The Accumulation of Radioactivity as Shown by a Limnological Study of the Columbia River in the Vicinity of Hanford Works : Preliminary Report (open access)

The Accumulation of Radioactivity as Shown by a Limnological Study of the Columbia River in the Vicinity of Hanford Works : Preliminary Report

The following report provides data collected during an investigation in the Columbia River. The purpose of this investigation was to research the radioactivity present in the bottom-living organisms of the river.
Date: November 12, 1948
Creator: Coopey, R. W.
System: The UNT Digital Library
Biology Seminar : methods of assaying for plutonium in biological materials (open access)

Biology Seminar : methods of assaying for plutonium in biological materials

From introduction: "Since plutonium is manufactured at the Hanford Works, a study of its effect on biological materials is important. To determine the amount of plutonium deposited in a biological sample, it is necessary to have an accurate method for extracting plutonium from these samples. Some of the different methods for plutonium assay are reviewed and given in this paper."
Date: November 1948
Creator: Case, A. C.
System: The UNT Digital Library
Visual Efficiency of a Phosphor Bombarded by Plutonium Alpha Particles (open access)

Visual Efficiency of a Phosphor Bombarded by Plutonium Alpha Particles

This report follows and experiment that was performed to determine the visual efficiency of a phosphor when bombarded by alpha particles.
Date: November 15, 1948
Creator: Wakefield, Ernest
System: The UNT Digital Library
A Colorimetric Determination for Traces of Cadmium in U₂O₂ Residues (open access)

A Colorimetric Determination for Traces of Cadmium in U₂O₂ Residues

The following report describes how to obtain traces of cadmium using dithizone as a reagent.
Date: November 1948
Creator: Schwebel, A. & Rosenwasser, H.
System: The UNT Digital Library
Paramagnetic Susceptibilities and Electronic Structures of Aqueous Cations of Elements 92 to 95 (open access)

Paramagnetic Susceptibilities and Electronic Structures of Aqueous Cations of Elements 92 to 95

Abstract: Magnetic susceptibilities per gram atomic weight of elements 92 to 95 in most of their oxidation states were measured at 20°C on 0.1 ml of solution which was 0.005 to 0.09M in heavy element. The values obtained (all paramagnetic) in units × 106 were: U(IV), 3690; Np(VI), 2060; Np(V), 4120; Np(IV), 4000; Pu(IV), 1610; Pu(III), 370; Am(III), 720. The results could be interpreted only on the basis of electronic configurations 5fn, even though susceptibilities were generally lower than the theoretical values and lower than experimental values for corresponding lanthanide 4fn cations. The lower values should be expected as a result of the Stark effect produced by electric fields of anions and of water dipoles. Failure of the Russell‐Saunders approximation to the coupling between electrons may account for some of the error in the theoretical calculations. That the susceptibilities of Pu(III) and Am(III) are manyfold lower than those of Sm(III) and Eu(III), respectively, is attributed to wider multiplet splitting in the actinide atoms.
Date: November 12, 1948
Creator: Howland, Jerome J. & Calvin, Melvin, 1911-1997
System: The UNT Digital Library
The Activity Coefficient of Plutonium(IV) Salts in Acidic Solutions (open access)

The Activity Coefficient of Plutonium(IV) Salts in Acidic Solutions

Summary: The activity coefficient of Pu(Cl04)4 was measured in perchloric acid solutions. The procedure used was to measure the extraction of the neutral plutonium(IV)-TTA chelate into benzene-TTA solutions at different perchloric acid concentrations. Equations are presented which show the relation of the extraction coefficients, obtained in the above manner, to the activity coefficient of plutonium(IV) per-chlorate. The activity coefficient of Pu(Cl0~)4 is similar to that of a strong acid, e.g., perchloric acid, in that its value increases rapidly when the perchloric acid concentration becomes greater than 2M. The distribution coefficient of TTA between benzene and aqueous perchloric acid solutions was found first to decrease slightly and then to increase two fold as the perchloric acid was varied from 0.01 to 6M. The activity coefficient of the uranous-TTA chelate in benzene was calculated from the results of solubility measurements. The values of the activity coefficient of UK4 are,within experimental error, identical with the values of the activity coefficient of TTA itself.
Date: November 1948
Creator: Connick, R. E. & Reas, W. H.
System: The UNT Digital Library