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Objectives of this program are to provide an advanced thermal barrier coating system with improved reliability and temperature capabilities. This report describes the manufacturing, deposition, bonding, non-destructive analysis; maintenance, and repair.

The objectives of this project were to provide an improved thermal barrier coating system with increased temperature capability and reliability. This report describes bond coat development, manufacturing, nondestructive evaluation, maintenance, and repair, and bench testing.

The 222-S Laboratory complex stores and uses over 400 chemicals. Many of these chemicals are used in laboratory analysis and some are used for maintenance activities. The majority of laboratory analysis chemicals are only used inside of fume hoods or glove boxes to control both chemical and radionuclide airborne concentrations. This evaluation was designed to determine the potential for laboratory analysis chemicals at the 222-S Laboratory complex to cause elevated airborne chemical concentrations under normal conditions. This was done to identify conditions and activities that should be subject to airborne chemical monitoring in accordance with the Westinghouse Hanford Company Chemical Hygiene Plan.

This report talks about the Alignment of the High Beta Magnets in the RHIC Interaction Regions

Sludge samples from the canisters in the Hanford K East Basin fuel storage pool have been retrieved and analyzed. Both chemical and physical properties have been determined. The results are to be used to determine the disposition of the bulk of the sludge and to assess the impact of residual sludge on dry storage of the associated intact metallic uranium fuel elements. This report is a summary and review of the data provided by various laboratories. Although raw chemistry data were originally reported on various bases (compositions for as-settled, centrifuged, or dry sludge) this report places all of the data on a common comparable basis. Data were evaluated for internal consistency and consistency with respect to the governing sample analysis plan. Conclusions applicable to sludge disposition and spent fuel storage are drawn where possible.

In 1995, P-SQUARED Technologies, Inc., (P2T) was tasked with defining the flood potential for seven buildings at the Y-12 Plant (Buildings 9204-2, 9204-2E, 9206, 9212, 9215, 9720-5, and 9995) in the assumed event of a design storm with a recurrence interval of 10,000 years. At the conclusion of the study, P2T prepared and submitted a report summarizing the flood potential for those seven buildings. In November of 1997, P2T was tasked with (1) defining flood potential for the same seven buildings listed above for design storms with recurrence intervals of 500 years and 2000 years, and (2) defining flood potential for Building 9720-38 for design storms with recurrence intervals of 500 years, 2000 years, and 10,000 years. This report presents the results of the analyses conducted to define flood potential at these locations and for these recurrence intervals. None of the buildings investigated are completely safe from flooding during the storms considered. Runoff from rooftops may cause limited flooding in any areas where water is allowed to pond next to doors, vents, windows, or other openings. Flooding depths inside buildings in these areas should be limited to 1 ft or less. Buildings with openings below the grade of adjacent roads …

The electron beams produced by two different welders were examined using computer assisted tomographic (CT) analysis. The machines used are Hamilton Standard welders with 150 kV/50mA maximum. One machine uses a ribbon filament while the other uses a hairpin filament. The objective of this study was to characterize the beam power distribution on each machine to see if weld parameters could easily be transferred between machines. Beam focus, voltage, and current settings were pre-selected to duplicate the welding conditions used in LLNL program applications. The results show that the actual beam currents measured by Faraday cup are 5 to 10% higher for the first machine and 30% lower for the second. The CT analysis of the beam shapes shows that the hairpin filament welder produces an elliptical beam shape in the sharp focus condition that defocuses to a diamond shape. The ribbon filament welder produced less of an elliptical beam shape in the sharp focus condition, but when defocused, acquires an elliptical shape. CT analysis of the effects of defocus on the peak power density shows that the hairpin filament drops in peak power density much more quickly than the ribbon filament for a given amount of defocus. Furthermore, it …

Column biooxidation tests with Kentucky coal confirmed results of earlier shake flask tests showing significant removal from the coal of arsenic, selenium, cobalt, manganese, nickel and cadmium. Rates of pyrite biooxidation in Kentucky coal were only slightly more than half the rates found previously for Indiana and Pittsburgh coals. Removal of pyrite from Pittsburgh coal by ferric ion oxidation slows markedly as ferrous ions accumulate in solution, requiring maintenance of high redox potentials in processes designed for removal of pyrite and hazardous air pollutant (HAP) precursors by circulation of ferric solutions through coal. The pyrite oxidation rates obtained in these tests were used by Unifield Engineering to support the conceptual designs for alternative pyrite and HAP precursor bioleaching processes for the phase 2 pilot plant. Thermophilic microorganisms were tested to determine if mercury could be mobilized from coal under elevated growth temperatures. There was no evidence for mercury removal from coal under these conditions. However, the activity of the organisms may have liberated mercury physically. It is also possible that the organisms dissolved mercury and it readsorbed to the clay preferentially. Both of these possibilities are undergoing further testing. The Idaho National Engineering and Environmental Laboratory�s (INEEL) slurry column reactor …

This is the eighth and final phase 1 quarterly technical progress report on this project which is investigating the microbiological removal of 13 inorganic hazardous air pollutant (HAP) precursors and pyrite from four U.S. coals. Since most of the HAP precursors are associated with sulfides, at least in part, pyrite-oxidizing bacteria are being tested for their ability to remove HAP precursors from coal. This report documents the completion of the final (reporting) task.

In September 1996, the seal tube at the 3CL window of the Interim Examination and Maintenance (IEM) Cell at the Fast Flux Test Facility (FFTF) failed. Replacement of the seal tube required removing the 3CL master slave manipulator (MSM) and shielding creating a streaming path for radiation from irradiated fuel and activated hardware in the IEM Cell. As a part of the preparation for the seal tube replacement, expected dose rates in the IEM Cell gallery outside the open 3CL penetration during the repair work were evaluated.

A change in field harmonics after quench and thermal cycles has been observed in superconducting magnets for the Relativistic Heavy Ion Collider (RHIC). This paper presents the results of a systematic investigation of this effect in a number of RHIC dipole and quadrupole magnets. These changes in field harmonics may limit the ultimate field quality and its reproducibility in superconducting magnets. A change in pre-stress has also been observed after quench and thermal cycles. A possible link between these two changes is explored.

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Nonmethane hydrocarbons (NMHCs) are involved in a complex series of reactions that regulate the levels of oxidants in the troposphere. Isoprene (C{sub 5}H{sub 8}), the primary NMHC emitted from deciduous trees, is one of the most important reactive hydrocarbons in the troposphere. The amount of isoprene entering the free troposphere is regulated by the compound's rate of emission from leaves and by chemical and physical processes in the forest canopy and the atmospheric boundary layer (ABL). This study uses a coupled canopy-ABL model to simulate these complex processes and compares calculated isoprene concentration profiles with those measured during aircraft flights above a forested region in the northeastern US. Land use information is coupled with satellite remote sensing data to describe spatial changes in canopy density during the field measurements. The high-resolution transport-chemistry model of Gao et al. (1993) for the ABL and the forest canopy layer is used to simulate vertical changes in isoprene concentration due to turbulent mixing and chemical reactions. The one-dimensional (1-D) ABL model includes detailed radiation transfer, turbulent diffusion, biogenic emissions, dry deposition, and chemical processes within the forest canopy and the ABL. The measured profiles are compared with the model simulations to investigate the biological, …

The Argonne Expedited Site Characterization (ANL ESC) methodology, developed by Argonne National Laboratory and popularly known as ESC, is an effective, cost- and time-saving approach for technically successful preremedial site characterizations. The major objective of the ANL ESC is to determine whether a site containing contamination requires remediation. The methodology is equivalent to a CERCLA RI/FS or a RCRA RFI/CMS investigation. The ANL ESC methodology is an interactive, integrated process emphasizing the use of existing data, multiple complementary characterization methods, and on-site decision making to optimize site investigations. The ANL ESC is the basis for the expedited site characterization standard of the ASTM (American Society for Testing and Materials). The methodology has been registered under the service mark QuickSite{trademark} to offer both clients and providers a mechanism for ensuring that they receive the ANL ESC methodology developed by Argonne. The ANL ESC is a flexible process and is neither site nor contaminant dependent. It can be tailored to fit the unique characteristics that distinguish one site from the next, in contrast to the traditional approach of making all sites conform to the same rigid, inflexible investigation regimen. The ANL ESC has been applied successfully to remedial site investigations of landfills …

The charge and longitudinal spin responses induced in a spin polarized quantum well by a weak electromagnetic field are investigated within the framework of the linear response theory. The authors evaluate the excitation frequencies for the intra- and inter-subband transitions of the collective charge and longitudinal spin density oscillations including many-body corrections beyond the random phase approximation through the spin dependent local field factors, G{sub {sigma}}{sup {+-}} (q,{omega}). An equation-of-motion method was used to obtain these corrections in the limit of long wavelengths, and the results are given in terms of the equilibrium pair correlation function. The finite degree of spin polarization is shown to introduce coupling between the charge and spin density modes, in contrast with the result for an unpolarized system.

We are developing low-temperature detectors for optical, ultraviolet, X-ray, and gamma-ray spectroscopy, and for biomolecular mass spectrometry. We present development work on these detectors and materials analysis and biomolecular mass spectrometry. We have measured thin-film Nb/Al/Al2O3/AlNb superconducting tunnel junction (STJ) X-ray detectors in the 0.2 to 1 keV band with a range of different junction sizes and aluminum film thicknesses. In one case, we have achieved the statistical limit to the energy resolution of 13 eV FWHM at 227 eV with an output count rate of 20,600 cts/s.

We study the two-dimensional global scale magnetic field structure for a system of two merging cylindrical plasmas in a steady state. In the limit of very large magnetic Reynolds numbers the reconnection process is slow, and the plasma almost everywhere finds itself in magnetostatic equilibrium. We show that under certain conditions the classical Syrovatskii-type Y-point configuration, with surface current concentrated only in the reconnection layer, is not possible. Instead, a cusp configuration is formed, with finite surface current in the separatrix. The equilibrium condition, together with constraints on the volume per flux, enables us to determine the shape of the separatrix and the magnetic field in the vicinity of the cusp point. Our solution is characterized by a singular power law dependence of current density on the flux coordinate ({psi}) near the separatrix: j({Psi}) {approx} |{Psi}|{sup -1/2}. This solution gives us the boundary conditions that are needed to find the flow in the reconnection and the separatrix regions.

The ODH analysis presented here covers the high bay and assembly hall docking area of the for the D-Zero detector. It includes the STand Alone helium Refrigerator (STAR) in the building. It also includes the D-Zero detector and it's associated cryogenic and gas systems. An ODH analysis is presented which shows that the D-Zero assembly building high bay including the detector docking area is ODH class O. Probabilities, leak rates, and fatality factors are generated for all items that are sources of inert gas. The scope of analysis included the calorimeter and gas components on the detector, the helium refrigerator/liquifier components, and the future solenoid and visible light photon counter cryogenics that will be added to the D-Zero detector. The analysis demonstrates that the calorimeter and helium refrigerator systems pose no ODH hazard to personnel.

In this report various forms of the Hamiltonian for particle motion in an accelerator will be derived. Except where noted, the treatment will apply generally to linear and circular accelerators, storage rings, and beamlines. The generic term accelerator will be used to refer to any of these devices. The author will use the usual accelerator coordinate system, which will be introduced first, along with a list of handy formulas. He then starts from the general Hamiltonian for a particle in an electromagnetic field, using the accelerator coordinate system, with time t as independent variable. He switches to a form more convenient for most purposes using the distance s along the reference orbit as independent variable. In section 2, formulas will be derived for the vector potentials that describe the various lattice components. In sections 3, 4, and 5, special forms of the Hamiltonian will be derived for transverse horizontal and vertical motion, for longitudinal motion, and for synchrobetatron coupling of horizontal and longitudinal motions. Hamiltonians will be expanded to fourth order in the variables.

This design-only conceptual design report (DOCDR) was prepared to support a funding request by the Department of Energy (DOE)-Office of Fissile Material Disposition (OFMD) for engineering design of the Pit Disassembly and Conversion Facility (PDCF) Project No. 99-D-141. The PDCF will be used to disassemble the nation`s inventory of surplus nuclear weapons pits and convert the plutonium recovered from those pits into a form suitable for storage, international inspection, and final disposition. The PDCF is a complex consisting of a hardened building that will contain the plutonium processes in a safe and secure manner, and conventional buildings and structures that will house support personnel, systems, and equipment. The PDCF uses the Advanced Recovery and Integrated Extraction System (ARIES), a low waste, modular pyroprocessing system to convert pits to plutonium oxide. The PDCF project consists of engineering and design, and construction of the buildings and structures, and engineering and design, procurement, installation, testing and start-up of equipment to disassemble pits and convert plutonium in pits to oxide form. The facility is planned to operate for 10 years, averaging 3.5 metric tons (3.86 tons) of plutonium metal per year. On conclusion of operations, the PDCF will be decontaminated and decommissioned.

Los Alamos National Laboratory (LANL) and its contractors have developed a conceptual design for a directional microborehole drilling system for hard-rock boring. Analytical calculations, simulations, and the results of laboratory testing of critical prototype drilling components have influenced the design. Two reduced-size drilling systems to produce small diameter, 500-ft-long, directionally drilled river crossing trajectories are proposed to prove feasibility of the concept: (1) a 2-1/4-in. diameter, early demonstration unit to drill directional ultraslimholes; and (2) a 1-1/8-in. diameter, ultimate design to drill directional microboreholes. Both concepts use versatile, coiled-tubing-deployed, hydraulically-powered drilling assemblies, and a surface platform that includes a tubing injector unit to develop high load insertion (snubbing) of the tubing into the sealed borehole. Surface injection will be used to develop the required bit thrust, and both concepts provide for the use of a commercial, real-time, location and steering system that is readily and routinely adapted for deployment on a coiled-tubing drilling platform. The conceptual drilling platform and its subassemblies are shown.

This document describes the Prioritization Phase Database that was prepared for the Project Hanford Management Contractors to support the implementation of DOE Order 5480.28. Included within this document are three appendices which contain the prioritized list of applicable Project Hanford Management Contractors Systems, Structures, and Components. These appendices include those assets that comply with the requirements of DOE Order 5480.28, assets for which a waiver will be recommended, and assets requiring additional information before compliance can be ascertained.

The authors have designed a new technique for measuring subpicosecond electron bunch lengths using coherent Smith-Purcell radiation. This new diagnostic technique involves passing the electron beam in close proximity of a grating with a period comparable to the electron bunch length. The emitted Smith-Purcell radiation will have a coherent component whose angular position and distribution are directly related to the electron bunch length and longitudinal profile, respectively. This new diagnostic technique is inherently simple, inexpensive and non-intercepting. The authors show that the new technique is also scaleable to femtosecond regime.