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The Hynol Process for conversion of coal and natural gas to methanol as a liquid fuel consists of three consecutive unit operations: (1) hydrogasification of coal, (2) steam reforming of the methane formed and added natural gas feedstock, and (3) catalytic methanol synthesis. The Hynol Process is a total recycle process. Using a process simulation computer program, mass and energy balances and yields and efficiency data have been obtained for a range of natural gas to coal feedstock ratios. Although the methanol yield increases with natural gas to coal feed ratio, the cost of feedstock per unit methanol is insensitive over a wide range of feedstock ratios. The Hynol Process produces a 13% increase in methanol yield compared to the equivalent of two separate conventional coal gasification and natural gas reforming plants. The CO{sub 2} emissions are reduced by 22% for the Hynol plant compared to the conventional processes with greater CO{sub 2} reductions at lower gas to coal feedstock ratios. A preliminary cost estimate for a 10,000 tons/day Hynol methanol plant indicates a lower production cost than the current cost of methanol by the conventional natural gas reforming plant. The lower unit energy cost for coal is beneficial in …

R2BaNiO5 (R = rare earth) quasi-1-D antiferromagnets are structurally equivalent to the well-studied 1-D S = 1 Haldane-gap compound Y2BaNiO5. Unlike the Y-nickelate though, these materials undergo 3-D magnetic ordering at finite temperatures. Recent inelastic neutron scattering studies of Pr2BaNiO5 and (Nd(x)Y(1-x))2BaNiO5 revealed purely one-dimensional gap excitations that propagate exclusively on the Ni-chains and are strikingly similar to Haldane gap modes in Y2BaNiO5. In the ordered phase these excitations survive and actually coexist with conventional spin waves. The results suggest that the Haldane singlet ground state of the Ni-chains is not fully destroyed by Neel ordering.

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The work carried out in this CRADA addressed the development of computational algorithms to simulate the response for commonly used electrochemical techniques. The goal was the incorporation of these algorithms into DigiSim^R, a generalized simulator for cyclic voltammetry (CV). CV, a ubiquitously applied electroanalytical technique used by nonelectrochemists as well as electrochemists, is sometimes referred to as "electrochemical spectroscopy". The latest version, DigiSim^R 2.1, is now being sold by the industrial partner, Bioanalytical Systems, Inc. The response of the electrochemical community to this latest program (as well as its predecessors, DigiSim^R 2.0 and the DOS version; versions 2.0 and 2.1 are for Windows), has been uniformly positive and numerous publications are now appearing which feature its application.

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