Absorption of Organic Acids on Thoria (open access)

Absorption of Organic Acids on Thoria

The adsorption of acetic and oleic acids on the surface of thoria was studied by means of infrared spectroscopy. An infrared analysis of the adsorbates before and after adsorption using differential double bean methods indicated that the adsorption of organic acids on thoria surfaces occurs by an esterification reaction between the organic acid and the hydroxylated thoria surface. Ammonia vapor will not adsorb on thoria, indicated the basic character of the hydroxylated surface.
Date: December 31, 1959
Creator: Bradford, Harold R. & Wadsworth, Milton E.
System: The UNT Digital Library
Accurate Nuclear Fuel Burnup Analyses; Eighth Quarterly Progress Report, (September - November 1963) (open access)

Accurate Nuclear Fuel Burnup Analyses; Eighth Quarterly Progress Report, (September - November 1963)

The objective of the Accurate Nuclear Fuel Burnup Analyses program is to develop more accurate methods for burnup analysis for general use than the current method of analysis of Ca-137 or Sr-90. The program will require from three to five years of effort.
Date: December 1, 1963
Creator: Rider, B. F.; Ruiz, C. P.; Luke, P. S., Jr.; Peterson, J. P., Jr. & Smith, F. R.
System: The UNT Digital Library
The Aircraft Nuclear Propulsion Project Quarterly Progress Report for Period Ending August 31, 1950 (open access)

The Aircraft Nuclear Propulsion Project Quarterly Progress Report for Period Ending August 31, 1950

Technical report outlining various experiments that took place in the Oak Ridge Area Critical Mass Laboratory until August 31, 1950. Experiments took place in categories of critical experiments, experimental engineering, heat transfer, radiation damage, nuclear measurements, reactor physics, ARE reactor design, circulating fuel reactors, and circulating moderator reactors. [From Summary]
Date: December 4, 1950
Creator: Ellis, C. B. & Thompson, W. E.
System: The UNT Digital Library
The Ammonia Reduction and its Application to the Preparation of Green Salt (open access)

The Ammonia Reduction and its Application to the Preparation of Green Salt

From introduction: The present report is a summary of the experimental work on a laboratory scale to date involving the ammonia reduction and the one step TF4 processes.
Date: December 29, 1945
Creator: Clinton Engineer Works
System: The UNT Digital Library
Analysis of TH( NO3 ) -Ca( NO3 )2 –HNO3 Solutions (open access)

Analysis of TH( NO3 ) -Ca( NO3 )2 –HNO3 Solutions

Abstract. Methods of analysis for thorium, calcium, and nitric acid in solutions from thorium extraction purification columns are described and the results and errors are outlined. A brief description of methods of analysis that were not successful is included.
Date: December 20, 1945
Creator: Warf, James C.; Patterson, J. H. & Banks, Charles V.
System: The UNT Digital Library
Analytic Approach for the Pion-Proton Scattering Phase Shifts (open access)

Analytic Approach for the Pion-Proton Scattering Phase Shifts

A simple method of solving for the phase shifts of the pion-proton scattering is presented. The rapid solution afforded can be utilized, as the Ashkin diagrams have been employed, to give starting values to an electronic computer or alternatively to analyze with more ease the variation of the phase shifts as a function of the input data in terms of the coefficients of the angular distributions. A new plot of a function of the total cross section versus the pion energy is introduced. The nearly straight line resulting should help to evaluate the experimental data.
Date: December 7, 1955
Creator: Rarita, William, 1907-
System: The UNT Digital Library
Anion Exchange of Neptunium in Nitrate Solutions (open access)

Anion Exchange of Neptunium in Nitrate Solutions

Technical report. From Abstract : "The absorption and elution of the anionic nitrate complex of neptunium (IV) were studied with several anion exchange resins and under a wide variety of conditions." From Introduction : "The objective of this study was to provide a technical basis for selecting process conditions for the recovery of Np."
Date: December 1960
Creator: Burney, Glenn A.
System: The UNT Digital Library
Annual Report of Research Progress (open access)

Annual Report of Research Progress

This technical report constitutes a brief review of the work undertaken, entirely or in part, under the Contract AT(30-1)-1772 with eh United States Atomic Energy Commission. The work published during 1959 is listed at the end of this report and copies of the reprints or reports are attached where available. These investigations have been concerned with the examination of defect production and behavior as it may be observed by high frequency ultrasonic attenuation and velocity (modulus) changes in such materials as quartz, silicon, germanium, alkali halides (especially NaCl and XCl), high purity aluminum, and glass containing boron. The irradiations used are cobalt 60 gamma-ray irradiation and the reactor irradiation obtained in the Brookhaven National Laboratory graphite reactor.
Date: December 31, 1959
Creator: Truell, Rohn, 1913-1968
System: The UNT Digital Library
Application of the Variational Method to the Calculation of the Time Dependence of the Neutron Flux in Small Pulsed Slabs, Cylinders and Spheres (open access)

Application of the Variational Method to the Calculation of the Time Dependence of the Neutron Flux in Small Pulsed Slabs, Cylinders and Spheres

The variational method is applied to the monoenergetic time dependent transport equation to obtain a simple relation for the asymptotic decay constant in small pulsed assemblies. The results indicate that flat trial functions may be a reasonable representation of the flux distributions in the thin slab limit. This approach is superior to many of the usual transport approximations.
Date: December 16, 1963
Creator: Judge, F. D. & Daitch, Paul B. (Paul Bernard), 1925-
System: The UNT Digital Library
Attempted Modification of Susceptibility of Tumors to X-Radiation : Final Report for August 1 1957 to August 31, 1959 (open access)

Attempted Modification of Susceptibility of Tumors to X-Radiation : Final Report for August 1 1957 to August 31, 1959

Attempts to secure a high degree of synchronization of cell division of the Krebs mouse ascites carcinoma, by combined use of aminopterin and citrovorum factor, and by use of colchicine and N-acetyl colchinol, were unsuccessful. In the course of the work, a new method for securing smears of ascites tumor cells was out, which we believe will be found useful
Date: December 31, 1959
Creator: Beck, Lyle Vibert, 1906-
System: The UNT Digital Library
An Automatic Polarograph for the Determination of Uranium in Process Waste Streams (open access)

An Automatic Polarograph for the Determination of Uranium in Process Waste Streams

The automatic polarograph is ideally suited for the analysis of waste streams for uranium in the Metal Recovery Process, and with modification, it is applicable to other processes, pilot plants, and even to laboratory set ups. The instrument is simple, dependable, and relatively trouble free in operation. It provides an immediate record of the uranium in the waste and, through better control of the process, lower processing costs.
Date: December 10, 1953
Creator: Koyama, K.; Michelson, C. E. & Alkire, G. J.
System: The UNT Digital Library
Biological Effects of Radiation, and Related Biochemical and Physical Studies : Semiannual Progress Report [for] Period May 1, 1959 - October 31, 1959 (open access)

Biological Effects of Radiation, and Related Biochemical and Physical Studies : Semiannual Progress Report [for] Period May 1, 1959 - October 31, 1959

Progress reports from four divisions are included: (1) Division of Biophysics; (2) Division of Clinical Investigation; (3) Division of Nucleoprotein Chemistry; and (4) Radiochemistry Section.
Date: December 1, 1959
Creator: Denues, Arthur Russell Taylor, 1914-
System: The UNT Digital Library
Boiling Reactors: A Preliminary Investigation (open access)

Boiling Reactors: A Preliminary Investigation

Technical report detailing kinetic equations that have been developed for a boiling-type reactor and inherent reactor stability studies that have been made on the basis of these equations. Presents features of the proposed reactor, comparisons of circulating types, investigations of bubble-rise velocities, effects of transient conditions of vapor mass in steam chest, and bubble time delay functions yield favorable results. [From Abstract]
Date: December 12, 1951
Creator: Stein, J. M. & Kasten, P. R.
System: The UNT Digital Library
The Boundary Layer Between a Plasma and a Magnetic Field - I (open access)

The Boundary Layer Between a Plasma and a Magnetic Field - I

"The problem of a steady boundary layer or sheath between a plasma and a magnetic field is considered. A self-consistent transition layer is found which joins a uniform magnetic field at plus infinity with a collisionless field-free plasma region with arbitrary velocity distribution at minus infinity, i.e., a magnetic field profile is found such that the exact particle orbits in this field produce a current which gives rise to this field. An interesting feature of the solution is that, with any nonsingular velocity distribution at minus infinity, the magnetic field the plasma extends to infinity, exponentially attenuated, into the magnetic field region. The scale of length is the Larmor radius. Electric fields arising from charge separation in the case of particles of different mass are ignored."
Date: December 28, 1960
Creator: Grad, Harold, 1923-
System: The UNT Digital Library
Charging and Discharge of Demineralizer Resins. Section IV. First Performance. Core I, Seed 1. Test Results DL-S-180, T-612085 (open access)

Charging and Discharge of Demineralizer Resins. Section IV. First Performance. Core I, Seed 1. Test Results DL-S-180, T-612085

The purpose of the test was to determine if the 1A Canal Water System Demineralizers can be satisfactorily charged with resin. The 1A Canal Water System Demineralizer was satisfactorily charged with resin and conductivity of the demineralizer effluent was less than 0.1 microbes as specified in the Test Procedure.
Date: December 3, 1959
Creator: Eckenrode, G. E.
System: The UNT Digital Library
Chemical Development, Quarterly Progress Report, July-September, 1953. (open access)

Chemical Development, Quarterly Progress Report, July-September, 1953.

Introduction: "During the last quarter, members of the Chemical Development Group have been concerned with six major projects. (1) thermal and radiation properties of organic materials as moderators and coolants, (2) thermal and radiation stability of mirconium hydride, (e) reactor accessibility (transport of radioactive materials in cooling systems, ................. There have been, in addition, a number of smaller service projects, mostly of an analytical nature.:
Date: December 7, 1953
Creator: Loftness, R. L.
System: The UNT Digital Library
Chemical Properties of Sodium Triethylhydroborate and Sodium Triisopropoxyhydroborate (open access)

Chemical Properties of Sodium Triethylhydroborate and Sodium Triisopropoxyhydroborate

Technical report abstract: Sodium hydride and triethylborane react to form sodium triethylhydroborate, NaBH(C2H5)3. This compound, a liquid at rooom temperature, was found to be soluble in hexane and mineral oil. A study was made of the thermal decomposition of sodium triethylhydroborate and its behavior toward boron trifluoride, boron trichloride, methyl borate, carbon dioxide, silane, and ethylene. Sodium triisopropoxyhydroborate, NaBH(OC3H7)3, was prepared and also found to be soluble in hexane and mineral oil. The reactions of this compound with methyl borate, triethylborane, silicon tetrachloride, and boron trichloride were investigated.
Date: December 13, 1956
Creator: Pearson, Richard King, 1926-; Edwards, L. J. & Maginnity, P. M.
System: The UNT Digital Library
The Chlorination of TO₃ (open access)

The Chlorination of TO₃

Abstract: The applicability of specific mixtures and organic chlorocarbons in general toward the chlorination of TO₃ has been tested by means of reactions is sealed glass tubes. The results show that thionyl chloride mixed with tetrachloroethylene or a bromothane of the tyoe CHBrC12 will produce TCI4 directly. This same result is produced by CBr2C12 alone.
Date: December 28, 1945
Creator: Gavlin, Gilbert; Hubbard, J. V. & Clewett, G. H.
System: The UNT Digital Library
Comparative Study of Alternative Fibrous Glass and Sand Exhaust Ventilation Air Filter Installations for Purex (open access)

Comparative Study of Alternative Fibrous Glass and Sand Exhaust Ventilation Air Filter Installations for Purex

Unanticipated radioactive contamination of the 200 Areas environs was discovered in the latter part of 1947, about 2.5 years after the startup of the Bismuth Phosphate Separation Plants. It was subsequently established that this contamination was due to radioactive particles emanating from the Separation Plants' stacks, and the need for exhaust ventilation air filtration equipment was recognized. Sand filters were installed in the fall of 1948 in the ventilation systems of the B and T Bismuth Phosphate Plants. These filter units essentially eliminated this contamination problem and have performed satisfactorily to the present time.
Date: December 14, 1953
Creator: Zahn, Lyle L., Jr.
System: The UNT Digital Library
A Comparison of Radiation--Induced Graft Copolymerization Utilizing Electron Accelerators and Isotope Sources as Radiation Initiators (open access)

A Comparison of Radiation--Induced Graft Copolymerization Utilizing Electron Accelerators and Isotope Sources as Radiation Initiators

"The grafting of methacrylic acid, styrene (2: 1 mole ratio) co-monomer mixture on polypropylene film and fabric, was studied to compare electron accelerators and isotopes as sources of radiation. An aluminum block that contalns i/8-in.-deep pockets covered with Mylar film for holding sample and monomer during mutual irradiatlon was developed. A preliminary comparison was made in post grafting polypropylene film and fabric preirradiated with Cow and with an electron accelerator source. It was found that post grafting was rapid at 80 ts C but slow at room temperature. Monomer equilibration before irradiation increased the grafting rate. Higher grafts were obtained when samples were irradiated in sparged and sealed containers. The grafting rate increased as dose rate decreased."
Date: December 1, 1960
Creator: unknown
System: The UNT Digital Library
Computer description APPR-1 simulator (open access)

Computer description APPR-1 simulator

The APPR-1 is a pressurized water reactor having a low specific heat fuel and a water primary coolant. The primary coolant loop delivers heat from the reactor to the steam generator. The secondary water in the steam generator is converted to steam and then taken to the turbine to drive an electrical generator. The simulation of this system is broken down into three primary areas: the neutron kinetics in the reactor which are necessary to generate the primary power function, the heat transfer in the reactor, and the heat transfer in the steam generator.
Date: December 15, 1958
Creator: RCA Service Company
System: The UNT Digital Library
The Concentration of Deuterium by Chemical Exchange Between Hydrogen and Ammonia (open access)

The Concentration of Deuterium by Chemical Exchange Between Hydrogen and Ammonia

Technical report describing the results of the chemical reaction between potassium amide and liquid ammonia and the exchange of hydrogen between hydrogen gas and liquid ammonia. This report finds that the reactions may be sufficiently rapid to be useful for isotope separations on a larger scale.
Date: December 15, 1951
Creator: Perlman, M. L. & Bigeleisen, J.
System: The UNT Digital Library
Concentration of Plutonium by Cation Exchange Part I - New Elutriants (open access)

Concentration of Plutonium by Cation Exchange Part I - New Elutriants

From summary: "The concentration of plutonium by cation exchange was significantly improved by using a solution of ammonium lactate and sulfamate as the elutriant instead of nitric and sulfamic acids. The new elutriant permitted essentially complete elution of the plutonium and also avoided formation of gases in the resin bed during elution. At 45ÂșC, 2.8M ammonium lactate plus 0.15M ammonium sulfamate eluted 99.3 per cent of the total plutonium at an average concentration of 43.8 grams per liter. It was found necessary to elute hydrogen and hydroxylammonium ions from the resin beds before elution of plutonium. The hydroxylammonium ions decompose to form gases in the resin bed at the desired temperature for plutonium elution. The hydrogen ions exchange with ammonium ions of the elutriant and decrease the concentration of plutonium in the eluate."
Date: December 1956
Creator: Bonner, Oscar D.; Burney, Glenn A. & Tober, Frank W., 1919-1995
System: The UNT Digital Library
Condensate System. Section II. Fifth Core I, Seed 1. Test Results DL-S-105 (open access)

Condensate System. Section II. Fifth Core I, Seed 1. Test Results DL-S-105

The purpose of the test was to fill the condensate storage tank and the Condensate System and obtain satisfactory preliminary operation. The components of the Condensate System performed adequately and satisfactorily with the exception of fill control valve (M9-VI). This valve (M9-VI) is not used in the current operation procedure.
Date: December 8, 1959
Creator: unknown
System: The UNT Digital Library