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Determination of Organic Acids in Process Solutions (open access)

Determination of Organic Acids in Process Solutions

Abstract: "A method has been established for the estimation of volatile organic acids in aqueous process solutions containing UNH, nitric acid, ANN, sodium dichromate and small amounts of hexone. The practice is to distill a 400 ul or 500 ul sample in the presence of an excess of phosphoric acid and ferrous sulfate under a high vacuum; a special apparatus utilizing a receiver cooled with a dry ice-isopropanol mixture is employed. The distillate is taken up in isopropanol and then titrated potentiometrically with standard potassium hydroxide solution. Since nitric acid and organic acids are present, two end points are observed. The potassium hydroxide added between these end points is equivalent to the organic acids. In the titration, CO2 from the atmosphere or in the potassium hydroxide is a source of error. The former was avoided and correction was made for the latter."
Date: June 29, 1949
Creator: Brouns, R. J. & Pollock, C. W.
System: The UNT Digital Library
Density and Viscosity of Solutions in the Tributyl Phosphate Process for Uranium Recovery (open access)

Density and Viscosity of Solutions in the Tributyl Phosphate Process for Uranium Recovery

The following report discusses the presentation of preliminary density and viscosity data which may explain whether higher viscosities of the Deo Base-TBP systems, and a change in density differences between the two phases will lead to unsatisfactory column operation.
Date: November 29, 1949
Creator: Burger, L. L. & Slansky, C. M.
System: The UNT Digital Library
Density and Viscosity of Solutions in the Tributyl Phosphate Process for Uranium Recovery (open access)

Density and Viscosity of Solutions in the Tributyl Phosphate Process for Uranium Recovery

This report addresses the density and viscosity of solutions in the tributyl phosphate process for uranium recovery.
Date: November 29, 1949
Creator: Burger, L. L. & Slansky, C. M.
System: The UNT Digital Library
A PreliminaryReport on the Mechanism of the Decomposition ofDiacetyl Peroxide in Acetic Acid (open access)

A PreliminaryReport on the Mechanism of the Decomposition ofDiacetyl Peroxide in Acetic Acid

The decomposition of diacetyl peroxide in acetic acid-2-C{sup 14} has been studied, The activity of the products in general confirmed the mechanism of the reaction as proposed by Kharasch and Gladstone, The presence and distribution of activity in the methyl acetate produced in this reaction is not explained by the previously proposed mechanism. There was no appreciable exchange of acetic acid and diacetyl peroxide under the conditions of the reaction. Essentially no exchange of methyl acetate and acetic acid was observed when those reagents mere heated at 100 for five hours.
Date: December 29, 1949
Creator: Fry, A.J.; Tolbert, B.M. & Calvin, Melvin
System: The UNT Digital Library
Experimental determination of the subsonic performance of a ram-jet unit containing thin-plate burners (open access)

Experimental determination of the subsonic performance of a ram-jet unit containing thin-plate burners

Report presenting the performance of a ramjet unit consisting of an intake diffuser, an exhaust nozzle, and a cluster of thin-plate burners contained in a semicircular combustion chamber as investigated in the induction aerodynamics laboratory.
Date: June 29, 1949
Creator: Henry, John R.
System: The UNT Digital Library
The Chelate Process:  [Part] 5.  Investigation in Horizontal Extractors (open access)

The Chelate Process: [Part] 5. Investigation in Horizontal Extractors

The recovery of plutonium has been demonstrated in a laboratory countercurrent horizontal extractor using the TTA process. Using three extractive stages and two washing stages in each step, a recovery of 91 percent has been obtained in the chelation step and a recovery of 99.9+ percent in the de-chelation step. With five extractive stages, recoveries of 94-98 percent have been found for the chelation step.
Date: July 29, 1949
Creator: Hicks, T. E.; Rubin, B. & Vermeulen, T.
System: The UNT Digital Library
Low-speed static-stability and rolling characteristics of low-aspect-ratio wings of triangular and modified triangular plan forms (open access)

Low-speed static-stability and rolling characteristics of low-aspect-ratio wings of triangular and modified triangular plan forms

Report presenting a low-speed investigation in the stability tunnel to determine the effects of changes in profile and aspect ratio on the low-speed static-stability and rolling characteristics of triangular wings. The investigation was expanded to determine the effects of adding fins to the upper surface and of cutting portions from the tips of a triangular wing to form low-aspect-ratio tapered wings.
Date: March 29, 1949
Creator: Jaquet, Byron M. & Brewer, Jack D.
System: The UNT Digital Library
Wing-tunnel investigation at low transonic speeds of the effects of number of wings on the lateral-control effectiveness of an RM-5 test vehicle (open access)

Wing-tunnel investigation at low transonic speeds of the effects of number of wings on the lateral-control effectiveness of an RM-5 test vehicle

Report presenting an investigation to determine the effects of number of wings on the aileron rolling effectiveness of an RM-5 test vehicle using the free-rolling wind-tunnel testing technique through a speed range to Mach number 0.9. The wings tested had neither taper nor sweepback and were equipped with full-span 20-percent-chord sealed and faired ailerons. Results indicated that increasing the number of wings resulted in a decrease in rolling effectiveness so that results obtained from the test of the three-wing model were closer to conventional-airplane-configuration results than the four-wing data.
Date: November 29, 1949
Creator: Johnson, Harold S.
System: The UNT Digital Library
Investigation of Stability and Control Characteristics of a 1/10-Scale Model of a Canadian Tailless Glider in the Langley Free-Flight Tunnel (open access)

Investigation of Stability and Control Characteristics of a 1/10-Scale Model of a Canadian Tailless Glider in the Langley Free-Flight Tunnel

"An investigation of the stability and control characteristics of a 1/10-scale model of a Canadian tailless glider has been conducted in the 10 Langley free-flight tunnel. The glider designated the N.R.L. tailless glider has a straight center section and outboard panels sweptback 43 deg. along the leading edge of the wing. The aspect ratio is 5.83 and the taper ratio is 0.323. From the results of the investigation and on the basis of comparison with higher-scale static tests of the National Research Council of Canada, it is expected that the longitudinal stability of the airplane will be satisfactory with flap up but unsatisfactory near the stall with flap down" (p. 1).
Date: March 29, 1949
Creator: Johnson, Joseph L.
System: The UNT Digital Library
An Analysis of Supersonic Aerodynamic Heating With Continuous Fluid Injection (open access)

An Analysis of Supersonic Aerodynamic Heating With Continuous Fluid Injection

From Introduction: "The aerodynamic heating problem assumes considerable importance at high-supersonic speeds. Sanger and Bredt (reference 1) have calculated the high-speed aerodynamic forces and equilibrium surface temperature at extremely high altitudes where the molecular mean free path is large (free-molecule-flow region) compared with a characteristic body dimension. The theoretical investigation of Lees (reference 2) on the stability of the laminar boundary layer in compressible flow indicates that the laminar boundary layer is completely stable at all Reynolds numbers at supersonic speeds for a sufficiently low ratio of surface temperature to stream temperature."
Date: September 29, 1949
Creator: Klunker, E. B. & Ivey, H. Reese
System: The UNT Digital Library
Line-Vortex Theory for Calculation of Supersonic Downwash (open access)

Line-Vortex Theory for Calculation of Supersonic Downwash

"The perturbation field induced by a line vortex in a supersonic stream and the downwash behind a supersonic lifting surface are examined to establish approximate methods for determining the downwash behind supersonic wings. Lifting-lines methods are presented for calculating supersonic downwash. A bent lifting-line method is proposed for computing the downwash field behind swept wings. When applied to triangular wings with subsonic leading edges, this method gives results that, in general, are in good agreement with the exact linearized solution" (p. 635).
Date: April 29, 1949
Creator: Mirels, Harold & Haefeli, Rudolph C.
System: The UNT Digital Library
Atomic Displacements Produced by Fission Fragments and Fission Neutrons in Matter (open access)

Atomic Displacements Produced by Fission Fragments and Fission Neutrons in Matter

About four-fifths of the energy of the fission process is shared by the two heavy fragments into which the nucleus splits. This energy, of about 80 Mev. per fragment, is transferred to the medium in which the fission takes place in two ways. First, because each fragment is stripped of about half of its electrons during most of its path, it will interact strongly with electrons and thus lose energy through ionizing collisions with other atoms. Secondly, the fragments will lose energy by elastic collisions with atoms as a whole. Each fragment leaves in its wake a cloud of moving electrons and atoms. This cloud will roughly resemble a cylinder whose radius will increase with time on account of the motion of the struck electrons and atoms. They may now investigate two features of the slowing down process. First as it affects the fragment, i.e. we calculate its range, straggling, etc. And secondly they may work out the motion of the cylinder of moving particles, its effect on the medium, etc.
Date: June 29, 1949
Creator: Ozeroff, J.
System: The UNT Digital Library
Hanford Works area investigation near serious accident, November 9, 1949 (open access)

Hanford Works area investigation near serious accident, November 9, 1949

None
Date: November 29, 1949
Creator: Prudich, T.
System: The UNT Digital Library
Precipitation of plutonium and uranium from off-standard aqueons wastes (open access)

Precipitation of plutonium and uranium from off-standard aqueons wastes

None
Date: November 29, 1949
Creator: Richards, R.B.
System: The UNT Digital Library
Events of importance for week ending June 29, 1949, Hanford Operations Office, Richland, Washington (open access)

Events of importance for week ending June 29, 1949, Hanford Operations Office, Richland, Washington

This report details events of importance as reported by the Hanford Operations Office for the week ending June 29, 1949.
Date: June 29, 1949
Creator: Schlemmer, F. C.
System: The UNT Digital Library
A Comparative Analysis of the Liquid Metal Heat Transfer Systems for WMA (open access)

A Comparative Analysis of the Liquid Metal Heat Transfer Systems for WMA

Introduction. As stated in Report KAPL 116, one of the objectives of the KAPL reactor is "to provide a prototype demonstration of the practical general of electrical power from Nuclear energy using molten sodium as the primary coolant. The reactor will generate steam at a temperature of 550 degrees F and 465 psia, including 90 degree superheat potentially capable of an efficiency of twenty-eight per cent in electrical output." The work reported here is intended to increase the scope and supply an independent check on the heat transfer system analysis that has previously been done. The purpose of these analyses is to investigate the effects on load rating and top reactor temperature.
Date: April 29, 1949
Creator: Selby, J. D.
System: The UNT Digital Library
Planing Characteristics of Three Surfaces Representative of Hydro-Ski Forms (open access)

Planing Characteristics of Three Surfaces Representative of Hydro-Ski Forms

Report presenting the planing characteristics, as determined by tank tests, of three surfaces representative of hydro-ski forms. One surface had a rectangular plan form with a flat bottom, one had a rectangular plan form with a transversely curved bottom, and the third had a flat bottom and triangular plan form. Results are provided in the form of plots of the load on the water, resistance, trimming moment, and draft against total wetted area with speed and trim as parameters.
Date: March 29, 1949
Creator: Wadlin, Kenneth L. & McGehee, John R.
System: The UNT Digital Library
EXPERIMENTAL FACILITIES PROVIDED IN THE MATERIALS TESTING REACTOR. Preliminary Report (open access)

EXPERIMENTAL FACILITIES PROVIDED IN THE MATERIALS TESTING REACTOR. Preliminary Report

None
Date: December 29, 1949
Creator: Winkleblack, R.K.
System: The UNT Digital Library