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Neptunium distribution coefficients from acid nitrate, chloride, and sulfate solutions by several organic nitiogen and phosphorus compounds were measured as functions of several extraction variables, including neptunium valence, acid and salt concentration, and reagent concentration. Extractability by all the reagents varied in the order Np(IV)> Np(VI)>> Np(V). Except for primary amines, all reagents extracted Np(IV) much more strongly from nitrate than sulfate solutions. Among organonitrogen compounds the order of extractability of Np(IV) was: quaternary> tertiary> primary and secondary from nitrate solutions but primary>> secondary> tertiary from sulfate solutions. Neptunium(IV) nitrate extractions with the different extractants passed through maxima at widely different acid concentrations. In most cases, extraction increased when nitric acid was replaced by nitrate salt. Extraction was usually approximately proportional to the square of the reagent concentration. (auth)

The soil microflora and its respiratory activity were measured in soil cores collected at different distances from an unshielded reactor. No direct correlation was found between dose received and microbial counts or respiration. Indication of a correlation between dose and microbial respiration was obtained after eliminating the overriding influence of moisture. Radiation probably affected the soil microflora through damage to the phanerogam vegetation rather than directly. This preliminary study indicates the need to have undisturbed sampling areas close to the ORNL fast burst reactor. Extensive dosimetry, both in and above the soil, in these areas, and a program of long-term ecological descriptibn, should be started before the reactor becomes operational. (auth)

This document is designed to present as complete a review of the hazards associated with the operation of the N Reactor as is feasible at this time. Where completeness is not possible the problems are indicated and probable paths of solution are suggested. Background material is provided to put the hazards in context. Supplements to this report will be issued when the additional data and information required for completeness are obtained. This review is organized into two parts. The first part issued as Volume I is in the nature of an expanded summary. The second part of the review will be issued in a succeeding volume or volumes and will consist of results of evaluations obtained following the publishing of this volume plus more detailed supporting information.

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