A procedure for diamond turning KDP crystals (open access)

A procedure for diamond turning KDP crystals

A procedure and the equipment necessary for single-point diamond flycutting (loosely referred to as diamond turning) potassium di-hydrogen phosphate (KDP) crystals are described. It is based on current KDP diamond turning activities at the Lawrence Livermore National Laboratory (LLNL), drawing upon knowledge from the Nova crystal finishing development during the 1980`s and incorporating refinements from our efforts during 1995. In addition to describing a step-by-step process for diamond turning KDP, specific discussions are included on the necessary diamond tool geometry and edge sharpness, cutting fluid, and crystal preparation, handling, cleaning, and inspection. The authors presuppose that the reader is already familiar with diamond turning practices.
Date: July 7, 1995
Creator: Montesanti, R. C. & Thompson, S. L.
Object Type: Report
System: The UNT Digital Library
Detection of Galactic Dark Matter by GLAST (open access)

Detection of Galactic Dark Matter by GLAST

The mysterious dark matter has been a subject of special interest to high energy physicists, astrophysicists and cosmologists for many years. According to theoretical models, it can make up a significant fraction of the mass of the Universe. One possible form of galactic dark matter, Weakly Interacting Massive Particles (WIMPs), could be detected by their annihilation into monoenergetic gamma-ray line(s). This paper will demonstrate that the Gamma-ray Large Area Space Telescope (GLAST), scheduled for launch in 2005 by NASA, will be capable of searching for these gamma-ray lines in the energy range from 20 GeV to {approx}500 GeV and will be sufficiently sensitive to test a number of models. The required instrument performance and its capability to reject backgrounds to the required levels are explicitly discussed.
Date: July 7, 1999
Creator: Bloom, Elliott D
Object Type: Report
System: The UNT Digital Library
Damage and fracture in large aperture, fused silica, vacuum spatial filter lenses (open access)

Damage and fracture in large aperture, fused silica, vacuum spatial filter lenses

Optical damage that results in large scale fracture has been observed in the large, high-fluence, fused-silica, spatial filter lenses on the Nova and Beamlet lasers. In nearly all cases damage occurs on the vacuum side of the lenses and because the vacuum side of the lens is under tensile stress this damage can lead to catastrophic crack growth if the flaw (damage) size exceeds the critical flaw size for SiO{sub 2}. The damaged 52 cm Nova lenses fracture into two and sometimes three large pieces. Although under full vacuum load at the time they fracture, the Nova lenses do not implode. Rather the authors have observed that the pieces lock together and air slowly leaks into the vacuum spatial filter housing through the lens cracks. The Beamlet lenses have a larger aspect ratio and peak tensile stress than Nova. The peak tensile stress at the center of the output surface of the Beamlet lens is 1,490 psi versus 810 psi for Nova. During a recent Beamlet high energy shot, a damage spot on the lens grew to the critical flaw size and the lens imploded. Post shot data indicate the lens probably fractured into 5 to 7 pieces, however, unlike …
Date: July 7, 1995
Creator: Campbell, J.H.; Edwards, G.J. & Marion, J.E.
Object Type: Article
System: The UNT Digital Library
Parasitic pencil beams caused by lens reflections in laser amplifier chains (open access)

Parasitic pencil beams caused by lens reflections in laser amplifier chains

Reflections from lens surfaces create parasitic beams that can damage optics in high-powered laser systems. These parasitic beams are low in energy initially, because of the low reflectivity of antireflection (AR) coated lens surfaces and because they are clipped by spatial filter pinholes, but subsequent amplification can raise them to damage fluence levels. Also, some of the pencil beams in multipass laser systems become pre-pulses at the output by by-pass one of more of the passes, arriving at the output ahead of the main pulse in time. They are insidious because pencil beams that are not initially a problem can become so due to a slow degradation of the AR coatings. Both the Nova and Beamlet laser systems at LLNL have had optics damaged by pencil beams. The best solution for pencil beams is to tip the lenses far enough to eliminate them altogether. This will be the approach taken for the National Ignition Facility (NIF).
Date: July 7, 1995
Creator: Murray, J. E.; Van Wonterghem, B. & Seppala, L.
Object Type: Article
System: The UNT Digital Library
Photorefractivity in liquid crystals doped with a soluble conjugated polymer. (open access)

Photorefractivity in liquid crystals doped with a soluble conjugated polymer.

Photoconductive polymers are doped into liquid crystals to create a new mechanism for space-charge field formation in photorefractive liquid crystal composites. The composites contain poly(2,5-bis(2{prime}-ethylhexyloxy)-1,4-phenylenevinylene) (BEH-PPV) and the electron acceptor N,N{prime}-dioctyl-1,4:5,8-naphthalenediimide, NI. Using asymmetric energy transfer (beam coupling) measurements that are diagnostic for the photorefractive effect, the direction of beam coupling as a function of grating fringe spacing inverts at a spacing of 5.5 {micro}m. We show that the inversion is due to a change in the dominant mechanism for space-charge field formation. At small fringe spacings, the space-charge field is formed by ion diffusion in which the photogenerated anion is the more mobile species. At larger fringe spacings, the polarity of the space charge field inverts due to dominance of a charge transport mechanism in which photogenerated holes are the most mobile species due to hole migration along the BEH-PPV chains coupled with interchain hole hopping. Control experiments are presented, which use composites that can access only one of the two charge transport mechanisms. The results show that charge migration over long distances leading to enhanced photorefractive effects can be obtained using conjugated polymers dissolved in liquid crystals.
Date: July 7, 1999
Creator: Niemczyk, M. P.; Svec, W. A.; Wasielewski, M. R. & Wiederrecht, G. P.
Object Type: Article
System: The UNT Digital Library
Recent developments pertinent to processing of ENDF/B-6 type resonance cross section data. (open access)

Recent developments pertinent to processing of ENDF/B-6 type resonance cross section data.

In view of our increasing dependence on computations rather than construction and operation of more costly experimental facilities, the rigor and accuracy achievable by calculational methods certainly deserve more attention. This is particularly so for the Monte Carlo methods which are generally regarded as the ultimate computational standard for the entire nuclear community around the globe. One obvious question that one may raise is whether the numerical algorithms deployed to process cross sections accurately reflect the rigor of the state-of-the-art nuclear data. The case in point is particularly essential in the resolved and the unresolved resonance regions, which constitute the most demanding task in all processing codes for reactor applications. For the resolved energy region, the point-wise cross sections are highly fluctuating functions of energy and temperature. In light of the availability of a large body of resonance data spanning over the much expanded energy ranges for most of major nuclides, critical examinations and improvement where appropriate, of the existing methods are apparently in order. For the unresolved energy region, improvement of traditional methods based on statistical approaches for treating the self-shielding effects is also desirable. From the perspective of the Monte Carlo approach, an alternative means for generating the …
Date: July 7, 1998
Creator: Hwang, R. N.
Object Type: Article
System: The UNT Digital Library
Progress Toward E-157: A 1 GeV Plasma Wakefield Accelerator (open access)

Progress Toward E-157: A 1 GeV Plasma Wakefield Accelerator

A plasma based wakefield acceleration (PWFA) experiment, scheduled to run this summer, will accelerate parts of a 28.5 GeV bunch from the SLAC linac by up to 1 GeV over a length of 1 meter. A single 28.5 GeV bunch will both induce the wakefields in the one meter long plasma and witness the resulting acceleration fields. The experiment will explore and further develop the techniques that are needed to apply high-gradient PWFA to large scale accelerators. This paper summarizes the goals of the first round of experiments as well as the status of the individual components: construction and diagnosis of the homogeneous lithium oven plasma source and associated ionization laser, commissioning of the electron beam, simulated performance of the electron beam energy measurement, and first PIC simulations of the full meter long experiment.
Date: July 7, 1999
Creator: Assmann, R
Object Type: Report
System: The UNT Digital Library
The National Ignition Facility front-end laser system (open access)

The National Ignition Facility front-end laser system

The proposed National Ignition Facility is a 192 beam Nd:glass laser system capable of driving targets to fusion ignition by the year 2005. A key factor in the flexibility and performance of the laser is a front-end system which provides a precisely formatted beam to each beamline. Each of the injected beams has individually controlled energy, temporal pulseshape, and spatial shape to accommodate beamline-to-beamline variations in gain and saturation. This flexibility also gives target designers the options for precisely controlling the drive to different areas of the target. The design of the Front-End laser is described, and initial results are discussed.
Date: July 7, 1995
Creator: Burkhart, S. C.; Beach, R. J.; Crane, J. H.; Davin, J. M.; Perry, M. D. & Wilcox, R. B.
Object Type: Article
System: The UNT Digital Library
User's Manual for the FEHM Application-A Finite-Element Heat- and Mass-Transfer Code (open access)

User's Manual for the FEHM Application-A Finite-Element Heat- and Mass-Transfer Code

This document is a manual for the use of the FEHM application, a finite-element heat- and mass-transfer computer code that can simulate nonisothermal multiphase multicomponent flow in porous media. The use of this code is applicable to natural-state studies of geothermal systems and groundwater flow. A primary use of the FEHM application will be to assist in the understanding of flow fields and mass transport in the saturated and unsaturated zones below the proposed Yucca Mountain nuclear waste repository in Nevada. The equations of heat and mass transfer for multiphase flow in porous and permeable media are solved in the FEHM application by using the finite-element method. The permeability and porosity of the medium are allowed to depend on pressure and temperature. The code also has provisions for movable air and water phases and noncoupled tracers; that is, tracer solutions that do not affect the heat- and mass-transfer solutions. The tracers can be passive or reactive. The code can simulate two-dimensional, two-dimensional radial, or three-dimensional geometries. In fact, FEHM is capable of describing flow that is dominated in many areas by fracture and fault flow, including the inherently three-dimensional flow that results from permeation to and from faults and fractures. …
Date: July 7, 1997
Creator: Zyvoloski, George A.; Robinson, Bruce A.; Dash, Zora V. & Trease, Lynn L.
Object Type: Report
System: The UNT Digital Library
Basin Analysis of the Mississippi Interior Salt Basin and Petroleum System Modeling of the Jurassic Smackover Formation, Eastern Gulf Coastal Plain (open access)

Basin Analysis of the Mississippi Interior Salt Basin and Petroleum System Modeling of the Jurassic Smackover Formation, Eastern Gulf Coastal Plain

The objective is to provide a comprehensive geologic analysis of the Mississippi Interior Salt Basin.
Date: July 7, 1998
Creator: Mancini, Ernest A.
Object Type: Report
System: The UNT Digital Library
Fault tolerance of the NIF power conditioning system (open access)

Fault tolerance of the NIF power conditioning system

The tolerance of the circuit topology proposed for the National Ignition Facility (NIF) power conditioning system to specific fault conditions is investigated. A new pulsed power circuit is proposed for the NIF which is simpler and less expensive than previous ICF systems. The inherent fault modes of the new circuit are different from the conventional approach, and must be understood to ensure adequate NIF system reliability. A test-bed which simulates the NIF capacitor module design was constructed to study the circuit design. Measurements from test-bed experiments with induced faults are compared with results from a detailed circuit model. The model is validated by the measurements and used to predict the behavior of the actual NIF module during faults. The model can be used to optimize fault tolerance of the NIF module through an appropriate distribution of circuit inductance and resistance. The experimental and modeling results are presented, and fault performance is compared with the ratings of pulsed power components. Areas are identified which require additional investigation.
Date: July 7, 1995
Creator: Larson, D.W.; Anderson, R. & Boyes, J.
Object Type: Report
System: The UNT Digital Library
Implementation of ISO 10110 optics drawing standards for the National Ignition Facility (open access)

Implementation of ISO 10110 optics drawing standards for the National Ignition Facility

LLNL plans to specify optical components for the National Ignition Facility according to ISO 10110, the new international standard for preparation of optics drawings. The standards have been approved by the international optics community and represent a fairly comprehensive language for describing optical components. We will describe our plan for implementation and experience to date in doing so.
Date: July 7, 1995
Creator: English, R. E., Jr.; Aikens, D. M. & Whistler, W. T.
Object Type: Article
System: The UNT Digital Library
On the Theory of Critical Currents and Flux Flow in Superconductors by the Mechanism of Plastic Deformation of the Flux-Line Lattice. (open access)

On the Theory of Critical Currents and Flux Flow in Superconductors by the Mechanism of Plastic Deformation of the Flux-Line Lattice.

In this paper I will discuss how the nature of the stress state in the flux-line lattice (FLL) of superconductors arises from the distribution, density, geometry, and strength of pinning centers. Under certain conditions this stress causes the onset of plastic deformation in the FLL for values of the current density below that required for flux-flow by general depinning. I will describe an analytic framework, based on a theory of plasticity of the FLL, which describes the flux-flow characteristics, including the possibility of thermally-activated flow and flux creep.
Date: July 7, 1999
Creator: Welch, D. O.
Object Type: Article
System: The UNT Digital Library
Plasma electrode pockels cell for ICF lasers (open access)

Plasma electrode pockels cell for ICF lasers

In a plasma-electrode Pockels cell (PEPC), plasma discharges serve as transparent electrodes on each side of, an electrooptic crystal such as KDP. These plasmas facilitate rapid and uniform charging and discharging of the crystal. The authors describe PEPC technology deployed on Beamlet and envisioned for the National Ignition Facility. Performance on Beamlet is discussed in detail. They also discuss models which have shed light on PEPC operation. These models describe both the high-voltage sheath that forms near the crystal surface and the characteristics of the bulk plasma column.
Date: July 7, 1995
Creator: Rhodes, M. A.; Boley, C. D.; Tarditi, A. G. & Bauer, B. S.
Object Type: Article
System: The UNT Digital Library
Improved Efficiency of Miscible C02 Floods and Enhanced Prospects for C02 Flooding Heterogeneous Reservoirs (open access)

Improved Efficiency of Miscible C02 Floods and Enhanced Prospects for C02 Flooding Heterogeneous Reservoirs

In this quarter, we used parallel isolated composite core to test the effectiveness of foam on oil recovery efficiency. This composite core differs from the previous core in two areas: 1) Pyrex® glass beads were used in the center region to form a high permeability region and 2) a fired Berea sandstone was used in the annulus region to form a low permeability region. We also started to conduct surfactant adsorption measurements on coreflooding substrates. Static measurements with three anionic surfactants were conducted on Pyrex® glass beads. Surfactant concentrations were determined to calculate the amount of surfactant adsorbed on the substrate. The preliminary results showed that the loss of surfactant due to adsorption at 500 ppm concentration were 0.34 mg/cm 3 , 0.29 mg/cm 3 , and 0.19 mg/cm 3 for surfactants Alipa®CD128, Chaser�CD1040 and Dowfax�8390, respectively. Simulations were performed to assess the applicability of horizontal wells as a tool to increase oil recovery in CO2 injection projects.
Date: July 7, 1998
Creator: Schechter, David S. & Grigg, Reid B.
Object Type: Report
System: The UNT Digital Library
Control of Growth Efficiency in Young Plantation Loblolly Pine and Sweetgum through Irrigation and Fertigation Enhancement of Leaf Carbon Gain (open access)

Control of Growth Efficiency in Young Plantation Loblolly Pine and Sweetgum through Irrigation and Fertigation Enhancement of Leaf Carbon Gain

The overall objective of this study was to determine if growth efficiency of young plantation loblolly pine and sweetgum can be maintained by intensive forest management and whether increased carbon gain is the mechanism controlling growth efficiency response to resource augmentation. Key leaf physiological processes were examined over two growing seasons in response to irrigation, fertigation (irrigation with a fertilizer solution), and fertigation plus pest control (pine only). Although irrigation improved leaf net photosynthesis in pine and decreased stomatal sensitivity to vapor pressure deficit in sweetgum, no consistent physiological responses to fertigation were detected in either species. After 4 years of treatment, a 3-fold increase in woody net primary productivity was observed in both species in response to fertigation. Trees supplemented with fertigation and fertigation plus pest control exhibited the largest increases in growth and biomass. Furthermore, growth efficiency was maintained by fertigation and fertigation plus pest control, despite large increases in crown development and self-shading. Greater growth in response to intensive culture was facilitated by significant gains in leaf mass and whole tree carbon gain rather than detectable increases in leaf level processes. Growth efficiency was not maintained by significant increases in leaf level carbon gain but was possibly …
Date: July 7, 1999
Creator: Samuelson, L.
Object Type: Report
System: The UNT Digital Library
The IFR Online Detector Control system at the BaBar Experiment (open access)

The IFR Online Detector Control system at the BaBar Experiment

The Instrumented Flux Return (IFR)[1] is one of the five subdetectors of the BaBar[2] experiment on the PEP II accelerator at SLAC. The IFR consists of 774 Resistive Plate Chamber (RPC) detectors, covering an area of about 2,000 m{sup 2} and equipped with 3,000 Front-end Electronic Cards (FEC) reading about 50,000 channels (readout strips). The first aim of a B-factory experiment is to run continuously without any interruption and then the Detector Control system plays a very important role in order to reduce the dead-time due to the hardware problems. The I.N.F.N. group of Naples has designed and built the IFR Online Detector Control System (IODC)[3] in order to control and monitor the operation of this large number of detectors and of all the IFR subsystems: High Voltage, Low Voltage, Gas system, Trigger and DAQ crates. The IODC consists of 8 custom DAQ stations, placed around the detector and one central DAQ station based on VME technology and placed in electronic house. The IODC use VxWorks and EPICS to implement slow control data flow of about 2500 hardware channels and to develop part of the readout module consisting in about 3500 records. EPICS is interfaced with the BaBar Run Control …
Date: July 7, 1999
Creator: Paolucci, Pierluigi
Object Type: Report
System: The UNT Digital Library
Synthesis, characterization and application of electrode materials (open access)

Synthesis, characterization and application of electrode materials

It has been known that significant advances in electrochemistry really depend on improvements in the sensitivity, selectivity, convenience, and/or economy of working electrodes, especially through the development of new working electrode materials. The advancement of solid state chemistry and materials science makes it possible to provide the materials which may be required as satisfactory electrode materials. The combination of solid state techniques with electrochemistry expands the applications of solid state materials and leads to the improvement of electrocatalysis. The study of Ru-Ti{sub 4}O{sub 7} and Pt-Ti{sub 4}O{sub 7} microelectrode arrays as introduced in paper 1 and paper 4, respectively, focuses on their synthesis and characterization. The synthesis is described by high temperature techniques for Ru or Pt microelectrode arrays within a conductive Ti{sub 4}O{sub 7} ceramic matrix. The characterization is based on the data obtained by x-ray diffractometry, scanning electron microscopy, voltammetry and amperometry. These microelectrode arrays show significant enhancement in current densities in comparison to solid Ru and Pt electrodes. Electrocatalysis at pyrochlore oxide Bi{sub 2}Ru{sub 2}O{sub 7.3} and Bi{sub 2}Ir{sub 2}O{sub 7} electrodes are described in paper 2 and paper 3, respectively. Details are reported for the synthesis and characterization of composite Bi{sub 2}Ru{sub 2}O{sub 7.3} electrodes. Voltammetric …
Date: July 7, 1995
Creator: He, L.
Object Type: Thesis or Dissertation
System: The UNT Digital Library
Matrix effects in inductively coupled plasma mass spectrometry (open access)

Matrix effects in inductively coupled plasma mass spectrometry

The inductively coupled plasma is an electrodeless discharge in a gas (usually Ar) at atmospheric pressure. Radio frequency energy generated by a RF power source is inductively coupled to the plasma gas through a water cooled load coil. In ICP-MS the {open_quotes}Fassel{close_quotes} TAX quartz torch commonly used in emission is mounted horizontally. The sample aerosol is introduced into the central flow, where the gas kinetic temperature is about 5000 K. The aerosol is vaporized, atomized, excited and ionized in the plasma, and the ions are subsequently extracted through two metal apertures (sampler and skimmer) into the mass spectrometer. In ICP-MS, the matrix effects, or non-spectroscopic interferences, can be defined as the type of interferences caused by dissolved concomitant salt ions in the solution. Matrix effects can be divided into two categories: (1) signal drift due to the deposition of solids on the sampling apertures; and/or (2) signal suppression or enhancement by the presence of the dissolved salts. The first category is now reasonably understood. The dissolved salts, especially refractory oxides, tend to deposit on the cool tip of the sampling cone. The clogging of the orifices reduces the ion flow into the ICP-MS, lowers the pressure in the first stage …
Date: July 7, 1995
Creator: Chen, Xiaoshan
Object Type: Thesis or Dissertation
System: The UNT Digital Library
Identification and evaluation of fluvial-dominated deltaic (Class 1 oil) reservoirs in Oklahoma. Quarterly technical progress report, January 1, 1995--March 31, 1995 (open access)

Identification and evaluation of fluvial-dominated deltaic (Class 1 oil) reservoirs in Oklahoma. Quarterly technical progress report, January 1, 1995--March 31, 1995

The Oklahoma Geological Survey (OGS), the Geological Information Systems department, and the School of Petroleum and Geological Engineering at the University of Oklahoma are engaging in a program to identify and address Oklahoma`s oil recovery opportunities in fluvial-dominated deltaic (FDD) reservoirs. This program includes the systematic and comprehensive collection and evaluation of information on all of Oklahoma`s FDD reservoirs and the recovery technologies that have been (or could be) applied to those reservoirs with commercial success. This data collection and evaluation effort will be the foundation for an aggressive, multifaceted technology transfer program that is designed to support all of Oklahoma`s oil industry, with particular emphasis on smaller companies and independent operators in their attempts to maximize the economic producibility of FDD reservoirs. Specifically, this project will identify all FDD oil reservoirs in the State; group those reservoirs into plays that have similar depositional and subsequent geologic histories; collect, organize and analyze all available data; conduct characterization and simulation studies on selected reservoirs in each play; and implement a technology transfer program targeted to the operators of FDD reservoirs to sustain the life expectancy of existing wells with the ultimate objective of increasing oil recovery. The elements of the technology …
Date: July 7, 1995
Creator: Mankin, C. J. & Banken, M. K.
Object Type: Report
System: The UNT Digital Library
Laser chain alignment with low power local light sources (open access)

Laser chain alignment with low power local light sources

Timely and repeatable alignment of the 192 beam National Ignition Facility (NIF) laser will require an automatic system. Demanding accuracy requirements must be met with high reliability at low cost while minimizing the turnaround time between shots. We describe an approach for internally self-consistent alignment of the mirrors in the laser chains using a network of local light sources that serve as near field and far field alignment references. It incorporates a minimum number of alignment lasers, handles many beams in parallel, and utilizes simple control algorithms.
Date: July 7, 1995
Creator: Bliss, E. S.; Feldman, M.; Murray, J. E. & Vann, C. S.
Object Type: Article
System: The UNT Digital Library
Identification of mine collapses, explosions and earthquakes using INSAR: a preliminary investigation (open access)

Identification of mine collapses, explosions and earthquakes using INSAR: a preliminary investigation

Interferograms constmcted from satellite-borne synthetic aperture radar images have the capability of mapping sub-cm ground surface deformation over areas on the order of 100 x 100 km with a spatial resolution on the order of 10 meters. We investigate the utility of synthetic aperture radar interferomehy (InSAR) used in conjunction with regional seismic methods in detecting and discriminating different types of seismic events in the context of special event analysis for the CTBT. For this initial study, we carried out elastic dislocation modeling of underground explosions, mine collapses and small (M<5.5) shallow earthquakes to produce synthetic interferograms and then analyzed satellite radar data for a large mine collapse. The synthetic modeling shows that, for a given magnitude each type of event produces a distinctive pattern of ground deformation that can be recognized in, and recovered from, the corresponding interferogram. These diagnostic characteristics include not only differences in the polarities of surface displacements but also differences in displacement amplitudes from the different sources. The technique is especially sensitive to source depth, a parameter that is crucial in discriminating earthquakes from the other event types but is often very poorly constrained by regional seismic data alone. The ERS radar data analyzed is …
Date: July 7, 1998
Creator: Foxall, B.; Sweeney, J. J. & Walter, W. R.
Object Type: Article
System: The UNT Digital Library
Test plan for immobilization of salt-containing surrogate mixed wastes using polyester resins (open access)

Test plan for immobilization of salt-containing surrogate mixed wastes using polyester resins

Past operations at many Department of Energy (DOE) sites have resulted in the generation of several waste streams with high salt content. These wastes contain listed and characteristic hazardous constituents and are radioactive. The salts contained in the wastes are primarily chloride, sulfate, nitrate, metal oxides, and hydroxides. DOE has placed these types of wastes under the purview of the Mixed Waste Focus Area (MWFA). The MWFA has been tasked with developing and facilitating the implementation of technologies to treat these wastes in support of customer needs and requirements. The MWFA has developed a Technology Development Requirements Document (TDRD), which specifies performance requirements for technology owners and developers to use as a framework in developing effective waste treatment solutions. This project will demonstrate the use of polyester resins in encapsulating and solidifying DOE`s mixed wastes containing salts, as an alternative to conventional and other emerging immobilization technologies.
Date: July 7, 1997
Creator: Biyani, R.K.; Douglas, J.C. & Hendrickson, D.W.
Object Type: Report
System: The UNT Digital Library
Vitrification of Simulated Fernald K-65 Silo Waste at Low Temperature (open access)

Vitrification of Simulated Fernald K-65 Silo Waste at Low Temperature

Vitrification is the technology that has been chosen to solidify approximately 18,000 tons of geologic mill tailings, designated as K-65 wastes, at the Fernald Environmental Management Project (FEMP) in Fernald, Ohio. The glass formula developed in this study for the FEMP wastes is a lithia substituted soda-lime-lithia-silica (SLLS) composition which melts at 1050 degrees Celsius. Low melting formulations minimize volatilization of hazardous species such as arsenic, selenium, chromium, and lead during vitrification. Formulation in the SLLS system avoids problematic phase separation known to occur in the MO-B2O3-SiO2 glass forming system (where MO = CaO, MgO, BaO, and PbO which are all constituents of the FEMP wastes). The SLLS glass passed the Environmental Protection Agency (EPA) Toxic Characteristic Leach Procedure (TCLP) for all the hazardous constituents of concern under the current regulations. The SLLS glass is as durable as the high melting soda-lime-silica glasses and is more durable than the borosilicate glasses previously developed for the K-65 wastes. Optimization of glass formulations in the SLLS glass forming system should provide glasses which will pass the newly promulgated Universal Treatment Standards which take effect of August 28, 1998.
Date: July 7, 1998
Creator: Jantzen, Carol M. & Pickett, J. B.
Object Type: Article
System: The UNT Digital Library