Machine learning is fast growing field as it can be applied to solve a large amount of problems. One large subsection of machine learning are artificial neural networks (ANN), these work on pattern recognition and can be trained with data sets of known solutions. The objective of this thesis is to discuss the creation of an ANN capable of classifying differences in propylene glycol concentrations, up to 10%. Utilizing a micro pipette thermal sensor (MTS) it is possible to measure the heat propagation of a liquid from a laser pulse. The ANN can then be trained beforehand with simulated data and be tested in real time with temperature data from the MTS. This method could be applied to find the thermal conductivity of unknown fluids and biological samples, such as cells and tissues.

Ecological, health and environmental concerns are driving the need for bio-resourced foams for the building industry and for other applications. This is because insulation is one of the most important aspects of the building envelope. Global building insulation is expected to reach USD 27.74 billion in 2022. Conventional insulation materials currently used in buildings are made from nonrenewable products (petroleum, fiber glass). However, they yield increasing unrecyclable eco-unfriendly waste at the end of their lives; styrene and polyurethane generates over 100,000 kg of waste insulation in US alone yearly. This is because they are non-biodegradable and can remain as microplastics in the environment for 1000 years. Polyurethane contains the same amount of energy as coal. Additionally, most of the processing techniques and blowing agents used in this manufacturing of these foams are cancerous and injurious to health when inhaled. Because buildings and their construction together account for 36% of global energy use and 39% of energy-related carbon dioxide emissions annually, there is a need to develop eco-friendly foams that will serve as possible substitutes to the currently used petroleum-based foams. This dissertation examined the development and characterization of eco-friendly foams that were developed using the melt mixing technique of bio-resourced …

Denton, Texas consistently reaches ozone nonattainment levels. This has led to a large focus of air pollution monitoring efforts in the region, with long-range transport being explored as a key contributor. For this study, the University of North Texas Discovery Park campus was chosen as a prospective location for an extensive air quality monitoring station. Sixteen years of ozone and meteorological data for five state-run monitoring sites within a 25 mile radius, including the nearest Denton Airport site, was gathered from TCEQ online database for the month of April for the years 2000 to 2015. The data was analyzed to show a historical, regional perspective of ozone near the proposed site. The maximum ozone concentration measured at the Denton Airport location over the 16 year period was measured at 96 ppb in 2001. Experimental ozone and meteorological measurements were collected at the Discovery Park location from March 26 to April 3 and April 8 to April, 2016 and compared to the Denton Airport monitoring site. A time lag in ozone trends and an increase in peak ozone concentrations at the proposed location were observed at the proposed site in comparison to the Denton Airport site. Historical and experimental meteorological data …

This thesis project investigates, analyzes, designs, simulates, constructs and tests a dual-axis solar tracker system to track the sun and concentrates the heat of the sunlight, using a Fresnel lens, into a small area, which is above of an evaporator, to increase the temperature of the seawater to convert it into freshwater. The dual-axis solar tracker was designed with the main objectives that the structure was portable, dismountable, lightweight, low cost, corrosion resistant, wires inside pipes, accurate, small size, follow the sun automatically, off-grid (electrical), use green energy (solar powered), and has an empty area right below of the lens. First, a 500 mm diameter flat Fresnel lens was selected and simulated based on an algorithmic method achieved by a previous PhD student at UNT using MATLAB®, to give the optimization lens dimensions. The lens profile was drawn with AutoCAD®, then output profile lens was simulated in COMSOL Multiphysics®. The objective was to provide the high efficiency, optimum and high precision of the focal rays and heat to the receiver of the evaporator. A novel dual-axis solar tracker system was then designed that is portable, dismountable, lightweight and corrosion resistant. The solar tracker tracks the sun in two axis of …

This dissertation focuses on studying membrane air dehumidification for a membrane moisture exchanger in a membrane heat pump system. The study has two parts: an optimization of membrane moisture exchanger for air dehumidification in the macroscale, and diffusion of water vapor in polymer nanocomposites membrane for humid air dehumidification in the nanoscale. In the first part of the research, the mass transport of water vapor molecules through hydrophilic silica nanochannel chains in hydrophobic polyurethane matrix was studied by simulations and experiments for different membrane moisture exchanger design configurations. The mass transport across the polymer nanocomposite membrane occurs with the diffusion of moist air water vapor molecules in the membrane moisture exchanger in a membrane heat pump air conditioning system for air dehumidification purposes. The hydrophobic polyurethane matrix containing the hydrophilic silica nanochannel chains membrane is responsible for transporting water vapor molecules from the feed side to the permeate side of the membrane without allowing air molecules to pass through.In the second part of the research, diffusion analysis of the polymer nanocomposite membrane were performed in the nanoscale for the polymer nanocomposite membrane. The diffusion phenomena through the polymer, the polymer nanocomposite without modifying the silica surfaces, and the polymer nanocomposite …

Natural fibers like kenaf, hemp, flax and sisal fiber are becoming alternatives to conventional petroleum fibers for many applications. One such applications is the use of Non-woven bio-fiber mats in the automobile and construction industries. Non-woven hemp fiber mats were used to manufacture plywood in order to optimize the plywood structure. Hemp fiber mats possess strong mechanical properties that comparable to synthetic fibers which include tensile strength and tensile modulus. This study focuses on the use of hemp fiber mat as a core layer in plywood sandwich composite. The optimization of fiber mat plywood was done by performing a three factor experiment. The three factors selected for this experiment were number of hemp mat layers in the core, mat treatment of the hemp mat, and the glue content in the core. From the analysis of all treatments it was determined that single hemp mat had the highest effect on improving the properties of the plywood structure.

This thesis project investigates the configuration of an enclosed evaporation chamber with the intention of converting seawater into potable freshwater. The evaporation chamber's sole heat source is provided by a Fresnel lens, located above the chamber, which concentrates sunlight onto a 3-inch diameter focal plate built into the core of the chamber. The design of the evaporation chamber is modeled after a solar still and is coupled with a heat exchanger to boost efficiency of the system. The chamber was designed with the objectives of being portable, lightweight, low cost, corrosion resistant, interchangeable, and size convenient with the goal of producing 1 Liter of freshwater per hour of operation. The evaporation chamber consists of two primary components, a core and an attached arrangement of fins, all of which are heated via the Fresnel lens. A consistent intake of 2 grams/second of saltwater enters from the top of the chamber and is then gravity fed across the fins. Fin orientation has been designed to inhibit the flow rate of water within the chamber, maximizing the surface area of contact with the heated fins. The evaporation chamber was modeled through SOLIDWORKS and underwent a physical optimization study to reduce material usage while …

Immersed boundary (IB) methods are attractive due to their ability to simulate flow over complex geometries on a simple Cartesian mesh. Unlike conformal grid formulation, the mesh does not need to conform to the shape and orientation of the boundary. This eliminates the need for complex mesh and/or re-meshing in simulations with moving/morphing boundaries, which can be cumbersome and computationally expensive. However, the imposition of boundary conditions in IB methods is not straightforward and numerous modifications and refinements have been proposed and a number of variants of this approach now exist. In a nutshell, IB methods in the literature often suffer from numerical oscillations, implementation complexity, time-step restriction, burred interface, and lack of generality. This limits their ability to mimic conformal grid results and enforce Neumann boundary conditions. In addition, there is no generic IB capable of solving flow with multiple potentials, closely/loosely packed structures as well as IBs of infinitesimal thickness. This dissertation describes a novel 2$ ^{\text{nd}} $ order direct forcing immersed boundary method designed for simulation of two- and three-dimensional incompressible flow problems with complex immersed boundaries. In this formulation, each cell cut by the IB is reshaped to conform to the shape of the IB. IBs …

The main objective of my thesis is to develop a numerical model for small-scale thermal energy storage system and to see the effect of dispersing nano-particles and using fractal-like branching heat exchanger in phase change material for our proposed thermal energy storage system. The associated research problems investigated for phase change material (PCM) are the low thermal conductivity and low rate of heat transfer from heat transfer fluid to PCM in thermal energy storage system. In this study an intensive study is carried out to find the best material for thermal storage and later on as a high conductive nano-particle graphite is used to enhance the effective thermal conductivity of the mixed materials. As a thermal storage material molten solar Salt (60% NaNO3+40%KNO3) has been selected, after that detailed numerical modeling of the proposed design has been done using MATLAB algorithm and following the fixed grid enthalpy method. The model is based on the numerical computation of 1-D finite difference method using explicit scheme. The second part of the study is based on enhancing the heat transfer performance by introducing the concept of fractal network or branching heat exchanger. Results from the numerical computation have been utilized for the comparison …

Fiber-metal laminates (FML) are the advanced materials that are developed to improve the high performance of lightweight structures that are rapidly becoming a superior substitute for metal structures. The reasons behind their emerging usage are the mechanical properties without a compromise in weight other than the traditional metals. The bond remains a concern. This thesis reviews the effect of pre-treatments, say heat, P2 etch and laser treatments on the substrate which modifies the surface composition/roughness to impact the bond strength. The constituents that make up the FMLs in our present study are the Aluminum 2024 alloy as the substrate and the carbon fiber prepregs are the fibers. These composite samples are manufactured in a compression molding process after each pre-treatment and are then subjected to different tests to investigate its properties in tension, compression, flexural and lap shear strength. The results indicate that heat treatment adversely affects properties of the metal and the joint while laser treatments provide the best bond and joint strength.

Fiber-reinforced concrete (FRC) is nowadays extensively used in civil engineering throughout the world due to the composites of FRC can improve the toughness, flexural strength, tensile strength, and impact strength as well as the failure mode of the concrete. It is an easy crazed material compared to others materials in civil engineering. Concrete, like glass, is brittle, and hence has a low tensile strength and shear capacity. At present, there are different materials that have been employed to reinforce concrete. In our experiment, nanostructures iron oxide was prepared by electrodepostion in an electrolyte containing 0.2 mol/L sodium acetate (CH3COONa), 0.01 mol/L sodium sulfate (Na2SO4) and 0.01 mol/L ammonium ferrous sulfate (NH4)2Fe(SO4)2.6H2O under magnetic stirring. The resulted showed that pristine Fe2O3 particles, Fe2O3 nanorods and nanosheets were synthesized under current intensity of 1, 3, 5 mA, respectively. And the pull-out tests were performed by Autograph AGS-X Series. It is discovering that the load force potential of nanostructure fibers is almost 2 times as strong as the control sample.

Emissions of air pollutants from non-conventional sources have been on the rise in the North Texas area over the past decade. These include primary pollutants such as volatile organic compound (VOC) and oxides of nitrogen (NOx) which also act as precursors in the formation of ozone. Most of these have been attributed to a significant increase in oil and gas production activities since 2000 within the Barnett Shale region adjacent to the Dallas-Fort Worth metroplex region. In this study, air quality concentrations measured at the Denton Airport and Dallas Hinton monitoring sites operated by the Texas Commission on Environmental Quality (TCEQ) were evaluated. VOC concentration data from canister-based sampling along with continuous measurement of oxides of nitrogen (NOx), ozone (O3), particulate matter (PM2.5), and meteorological conditions at these two sites spanning from 2000 through 2014 were employed in this study. The Dallas site is located within the urban core of one of the fastest growing cities in the United States, while the Denton site is an exurban site with rural characteristics to it. The Denton Airport site was influenced by natural gas pads surrounding it while there are very few natural gas production facilities within close proximity to the Dallas …

Commercially pure titanium can take up to six months to successfully manufacture a six-inch in diameter ingot in which can be shipped to be melted and shaped into other useful components. The applications to the corrosion-resistant, light weight, strong metal are endless, yet so is the manufacturing processing time. At a cost of around $80 per pound of certain grades of titanium powder, the everyday consumer cannot afford to use titanium in the many ways it is beneficial simply because the number of processing steps it takes to manufacture consumes too much time, energy, and labor. In this research, the steps it takes from the raw powder form to the final part are proposed to be reduced from 4-8 steps to only 2 steps utilizing a new technology that may even improve upon the titanium properties at the same time as it is reducing the number of steps of manufacture. The two-step procedure involves selecting a cylindrical or rectangular die and punch to compress a small amount of commercially pure titanium to a strong-enough compact for transportation to the friction stir welder to be consolidated. Friction stir welding invented in 1991 in the United Kingdom uses a tool, similar to …

Several types of research are ongoing throughout the world, to discover economical and reliable techniques to create hydrogen, and propagate the vision of a hydrogen economy. This research examines a COMSOL Multiphysics 5.4 heat transfer model for a hydrogen production system consisting of a retort with two different heat sources, namely a heat tape and an infrared (IR) lamp. The main objective was to compare the two heat sources and find out which one offers a better technique for producing hydrogen by raising the internal center core temperature of the retort from ambient to the highest temperature, preferably 700℃, within the shortest time possible and using less power consumption in attaining the targeted temperature. Through this study, it was established that the IR lamp could potentially help with energy savings by using just 4 kWh to reach the targeted temperature within an hour.

Novel tissue mimicking materials have been developed for cancer treatment research. In the present research work, the tissue mimicking material is printed using 3D bioprinting technology. The nanoparticles are homogeneously mixed with tissue mimicking materials to enhance the heating capacity. The thermal conductivity of tissue mimicking materials is measured using a micropipette thermal sensor (MTS). Further, the optimal value is identified based on optimization technique and incorporated into a theoretical model to predict the surface temperature of microsphere. The heat conduction governing equation with Lambert law is numerically solved using COMSOL Multiphysics software. To validate the present simulation results, the experiments are conducted using a continuous laser system.

In this study, the thermal properties of low dimensional materials such as graphene and boron nitride nanotube were investigated. As one of important heat transfer characteristics, interfacial thermal resistance (ITR) between graphene and Cu film was estimated by both experiment and simulation. In order to characterize ITR, the micropipette sensing technique was utilized to measure the temperature profile of suspended and supported graphene on Cu substrate that is subjected to continuous wave laser as a point source heating. By measuring the temperature of suspended graphene, the intrinsic thermal conductivity of suspended graphene was measured and it was used for estimating interfacial thermal resistance between graphene and Cu film. For simulation, a finite element method and a multiparameter fitting technique were employed to find the best fitting parameters. A temperature profile on a supported graphene on Cu was extracted by a finite element method using COMSOL Multiphysics. Then, a multiparameter fitting method using MATLAB software was used to find the best fitting parameters and ITR by comparing experimentally measured temperature profile with simulation one. In order to understand thermal transport between graphene and Cu substrate with different interface distances, the phonon density of states at the interface between graphene and Cu …

The thesis describes novel glass micropipette thermal sensor fabricated in cost-effective manner and thermal conductivity measurement of carbon nanotubes (CNT) thin film using the developed sensor. Various micrometer-sized sensors, which range from 2 µm to 30 µm, were produced and tested. The capability of the sensor in measuring thermal fluctuation at micro level with an estimated resolution of ±0.002oC is demonstrated. The sensitivity of sensors was recorded from 3.34 to 8.86 µV/oC, which is independent of tip size and dependent on the coating of Nickel. The detailed experimental setup for thermal conductivity measurement of CNT film is discussed and 73.418 W/moC was determined as the thermal conductivity of the CNT film at room temperature.

Cellular metals exhibit combinations of mechanical, thermal and acoustic properties that provide opportunities for various implementations and applications; light weight aerospace and automobile structures, impact and noise absorption, heat dissipation, and heat exchange. Engineered cell topologies enable one to control mechanical, thermal, and acoustic properties of the gross cell structures. A possible way to manufacture complex 3D metallic cellular solids for mass production with a relatively low cost, the investment casting (IC) method may be used by combining the rapid prototyping (RP) of wax or injection molding. In spite of its potential to produce mass products of various 3D cellular metals, the method is known to have significant casting porosity as a consequence of the complex cellular topology which makes continuous fluid's access to the solidification interface difficult. The effects of temperature on the viscosity of the fluids were studied. A comparative cost analysis between AM-IC and additive manufacturing methods is carried out. In order to manufacture 3D cellular metals with various topologies for multi-functional applications, the casting porosity should be resolved. In this study, the relations between casting porosity and processing conditions of molten metals while interconnecting with complex cellular geometries are investigated. Temperature, and pressure conditions on the …

Additively manufactured (AM) 316L and 17-4PH stainless steel parts, concretely made by laser powder bed fusion (L-PBF), are characterized and micro-mechanical properties of those steels are analyzed. This study also explored and extended to proton irradiation and small-scale mechanical testing of those materials, to investigate how irradiation affects microstructural evolution and thus mechanical properties at the surface level, which could be detrimental in the long term in nuclear applications. In-depth anisotropy analysis of L-PBF 316L stainless steel parts with the variations of volumetric energy density, a combined study of nanoindentation with EBSD (electron backscatter diffraction) mapping is shown to be an alternative methodology for enriching qualification protocols. Each grain with a different crystallographic orientation was mapped successfully by proper indentation properties. <122> and <111> oriented grains displayed higher than average indentation modulus and hardness whereas, <001>, <101>, and <210> oriented grains were found to be weaker in terms of indentation properties. Based on an extensive nanoindentation study, L-PBF 17-4 PH stainless steels are found to be very sensitive to high load rates and irradiation further escalates that sensitivity, especially after a 0.25 s-1 strain rate. 3D porosity measurement via X-ray microscope ensures L-PBF stainless steel parts are of more than …

Laminar natural convection heat transfer from the vertical surface of a cylinder is a classical subject, which has been studied extensively. Furthermore, this subject has generated some recent interest in the literature. In the present investigation, numerical experiments were performed to determine average Nusselt numbers for isothermal vertical cylinders (103 < RaL < 109, 0.5 < L/D <10, and Pr = 0.7) with and without an adiabatic top in a quiescent ambient environment which will allow for plume growth. Results were compared with commonly used correlations and new average Nusselt number correlations are presented. Furthermore, the limit for which the heat transfer results for a vertical flat plate may be used as an approximation for the heat transfer from a vertical cylinder was investigated.

The research focuses on the synthesis and application of multifunctional lignocellulosic biomass bioadsorbent and nanobiocomposites for water purification. A bioadsorbent was prepared from kenaf fiber by self-activation without the use of any toxic chemicals in an innovative method. Silver nanoparticles were synthesized by the green route and then impregnated on the surface of kenaf-based activated carbon (KAC), and hemp fibers by heating and photoirradiation. The formation of hemp-based and kenaf-based silver nanocomposites was confirmed using an environmental scanning electron microscope and energy-dispersive x-ray spectroscopy. Low-cost benign nanoadsorbents demonstrated excellent capabilities for the anionic dye Congo red (CR) and cationic dye brilliant green (BG) degradation, inorganic heavy metals [Cu (II), Pb (II), and Cd (II)] adsorption and antibacterial activities. Antibacterial test via a modified disc diffusion method and minimum inhibitory concentrations was assessed towards the pathogenic strains of bacteria, E. coli and S. aureus. A working portable point-of-use filter was designed and developed, with the filter column encapsulated with nanobiocomposites for the removal of multi-metals and dye. Water samples collected from a wastewater treatment plant in Texas and a mining site in Mexico were used to determine the efficacy of the nanobiocomposites columned in the filter. A comparative analysis was also …

The goal of this research is to measure viscosity via the analysis of amplitude response of a piezo driven vibrating cantilevers partially immersed in a viscous medium. As a driving frequency is applied to a piezoceramic material, the external forces acting on the system will affect its maximum amplitude. This thesis applies this principle through experimental and analytical analyses of the proportional relationship between viscosity and the amplitude response of the first natural frequency mode of the sinusoidal vibration. Currently, the few cantilever-based viscometer designs that exist employ resonant frequency response as the parameter by which the viscosity is correlated. The proposed piezoelectric viscometer employs amplitude response in lieu of resonant frequency response. The goal of this aspect of the research was to provide data confirming amplitude response as a viable method for determining viscosity. A miniature piezoelectric plate was mounted to a small stainless-steel cantilever beam. The tip of the cantilever was immersed within various fluid test samples. The cantilever was then swept through a range of frequencies in which the first frequency mode resided. The operating principle being as the viscosity of the fluid increases the amplitude response of cantilever vibration will decrease relatively. What was found was …

Microchannels have been used in electronics cooling and in air conditioning applications as condensers. Little study has been made in the application of microchannels in automotive heat exchangers, particularly the radiator. The presented research captures the need for the design improvement of radiator heat exchangers in heavy-duty vehicles in order to reduce aerodynamic drag and improve fuel economy. A method for analyzing an existing radiator is set forth including the needed parameters for effective comparisons of alternative designs. An investigation of microchannels was presented and it was determined that microchannels can improve the overall heat transfer of a radiator but this alone will not decrease the dimensions of the radiator. Investigations into improving the air-side heat transfer were considered and an improved fin design was found which allows a reduction in frontal area while maintaining heat transfer. The overall heat transfer of the design was improved from the original design by 7% well as 52% decrease in frontal area but at the cost of 300% increase in auxiliary power. The energy saved by a reduction in frontal area is not substantial enough to justify the increase of auxiliary power. The findings were verified through a computational fluid dynamic model to …

The present study investigates vortex phase separator (VPS) technology as a new approach for a liquid amine CO2 removal system. Experimental results obtained using a 99.99% pure CO2 stream and liquid amine with varying concentrations demonstrate the VPS' ability to decrease CO2 volume at its gas outlet. Operating parameters such as CO2 flow rate, relative humidity (RH), and temperature were systematically varied during experimental procedure, as well as working fluid temperature, volume, and flow rate. The subscale design for a VPS with a 3" inner diameter, 3.5" outer diameter, and 3.63" height removed a maximum of 84% of CO2 from a CO2 stream at 3.7 SCFH flow rate, 14°C temperature, and 82% RH, using 100 mL of 100% amine circulated at 1.52 LPM flow rate. The designed VPS also showed to be effective in removing relative humidity of the CO2 stream by up to 26% for the stated parameters. Regeneration of liquid amine in the VPS system is also proposed to allow for continuous CO2 removal. The results obtained in this work characterize the VPS system for CO2 removal in terms of various operating parameters for the gas (CO2) and liquid (liquid amine) phases, as well as provide initial insights …