Theoretical investigation on the nature of ion exchange of acidified uranyl sulfate solutions with Dowex 21K, a strong base ion exchange resin.

Abstract: "The leakage neutron spectrum of a U²³³ spherical critical assembly (Jezebel) has been measured using nuclear emulsions as radiator and detector. The spectrum obtained is compared with similar measurements on the U-235 and Pu-239 analogues of Jezebel U²³³; it is found to agree closely with that of the Pu-239 assembly and to be harder than that of the U-235 assembly. All three spectra are compared with theoretical spectra obtained from a numerical approximation to the neutron transport equation."

Abstract: "The calculation of the efficiency of the Los Alamos hydrogen bubble chamber for detection of neutrons in the energy range 5 to 35 MeV has been done using a "Monte Carlo" technique. The detection efficiency is calculated as a function of energy of the neutron and angle of the proton recoil."

Description and outline of the geology of the U12j and U12j.01 tunnels in the Survey Butte Member of the Piapi Canyon Formation in Nevada.

From introduction: Under the general supervision of the Health Division of the Los Alamos Scientific Laboratory, the U.S. Geological Survey is participating in geologic and hydrologic studies of the tile field constructed in Jackass Flats in the southwestern part of the Nevada Test Site as related to waste disposal, M. D. Shutler rendered valuable assistance in obtaining and evaluating portions of the data in this report. These investigations were done on behalf of the U.S. Atomic Energy Commission and were supported by the Division of Reactor Development and by the Albuquerque Operations Office.

Quarterly report issued by the Knolls Atomic Power Laboratory to report to the industry on developments in unclassified reactor technology. This issue focuses on chemistry information.

This technical report provides a design criteria for a technical support facility for the Lithium Cooled Reactor Experiment (LCRE) and SNAP-50-DR-1 Test Facilities. The support facility is adjacent to the LCRE Test Facility and is located completely within the existing Building 629 structure at the former ANP area of the National Reactor Testing Station (NRTS) near Idaho Falls, Idaho. The information and specifications presented establish the basis for the design of laboratories, shops and engineering areas required to support the installation, operation, maintenance and disassembly of the LCRE and SNAP-50 tests. The construction and modification required to adapt the building to reactor test support operations are described in detail in the following report.

From introduction: The broad objectives of the Survey's program are to provide the basic geologic and geophysical information needed to define the pre- and post-shot geologic and physical properties of salt and other rocks affected by the explosion. To provide geologic and hydrologic information on the pre- and post-shot hydrologic conditions at the Gnome site and surrounding region.

Discussing a computer program, GAMLOG, used to interpret gamma-ray logs of uranium ores.

"Uranium and zirconium were bonded by melting the two metals in contact with one another in a bimetallic casting process. Tensile tests of specimens containing the original zone of interface between the two metals showed that all failures were at locations other than the interface. The coefficients obtained for diffusion between molten uranium and molten zirconium varied from 2.13 cm squared per day at 3,380 degrees F. to 9.17 cm squared per day at 3,510 degrees F. the activation energy for the diffusion process was calculated to be 182,000 calories per gram mole."

From introduction: The primary objective of Project 30.2 was to evaluate the protection afforded by a reinforced-concrete dual-purpose underground parking garage and personnel shelter against effects of a nuclear detonation.

Details are given of an apparatus used to dissolve irradiated ceramic, metallic, and carbide fuel specimens, to dilute the dissolver solutions accurate to a known volume, and to take aliquots with a specially adapted automatic burette. Procedures for its use are given.

Methods are described for the determination of traces of Be, Th, and U in concentrated sulfuric-phosphoric acid mixtures. When the Be concentration is sufficiently high, the chrome azurol S spectrophotometric method may be applied directly, and a small correction made for phosphate interference. At lower concentrations Be should be first separated by an acetylacetone extraction. Th must be separated from sulfate and phosphate before the thoronol spectrophotometric method can be used. This is achieved by precipitating Th as the fluoride, using Y carrier. U may be determined spectrophotometrically with arsonazo after separating Be, Th, suIfate, phosphate, and other impurities by anion-exchange from hydrochloric acid solution. In an alternative procedure, U is reduced to the tetravalent state and precipitated with Th as the fluoride, again using Y carrier. The determination is then completed by a-c polarography.

The dissolution of dense beryllia was studied in a variety of reagents. The dissolution rates were too slow to be of practical importance except those for hydrofluoric acid, sulfuric acid, and mixtures of sulfuric and phosphoric acids. The reaction with hydrofluoric acid was studied in more detail in an attempt to throw some light on the dissolution process. The initial dissolution rate appeared to be proportional to the square of the acid concentration between 0 and 20M. An apparent activation energy of 12 Kcal/mole BeO was obtained from the temperature coefficient of the dissolution.

Technical report. From Abstract : "The MBr3 + M phase diagrams for lanthanum, cerium, and praseodymium are presented. Lanthanum and cerium exhibit simple solutions of metal, with 14 and 12 mole % dissolved at eutectic temperatures of 728 and 687°, respectively. The compound PrBr2.38 is found, melting incongruently to a solution of 16% Pr in PRBr3 and Pr(s) at 601°. For praseodymium the cryoscopic behavior of dilute solutions of metal is consistent with the primary formation of the Pr2+ solute. But with lanthanum and cerium the results are anomalous, as the cryoscopic analyses indicate 1.6-1.7 and 2.0 new particles (cation basis) per metal dissolved instead of ~3."

Technical report. From Abstract : "Reaction of NbBr5 and niobium metal in a sealed tube under a temperature gradient from 410° to 350° gave NbBr4 in good yields. However, an increase in the higher temperature from 410° to 450° was sufficient to eliminate NbBr4 as a product and cause deposition of a lower bromide."

Technical report. From Abstract : "The necessary conditions for preparation of TaBr4 and TaI4 by reduction of the pentahalides with tantalum or aluminum metal in a sealed tube under a controlled temperature gradient have been demonstrated."

Technical report outlining the element calcium as well as its occurrences, physical properties, chemical properties, methods of manufacture, economic aspects, and uses.

Technical report. From Abstract : "Accurate measurements on boiling points and surface tensions of mixtures of benzyl acetate with dioxan, aniline and meta-cresol over the entire range of concentration are reported. The results have been analysed in terms of quasi-crystalline model which is partially successful in representing the composition dependence of heats of mixing, boiling points and surface tension except for composition dependence of boiling points of benzyl acetate and meta-cresol."

Technical report. From Abstract : "The term 'rare earths' is the classic name given to the group of elements with atomic numbers 57 to 71. The element yttrium is usually included in this group. The chemical properties of these elements are so strikingly similar that they always occur together in nature and their separation from each other is a singularly difficult task. With but few exceptions, mixtures of these elements have also defied analysis by classical methods of analytical chemistry. Consequently for the analysis of ores, minerals, and mixtures obtained from fractionation processes, and for the assessment of the purity of isolated elements, it has been necessary to resort to measurements on physical properties. Of these properties, emission and absorption spectra of these elements have found the widest application."

Technical report. From Abstract : "Paramagnetic susceptibilities of samarium structure alloys in the systems La-Gd, Nd-Y, Nd-Tm, and Ce-Y were measured from 4.2 - 300°K to determine what effect the formation of this structure has on the magnetic properties of the alloys. Susceptibility maxima were observed in the Nd-Y and Nd-Tm alloys, at 34.5 and 28.5°K, respectively. Slope changes were observed in the curve of 1/x versus T for the La-Gd alloy at 155 and 130°K, and the susceptibility of this alloy remained temperature-independent from 130-7°K. A rather poorly defined region of constant susceptibility was also observed or the Ce-Y alloy, from 26-37°K. Above these transition temperatures, the alloys obeyed the Curie-Weiss law, the susceptibilities of the La-Gd and Ce-Y samples indicating the possibility of electron transfer occurring in these cases."

From Synopsis: "This paper deals mainly with cement paste in terms of its porosity, internal surface area, interaction between solid substance and evaporable water and related properties."

Abstract: "The energy absorption spectrum of cosmic ray mu mesons at sea level was inferred from the omnidirectional momentum, the latter being obtained from the directional intensities of muons in various energy intervals at zenith angles of 0, 30, 60, and 68 degrees. ...From the energy absorption spectrum, a sea level muon dose rate of 2.23 microrads per hour was determined. This is consistent with measurements of the total cosmic dose rate."

The designer's concept of a test program for the 30-Mw prototype intermediate heat exchanger and steam generator designed and fabricated as part of the Sodium Components Development Program is presented. The performance data will serve to verify the thermal design, or allow application of improved techniques to future designs, give an improved basis for stress analysis in design of future units, and demonstrate the capability and limitations of the units in relation to the performance specifications for which they were designed. Welding techniques for type 316 stainless steel are described. The specifications and operating conditions of the units are given along with instrumentation drawings showing test equipment design and arrangement.