Selective Separation of Trivalent Actinides from Lanthanides by Aqueous Processing with Introduction of Soft Donor Atoms (open access)

Selective Separation of Trivalent Actinides from Lanthanides by Aqueous Processing with Introduction of Soft Donor Atoms

Implementation of a closed loop nuclear fuel cycle requires the utilization of Pu-containing MOX fuels with the important side effect of increased production of the transplutonium actinides, most importantly isotopes of Am and Cm. Because the presence of these isotopes significantly impacts the long-term radiotoxicity of high level waste, it is important that effective methods for their isolation and/or transmutation be developed. Furthermore, since transmutation is most efficiently done in the absence of lanthanide fission products (high yield species with large thermal neutron absorption cross sections) it is important to have efficient procedures for the mutual separation of Am and Cm from the lanthanides. The chemistries of these elements are nearly identical, differing only in the slightly stronger strength of interaction of trivalent actinides with ligand donor atoms softer than O (N, Cl-, S). Research being conducted around the world has led to the development of new reagents and processes with considerable potential for this task. However, pilot scale testing of these reagents and processes has demonstrated the susceptibility of the new classes of reagents to radiolytic and hydrolytic degradation. In this project, separations of trivalent actinides from fission product lanthanides have been investigated in studies of 1) the extraction …
Date: September 22, 2009
Creator: Nash, Kenneth L.
Object Type: Report
System: The UNT Digital Library
2008 Kansas City Plant Annual Illness and Injury Surveillance Report (open access)

2008 Kansas City Plant Annual Illness and Injury Surveillance Report

The U.S. Department of Energy’s (DOE) commitment to assuring the health and safety of its workers includes the conduct of epidemiologic surveillance activities that provide an early warning system for health problems among workers. The Illness and Injury Surveillance Program monitors illnesses and health conditions that result in an absence of workdays, occupational injuries and illnesses, and disabilities and deaths among current workers.
Date: September 22, 2009
Creator: United States. Department of Energy. Office of Health, Safety, and Security.
Object Type: Report
System: The UNT Digital Library
Compatible Relaxation and Coarsening in Algebraic Multigrid (open access)

Compatible Relaxation and Coarsening in Algebraic Multigrid

We introduce a coarsening algorithm for algebraic multigrid (AMG) based on the concept of compatible relaxation (CR). The algorithm is significantly different from standard methods, most notably because it does not rely on any notion of strength of connection. We study its behavior on a number of model problems, and evaluate the performance of an AMG algorithm that incorporates the coarsening approach. Lastly, we introduce a variant of CR that provides a sharper metric of coarse-grid quality and demonstrate its potential with two simple examples.
Date: September 22, 2009
Creator: Brannick, J J & Falgout, R D
Object Type: Article
System: The UNT Digital Library