Analysis of Bevatron Tau Mesons (open access)

Analysis of Bevatron Tau Mesons

The following document analyzes one hundred and seventy-seven bevatron tau mesons for Q value of the tau decay, tau spin and parity, and possible polarization effects.
Date: November 5, 1956
Creator: Haddock, Roy Phillip, 1928-
System: The UNT Digital Library
The coordination and atom transfer chemistry of titanium porphyrin complexes (open access)

The coordination and atom transfer chemistry of titanium porphyrin complexes

Preparation, characterization, and reactivity of ({eta}{sup 2}- alkyne)(meso-tetratolylpoprphrinato)titanium(II) complexes are described, along with inetermetal oxygen atom transfer reactions involving Ti(IV) and Ti(III) porphyrin complexes. The {eta}{sup 2}- alkyne complexes are prepared by reaction of (TTP)TiCl{sub 2} with LiAlH{sub 4} in presence of alkyne. Structure of (OEP)Ti({eta}{sup 2}-Ph-C{triple_bond}C-Ph) (OEP=octaethylporphryin) was determined by XRD. The compounds undergo simple substitution to displace the alkyne and produce doubly substituted complexes. Structure of (TTP)Ti(4-picoline){sub 2} was also determined by XRD. Reaction of (TTP)Ti{double_bond}O with (OEP)Ti-Cl yields intermetal O/Cl exchange, which is a one-electron redox process mediated by O atom transfer. Also a zero-electron redox process mediated by atom transfer is observed when (TTP)TiCl{sub 2} is reacted with (OEP)Ti{double_bond}O.
Date: November 5, 1993
Creator: Hays, J. A.
System: The UNT Digital Library