An extreme ultraviolet (EUV) study of the emissions from intrinsic and injected impurities in TMX is presented. Two survey spectrographs were used to determine that the major impurities present were oxygen, nitrogen, carbon, and titanium. Three absolutely-calibrated monochromators were used to measure the time histories and radial profiles of these impurity emissions in the central cell and each plug. Two of these instruments were capable of obtaining radial profiles as a function of time in a single shot.

Significant progress has been made in better understanding the electron transport and reaction properties of model liquids and biological systems. The new results complement earlier studies of electrons and are important to all aspects of the interaction of radiation with matter and to the myriad of electronic processes that occur in a variety of systems. These processes range from dielectric breakdown to carcinogenesis as is illustrated in the following list of electron transport and reaction studies that were conducted in this contract period. The studies included: (1) effect of an external electric field on the electron attachment rate constant, k/sub e/, of SF/sub 6/ observed in the molecular liquids ethane and propane; (2) implications of field-dependent k/sub e/'s to dielectric breakdown in liquids; (3) influence of the electron-acceptor dipole moment on k/sub e/ in i-octane and the effect of solvent on electron-dipole interaction; (4) solvent effects on the electron-attachment process through measurements of the k/sub e/ of CCl/sub 4/ and ethyl bromide in i-octane/TMS mixtures; (5) electron attachment to reversed-micellar aggregates and comparison of the influence of the micellar water pool on the electron-capture process in the solvents i-octane and TMS; (6) correlation of diffusion-controlled k/sub e/'s with carcinogenicity and …

During the past contract year, considerable progress was made in characterization and activity/selectivity testing of iron and cobalt catalysts. Preparation of boride promoted cobalt and iron catalysts was refined and nearly completed. H/sub 2/ and CO adsorption and oxygen titration measurements were performed on a number of supported and unsupported catalysts, especially several boride promoted cobalt and iron catalysts. Activity/selectivity tests of 3 and 15% Fe/SiO/sub 2/ and Co/SiO/sub 2/ and of 6 borided cobalt and iron catalysts were completed. The product distributions for iron and cobalt boride catalysts are unusual and interesting. Boron promoted iron is more active and stable than iron/silica; cobalt boride has an unusually high selectivity for alcohols. Tests to determine effects of H/sub 2/S poisoning on activity/selectivity properties of 15% Co/SiO/sub 2/ indicate that a significant loss of activity occurs over a period of 24 to 28 h in the presence of 10 to 20 ppM H/sub 2/S. Product selectivity to liquids increased through a maximum during the gradual addition of sulfur. Reactant CO and H/sub 2/S interact partially to form COS which is less toxic than H/sub 2/S. H/sub 2/ and CO adsorption data were obtained for 3, 6 and 9% Co/ZSM-5 catalysts prepared …

Extensive NMR measurements of the proton relaxation times have been performed on low (i.e., alpha-phase) and intermediate (i.e., alpha'-phase) hydrogen concentrations in TiCr{sub}2H{sub}x with both the hexagonal Cl4 and cubic Cl5 Laves structures. The relaxation times indicate rapid diffusion rates above 200 K for all the TiCr{sub}2H{sub}x phases; however, large differences in the diffusion activation energies are observed. This behavior is associated with the hydrogen interstitial site occupancies and diffusion pathways becoming restricted in the Cl4 structure.

The turbine tests and results for the Brayton cycle subatmospheric system (SAS) are summarized. A scaled model turbine was operated in the same environment as that which a full-scale SAS machine would experience from the hot effluent flue gas from a glass container furnace. The objective of the testing was to evaluate the effects of a simulated furnace flue gas stream on the turbine nozzles and blades. The following specific areas were evaluated: erosion of the turbine nozzles and blades from the dust in the flue gas, hot corrosion from alkali metal salts in the dust and acid vapor (sulfur trioxide and hydrogen chloride) in the flue gas, and fouling and flow blockage due to deposition and/or condensation from the flue gas constituents.

Calculation of possible off-gases expected during the fabrication of SYNROC showed that volatilization of cesium would be a significant problem. Samples of the cesium containing minerals pollucite, CsAlSi/sub 2/O/sub 6/, and barium-cesium hollandite, (Ba,Cs)Al/sub 2/Ti/sub 6/O/sub 16/, were prepared for vaporization studies. Fifteen vaporization runs were made with the hollandite samples. With dry air as the carrier gas, the vapor pressure of cesium over Ba/sub 0/ /sub 8/Cs/sub 0/ /sub 4/Al/sub 2/Ti/sub 6/O/sub 16/ was found to be about 1 x 10/sup -7/ atm at 1050/sup 0/C.

Investment decisions pertaining to hydrothermal well fields and electric power plants are analyzed. Geothermal investment decision models were developed which, when coupled to a site-specific stochastic cash flow model, estimate the conditional probability of a positive decision to invest in the development of geothermal resource areas. Quantitative decision models have been developed for each major category of investor currently involved in the hydrothermal projects. These categories include: large, diversified energy resource corporations; independently operating resource firms; investor-owned electric utilities; municipal electric utilities; state-run resource agencies; and private third-party power plant investors. The geothermal cash flow, the investment decision analysis, and an example of model application for assessing the likely development of geothermal resource areas are described. The sensitivity of this investment behavior to federal incentives and research goals is also analyzed and discussed.

Silicon dendritic web is a single crystal ribbon form of silicon capable of fabrication into solar cells with AM1 conversion efficiency in excess of 15%. Progress on a study to demonstrate the technology readiness of the web process to meet the national goals for low cost photovoltaic power is reported. Several refinements were introduced into the sensing and control equipment for melt replenishment during web growth and also several areas were identified for cost reduction in the components of the prototype automated web growth furnace. A new circuit has been designed, assembled and tested to eliminate the sensitivity of the detector signal to the intensity of the reflected laser beam used to measure melt level. Noise due to vibrations on the silicon melt surface has also been eliminated. A new variable speed motor has been identified for the silicon feeder. Pellet feeding will be accomplished at a rate programmed to match exactly the silicon removed by web growth. A system to program the initiation of web growth automatically has been designed and first tests initiated. This should eventually result in reduced labor content and improved process reproducibility. Potential cost reductions in the furnace chamber and storage reel have been identified. …

A parameterization is provided for the bremsstrahlung spectrum in the incident electron energy range 10 to 500 keV for all elements, with particular emphasis on the range 20 to 100 keV for Z = 41 to 92. A general accuracy of 20% is achieved, with 50% in the worst cases, in most ranges utilizing simple one variable functions.

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The tracker uses a single photo sensor, and a rotating aperature to obtain tracking accuracies better than 1.5 mrads (0.1 degs). Peak signal detection is used to eliminate tracking of false sources, i.e., clouds, etc. A prism is employed to obtain an extended field of view (150 degs axially - 360 degs radially). The tracker digitally measures the Suns displacement angle relative to the concentrator axis, and repositions it incrementally. This arrangement permits the use of low cost non-servo motors. The local controller contains microprocessor based electronics, incorporating digital signal processing. A single controller may be time shared by a maximum of sixteen trackers, providing a high performance, cost effective solar tracking system, suitable for both line and point focus concentrators. An installation may have the local controller programmed as a standalone unit or slaved to a central controller. When used with a central controller, dynamic data monitoring and logging is available, together with the ability to change system modes and parameters, as desired.

In recent years, members of the Maryland Theory Group have made significant contributions to the national fusion theory programs and in many cases these theoretical development helped to interpret experimental results and to design new experimental programs. In the following, the authors summarize the technical progress in five major areas: (1) rf interaction with plasmas including wave propagation, rf heating, rf induced runaways and current drive; (2) spheromak -- formation, equilibrium, and stability; (3) stability of nonaxisymmetric systems (EBT, mirror, etc.); (4) stability theory of toroidal plasmas -- tokamak, RFP, etc.; and (5) nonlinear theory.

Investigations of ion generation and recombination mechanisms in the cesium plasma as they pertain to the advanced mode thermionic energy converter are described. The changes in plasma density and temperature within the converter have been studied under the influence of several promising auxiliary ionization candidate sources. Three novel approaches of external cesium ion generation have been investigated in some detail, namely vibrationally excited N/sub 2/ as an energy source of ionization of Cs ions in a DC discharge, microwave power as a means of resonant sustenance of the cesium plasma, and ion generation in a pulse N/sub 2/-Cs mixture. The experimental data obtained and discussed show that all three techniques - i.e. the non-LTE high-voltage pulsing, the energy transfer from vibrationally excited diatomic gases, and the external pumping with a microwave power - have considerable promise as schemes in auxiliary ion generation applicable to the advanced thermionic energy converter.

Recent (1977 to 1978) gravity and aeromagnetic surveys of the Timber Mountain region, southern Nevada, have revealed new details of subsurface structure and lithology. The data strongly suggest that deformation caused by volcanic events has been accommodated along straight-line faults combining in such a fashion as to given a curvilinear appearance to regional structure. The magnetic data suggest that rock units in the central graben and along the southeast margin of Timber Mountain may have been altered, perhaps thermally, from their original state. The gravity data indicate that the south part of the Timber Mountain is underlain by relatively dense rock possibly intrusive rock, like that which crops out along its southeast side. The gravity data also suggest that the Silent Canyon caldera may extend considerably south of its presently indicated southern limit and may underlie much of the area of Timber Mountain. The moat areas appear to be more rectangular or triangular than annular in shape. The southern part of Timber Mountain caldera is separated from the Yucca Mountain area to the south by a triangular horst. The structural relations of the rock units making up the horst are complex. Several linear terrain features in the southern part of …

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The overall objective of this program is to determine the optical properties of i-Carbon (diamond-like) films and determine if these films can be developed into antireflecting (AR) coatings for silicon solar cells. The i-C films have been produced on glass, silicon, and KCl by radio frequency (RF) plasma decomposition of the alkane gases. Films were also produced on silicon solar cells by low-energy ion beam techniques. These coatings did not perform as well as those made from hydrocarbon gases. Significant progress has been made in understanding the deposition parameters that affect the optical properties of the films. The optical constants n and k have been determined over a large range of process parameters and source gas. The degree of hydrogen incorporation in these films has been studied by SIMS analysis. It was found that the lower optically absorbing films contain more hydrogen. This hydrogen does not, however, manifest itself in fundamental C-H absorption bands in the infrared. Very efficient single-layer quarter-wave i-C AR coatings have been produced on single-crystal and SOC Si solar cells. An increase in cell efficiency of 40% over uncoated cells has been achieved.

From Abstract: "Field and laboratory data are presented for 331 water samples and 1,693 sediment samples from the Aztec Quadrangle, New Mexico. Uranium values have been reported by Los Almos National Laboratory in Report GJBX-129(78). The samples were collected by Los Almos National Laboratory; laboratory analysis and data reporting were performed by the Uranium Resource Evaluation Project at Oak Ridge, Tennessee."

This report presents field and laboratory data for 467 water samples and 1680 soil samples collected from the Carlsbad quadrangle in New Mexico.

This report presents field and laboratory data for 1098 water samples collected from the Choteau quadrangle in Montana.

From Abstract: "Field and laboratory data are presented for 451 water samples and 900 sediment samples from the Clifton Quadrangle, New Mexico; Arizona."

Abstract: "Field and laboratory data are presented for 1,342 water samples and 1,446 sediment samples from the Cutbank Quadrangle, Montana. The samples were collected by Los Alamos National Laboratory; laboratory analysis and data reporting were performed by the Uranium Resource Evaluation Project at Oak Ridge, Tennessee."

From abstract: Results of a reconnaissance geochemical survey of the Dallas Quadrangle, Texas are reported. Field and laboratory data are presented for 284 groundwater and 545 stream sediment samples. Statistical and areal distribution plots of uranium and possible uranium-related variables are displayed. A generalized geologic map of the survey area is provided.

This report presents field and laboratory data for 287 water samples and 622 soil samples collected from the Driggs quadrangle in Wyoming and Idaho.