Chloride content of Rocky Flats scrub alloy twelfth campaign solution following head end treatment (open access)

Chloride content of Rocky Flats scrub alloy twelfth campaign solution following head end treatment

A single batch of dissolver solution from the twelfth Rocky Flats Scrub Alloy (RFSA) campaign has been analyzed for chloride content following head end treatment to reduce its concentration. Scrub alloy buttons were dissolved in Tank 6.4D during July. In subsequent head end processing, chloride was precipitated with mercurous ion added as the nitrate. The precipitate, Hg{sub 2}Cl{sub 2}, was co-removed with the gelatin floc via centrifugation. Duplicate samples from Tank 11.2, containing the head end product, produced excellent agreement between their density measurements and acid analyses, indicating them to be truly representative of the tank`s contents. Duplicate aliquots from each of these solutions were analyzed using the turbidimetric chloride method developed in the Separations Technology Laboratory. These resulted in an average chloride value of 53 ppm ({micro}g/mL) chloride for the head end product. Relative standard deviation of the measurement was {+-}6 ppm (n = 4), a precision of {+-}11%. Such a variance is normal at this low chloride level. Since initial chloride values prior to head end averaged 1365 ppm (0.0385M), as analyzed by Laboratories Department, a chloride DF of approximately 26 was obtained. Such a reduced chloride level (to less than 100 ppm) in the treated solution will …
Date: August 8, 1988
Creator: Holcomb, H. P.
Object Type: Report
System: The UNT Digital Library
Hyperfine interactions, the key to multiquark physics (open access)

Hyperfine interactions, the key to multiquark physics

Clues in the search for a fundamental description of hadron physics based on QCD may be obtained from a phenomenological constituent quark model in which the color-electric force binds quarks into saturated color-singlet hadrons, and finer details of the spectrum and multiquark physics are dominated by the color-magnetic hyperfine interaction. 47 refs.
Date: August 8, 1988
Creator: Likpink, H.J.
Object Type: Article
System: The UNT Digital Library
Study of heavy ion beams during longitudinal compression using particle simulation (open access)

Study of heavy ion beams during longitudinal compression using particle simulation

Particle simulations show that during longitudinal compression, there is little growth in beam longitudinal and transverse emittance. Both longitudinal and transverse temperatures follow adiabatic laws. The compressed beam has negligible longitudinal momentum spread and therefore can satisfy stringent requirements for final focusing. 4 refs., 3 figs.
Date: August 8, 1988
Creator: Ho, D.D.M. & Brandon, S.T.
Object Type: Article
System: The UNT Digital Library
X-ray diffractometry of lanthanum-nickel-aluminum alloys. Part 1 (open access)

X-ray diffractometry of lanthanum-nickel-aluminum alloys. Part 1

X-ray diffractometry provides much useful information on LANA alloys that complements data obtained by SEM and Electron Microprobe Analysis. Accurate measurements of the hexagonal lattice parameters of the primary LaNi{sub 5-y}Aly phase reveal the aluminum content (y) and allow the prediction of desorption pressures for the hydrogen isotopes. A study of the broadening of x-ray diffraction lines of the LaNi{sub 5-y}Aly primary phase caused by cyclic absorption and desorption of hydrogen suggests that substitution of aluminum for nickel stabilizes the primary phase with respect to formation of antistructure defects that could cause undesirable trapping of hydrogen isotopes. Correlation of XRD with SEM and EMPA results has helped identify secondary phases, determine their abundances in volume percent, and reveal how they react with hydrogen and the atmosphere. Characterizations of LANA alloys used in process development has provided the bases for development of specifications for alloys to be used in the Replacement Trittium Facility. 28 refs., 4 tabs., 12 figs.
Date: August 8, 1988
Creator: Mosley, W. C.
Object Type: Article
System: The UNT Digital Library
X-ray diffractometry of lanthanum-nickel-aluminum alloys (open access)

X-ray diffractometry of lanthanum-nickel-aluminum alloys

X-ray diffractometry provides much useful information on LANA alloys that complements data obtained by SEM and Electron Microprobe Analysis. Accurate measurements of the hexagonal lattice parameters of the primary LaNi{sub 5-y}Aly phase reveal the aluminum content (y) and allow the prediction of desorption pressures for the hydrogen isotopes. A study of the broadening of x-ray diffraction lines of the LaNi{sub 5-y}Aly primary phase caused by cyclic absorption and desorption of hydrogen suggests that substitution of aluminum for nickel stabilizes the primary phase with respect to formation of antistructure defects that could cause undesirable trapping of hydrogen isotopes. Correlation of XRD with SEM and EMPA results has helped identify secondary phases, determine their abundances in volume percent, and reveal how they react with hydrogen and the atmosphere. Characterizations of LANA alloys used in process development has provided the bases for development of specifications for alloys to be used in the Replacement Trittium Facility. 28 refs., 4 tabs., 12 figs.
Date: August 8, 1988
Creator: Mosley, W. C.
Object Type: Article
System: The UNT Digital Library