This quarterly progress details the ongoing work of the Protective Equipment Evaluation Program at the Oak Ridge National Laboratory. Topics discussed include aerosol generation, penetration studies, particle size measurement, and an appendix with analytical methods.

This report describes the development and design of a large bakeable valve that is based on a unique seat arrangement and a novel motion seal.

Preliminary measurements of the corrosion of titanium were made in 13 M HNO3-0.05 M fluoride using 0.1 M H3BO3 as a liquid and vapor phase complexing agent. Titanium Ax-55 was attacked at average rates of 0.58 and 0.33 mils/month in the liquid and vapor. In dissolver solutions containing 0.5 and 1.0 M titanium, all rates were less than 0.1 mils/month.

From abstract: "The dissociation of acids in tertiary butyl alcohol has been studied by potentiometric, spectrophotometric, and conductimetric methods. Values for the over-all dissociation of perchloric and picric acids and several tetrabutylammonium salts were estimated by the Fuoss-Kraus treatment of conductance data. Potentiometric studies were carried out at constant ionic strength in order to minimize activity coefficient variations. An acidity scale was established from potentiometric measurements at a glass electrode, and conductance values of dissociation constants. A method was developed for the evaluation of the over-all dissociation constant of weak acids using potentiometric data for hydrogen ion activities and conductance data for the corresponding anion activities. Over-all dissociation constants are reported for perchloric acid, picric acid, 2,4-dinitrophenol, and benzoic acid. Apparent dissociation constants from potentiometric measurements at a constant ionic strength were determined for hydrobromic, nitric, hydrochloric, picric, and p-toluenesulfonic acids."