Abstract: "Decontamination factors of the order of 10-4 were obtained for Beta and Gamma emitters present as fission products when uranium was precipitated from 50 mC activity level solutions as uranyl oxalate under normal uranium yield conditions for three cycles (~60%). Factors of the order of 10-3 were obtained by the use of this reaction with similar solutions under relatively high uranium yield conditions for three cycles (~90%). The uranium peroxide precipitation reaction proved to be of no value on such solutions, yielding decontamination factors of only 17.1 Beta emitters and 1.2 for Gamma emitters for three cycles."

The total cross sections of the reactions DDp, DDn, TD at 10 kev to 10 Mev are estimated from a review of the experimental data up to January 1951. Maxwell averages for DDp and TD computed from these estimates are given, together with some fitted analytic expressions provided for machine use. A collection of the identifiable earlier estimates is also included for reference and for comparison with the new figures. For relative order of magnitude purposes, cross sections and the derived Maxwell averages are given down to 50 ev using the theoretical Gamow slopes for the extrapolation. Gamow plots for the derived cross sections above l0 kev arc also given. Much of the primary experimental data exists in the form of thick target yields and we find the most uncertain factor in converting these thick targets yields into cross sections is the magnitude of the D/sub 2/O stopping cross section. The particular D/sub 2/O stopping cross section relation used in this derivation together with some of the earlier stopping cross sections are given. Thick target yields are included for both DD and TD on D/sub 2/ targets, at 0.01 to 1 Mev, experimental values being supplemented by calculated values.

It has been found relatively easy to form uranium in the gamma phase temperature range by hot pressing, forging, or extrusion. The metal is quite plastic and flows readily to form a shape. Several temperatures from 800 degree C to 1000 degree C were investigated. No forming difficulties were experienced with the metal at the several temperatures concerned. The major difficulty in gamma phase hot pressing or extruding was associated with the tools. Metals or ceramics were not successful as tools for one or more reasons concerned with: lack of hot strength, reactions with the uranium, failure in thermal shock, and tendency to spall. Graphite was found to be the best material available, but it is not entirely satisfactory because of low strength. Uranium formed in the gamma phase possesses some refinement of grain structure as compared with as-cast metal; however, the grain size is quite large. No physical properties of the gamma phase formed metal were determined.

Strubl's polarographic method for the determination of uranium in the presence of iron can be used for the determination of uranium in plutonium solutions. A hydroxylamine hydrochloride solution (2M) is used as the supporting electrolyte. This reduces the plutonium to the plus three oxidation state without reducing the uranium. The uranium may then be determined polarographically by measuring the height of the uranyl reduction wave (UVI to UV) at -0.35 volts (vs. S.C.E.) applied potential. Solutions with a U/Pu weight ratio as low as 3.5 x 10(-3) were analyzed with an error of less than 2%. This error increased to 6% for solutions of 1 x 10(-3) U/Pu ration and is considerably larger for smaller U/Pu ratios.