The following report summarizes an investigation made to determine the extent to which zirconium and zirconium alloys exhibit delayed failure as caused by a combination of absorbed hydrogen and applied stress during the period September 15, 1961, to September 14, 1962.

From abstract: "This report describes and evaluates the variables affecting contamination of precise devices...In the present report these variables are discussed in more detail and the basis for their inclusion in the listing are given. The relative importance of the several parameters will be discussed in another report."

Quarterly report describing the progress and development of improved zirconium alloys for service in superheated water and steam. This report covers the period between July 1 to September 30, 1962 and was conducted by the United States and the European Atomic Energy Community (EURATOM).

"lsotope dilution techniques are described for the assay of chlorinated hydrocarbon pesticides and organic phosphorus pesticides in foods. Results are given for the determination of tetranitro-DDT-dianilide, dianilide of tetranitro- DDE, dieldrin, systox, and derivatives of these compounds. "

Technical report. From Abstract : "Bis(di-2-ethylbutylphosphinyl)methane, EBDPM, forms complexes with uranium (VI) nitrate and thorium (IV) nitrate in which EBDPM acts as a bidentate ligand and the nitrato groups appear to be coordinated. The complex with uranium (VI) is a monomer, UO2(NO3)29EBDPM), while the complex with thorium in a dimer, [Th(NO3)4]2(EBDPM)3. Both complexes are of high thermal stability."

Technical report. From Summary : "At the present time arsenazo appears to be widely used for the spectrophotometric determination of rare earths. Unfortunately, the method is not selective. The separation of rare earths and yttrium from interfering elements has been studied, and the following method has been proposed. Rare earths are precipitated as fluorides using fluorides using calcium fluoride as the carrier. Thorium and zirconium are removed by extraction with thenoyltrifluoroacetone (TTA) in xylene at pH 1.3. Small amounts of residual aluminum, iron, etc. are removed by extraction with 8-quinolinolchloroform at pH 4.5. Rare earths are separated from calcium by TTA extraction at the same pH, and they are then back-extracted into 1 M nitric acid. After evaporation of the solution, the rare earths are determined spectrophotometrically with arsenazo."

Technical report. From Abstract : "The acidity of a solution of acid, HX, and salt, MX, is affected by both the concentration of X- and M+ owing to incomplete dissociation of the salt, MX. it was possible to increase the acidity of a solution of 2,6-di-tert-butylphenol - tetrabutylammonium 2,6-di-tert-butylphenolate relative to a dilute solution of tetrabutylammonium hydroxide by increasing the tetrabutylammonium bromide content. This indicates that the dissociation constant of the hydroxide base is sufficiently large that extensive dissociation occurs in dilute solutions. The addition of tetrabutylammonium bromide is therefore recommended as a general method for increasing the acidity and improving the titration characteristics of extremely weak acids."

Technical report. From Abstract : "The silver-1,10-phenanthroline system has been studied and the stability constants determined for the 1:1 and 2:1 complexes using the silver electrode. This known system was then used to study the complexes of 1,10-phenanthroline with other metals. The log βn values found for the over-all stoichiometric stability constants are as follows: Ag, 5.02, 12.07; Mn, 3.88, 7.04, 10.11; Cd, 5.93, 10.52, 14.30; Zn, 6.83, 12.05, 16.92. The stoichiometric stability constants determined for copper are log k2 = 6.42 and log k2k3 = 11.05."

Technical report. From Abstract : "The scandium-yttrium and scandium-zirconium were studied by thermal and x-ray methods. Both systems are characterized by complete solid solubility in the low temperature hexagonal form and in the high temperature bcc form. In the Sc-Y system, there is a minimum in the solidus at 50 at. pct and 1365°C, while the solidus in the Sc-Zr system follows a nearly straight line relationship between the melting point of scandium and zirconium. There is a minimum in the temperature of transition from hexagonal to bcc in the Sc-Y system at 43 at. pct Y and 1175°C; while the temperature of transition is raised in the Sc-Zr system to a maximum of 1415°C at 30 at. pct Zr."

Technical report. From Abstract : "Plutonium (principally Pu238) was separated from neptunium, and both the plutonium and neptunium were purified from fission products and cations by a three-cycle anion exchange process."

The purpose of the Chemo-nuclear In-pile Research Loop is to provide a versatile facility for investigating chemo-nuclear reactions under flow conditions. The loop os designed to handle gaseous systems in conjunction with fixed packages of solid fuel.

The rf particle separator, proposed in 1959 by W.K.H. Panofsky and now in preparation for the Brookhaven Alternating Gradient Synchrotron, required a rf structure which gives a transverse impulse to a passing relativistic particle. In order to produce an accumulative transverse deflection of a traveling charged particle with an electromagnetic field, it is necessary that the field contains a synchronous component and in principle, waveguides and cavities are equivalent with respect to the particle dynamics. It was pointed out by H.G. Hereward, that the electric and magnetic deflection of a transverse electric mode (i.e., with no electric field component parallel to the direction of the particle velocity) cancel exactly at all particle velocities. The deflecting force of a transverse magnetic mode on a synchronous particle with the velocity v is proportional to the factor 1-(v/c)2 and vanishes therefore in the case of relativistic particles.

The purpose if this paper is to present tables of perturbed wave functions which have been obtained in three recent investigations: (1) wave functions v1'(nℓ→ℓ') which pertains to the perturbation of the d electrons of various ions as a result of the potential due to a nuclear quadrupole moment Q3 (2) wave functions v1',H(nℓ→ℓ) which represent the antishielding of the d electrons for a possible nuclear hexadecapole moment H; (3) wave functions u2'(ns→p) which pertain to the dipole perturbation of the valence (ns) electrons of the alkali atoms. Throughout this paper, the notation is the same as in a previous report in which a similar tabulation of perturbed wave function was made.

An air cored pulse deflection coil has been constructed for the Brookhaven AGS. The system produces a deflecting pulse with a peak radial deflection of 2.5 cms and duration of 70 microseconds. Beam spill duration of 15 to 50 microseconds from the target is readily achieved. One deflector has given satisfactory service for over a year and a second unit has been installed this summer.

Three thin-wall stainless steel fuel specimens made using fabrication processes and materials similar to the Consumers Big Rock Plant research and development fuel rods were power cycled 3000 times between 500,000 and 75,000 BTU/hr-ft2 in the General Electric Test Reactor (GETR) Trail Cable facility. The fuel specimens were exposed to 1000 psi boiling water. All of the fuel specimens withstood the test without failing or without any significant changes in the clad characteristics.

The work described in this report represents progress toward an agreement signed by the United States and the European Atomic Energy Community which provides a basis for cooperation in programs for the advancement of peaceful applications of atomic energy.

Work has continued on the development of accurate nuclear fuel burnup analysis. Work performed by the third quarter of 1962 is summarized.

This report is a supplement to GEAP-3759, Plastic Strain In Thin Fuel Element Cladding Due to UO2 Thermal Expansion. Cladding growth results are reported for repetitively irradiated, UO2 pellet-filled, annular capsules: for two UO2 powder-filled, annular capsules: and for six solid cylindrical pellet-filled capsules. Dimensional changes of the capsules irradiated during the entire program were analyzed, and the relationship of these results to the over-all fuel development program were evaluated.

A digital computer program, FORE, which calculates transients for a fast reactor, has been coded for the TRANSAC 2000 computer. Its purpose is to provide understanding of the dynamics of fast reactors with particular emphasis on large ceramic-fueled fast reactors. The program calculates reactor power and temperatures of fuel, coolant, clad, and structure.

The Fuel Cycle Program is an integrated program of investigation in the Vallecitos Boiling Water Reactor (VBWR) and other facilities to improve the technological limits of boiling water reactors.

The Big Rock Point Reactor of the Consumers Power Company went critical for the first time on September 27, 1962. Summarized here are objectives and accomplishments of the pre-operational period as well as an indication of work scope remaining.