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Absorption of Organic Acids on Thoria (open access)

Absorption of Organic Acids on Thoria

The adsorption of acetic and oleic acids on the surface of thoria was studied by means of infrared spectroscopy. An infrared analysis of the adsorbates before and after adsorption using differential double bean methods indicated that the adsorption of organic acids on thoria surfaces occurs by an esterification reaction between the organic acid and the hydroxylated thoria surface. Ammonia vapor will not adsorb on thoria, indicated the basic character of the hydroxylated surface.
Date: December 31, 1959
Creator: Bradford, Harold R. & Wadsworth, Milton E.
Object Type: Report
System: The UNT Digital Library
Acceleration of a Plasma by Time-Varying Magnetic Fields (open access)

Acceleration of a Plasma by Time-Varying Magnetic Fields

Abstract: An application of the magnetic mirror principle to the acceleration of a plasma is described. It is shown that an axially symmetric magnetic field which increases with time but decreases with distance along the axis can impart a net translational energy to a plasma. This effect on a plasma is contrasted with that arising from an impressed electric field, which is not effective in producing acceleration.
Date: December 6, 1954
Creator: Post, Richard F.
Object Type: Report
System: The UNT Digital Library
Acceleration of Deuterons or Alpha Particles in the AGS (open access)

Acceleration of Deuterons or Alpha Particles in the AGS

The magnetic field of the AGS ring can contain particles of magnetic rigidity about 34 Bv/c. This includes not only protons of kinetic energy 33 Bev, but also 32 Bev deuterons, 64 Bev alpha particles, and conceivably heavier nuclei such as 188 Bev carbon nuclei. It will be shown in this paper that such nuclei can be injected and accelerated in the AGS if some rather small modifications are made in the injection and acceleration systems. What physics could be done with such beams? Several types of experiments may be suggested. In the first place, since the deuteron is a rather loosely bound combination of a neutron and a proton, it is likely to break up when it hits a target nucleus (stripping reaction). In a considerable fraction of the collisions the neutron will go straight on with essentially unchanged energy (half the deuteron energy). Therefore, with an internal target bombarded by 30 Bev deuterons one should obtain an intense, rather well collimated and monochromatic beam of 15 Bev neutrons in the forward direction.
Date: December 28, 1962
Creator: Courant, E. D.
Object Type: Report
System: The UNT Digital Library
Accurate Nuclear Fuel Burnup Analyses; Eighth Quarterly Progress Report, (September - November 1963) (open access)

Accurate Nuclear Fuel Burnup Analyses; Eighth Quarterly Progress Report, (September - November 1963)

The objective of the Accurate Nuclear Fuel Burnup Analyses program is to develop more accurate methods for burnup analysis for general use than the current method of analysis of Ca-137 or Sr-90. The program will require from three to five years of effort.
Date: December 1, 1963
Creator: Rider, B. F.; Ruiz, C. P.; Luke, P. S., Jr.; Peterson, J. P., Jr. & Smith, F. R.
Object Type: Report
System: The UNT Digital Library
Accurate Nuclear Fuel Burnup Analyses: Fourth Quarterly Progress Report September-November, 1962 (open access)

Accurate Nuclear Fuel Burnup Analyses: Fourth Quarterly Progress Report September-November, 1962

Work has continued on the development of accurate nuclear fuel burnup analysis. Work performed during the fourth quarter is summarized here.
Date: December 1, 1962
Creator: Rider, B. F.; Ruiz, C. P. & Peterson, J. P.
Object Type: Report
System: The UNT Digital Library
The Aeolotropic Elastic Relations for Uranium Crystals (open access)

The Aeolotropic Elastic Relations for Uranium Crystals

Handwritten report. This theoretical introduction to the anisotropic elastic properties of the orthorombic [sic] uranium crystal presents certain basic ideas which are useful in the study of experimental methods for determining preferred orientations in polycrystalline bodies. The method of analysis used to determine the elastic constants suggests explanations and correlations for the observations of sonic wave experiments on bars having preferred orientations and also serves as an introduction into the type of mathematical relations used in the study of anisotropic crystals.
Date: December 17, 1954
Creator: Merckx, K. R.
Object Type: Report
System: The UNT Digital Library
After Shutdown Heating in the HFIR (open access)

After Shutdown Heating in the HFIR

After shutdown heating rates have been calculated for the target, control plates, and the beryllium reflector of the HFIR. Hilvety previously calculated the after shutdown heating rates in the element and his results are reported in ORNL CP-60-4-110. Decay times of 1.0 10, 10^2, 10^3, 10^4, and 10^5 seconds have been considered, and heat fluxes have been computed for all of the mentioned components. The greatest heat fluxes were found to be at the surfaces of the control plates and the permanent beryllium reflector.
Date: December 29, 1960
Creator: McLain, H. A.
Object Type: Report
System: The UNT Digital Library
Air Sample Activity vs Flow Rate (open access)

Air Sample Activity vs Flow Rate

A bibliography on the subject of air sample activity vs flow rate has been prepared. The findings in two documents reviewed have been applied directly to this problem. It is concluded that air sample activity is not dependent on flow rate when sampling particles whose average diameter in 0.06 micron or greater.
Date: December 27, 1954
Creator: Clark, R. G.
Object Type: Report
System: The UNT Digital Library
The Aircraft Nuclear Propulsion Project Quarterly Progress Report for Period Ending August 31, 1950 (open access)

The Aircraft Nuclear Propulsion Project Quarterly Progress Report for Period Ending August 31, 1950

Technical report outlining various experiments that took place in the Oak Ridge Area Critical Mass Laboratory until August 31, 1950. Experiments took place in categories of critical experiments, experimental engineering, heat transfer, radiation damage, nuclear measurements, reactor physics, ARE reactor design, circulating fuel reactors, and circulating moderator reactors. [From Summary]
Date: December 4, 1950
Creator: Ellis, C. B. & Thompson, W. E.
Object Type: Report
System: The UNT Digital Library
Los Alamos Power Reactor Experiment and its Associated Hazards (open access)

Los Alamos Power Reactor Experiment and its Associated Hazards

The following report describes the high pressure and temperature homogeneous reactor experiment which has been started at Los Alamos, as well as the hazards and safety aspects for the experiments.
Date: December 2, 1953
Creator: King, L. D. P.
Object Type: Report
System: The UNT Digital Library
The Ammonia Reduction and its Application to the Preparation of Green Salt (open access)

The Ammonia Reduction and its Application to the Preparation of Green Salt

From introduction: The present report is a summary of the experimental work on a laboratory scale to date involving the ammonia reduction and the one step TF4 processes.
Date: December 29, 1945
Creator: Clinton Engineer Works
Object Type: Report
System: The UNT Digital Library
Analog Computer Analysis of the Thermal Behavior of the EDCR Due to Reactivity Accidents (open access)

Analog Computer Analysis of the Thermal Behavior of the EDCR Due to Reactivity Accidents

The ORNL analog computer was used to examine one aspect of a safety system for the EGCR. The thermal behavior of the fuel as a result of increases in reactivity at various power levels and gas flows was examined. Safety actions initiated by wither a flux-minus-flow signal or a reactor outlet gas temperature signal were included in simulation.
Date: December 16, 1960
Creator: Pierce, R. M.
Object Type: Report
System: The UNT Digital Library
An Analysis of Project Data on the Corrosion of Uranium in Various Media (open access)

An Analysis of Project Data on the Corrosion of Uranium in Various Media

This is a summarizing and reviewing report in which almost all the experimental data representing Project work done prior to 1949 on the corrosion of pure uranium are brought together and analyzed. New data obtained in this laboratory on corrosion rates in laboratory atmosphere and on the identification of corrosion products by electron diffraction are included. The data for corrosion in each of several different media have been plotted according to logarithm-of-the-rate versus reciprocal-temperature coordinates; and from these plots values for the energies and entropies of activation of the corrosion reactions have been obtained. By theoretical treatment of the role of oxygen as a negative catalyst, it is shown that this element may be expected to "poison" the corrosion rection and then act as a corrosion inhibitor. A practical significance of these data analyses is that they explain why machined uranium parts stored in inert atmospheres (helium or argon) containing only very small amounts of water vapor will corrode relatively rapidly with the formation of loose powdery oxide, whereas similar parts may be kept in dry air almost indefinitely with formation on their surface of only a discoloring, but adhered, oxide coating.
Date: December 22, 1948
Creator: Waber, James T. (James Thomas), 1920-
Object Type: Report
System: The UNT Digital Library
Analysis of TH( NO3 ) -Ca( NO3 )2 –HNO3 Solutions (open access)

Analysis of TH( NO3 ) -Ca( NO3 )2 –HNO3 Solutions

Abstract. Methods of analysis for thorium, calcium, and nitric acid in solutions from thorium extraction purification columns are described and the results and errors are outlined. A brief description of methods of analysis that were not successful is included.
Date: December 20, 1945
Creator: Warf, James C.; Patterson, J. H. & Banks, Charles V.
Object Type: Report
System: The UNT Digital Library
An Analysis of the In-Line Uranium Photometer Data from Purex Hot Semi-Works Runs PX-2 Through PX-9 (open access)

An Analysis of the In-Line Uranium Photometer Data from Purex Hot Semi-Works Runs PX-2 Through PX-9

Results of eight runs using in-line U photometers in organic and aqueous streams of the Purex Hot Semi-Works are presented. Their operation, both mechanically and electrically, was satisfactory, indicating changes in stream U concentrations over wide ranges.
Date: December 7, 1955
Creator: Scott, F. A.
Object Type: Report
System: The UNT Digital Library
Analysis of Uranium Fuel-Element Wafers from Atomics International for Uranium, Plutonium and Samarium (open access)

Analysis of Uranium Fuel-Element Wafers from Atomics International for Uranium, Plutonium and Samarium

Five irradiated and five unirradiated wafers were analyzed. Each wafer was analyzed for samarium by emission spectrography. The unirradiated wafers were analyzed for uranium by coulometric and potentiometric methods and for uranium isotopes by mass spectrometry. The irradiated wafers were analyzed for uranium and plutonium by coulometric methods, for plutonium isotopes by the 256-channel alpha pulse analyzer, and for the isotopes of uranium and of plutonium by mass spectrometry. The methods of preparing wafers for analysis are discussed; the data are tabulated.
Date: December 27, 1960
Creator: Gaitanis, M. J.
Object Type: Report
System: The UNT Digital Library
Analytic Approach for the Pion-Proton Scattering Phase Shifts (open access)

Analytic Approach for the Pion-Proton Scattering Phase Shifts

A simple method of solving for the phase shifts of the pion-proton scattering is presented. The rapid solution afforded can be utilized, as the Ashkin diagrams have been employed, to give starting values to an electronic computer or alternatively to analyze with more ease the variation of the phase shifts as a function of the input data in terms of the coefficients of the angular distributions. A new plot of a function of the total cross section versus the pion energy is introduced. The nearly straight line resulting should help to evaluate the experimental data.
Date: December 7, 1955
Creator: Rarita, William, 1907-
Object Type: Report
System: The UNT Digital Library
Analytical Chemistry Division Semiannual Progress Report For Period Ending October 20, 1955 (open access)

Analytical Chemistry Division Semiannual Progress Report For Period Ending October 20, 1955

The development of ionic methods for the determination of corrosive products in the highly radioactive Homogeneous Reactor (HR) fuels has been of major interest in the work of the Ionic Analyses Laboratory. Methods for the spectrophotometric determination of aluminum and for the polarographic determination of iron in HR fuels have been developed. The polarographic determination of molybdenum in uranyl sulfate solutions was studied. A polarographic method for the determination of zinc was developed. A fluorometric method for the determination of microgram amounts of fluoride was studied. Three organic reagents were investigated as precipitants for microgram quantities of zirconium in HR fuel. The automatic photometric titration technique was applied to the determination of thorium and of sulfate. A method was developed for the ion-exchange separation and potentiometric titration of cobalt. The ultraviolet absorption spectra of technetium and rhenium were studied.
Date: December 27, 1955
Creator: Kelley, M. T.; Susana, C. D. & Rooen, H. P.
Object Type: Report
System: The UNT Digital Library
Anion Exchange of Neptunium in Nitrate Solutions (open access)

Anion Exchange of Neptunium in Nitrate Solutions

Technical report. From Abstract : "The absorption and elution of the anionic nitrate complex of neptunium (IV) were studied with several anion exchange resins and under a wide variety of conditions." From Introduction : "The objective of this study was to provide a technical basis for selecting process conditions for the recovery of Np."
Date: December 1960
Creator: Burney, Glenn A.
Object Type: Report
System: The UNT Digital Library
Annual Report of Research Progress (open access)

Annual Report of Research Progress

This technical report constitutes a brief review of the work undertaken, entirely or in part, under the Contract AT(30-1)-1772 with eh United States Atomic Energy Commission. The work published during 1959 is listed at the end of this report and copies of the reprints or reports are attached where available. These investigations have been concerned with the examination of defect production and behavior as it may be observed by high frequency ultrasonic attenuation and velocity (modulus) changes in such materials as quartz, silicon, germanium, alkali halides (especially NaCl and XCl), high purity aluminum, and glass containing boron. The irradiations used are cobalt 60 gamma-ray irradiation and the reactor irradiation obtained in the Brookhaven National Laboratory graphite reactor.
Date: December 31, 1959
Creator: Truell, Rohn, 1913-1968
Object Type: Report
System: The UNT Digital Library
Anodic Etching Procedure for Uranium: Useful Lifetime of Baths Without Regeneration (open access)

Anodic Etching Procedure for Uranium: Useful Lifetime of Baths Without Regeneration

The useful lifetimes of the phosphoric-hydrochloric anodic etching solution and the nitric acid stripping solutions were studied. Groups of uranium wafers of surface areas approximately 0.033 sq ft were anodically etched and stripped. From the losses in weight observed, it was concluded that at least three square feet of uranium may be anodized per liter of phosphoric-hydrochloric acid solution without regeneration. The nitric acid stripping solution was found to be satisfactory for at least one square foot of uranium per liter, but the reaction rate decreased rapidly after the treatment of two square feet per liter.
Date: December 14, 1954
Creator: Pitzer, E.C.; Katayama, Y. B. & Budke, W. C.
Object Type: Report
System: The UNT Digital Library
Antiproton-Nucleon Cross Sections From 0.5 To 1.0 Bev (open access)

Antiproton-Nucleon Cross Sections From 0.5 To 1.0 Bev

Antiproton-production and nucleon-interaction cross sections were investigated for antiprotons in the energy range 0.5 to 1.0 Bev. The antiprotons were distinguished from other particles produced at the Bevatron by a system of scintillation- and velocity-selecting Cerenkov counters. The excitation function and momentum distribution were recorded for antiproton production in carbon and compared with statistical model expectations.
Date: December 12, 1961
Creator: Elioff, Tommy; Agnaw, Louis; Chamberlain, O. (Owen); Steiner, Herbert M.; Wiegand, Clyde (Clyde Edward), 1915-1996 & Ypsilantis, Tom
Object Type: Report
System: The UNT Digital Library
Application of the Variational Method to the Calculation of the Time Dependence of the Neutron Flux in Small Pulsed Slabs, Cylinders and Spheres (open access)

Application of the Variational Method to the Calculation of the Time Dependence of the Neutron Flux in Small Pulsed Slabs, Cylinders and Spheres

The variational method is applied to the monoenergetic time dependent transport equation to obtain a simple relation for the asymptotic decay constant in small pulsed assemblies. The results indicate that flat trial functions may be a reasonable representation of the flux distributions in the thin slab limit. This approach is superior to many of the usual transport approximations.
Date: December 16, 1963
Creator: Judge, F. D. & Daitch, Paul B. (Paul Bernard), 1925-
Object Type: Report
System: The UNT Digital Library
Applied Potential Corrosion of Aluminum : Final Report (open access)

Applied Potential Corrosion of Aluminum : Final Report

Report describing data resulting from dynamic tests to determine applied potential corrosion of aluminum.
Date: December 5, 1955
Creator: Sanborn, Kenneth L.
Object Type: Report
System: The UNT Digital Library