An Ion Exchange Study of Possible Hybridized 5f Bonding in the Actinides (open access)

An Ion Exchange Study of Possible Hybridized 5f Bonding in the Actinides

A study was conducted on the elution behavior of curium (III), americium (III), plutonium (III), actinium (III), plutonium (IV), neptunium (IV), uranium (IV), thorium (IV), neptunium (V), plutonium (VI), uranium (VI), lanthanum (III), cerium (III), europium (III), ytterbium (III), ytterium (III), strontium (II), barium (II), radium (II), cesium (I) with 3.2 M, 6.2 M, and 12.2 M HCI solutions from Dower-50 cation exchange resin columns. These elutions show that in high concentrations of hydrochloric acid the actinides form complex ions with chloride ion to a much greater extent than the lanthanides. In order to explain these results, a partial covalent character may be ascribed to the bonding in the transuranium complex ions. It is shown that a reasonable structure for such covalent bonding involves hybridization of the 5g-ortibals in the actinide elements.
Date: August 28, 1951
Creator: Diamond, R. M.; Street, K., Jr. & Seaborg, Glenn T. (Glenn Theodore), 1912-1999
System: The UNT Digital Library
Energy and Ionization of Light Particles as a Function of H(P) (open access)

Energy and Ionization of Light Particles as a Function of H(P)

Energy values are generally accurate to 5%, except in the low energy region and except for He(3) and He(4) for which a non-relativistic conversion was made.
Date: August 1951
Creator: Johnson, Donald
System: The UNT Digital Library
Procedures in Magnetic Measurements at the University of California Radiation Laboratory, Berkeley:  Fields Which are Constant or Vary Slowly with Time (open access)

Procedures in Magnetic Measurements at the University of California Radiation Laboratory, Berkeley: Fields Which are Constant or Vary Slowly with Time

The flux standard is a device which will give a known flux-linkage change to be used as a calibration. At the Radiation Laboratory, two types of flux standards are used, a stationary type and a portable type.
Date: August 16, 1949
Creator: Richardson, Robert E.
System: The UNT Digital Library
Studies of the Metabolism of Certain Fission Products and Plutonium (open access)

Studies of the Metabolism of Certain Fission Products and Plutonium

A short survey of some of the metabolic relationships of the elements, cerium, colurbium, plutonium, strontium, yttrium, and zirconium is presented. While the results of internally deposited radium have not been investigated in these experiments, they have been extensively studies by others. Because so much is known of its biological effects, it has been included in this historical survey.
Date: August 7, 1950
Creator: Kawin, Bergane; Copp, D. H. & Hamilton, J. G.
System: The UNT Digital Library
The Photoproduction of Mesons from Hydrogen (open access)

The Photoproduction of Mesons from Hydrogen

In an effort to gain information on the nature of the photon-meson and photon-nucleon interaction, a study of the artificial production of mesons by photons has been made at the Berkeley synchrotron. The major effort of this research was concentrated on a measurement of the energy and angular distribution of u+-mesons produced when the photons strike a target of liquid hydrogen. Detection of the mesons is accomplished electronically by the technique of delayed coincidence.
Date: August 24, 1950
Creator: Bishop, Amasa Stone
System: The UNT Digital Library
A Note on the Mechanism of the Formation of Alpha-Acylamino Ketones from Amino Acids (open access)

A Note on the Mechanism of the Formation of Alpha-Acylamino Ketones from Amino Acids

The reaction of alanine-1-C14 and phenylalanine-1-C14 with acetic anhydride in the presence of pyridine has been studied and the carboxyl group of the amino acid has been shown to be the exclusive source of carbon dioxide involved.
Date: August 23, 1950
Creator: Fry, Arthur & Rapoport, Henry
System: The UNT Digital Library
Complex Ions of Lanthanum in Aqueous Solutions (open access)

Complex Ions of Lanthanum in Aqueous Solutions

The complexing of lanthanum by various anions and weak acids was investigated by observing the light absorption of the complex formed with thenoyltrifluoracetone (TTA). This species showed the properties needed for a satisfactory specgtrophotometric method of analysis.
Date: August 1, 1951
Creator: Mattern, Kenneth Lawrence
System: The UNT Digital Library