Degree Department
Degree Level
Year
Month
2 Matching Results
Results open in a new window/tab.
Results:
1 - 2 of
2
A Study of Intra- and Interaggregate Exchange Processes of Alkyllithium Compounds Using One- and Two- Dimensional NMR Spectroscopy
One- and two-dimensional NMR spectroscopy, including 13C{6Li}{1H} triple resonance techniques, were used to characterize a series of mixed alkyllithium aggregates and to study their exchange processes.
Date:
May 1992
Creator:
Pannell, Daniel K. (Daniel Kirk)
System:
The UNT Digital Library
Solution Studies of the Structures and Stability of Mixed Lithium Alkoxide/Alkvllithium Aggregates
New one- and two-dimensional NMR techniques were used to elucidate the solution structures of these complex mixtures. The system, lithium tert-butoxide/tert-butyllithium, was studied as a model system with O/Li ratios varying from 0/1 to 1/1. It was found that at low O/Li ratios, a single mixed tetrameric aggregate was formed. At higher O/Li ratios, mixed hexameric species were formed. Two other systems, lithium isopropoxide/iso-propyllithium and lithium n-propoxide/n-propyllithium were also studied at low O/Li ratios.
Date:
December 1992
Creator:
DeLong, George T. (George Thomas)
System:
The UNT Digital Library