Technical report abstract: Since UNH is a highly dissociated compound which ionizes to NO3 and (UO2), the latter ion being very weakly basic, a solution of pure UNH is quite acid (pH about 3). It is possible to titrate to a phenolphthalein and point with standard caustic solution and obtain a figure which represents the free acid plus the NO3 from the the UNH. However, titration of the free nitric acid alone in such a solution presents quite a problem. By precipitating and removing uranium from solution by means of potassium ferrocyanide, the residual free acid may be titrated directly by means of standard caustic using either methyl red or phenolphthalein indicators, with an error of less than 4%. A method is given to determine formic acid, should that acid be present in the mixture.

Technical report. The object of the research is to determine the procedure and equipment for the preparation of U233 on a semi-works scale. The general proposed procedure is that thorium carbonate in aluminum cans will be irradiated with pile neutrons. The Pa233 resulting from neutron absorption the Th232 and the decay of Th233 will be extraction from 99% of the thorium and the natural U in thorium by MnO2 precipitations. The Pa233 will then be allowed to decay to U233 which in turn will be isolated from the remaining Th and partially decayed Pa233 by ether extraction.

Technical report. The effect of temperature during pile exposure on the fast-neutron-induced change in properties of graphite was studied. Temperatures up to 125 degrees C have no effect upon the rate of increase of elastic modulus; pieces exposed at 300 degrees C on the other hand show no change at all in elastic modulus. The increase in electrical resistance s an inverse function of the temperature of exposure at all temperatures in the range 60 to 300 degrees C.

Technical report abstract. The present state of knowledge concerning the effect of pile radiation on a variety of solid materials is reviewed. Radiation corrosion will not be a serious hazard for aluminum or stainless steel but it can be for iron or lead if either are exposed to water. Apart from corrosion the principal uncertainty is in regard to the Wigner effect on the behavior of metals. There is at present no ground for optimism regarding the behavior of tuballoy. The effect on aluminum or a bonding material while less severe must also be considered serious. The expectation in regard to graphite is that its behavior will not cause trouble during the first 100 days of operation although serious troubles will probably arise within two years of operation. Organic materials can be used safely only in regions of limited exposure.

Technical report with short articles on (1) Uranium-oxygen system compositions UO2 to U3O3; (2) Thorium hydride; (3) Production of cerium; and (4) Production of thorium.

Abstract: Pure UO2F2 is made by reaction between anhydrous HF and pure UO3. Although it is difficult to prepare free of water, it is not very hygroscopic. Prolonged heating at 100-105 degrees releases 99.9% of the water in an aqueous solution; the rate of loss of water is very small after saturation is reached. X-ray diffraction data give a density of 6.2 for the solid. The density of a 1.004 M solution is 1.274; the density of a saturated solution (5.130 M) is 2.400. The densities of F-9 solutions have been calculated from the densities of ordinary aqueous solutions, and the values are compared graphically. Data on the solubility indicate that there is a small increase in the range 25-100 degrees. Recovery of pure F-9 from a solution is hampered by hydrolysis of U)2F2 to give HF. The HF may be held back by addition of UO3 or CaO; the use of the latter, however, makes more difficult the recovery of all the F-9. Molar conductivities of UO2F2 solutions at 25 degrees, as well as the specific conductivities of a 1 molar solution containing various concentrations of UO3, have been determined. The addition of UO3 lowers the conductivity. The low …

Abstract. The effect of various inhibitors on the production of CrIII in W waters containing chromatic has been studies at a variety of pH's in the CP-3 pile. The addition of 2 ppm NaClO3 appears to have little effect a a pH of 5.3, but 2 ppm NaClO3 cr 0.15 ppm of Cl2 (in the form of NaOCl) somewhat decreases the amount of chromatic reduced at a pH of 7.1. The inhibition is not great enough, however, to reduce the amount of CrIII formed to the maximum concentration permissible at W (0.02 ppm). The addition of 3 ppm (NH4)2S2O3 as an inhibiter will permit W water to be used a a Ph of 7.0, but not at a pH of 6.5 as far as chromate reduction is concerned. The concentration of CrIII would be 0.01 ppm and 0.05 ppm, respectively, after one passage through the pile. Previous conclusion as to the effects of temperature, pH, intensity and the addition of ammonium persulfate, which had been reached from experiments with simulation W water, have been checked by studies with solutions made from water chipped directly from Hanford. All of the effects noted were found to be similar to those already reported, …

Abstract. In addition to the hexagonal and monoclinic bismuth phosphate precipitates, whose structures are now known, a third crystalline phase has been found to appear in BiPO4 precipitates after (a) extremely long digestion in concentrated nitric acid; (b) oven drying at 800 degrees to 1000 degrees. Thought very small single crystals of the component have been isolated, nor crushed sample contained less than 30% of the beta-form. The cell size and symmetry of the crystal indicates that there ae two bismuth atoms in the cell, and there is no evidence that the compound is not BiPO4. It is suggested that this maty be a third form of BiPO4, stable over a short range of conditions, and tending to revert to the beta-form.

Geological, aerial, and detail maps of mines in the Blanding disctrict of the San Juan Basin area.

Index maps, detailed figures, columnar sections and calculation tables of the Carpenter Ridge District, Delores Plateau Area, Colorado.

Technical report with short reports on (1) P-9 recovery from UO2F2 solution; (2) Correlation of theories on action of radiation on matter; (3) Literature surveys on organic compounds and on chemistry of UO2F2; (4) effect of radiation on organic compounds; and (5) Effect of radiation on 100 area construction materials.

Technical report with short reports on (1) Heavy water analysis and standardization, and Specific gravity of pure D2O; (2) Homogenous exponential experiment; (3) Recombination of pile gases; (4) Slurry pumping studies; and (5) Electron microscope laboratory.