Degree Discipline

Month

1 Matching Results

Results open in a new window/tab.

Vibrational Dephasing of Haloalkanes and Halobenzenes (open access)

Vibrational Dephasing of Haloalkanes and Halobenzenes

The Raman linewidths of the carbon-halogen stretching mode was measured as a function of temperature in ethyl bromide, isopropyl chloride, isopropyl bromide, t-butyl chloride, t-butyl bromide, chlorobenzene, bromobenzene, iodobenzene and o-dichlorobenzene. The vibrational relaxation times showed a very clear trend. Together with earlier work on methyl iodide, these results provide evidence that the vibrational dephasing efficiencies (T^-1_iso) of the carbon-halogen mode vary in the order of Cl > Br > I. Vibrational dephasing times were calculated from the Fischer-Laubereau Isolated Binary Collision Mode. If further work shows this transferability to extend to other types of skeletal modes in molecular systems, this would have significant ramifications on future vibrational lineshape studies.
Date: May 1983
Creator: Ho, Salina Yuen-Han
System: The UNT Digital Library