interchain hole hopping. Control experiments are presented, which use composites that can access only one of the two charge transport mechanisms. The results show that charge migration over long distances leading to enhanced photorefractive effects can be obtained using conjugated polymers dissolved in liquid crystals.
Date: July 7, 1999
Creator: Niemczyk, M. P.; Svec, W. A.; Wasielewski, M. R. & Wiederrecht, G. P.
System: The UNT Digital Library
Solicitation - Geothermal Drilling Development and Well Maintenance Projects (open access)

Solicitation - Geothermal Drilling Development and Well Maintenance Projects

Energy (DOE)-industry research and development (R and D) organization, sponsors near-term technology development projects for reducing geothermal drilling and well maintenance costs. Sandia National Laboratories (Albuquerque, NM) administers DOE funds for GDO cost-shared projects and provides technical support. The GDO serves a very important function in fostering geothermal development. It encourages commercialization of emerging, cost-reducing drilling technologies, while fostering a spirit of cooperation among various segments of the geothermal industry. For Sandia, the GDO also serves as a means of identifying the geothermal industry's drilling fuel/or well maintenance problems, and provides an important forum for technology transfer. Successfully completed GDO projects include: the development of a high-temperature borehole televiewer, high-temperature rotating head rubbers, a retrievable whipstock, and a high-temperature/high-pressure valve-changing tool. Ongoing GDO projects include technology for stemming lost circulation; foam cement integrity log interpretation, insulated drill pipe, percussive mud hammers for geothermal drilling, a high-temperature/ high-pressure valve changing tool assembly (adding a milling capability), deformed casing remediation, high- temperature steering tools, diagnostic instrumentation for casing in geothermal wells, and elastomeric casing protectors.
Date: July 7, 1999
Creator: Sattler, A.R.
System: The UNT Digital Library
Use of COTS [commercial-off-the-shelf] Microelectronics in Radiation Environments (open access)

Use of COTS [commercial-off-the-shelf] Microelectronics in Radiation Environments

This paper addresses key issues for the cost-effective use of COTS microelectronics in radiation environments that enable circuit or system designers to manage risks and ensure mission success. COTS parts with low radiation tolerance should not be used when they degrade mission critical functions or lead to premature system failure. We review several factors and tradeoffs affecting the successful application of COTS parts including (1) hardness assurance and qualification issues, (2) system hardening techniques, and (3) life-cycle costs. The paper also describes several experimental studies that address trends in total-dose, transient, and single-event radiation hardness as COTS technology scales to smaller feature sizes. As an example, the level at which dose-rate upset occurs in Samsung SRAMS increases from 1.4x10{sup 8} rads(Si)/s for a 256K SRAM to 7.7x10{sup 9} rads(Si)/s for a 4M SRAM, indicating unintentional hardening improvements in the design or process of a commercial technology. Additional experiments were performed to quantify variations in radiation hardness for COTS parts. In one study, only small (10-15%) variations were found in the dose-rate upset and latchup thresholds for Samsung 4M SRAMS from three different date codes. In another study, irradiations of 4M SRAMS from Samsung, Hitachi, and Toshiba indicate large differences in …
Date: July 7, 1999
Creator: Winokur, P. S.; Lum, G. K.; Shaneyfelt, M. R.; Sexton, F. W.; Hash, G. L. & Scott, L.
System: The UNT Digital Library