A process is being developed by the Sodium Waste Technology Program at ANL-W to remove metallic sodium from scrap and waste. The final step in the process is the removal of residual metallic sodium by evaporation at temperatures up to 482 C (900 F) and at pressures of about 10⁻² torr (1.3 Pa). Efficient operation of this process requires that the operators have a method to indicate the completion of the evaporation. This end point would signify when the chamber and scrap and waste is free of metallic sodium. It was determined that a measure of the vacuum was not sufficiently sensitive, and a research effort was undertaken to select an on-line monitoring device. In this effort, three promising methods were reviewed. The use of quadrupole mass spectrometer was recommended and an on-line device was designed for use in a Sodium Process Demonstration (SPD) Plant.

This report describes the preparation of a series of manganese oxides and an analysis of their sorptive, structural, and surface characteristics as low-energetic desiccants for passive dehumidification and active desiccant cooling systems. A cusped Type III isotherm for the adsorption of water is reported for the first time. The data are interpreted as evidence of a first-order phase change from a two-dimensional gas to a liquid film in the first reversibly adsorbed layer. It appears that the water adsorption characteristics of MnO2 compared to standard desiccants which exhibit Type II isotherms are due at least in part to differences in the physical topography and electronic properties of the desiccant substrates: MnO2 is a p-type semiconductor with essentially-flat, monoenergetic surface structures, while standard desiccants like silica gel are electronic insulators with irregular, heteroenergetic surfaces.

The need to understand concrete behavior under high temperatures in the nuclear industry has become rather acute. For this purpose, a constitutive model of concrete especially developed for this severe environment is indispensable. This report reviews the presently available constitutive models of concrete at standard-temperature conditions and considers their advantages and drawbacks. A rather simple but effective approach is selected to treat concrete behavior at high temperatures. Special emphasis is devoted to the modeling of concrete up to and including failure. The derived constitutive model is checked with biaxial and triaxial benchmark experimental results. Very good agreement is obtained.

Measurements of the optical properties of metallic aluminum are reviewed and available data are analyzed to obtain the bulk values of the optical constants and the complex dielectric function from 0.04 eV to 10 keV. The intra- and interband contributions to the dielectric function are discussed briefly, and recently proposed values for the Drude parameters describing the intraband absorption are critically considered. Factors influencing experimental measurements are discussed with emphasis on sample properties such as surface oxide layers, bulk inclusion of gases, surface roughness, and degree of crystallinity. The results of recent optical measurements are tabulated, along with recommended values of the optical properties resulting from a self-consistent Kramers-Kronig analysis of reflectance, transmission, and electron-energy-loss studies. The tabular data include the complex dielectric function, the complex index of refraction, and the reflectance and phase shift for normal incidence on a smooth, oxide-free surface. Detailed tabulations are given for the infrared, visible, and ultraviolet regions of the spectrum.

This conference evolved out of an idea that originated Department of Energy contractor's meeting in Gettysburg to have a conference devoted to topics of interest to both radiation chemists and physicists in radiation research. Radiation chemists tend to operate in a time domain where chemical reactions can be observed and to deduce values from that data. Meanwhile, physicists naturally focus considerable attention on initial energy deposition events and perform calculations which should predict the same initial yields. Contributed papers and remarks have been grouped according to broad subjects.

A nodal method is developed for the solution of the neutron-diffusion equation in two- and three-dimensional hexagonal geometries. The nodal scheme has been incorporated as an option in the finite-difference diffusion-theory code DIF3D, and is intended for use in the analysis of current LMFBR designs. The nodal equations are derived using higher-order polynomial approximations to the spatial dependence of the flux within the hexagonal-z node. The final equations, which are cast in the form of inhomogeneous response-matrix equations for each energy group, involved spatial moments of the node-interior flux distribution plus surface-averaged partial currents across the faces of the node. These equations are solved using a conventional fission-source iteration accelerated by coarse-mesh rebalance and asymptotic source extrapolation. This report describes the mathematical development and numerical solution of the nodal equations, as well as the use of the nodal option and details concerning its programming structure. This latter information is intended to supplement the information provided in the separate documentation of the DIF3D code.

REBUS-3 is a system of programs designed for the fuel-cycle analysis of fast reactors. This new capability is an extension and refinement of the REBUS-3 code system and complies with the standard code practices and interface dataset specifications of the Committee on Computer Code Coordination (CCCC). The new code is hence divorced from the earlier ARC System. In addition, the coding has been designed to enhance code exportability. >Major new capabilities not available in the REBUS-2 code system include a search on burn cycle time to achieve a specified value for the multiplication constant at the end of the burn step; a general non-repetitive fuel-management capability including temporary out-of-core fuel storage, loading of fresh fuel, and subsequent retrieval and reloading of fuel; significantly expanded user input checking; expanded output edits; provision of prestored burnup chains to simplify user input; option of fixed-or free-field BCD input formats; and, choice of finite difference, nodal or spatial flux-synthesis neutronics in one-, two-, or three-dimensions.

Quarterly report of the Argonne National Laboratory Chemical Engineering Division regarding activities related to properties and handling of radioactive materials, operation of nuclear reactors, and other relevant research.

Annual report of the environmental monitoring program at Argonne National Laboratory, discussing activities and findings of the group.

Report issued by the National Bureau of Standards on "surge response to turbulent wind in the presence of current and waves" (p. iii). Methods for estimating surge response are discussed. This report includes tables, graphs, and illustrations.

Report issued by the National Bureau of Standards over the energy performance of a day-lighted building. The different models and functions are discussed. This report includes tables, graphs, illustrations, and photographs.

Abstract: This report summarizes NBS standards committee activities and accomplishments during, calendar year 1982. It describes the management of standards activities at NBS, profiles NBS staf* participation on outside standards committees, and highlights significant technical and individual contributions made by NBS staff. In 1982, 457 staff members (or 29% of NBS' professional, scientific, and technical staff) participated in 1,046 outside standards committees of 97 national and international standards organizations.

"This document contains geologic and mineral resources reports for the Baltimore, Boston, Lake Champlain, and Providence 1 x 2 National Topographic Map Series (NTMS) Quadrangles in the Northeastern United States."

Partial abstract: "This report reviews the scope of a research effort initiated in 1974 at the U.S. Army Engineer Waterways Experiment Station with the objectives of (a) assessing the state of the art in geophysical cavity detection and delineation methodology and (b) developing new methods and improving or adapting old methods for application to cavity detection and delineation." This report discusses the geography, topography, site drilling tests, magnetic and microgravimetric surveys, and other information about the Medfor Cave site in Florida.

Final report regarding studies of weir jetties as an alternative for jetty design at tidal inlets. "The hydraulic model investigation was performed to study important design parameters for a weir jetty system including weir length, elevation, orientation with respect to the shoreline and the conventional portion of the jetty structure, tidal currents over the weir section, flow patterns in the vicinity of the weir section, sediment movement over the weir and effects of the weir jetty on accretion, and erosion upcoast of the jetty system" (abstract, para. 2).

From abstract: This report summarizes the results of a comprehensive survey conducted to identify and characterize portable dredges available in the United States.

From introduction: The purpose of this report is to present a sensitivity analysis on the effects that biased sampling of young calves and lactating females would have on the various estimated life history parameters. This sensitivity analysis provides one measure of reliability of the various estimates. Also, where inconsistencies in the estimates can be identified, this analysis provides one means for evaluating which estimates are likely in error.

From introduction: The purpose of this report is (1) to describe the geology, hydrology, and quality of water of Manatee County and (2) to evaluate the availability of surface and ground water for development. The report provides Manatee County, the Southwest Florida Water Management District, and the Florida Department of Natural Resources with a data base and an evaluation of the water resources of the area so that water-quality and water-resource problems and water-management and regulatory needs can be adequately defined and documented.

From purpose and scope: This report describes the effect of land application of effluent from wastewater treatment plants on ground-water quality in the Livermore-Amador Valley. The report focuses on five wastewater application areas contiguous to or near following wastewater treatment plants: Livermore, Pleasanton, Dublin-San Ramon Services District (was Valley Community Services District), Castlewood Corporation, and Veterans Administration Hospital.

Abstract: The Pinellas County landfill site is on a flat, coastal area characterized by a nearsurface water table. Part of the site is subject to tidal flooding; altitudes within the study area range from 8 to 12 feet above sea level. Three geohydrologic units underlie the landfill site. In descending order, these are: a surficial aquifer about 19 feet thick composed of sand and shell, a confining bed about 35 feet thick composed of marl and clay, and the Floridan aquifer composed of limestone. Landfill operations have not altered surface-water quality. Although leachate movement downward into the Floridan _aquifer is not indicated, vertical movement through the confining bed is about 0.005 foot per year. The rate of lateral movement of ground-water away from the site is about 1.2 feet per year; . however, the rate of movement along the boundary from the oldest section of the landfill through the surficial aquifer is about 20 feet per year. Peaks in concentration of selected chemical parameters and flow-rate analysis of water from trenches indicate the possibility of intermittent release of leachate from the landfill.

"This document provides geologic and mineral resources data for the Caliente, Ely, Klamath Falls, Vya and Wells 1 x 2 National Topographic Map Series (NTMS) Quadrangles, located in the Western United States."

A report regarding a comparative evaluation of radon measurement techniques for uranium exploration.

A report regarding a mineral evaluation of part of the Gold Butte district, in Clark County, Nevada