In regard to the production of ozone and various nitrogen oxides in air by action of x-rays or gamma rays, thre seems to be no direct experimental data which can be used. There is some data on the action of alpha particles on air and some on the action of cathode rays.

Describes the investigation of a particular method of extracting ions from an arc. Experimental results of a low extraction voltage ion source are given in some detail.

A buncher and pre-accelerator for A-12 is described that has 360 degree acceptance and could handle a current of one ampere from a low voltage source.

Two xenon extraction runs were made this month. It appears that a small design change in Trap #2 will be necessary so that a dry ice-trichloroethylene slurry can be used for coolant rather than liquid freon. For each of the runs this month the enriched generator was exposed for four hours in the est pile operating at 100 watts. A period of eight hours for cooling and xenon builidup was allowed before the collection and separation runs were started.

Hanford uranium contains minute angular inclusions which affect the microstructure, reactivity, and other important factors controlling the serviceability of the metal. Small quantities of the inclusions have been isolated by chemical means, and the x-ray diffraction patterns and chemical analyses of the isolated materials have been determined. As a first step in the identification of the inclusions present in rolled uranium, a search was made for a chemical method of separating the inclusions from the matrix metal.

An improved method for the determination of boron in plutonium is reported. Precipitation of plutonium (III) acid oxalate prior to color development with curcumin results in increased precision, greater speed, and lower costs. Results are presented of a statistical study involving all variables.

Impurities are separated from plutonium solutions by means of TTA (thenoyltrifluoracetone) extractions. Plutonium in hydrochloric acid solution is reduced to the trivalent state with hydroxylamine, and some impurities are extracted into hezone or a solution of TTA in hezone. The organic phase is removed, and the plutonium in the aqueous phase is oxidized to the tetravalent state with nitric acid. Investigations of several variables which affect the extraction are described..

The first of two general methods are discussed based on the removal of the thin layer of aluminum to which graphite adheres. Two electro-polishing techniques, an electrolytic etch, an anodization-deanodication cycle and two chemical etches are described.

The monitoring of thermal and resonance neutron flux in a thermal reactor having high flux over periods of time from 1 to 12 months using think Co foils is considered. Special attention is paid to the many correction factors to be applied to the activation data; neutron temperature, effective cadmium cutoff energy, burnout of Co59 and Co60, and decay of Co60. Results on a homogeneity test of 10 mil, 0.08% Co-A1 alloy foils is given.

This is the sixteenth quarterly report of the research and development activities of the Radiological Sciences Department, Hanford Atomic Products Operation, as before, includes some items charged to control but included for general interest. Such are identified as "not charged to research."

The hydrogen contents of several types of fabricated uranium have been determined by a vacuum method and expressed in terms of ccH2/ccU. The data indicate that alpha-rolled metal contains about 0.25 ccH2(STP)/ccU whereas beta heat-treated uranium yielded values between 0.30 and 0.37 cc per cc. Restricted efforts were made to determine where in the heat treatment the 5 to 10 cc of hydrogen per slug were taken up. It appears that no one operation is wholly responsible for this additional gas, although reactions between beta heat treated surfaces containing microscopic defects, and nitric acid may possibly play a large role. In general it may be said that slug produced by powder metallurgical techniques contain less hydrogen than pieces produced by rolling and heat treatment.

Thirty gram patches of plutonium dioxide can be readily chlorinated by reaction with phosgene or carbon tetrachloride at temperatures of 350 and 450 C respectively. Plutonium trichloride prepared by either method can be reduced to the metal in a hermetically sealed bomb by reaction with calcium. On a twenty gram scale yields of approximately 97 per cent are obtained when a calcium-iodine booster is employed. It has been demonstrated that a method for reduction of plutonium trichloride to the metal without the use of a booster can be development.

Laboratory studies have shown that the double salt, CaF2-PuF4, can be precipitated by rapid addition of hydro-fluoric acid to solutions containing 25 to 75 g Pu/1, caleium equimolar to plutonium, and 1 to 10 M HNO3. The precipitate, which is subsequently washed with water and dried to 300 degrees C in dehumidified, deoxygenated argon, can be reduced thermally by calcium to give high yields of plutonium metal.

Large savings in waste storage space may be realized by lowering the pH at which TBP waste is stored. Additional savings in neutralizing chemicals and operating time would also increase the monetary gain from such a process change. However, before such a change could be made, the corrosive effect of TBP waste at a lower pH on the mild steel waste storage tanks had to be determined.

Abstract: The results of activity buildup studies in the SM-1 (APPR-1) performed from February 1958 to January 1959 are reported. Data are presented on the extent, nature, and mechanism of the buildup of long-lived gamma emitting nuclides in the reactor primary system. Mathematical equations to describe the activity buildup are derived. Radiation levels after reactor shutdown are presented, as well as the predicted radiation levels at the end of core life.

Abstract: Critical experiment studies were performed, varying the parameters U235, B10 and metal to water ratio, in the SM-2 7 x 7 core configuration with 38 stationary elements and seven control rods of the SM-1 (APPR-1) type. An experimental mock-up of the SM-1 was assembled using the basic SM-2 fuel plates. Excellent agreement between the SM-1 boron loading, determined by chemical analysis, and the SM-1 mock-up boron loading, for equivalent bank positions, was noted. Several SM-2 mock-ups, cold clean and midlife, were assembled and studied with regard to reflector effects, flow divider effects, relative control rod array worths, critical rod configurations, and relative power distributions. The results of these experiments indicate as satisfactory a U235 loading of 36.4 Kg and a B10 loading of 63.4 grams for the SM-2. Attention is drawn to numerous power peaks present in the active core. The open seven control rod array has a slight reactivity advantage over the closed seven array and consequent minor disadvantage with respect to "stuck rod" criteria.

Abstract: This technical report is concerned with the program and results of the SM-1 reactor vessel head removal and core inspection at Fort Belvoir, Virginia from the period March 7, 1969 to May 17, 1959. It covers the operating procedures in detail and records the conditions found and problems encountered in order to make a record for reference in future work of this nature. The major objective of the program, to obtain irradiation data on the SM-1 type core, has been met. The boron control rod elements were found unsatisfactory for full core life, and europium oxide elements were placed in the core for future irradiation stability data. A major problem was experienced with the cracked pressure vessel head studs. The methods developed for the removal of the broken studs are presented. The complete metallurgical study of the stud failure from stress corrosion is included as Appendix B.

Abstract: An element by element reactivity check for SM-1 Core II fuel elements and control rod absorber sections was performed and the burnable nuclear poison loading in the SM-1 Core II stationary fuel elements was established. An approach to criticality of the SM-1 Core II was performed by the inverse multiplication method and the critical rod bank position obtained as a function of fuel loading up to the full SM-1 Core II loading. Maximum and minimum core reactivity measurements were obtained by selective loading of stationary fuel elements and the total "excess K" for the core established. Power distribution measurements in the region of the core-reflector interface and the fuel-absorber interface in the control rod assemblies were performed. The effectiveness of europium flux suppressors in the top of control rod fuel elements and the power peaking in stationary elements adjacent to water gaps in control rod assemblies were measured. Survey measurements established the worth of spiking cold clean SM-1 cores with SM-2 elements, and of water holes in the SM-1 core which might be utilized as flux traps for materials irradiation.

Abstract: This technical report summarizes the data obtained in a recent literature survey conducted to determine the effects of neutron irradiation on the impact and other mechanical properties of both ferritic steels and austenitic stainless steels. The survey was primarily aimed at obtaining sufficient data on the behavior of pressure vessel steels at high integrated neutron flux levels in order that a reference material of construction could be selected for the SM-2 (APPR-1B) reactor vessel. Materials studied in this literature survey included carbon and low alloy steels such as: ASTM A-212B, ASTM A-201, ASTM A-301B (CR-Mo), ASTM A-106 (coarse and fine grained), ASTM A-285, ASTM A-302B (Mn-Mo), ASTM A-353, ASTM A-203 Grade D, E-7016 carbon steel weld metal, USS Carilloy T-1, HY-65 and HY-80. In addition, Types 304 and 347 stainless steels were also investigated as representative austenitic materials which might be used in pressure vessel construction. A careful evaluation was made of the irradiation induced changes in the mechanical properties of the above materials. The ferritic steels were evaluated primarily on the basis of increases in transition temperature due to irradiation and decreases in the amount of maximum energy absorbed prior to ductile failure. Factors such as industrial experience, …

Abstract: This technical report contains a description of the nuclear analysis performed upon the SM-2 core and vessel for the period September 1, 1958 to December 31, 1959. Calculations are given for core reactivity, power distributions, lifetime, reactor control, kinetics, radiation problems, fuel and poison burn-ups, and the nuclear effects of poisons, temperature, and geometry. Wherever possible, experimental data is included in order to test the validity of the analytical models. The SM-2 nuclear analysis was performed by Alco Products, in. under Tasks 1, 8, and 10 of Contract No. AT(30-2)-326 for the Atomic Energy Commission.

This report describes the work carried out in 321 Building semiworks equipment, to define the factors contributing to high corrosion-product contamination and presents recommendations for reducing the impurity level to meet current specifications (maximum of 200 parts total metals per million parts U).

Abstract: Development of welding processes for stainless steel fuel elements, previously initiated by Alco Products, was continued in Task 5. Three objectives were accomplished; (1) development of a suitable reference welding process, (2) evaluation by out-of-pile tests of the structural integrity of reference welded fuel elements, and (3) preparation of specifications and fabrication procedures for the reference welding process.

Abstract: An analysis of SM-1 Core II and SM-1A Core I zero power experiments was made by comparing these cores to each other and to AM-1 Core I on the basis of critical bank positions, bank calibrations and available chemical analyses of the fuel plate compositions. The effects of replacing boron absorbers by europium absorbers upon rod worth and stuck rod conditions were studied. Comparisons of measured and calculated power distributions were made. It was concluded that both SM-1 Core II and SM-1A Core I contain nearly identical B-10 loading of 17.79 grams, compared to the best estimate of 15.75 grams for SM-1 Core I. The available data indicates that all three cores possess similar nuclear characteristics.

Abstract: A zero power experiment on the SM-1 Core II included an element by element reactivity check of fuel elements and control rod absorber sections, and an estimate of burnable nuclear poison loading in stationary fuel elements. An approach to criticality was made by the inverse multiplication method, and critical rod bank position obtained as a function fuel loading up to full core loading. Minimum and maximum core reactivity measurements were obtained by selective loading of stationary fuel elements, and total excess K of the core was established. Power distribution measurements were taken in the regions of the core-reflector interface and the fuel-absorber interface in the control rod assemblies. The effectiveness of europium flux suppressors in the top of control rod fuel elements was determined, and power peaking was measured in stationary elements adjacent to control rod assembly water gaps. Survey measurements established the work of spiking clean, cold SM-1 cores with SM-2 elements and the work of water holes in the SM-1 Core. The reduced scope zero power experiment performed on SM-1A core I included an element by element uniformity check of stationary fuel elements, a core assembly test, comparison of Eu2O3 and B4C absorber sections, and development of …