This paper describes methods for solid phase extraction and high performance liquid chromatography (HPLC). The following are described: Effects of Resin Sulfonation on the Retention of Polar Organic Compounds in Solid Phase Extraction; Ion-Chromatographic Separation of Alkali Metals In Non-Aqueous Solvents; Cation-Exchange Chromatography in Non-Aqueous Solvents; and Silicalite As a Stationary Phase For HPLC.

Directional solidification of eutectic alloys shows different types of eutectic morphologies. These include lamellar, rod, oscillating and tilting modes. The growth of these morphologies occurs with a macroscopically planar interface. However, under certain conditions, the planar eutectic front becomes unstable and gives rise to a cellular or a dendritic structure. This instability leads to the cellular/dendritic structure of either a primary phase or a two-phase structure. The objective of this work is to develop a fundamental understanding of the instability of eutectic structure into cellular/dendritic structures of a single phase and of two-phases. Experimental studies have been carried out to examine the transition from a planar to two-phase cellular and dendritic structures in a ceramic system of Alumina-Zirconia (Al{sub 2}O{sub 3}-ZrO{sub 2}) and in a transparent organic system of carbon tetrabromide and hexachloroethane (CBr{sub 4}-C{sub 2}Cl{sub 6}). Several aspects of eutectic interface stability have been examined.

Working directly on affine Lie groups, we construct several new formulations of the WZW model, the gauged WZW model, and the generic affine-Virasoro action. In one formulation each of these conformal field theories (CFTs) is expressed as a one-dimensional mechanical system whose variables are coordinates on the affine Lie group. When written in terms of the affine group element, this formulation exhibits a two-dimensional WZW term. In another formulation each CFT is written as a two-dimensional field theory, with a three- dimensional WZW term, whose fields are coordinates on the affine group. On the basis of these equivalent formulations, we develop a translation dictionary in which the new formulations on the affine Lie group are understood as mode formulations of the conventional formulations on the Lie group. Using this dictionary, we also express each CFT as a three-dimensional field theory on the Lie group with a four-dimensional WZW term. 36 refs.

The potential risk of lung cancer has evoked interest in the properties of radon decay products. There are two forms of this progeny: either attached to ambient aerosols, or still in the status of ions/molecules/small clusters. This ``unattached`` activity would give a higher dose per unit of airborne activity than the ``attached`` progeny that are rather poorly deposited. In this thesis, a system for determining unattached radon decay products electrical mobility size distribution by measuring their electrical mobilities was developed, based on the fact that about 88% of {sup 218}Po atoms have unit charge at the end of their recoil after decay from {sup 222}Rn, while the remainder are neutral. Essential part of the setup is the radon-aerosol chamber with the Circular Electrical Mobility Spectrometer (CEMS) inside. CEMS is used for sampling and classifying the charged radioactive clusters produced in the chamber. An alpha- sensitive plastic, CR-39 disk, is placed in CEMS as an inlaid disk electrode and the alpha particle detector. CEMS showed good performance in fine inactive particles` classification. If it also works well for radon decay products, it can offer a convenient size distribution measurement for radioactive ultrafine particles. However, the experiments did not obtain an acceptable …

Synchrotron small angle x-ray scattering (SAXS) has been applied to the structural study of several biological systems, including the nitrogenase complex, the heat shock cognate protein (hsc70), and lysozyme folding. The structural information revealed from the SAXS experiments is complementary to information obtained by other physical and biochemical methods, and adds to our knowledge and understanding of these systems.

The interaction of aerosol particles with wall surfaces is important in modeling their behavior. This interaction is usually represented in theoretical models as a loss term. The loss rate is the rate at which particles deposit or react with the surfaces. This loss term is important in many branches of aerosol science including human health and indoor air quality. Increased surface deposition usually means lower concentrations of airborne particles and hence, lower exposure to the inhabitants. If the efficiency of the particle deposition is influenced by factors other than the particle size, such as a natural convection of the air, this has to be taken into account to evaluate the results. In this research, test aerosol sized from 15 nm to 3 {micro}m are produced by several different aerosol generators; the gas burner, the Collison nebulizer, the condensation aerosol generator, the orifice atomizer and the Vibrating Orifice Aerosol Generator (VOAG). A rectangular chamber whose dimensions are 75 x 75 x 180 cm{sup 3} was used in this study. The particles were injected into the chamber, with a known ventilation and the concentration decay was monitored by the Ultrafine Condensation Particle Counter (UCPC) and Optical Particle Counter (OPC). During the measurement, …