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Quadrupole mass-filter sensitivities of H/sub 2/, HD, D/sub 2/, and T/sub 2/, and the kinetics of. beta. -particle induced exchange between H/sub 2/, D/sub 2/, and T/sub 2/ at 25. 4/sup 0/C
We have constructed a quadrupole-mass filter system to measure the equilibrium constants and rates of reaction of the ..beta..-particle-induced exchanges between H/sub 2/, D/sub 2/, and T/sub 2/ at cryogenic temperatures. Even with careful calibration experiments at 25.4/sup 0/C, we could not completely remove the mass discrimination inherent in our method. We estimate the accuracy of our mixture analyses to be +-2.2% in the D/sub 2/-DT-T/sub 2/ system, and +-9% in the H/sub 2/-HT-T/sub 2/ system. Preliminary kinetic experiments showed that the time to reach equilibrium in the exchange H/sub 2/ + T/sub 2/ = 2HT is 7 to 14 h. The equivalent time interval in the exchange D/sub 2/ + T/sub 2/ = 2DT is 3 to 7 h. This measured isotope effect of two can be used to predict the rates of the DT exchange from the HT rates in the literature.
Date:
January 11, 1978
Creator:
Pyper, J. W.; Kelly, E. M.; Magistad, J. G.; Tsugawa, R. T.; Roberts, P. E. & Souers, P. C.
Object Type:
Report
System:
The UNT Digital Library
[Photograph 2012.201.B0225.0282]
Photograph taken for a story in the Daily Oklahoman newspaper. Caption: "At right, using hand puppets Kate Hammett, left, and Jayme Howell tell the story of 'Clyde the Camel,' a descendent of the camels who carried the Wise Men to Bethlehem to see the infant Jesus."
Date:
December 11, 1978
Creator:
Hoke, Doug
Object Type:
Photograph
System:
The Gateway to Oklahoma History
[Photograph 2012.201.B0229.0390]
Photograph taken for a story in the Daily Oklahoman newspaper. Caption: "A Norfolk & Western Railroad yard worker keeps switching facility in Willianson, W. Va."
Date:
March 11, 1978
Creator:
unknown
Object Type:
Photograph
System:
The Gateway to Oklahoma History
[Photograph 2012.201.B0225.0283]
Photograph taken for a story in the Daily Oklahoman newspaper. Caption: "Members of Chi Omega Junior Alumnae of Oklahoma City, above, perform their own rendition of 'The Twelve Days of Christmas."
Date:
December 11, 1978
Creator:
Hoke, Doug
Object Type:
Photograph
System:
The Gateway to Oklahoma History
[Photograph 2012.201.B0051.1039]
Photograph taken for a story in the Daily Oklahoman newspaper. Caption: "Oklahoma City firemen work to free Marllee Braley, 6124 N Meridian, who was injured when her compact car went out of control and overturned on the icy Broadway Extension north of the Britton Road interchange Wednesday."
Date:
January 11, 1978
Creator:
Miller, Joe
Object Type:
Photograph
System:
The Gateway to Oklahoma History
[Photograph 2012.201.B0096.0680]
Photograph used for a story in the Daily Oklahoman newspaper. Caption: "Potential purchasers expect to tour bakery this week."
Date:
May 11, 1978
Creator:
Hoke, Doug
Object Type:
Photograph
System:
The Gateway to Oklahoma History
[Photograph 2012.201.B0125.0327]
Photograph used for a newspaper owned by the Oklahoma Publishing Company.
Date:
September 11, 1978
Creator:
unknown
Object Type:
Photograph
System:
The Gateway to Oklahoma History
[Photograph 2012.201.B0142.0633]
Photograph used for a story in the Daily Oklahoman newspaper. Caption: "World War I veteran Thomas R. Cooksey salutes the flag during Veterans Day memorial services at the capitol Saturday."
Date:
November 11, 1978
Creator:
Southerland, Paul
Object Type:
Photograph
System:
The Gateway to Oklahoma History
[Photograph 2012.201.B0136.0296]
Photograph used for a story in the Oklahoma Times newspaper. Caption: "The oldest two residents of the Classen Senior Citizens Center, 912 NW 13th, helped the center celebrate its sixth birthday last week."
Date:
January 11, 1978
Creator:
Argo, Jim
Object Type:
Photograph
System:
The Gateway to Oklahoma History
[Photograph 2012.201.B0148.0576]
Photograph used for a story in the Oklahoma Times newspaper. Caption: "Ruth Croft, Warr Acres."
Date:
April 11, 1978
Creator:
Hoke, Doug
Object Type:
Photograph
System:
The Gateway to Oklahoma History
[Photograph 2012.201.B0174.0073]
Photograph used for a story in the Oklahoma Times newspaper. Caption: "Parents of Northern Hills Elementary School pupils turned out on a warm spring evening this week to hear their 500 youngsters perform."
Date:
April 11, 1978
Creator:
Tullous, Don
Object Type:
Photograph
System:
The Gateway to Oklahoma History
[Photograph 2012.201.B0171.0160]
Photograph used for a story in the Daily Oklahoman newspaper. Caption: "RIGHT OFF when the invitation said "luncheon at 12:30, viewing at noon," I knew it was a special occasion."
Date:
May 11, 1978
Creator:
Miller, Joe
Object Type:
Photograph
System:
The Gateway to Oklahoma History
[Photograph 2012.201.B0153.0625]
Photograph used for a story in the Oklahoma Times newspaper. Caption: "Chief of Oklahoma City's park rangers, John Davee, checks over some recent incident reports."
Date:
May 11, 1978
Creator:
Thompson, Michal
Object Type:
Photograph
System:
The Gateway to Oklahoma History
[Photograph 2012.201.B0150.0442]
Photograph used for a story in the Daily Oklahoman newspaper. Caption: "Fantastic fashion is the keynote of the annual Ebony Fashion Fair a traveling show which features Clothes by the world's best designers."
Date:
February 11, 1978
Creator:
Argo, Jim
Object Type:
Photograph
System:
The Gateway to Oklahoma History
[Photograph 2012.201.B0171.0161]
Photograph used for a story in the Daily Oklahoman newspaper. Caption: "Colorful iris and hand-painted dishes dominate the table, left photo, decorated by Mrs. Joe Riggs."
Date:
May 11, 1978
Creator:
Miller, Joe
Object Type:
Photograph
System:
The Gateway to Oklahoma History
[Photograph 2012.201.B0149.0708]
Photograph used for a newspaper owned by the Oklahoma Publishing Company. Caption: "Vice Adm. William J. Crowe Jr. - US Navy - Deputy Chief of Naval Operations"
Date:
September 11, 1978
Creator:
unknown
Object Type:
Photograph
System:
The Gateway to Oklahoma History
[Photograph 2012.201.B0172.0087]
Photograph used for a newspaper owned by the Oklahoma Publishing Company. Caption: "Housing & Homes in Edmond Okla."
Date:
October 11, 1978
Creator:
unknown
Object Type:
Photograph
System:
The Gateway to Oklahoma History
[Photograph 2012.201.B0134.0446]
Photograph used for a story in the Daily Oklahoman newspaper. Caption: "Jamie and Kenneth Chuculate survey their luxurious living room, the result of hundreds of hours of labor.."
Date:
July 11, 1978
Creator:
Hoke, Doug
Object Type:
Photograph
System:
The Gateway to Oklahoma History
[Photograph 2012.201.B0138.0806]
Photograph used for a story in the Daily Oklahoman newspaper. Caption: "Dressed in her best 1901 Sunday outfit, "schoolteacher Lizzi Staples," left, guides Mr. and Mrs. B.R. Olhausen of Port Lavaca, Texas, through the general store in West of Yesterday exhibit at the National Cowboy Hall Of Fame and Western Heritage Center."
Date:
August 11, 1978
Creator:
Miller, Joe
Object Type:
Photograph
System:
The Gateway to Oklahoma History
[Photograph 2012.201.B0135.0807]
Photograph used for a story in the Daily Oklahoman newspaper. Caption: "Southeast's Matt Clark leaps over Monroe Bird of Northwest (25) for a rebound in Thursday night's All-City basketball game."
Date:
May 11, 1978
Creator:
Tullous, Don
Object Type:
Photograph
System:
The Gateway to Oklahoma History
[Photograph 2012.201.B0134.0448]
Photograph used for a story in the Daily Oklahoman newspaper. Caption: "The exterior of the Chuculate home in Mesta Park ."
Date:
July 11, 1978
Creator:
Hoke, Doug
Object Type:
Photograph
System:
The Gateway to Oklahoma History
[Photograph 2012.201.B0141.0442]
Photograph used for a story in the Daily Oklahoman newspaper. Caption: "In above photo, Nancy and Les Conner were among the party guests."
Date:
November 11, 1978
Creator:
Reed, Monty
Object Type:
Photograph
System:
The Gateway to Oklahoma History
[Photograph 2012.201.B0134.0447]
Photograph used for a story in the Daily Oklahoman newspaper. Caption: "The former maid's room become the new downstairs bathroom with the help of an antique vanity and a tub converted from a horse-watering trough..."
Date:
July 11, 1978
Creator:
Hoke, Doug
Object Type:
Photograph
System:
The Gateway to Oklahoma History
[Photograph 2012.201.B0144.0699]
Photograph used for a story in the Daily Oklahoman newspaper. Caption: "Cotton modules wait to be processed at the Cotton Growers Gin Yard at Altus as cotton harvesting operations get into full swing."
Date:
November 11, 1978
Creator:
unknown
Object Type:
Photograph
System:
The Gateway to Oklahoma History