Helen Kotas was an accomplished musician and teacher who helped open the door for women in major US orchestras. In 1941 the Chicago Symphony hired its first female brass musician, principal hornist Helen Kotas. With that daring move, she became a pioneer for her gender in the major orchestras of North America. Despite her many contributions to the musical community, Kotas's life has not been researched and documented. This paper looks at Helen Kotas's career as well as a glimpse at her life and personality. In addition to documenting her life, this dissertation attempts to show at least a portion of Kotas's philosophy of teaching and horn playing. She was an accomplished horn soloist and studied the literature extensively. Kotas performed in the Chicago Civic Orchestra, the Woman's Symphony Orchestra, and Leopold Stokowski's All-American Youth Orchestra. Kotas was hired by Fritz Reiner as third horn of the Pittsburgh Symphony. When Frederick Stock, conductor of the Chicago Symphony Orchestra, heard that Helen Kotas was going to Pittsburgh, he insisted that she audition for the CSO. Kotas auditioned on the Concerto for Horn by Richard Strauss and the concertmaster said, "Hire her!" She performed as principal horn with the orchestra until Artur …

The inspiration for The Fallow Ground is the time period of the Second Great Awakening (1790-1840s) and, in particular, the life and impact of one of the period's central figures: Charles Grandison Finney. Finney was a lawyer-turned-evangelist whose preaching style led to explosive and emotional conversions and helped spread the fire of revival throughout the state of New York and eventually throughout the country. In The Fallow Ground I have taken different events from Finney's life and the revivalist culture to create musical analogs that examine and critique the events within a twenty-first century musical aesthetic. Quotation and allusion of revival period hymns play a significant part in The Fallow Ground. Inspired by the works of Ives, Crumb, Ligeti, and Schnittke, quotation is used in this piece to develop or subvert the material, thus creating different contextual meanings from familiar material. In this way, the quotation not only alludes to an idea outside of the piece, but also casts a critical view of that idea by its placement in the context of the piece. Concerning the instrumentation, The Fallow Ground is written for what is commonly called the Pierrot ensemble (flute, clarinet, violin, cello, piano, and percussion) with male soloist. …

The kinetics of the reaction of atomic sulfur and nitrogen dioxide have been investigated over the temperature range 298 to 650 K and pressures from 14 - 405 mbar using the laser flash photolysis - resonance fluorescence technique. The overall bimolecular rate expression k (T) = (1.88 ± 0.49) x10-11 exp-(4.14 ± 0.10 kJ mol-1)/RT cm3 molecule-1 s-1 is derived. Ab initio calculations were performed at the CCSD(T)/CBS level of theory and a potential energy surface has been derived. RRKM theory calculations were performed on the system. It is found that an initially formed SNO2 is vibrationally excited and the rate of collisional stabilization is slower than the rate of dissociation to SO + NO products by a factor of 100 - 1000, under the experimental conditions.

C. halicacabum (Sapindaceae) is an invasive plant that is considered a nuisance species in Texas riparian environments. Little is known of the tolerance of C. halicacabum to flooding and drought; however, this information may provide insight into the characteristics that contribute to C. halicacabum purported invasiveness. C. halicacabum seedlings (n = 92) were exposed to one of four levels of water availability (flooded, saturated, intermediate and dry) over six weeks under greenhouse conditions. Plant performance was affected by water availability; however, there was no effect on survivorship. Flooded and saturated plants exhibited morphological adaptations; producing adventitious roots, hypertrophy, and aerenchyma tissue. Morphological measures, anatomical responses, and patterns of biomass allocation all indicate that C. halicacabum is able to survive periodic inundation, perform in saturation, and establish and thrive on the drier end of a moisture gradient.

The current understanding of the atomic scale phenomenon associated with the influence of beta phase instabilities on the evolution of microstructure in titanium alloys is limited due to their complex nature. Such beta phase instabilities include phase separation and precipitation of nano-scale omega and alpha phases in the beta matrix. The initial part of the present study focuses on omega precipitation within the beta matrix of model binary titanium molybdenum (Ti-Mo) alloys. Direct atomic scale observation of pre-transition omega-like embryos in quenched alloys, using aberration-corrected high resolution scanning transmission electron microscopy and atom probe tomography (APT) was compared and contrasted with the results of first principles computations performed using the Vienna ab initio simulation package (VASP) to present a novel mechanism of these special class of phase transformation. Thereafter the beta phase separation and subsequent alpha phase nucleation in a Ti-Mo-Al ternary alloy was investigated by coupling in-situ high energy synchrotron x-ray diffraction with ex-situ characterization studies performed using aberration corrected transmission electron microscopy and APT to develop a deeper understanding of the mechanism of transformation. Subsequently the formation of the omega phase in the presence of simultaneous development of compositional phase separation within the beta matrix phase of a …

Within the United States, probation has customarily been used as a way to divert offenders away from prison. Over the past two decades the number of offenders who are sentenced to probation has increased tremendously. While there have been more offenders sentenced to probation, there has also been an increase in the number of probationers having that sentence revoked. The most prevalent type of revocation is a technical revocation. Probationers receive technical violations culminating in a revocation when they fail to satisfy the conditions of their probation sentence such as attending rehabilitative programming. The present study adds to the literature on technical revocations by examining characteristics of felony probationers from a large Southern state who were revoked between January 1, 2008 and December 31, 2009. Findings revealed that female probationers, older probationers, white probationers, and those probationers who had not completed high school were significantly more likely to be revoked for a technical revocation. Implications for practice and suggestions for future research based on these findings are discussed.

Diabetes mellitus affects 7.8% of the American population. National health statistic data and other research shows that racial/ethnic disparities exist in terms of prevalence and treatment outcomes. The present study investigated the role of patient health beliefs (i.e., locus of control, self-efficacy) and the doctor-patient relationship (e.g., satisfaction and collaboration with health care provider), as relative predictors of diabetic control (i.e., HbA1c levels) and overall satisfaction with diabetes care, in older adult participants with diabetes. Demographic, psychosocial, and diabetes-related data from the Health and Retirement Study (HRS) 2003 Diabetes Study were analyzed to compare treatment outcomes among non-Hispanic White, non-Hispanic Black, and Hispanic individuals with various types of diabetes. Non-Hispanic White individuals exhibited better diabetic control than their minority counterparts (F(2, 592) = 7.60, p < .001); however, no significant group differences were noted in terms of psychosocial factors. Diabetic control was best predicted by time since diagnosis (&#946; = -.21, p < .001), satisfaction with diabetes self-care (&#946; = .19, p < .001) and age (&#946; = .12, p < .01). In addition, satisfaction with provider care was best predicted by perceived collaboration with provider (&#946; = .44, p < .001), satisfaction with diabetes self-care (&#946; = .22, p …

In this thesis, I present my study on the impact of multi-group network structure on the performance of consensus building strategies, and the preliminary mathematical formulation of the problem on improving the performance of the National Airspace system (NAS) through long-term investment. The first part of the thesis is concerned with a structural approach to the consensus building problem in multi-group distributed sensor networks (DSNs) that can be represented by bipartite graph. Direct inference of the convergence behavior of consensus strategies from multi-group DSN structure is one of the contributions of this thesis. The insights gained from the analysis facilitate the design and development of DSNs that meet specific performance criteria. The other part of the thesis is concerned with long-term planning and development of the NAS at a network level, by formulating the planning problem as a resource allocation problem for a flow network. The network-level model viewpoint on NAS planning and development will give insight to the structure of future NAS and will allow evaluation of various paradigms for the planning problem.

The primary focus of this dissertation was to explore students' perceptions of adopting Web 2.0 applications at the School of Basic Education (SBE) in Kuwait. Although Web 2.0 applications are becoming more popular among the digital generation, there is still no evidence of students' perceptions of adopting the innovation of Web 2.0 technologies in Kuwait. The problem this study addresses is that the current status of Web 2.0 technologies usage by academic students has remained educationally unknown in Kuwait. Therefore, there was a need to investigate the extent to which academic students in SBE are aware of and their usage of Web 2.0 technologies, as well as the factors and obstacles that affect using these technologies. Rogers' diffusion of innovation theory (DoI) is employed in this study to specify the factors that influence student perceptions of adopting Web 2.0 applications as learning tools. Data used in this dissertation was gathered via a survey instrument from 350 students at the SBE and was statistically analyzed to find out the answers of the research questions. This study identified the low rate of Web 2.0 awareness and adoption by the students. Descriptive statistical analysis, such as mean scores and standard deviation, were used …

Development is a dynamic process characterized by critical periods in which organ systems are sensitive to changes in the surrounding environment. In the current study, critical windows of embryonic growth and kidney development were assessed in the embryonic chicken. All&#8208;trans retinoic acid (tRA) influences not only organogenesis and cell proliferation, but also targets metanephric kidney nephrogenesis. Embryonic chickens were given a single injection of tRA on embryonic day 8. tRA decreased embryo, kidney, and heart mass from day 16 to day 18. However, mass specific kidney and heart masses showed no differences. Whole blood, plasma, and allantoic fluid osmolality were altered in tRA treated embryos from day 16 to day 18. In addition, hematocrit, red blood cell count, and hemoglobin concentration were altered in tRA treated embryos. The results suggest that although nephrogenesis was not affected by tRA, the developing osmoregulatory system was altered in tRA treated embryos.

In recent years, organizations have invested increasing financial and labor-related resources on employee training. The assumption is that training will benefit the organization through improved performance which will result in greater efficiency, greater customer satisfaction and, ultimately, increased revenue and profits. Further, employees are assumed to benefit because their improved performance should lead to career advancement and increased compensation. However, measuring the effect of training on employee performance has been problematic due to the difficulty of isolating the effect of training from other human resource management practices and environmental and organizational influences. Hierarchical multiple regression analyses were used to test a model for predicting merit pay increase, job promotion and performance ratings from measures of general and finance training, as well as employee tenure, gender, educational level and organizational level. It was found that while significant contributions (i.e., betas) were made by finance and general training for performance ratings, promotion and merit pay increase, they did not increase the variance accounted for by tenure, organizational level and gender.

The use of a counter-balance weight system of a Smith machine affects measures of bench press throw performance. Twenty-four men performed bench press throws at 30% of their one-repetition maximum under four different conditions: 1) counter-balance and rebound movement (RC), 2) no counter-balance and rebound movement (RNC), 3) counter-balance and concentric only movement (CC), and 4) no counter-balance and concentric only movement (CNC). Peak power, force, and concentric and eccentric velocities were measured using a linear accelerometer; and peak ground reaction force (GRF) was measured using a forceplate. Peak measures for concentric and eccentric velocities showed that NCB> CB and RBT > CBT. Peak GRF measures showed CB > NCB and RBT > CBT. The lower performance measures for CB were likely due to an increase in the net external load when the barbell accelerates faster than the gravitational constant causing the counter-balance weight becomes ineffective.

Corporate diversification continues to be an important phenomenon in the modern business world. More than thirty years of research on diversification suggests that the degree of relatedness among a firm's business units is a factor that can affect firm performance, but the true effect of diversification relatedness on firm performance is still inconclusive. The purpose of this dissertation is to shed more light on this inconclusive association. However, attention is focused on the performance implications of individual diversification actions (e.g., acquisitions and joint ventures) rather than on the overall performance of firms with different levels of diversification. A non-experimental, longitudinal analysis of secondary data was conducted on over 450 unique acquisitions and on more than 210 joint ventures. Results suggest that even when individual diversification actions rather than entire business portfolios are examined, an inverted curvilinear association between diversification relatedness and performance is likely to emerge. This pattern is observed in both acquisitions and joint ventures. However, the association between diversification relatedness and performance in acquisitions is moderated by the level of industry adversity, though factors such as corporate coherence and heterogeneous experience do not moderate the association between diversification relatedness and performance. This study augments the body of knowledge …

Dream of a Thousand Keys is a concerto for piano and orchestra, which consists of four movements presenting multiple dimensional meanings as suggested by the word "key." I trace the derivation of Korean traditional rhythmic cycles and numerical sequences, such as the Fibonacci series, that are used throughout the work, and explore the significant role of space between the soloist and piano that are emphasized in a theatrical aspect of the composition. The essay addresses the question of musical contrasts, similarities, and metamorphosis. Lastly, I cover terms and concepts of significant 21st-century compositional techniques that come into play in the analysis of this work.

Homeless youth face numerous risks. Data on 602 homeless youth from the Midwest Homeless and Runaway Study and binary logistic regression were used to identify factors associated with their participation in risky sexual behaviors. Specifically, the effects of abuse/neglect and three potential moderating resiliency indicators, namely self-esteem, parental warmth, and parental monitoring, on having sex before adulthood and thinking about trading sex for food or shelter were examined. While none of the three resiliency indicators had the hypothesized moderating effects, controlling for abuse/neglect and various sociodemographic characteristics, parental monitoring had a direct, negative effect on having sex before adulthood, and self-esteem and parental warmth had direct, negative effects on thinking about trading sex for food or shelter. Policy implications of the findings are discussed.

This documentary film explores the damages produced by the illegal dumping of toxic waste in the environment and the rise in health concerns specific to the Campania region in Southern Italy. The management of waste material in the region is in the hands of the Camorra - a mafia organization with vast economic and political power. Through the narration of personal stories, the documentary reveals the broken emotional and cultural balance between the people from the region and their land.

In the last decade emerging contaminants research has intensified in a bid to answer questions about fate, transport, and effects as these chemicals as they get released into the environment. The chemicals of interest were the antimicrobials; triclocarban (TCC) and triclosan (TCS), and a metabolite of triclosan, methyl triclosan (MTCS). This research was designed to answer the question: what is the fate of these chemicals once they are released from the waste water treatment plant into receiving streams. Three different assessment methods; field monitoring, in-situ experiments, and laboratory studies were used to answer the overall question. TCS, TCC, and MTCS levels were measured in surface water, sediment and the Asiatic clam Corbicula fluminea. Field studies were conducted using four sites at Pecan Creek, Denton TX. Levels of all three chemicals in clams were up to fives orders of magnitude the water concentrations but an order of magnitude lower than in sediment. Highest sediment levels of chemicals were measured in samples from the mouth of Pecan Creek (highest organic matter). TCC was the most and TCS was the least accumulated chemicals. In-situ and lab studies both indicated that uptake of these chemicals into the clams was very rapid and measurable within …

While conventional turbines have been extensively researched and tested, Tesla and boundary layer type turbines have not. In order to construct a dynamometer, thermodynamic flow apparatus and future turbines, we modeled the Tesla turbine using theoretical calculations and preliminary experiments. Thus a series of experiments were run to determine stall torque and maximum run speed for a known pressure range. This data was then applied to modeling formulas to estimate stall torque over an extended range of variables. The data were then used to design an appropriate dynamometer and airflow experiment. The model data also served to estimate various specifications and power output of the future turbine. An Obi Laser SSTG&#8208;001 Tesla turbine was used in the experiments described. Experimental stall torque measurements were conducted in two stages. Shaft speed measurements were taken with an optical laser tachometer and Tesla turbine stall torque was measured using a spring force gauge. Two methods were chosen to model Tesla turbine stall torque: 1) flow over flat plate and 2) free vortex with a sink. A functional dynamometer and thermodynamic apparatus were constructed once the model was confirmed to be within the experimental uncertainty. Results of the experiments show that the experimental turbine …

Scholarly research has been written on the forces behind the barriers preventing Hispanic women from reaching the top of the public school ladder. These barriers are to be recognized and addressed. This study focuses not on the barriers which hinder forward and upward career movement, but instead examines how many Hispanic American women have not allowed these barriers to prevent them from achieving their goals of attaining the principalship. This study seeks to determine how Hispanic women principals came to grips with the challenges and barriers to promotion, and to success as K&#8210;12 school leaders. This qualitative research study consisted of 12 Hispanic female school principals from the Dallas/Fort Worth metropolitan area. The three districts selected were Fort Worth Independent School District, Arlington Independent School District, and Grand Prairie Independent School District. Three principals were from Grand Prairie Independent School District, two principals were from Arlington Independent School District, and seven principals were from the Fort Worth Independent School District. All of the 12 Hispanic school principals were interviewed. From the responses to each of the questions, themes became evident. The themes expressed what individual principals had done and the strategies they used to overcome the varied barriers which they …

This thesis analyzes and demonstrates the similarities and differences between some of the national symbols of France and the United States. This includes the shared and borrowed aspects of each one and the ways in which each culture is reflected through, and built around them. The flags, national anthems, and several national icons such as France's Marianne and Uncle Sam are discussed. This analysis deals with the historical contexts and cultural meanings of the symbols, showing the changes each has undertaken in form and in national and international importance. Through the study of national symbols, this thesis reveals the similarities along with the differences between the two nations, which are often perceived as being highly dissimilar and even opposing in belief systems, cultures, and histories.

The purpose of this study was to examine the leadership and school outcome effects of the Texas Principal Improvement program; which authorized the School Leadership Pilot Program under Texas Education Code 11.203. The specific research questions were: What effects did participating in the Texas Principal Excellence Program in 2009-2010 have on participants and their schools? What changes in participants' self-reported and peer-observed leader behaviors occurred between the initial assessment at the onset of the program and the final assessment once the program was completed? What changes were experienced in school's passing rate on mathematics and reading TAKS in schools having the same principal for the two years in 2008-2009 (pre-participation) and 2009-2010 (post participation). The research used TxPEP participating principals who agreed to take part in the study. Principals and a selected group of people who worked with them completed a 360-degree leadership feedback instrument addressing nine leadership competencies at the beginning and end of the program. Paired samples t-tests were used to determine if changes from pre-participation to post-participation were statistically significant. When a statistically significant difference was found, effect size and confidence intervals were calculated to place the data in context. Multiple regression and propensity score matching were …

This qualitative study addressed the experiences of African American males attending a predominantly White university as undergirded by the social integration aspects of Tinto's model of academic and social integration. The methodology was case study. Sixteen semi-structured interviews were held with currently enrolled seniors to capture the lived experiences of their reasons for attending college as well as major influences that contributed to their persistence decisions. The results revealed emerging themes of positive and negative family influence, religious beliefs, and a sense of self-efficacy as instrumental factors for the students' persistence. The level of social integration tended to differ by the age classification (traditional college-going versus non-traditional college student) and by the level of parental education. The components of the social integration model, as developed by Tinto contributed little to the sample's persistence decisions when compared to the themes presented during the interviews. Three observations emerged from the data: (1) The experiences of the non-traditional aged participants were different from the traditional aged college student experiences; (2) Although the participants experienced varying levels of social integration, for most of the 16 students, their persistence decisions were influenced more by their positive and negative relationships with family, religious beliefs, and sense …

Siblings of children who have been diagnosed with autism can play important roles in the lives of their brothers or sisters. Previous literature shows that siblings can effectively change behavior and can increase play interactions. Furthermore, the use of preferred materials may enhance social interactions between the siblings. The purpose of this study was to determine, the effects that material preferences and choices have on sibling social bids and cooperative play during a sibling training program. There were two main objectives. The first objective was to evaluate the effects of teaching with the high preference toy of the neuro-typical sibling during sibling training. The second objective was to determine if the training would produce different effects across four different toy conditions. Measures included social bids made by each of the siblings and cooperative play. Results indicate that teaching with the neuro-typical siblings' high preference toy during sibling training can be an effective method to increase social bids and cooperative play. The results of this study are discussed in the contexts of preference and choice selections, physical environments, motor skills, carry over effects, and participations based on gender.

Manuel Machado is known as one of the most innovative Spanish modernist poets of the twentieth century. Despite his recognition as a literary figure in Spain, the mimetic descriptions in Machado's poetics are interpreted as mere innovations in Spanish poetry. Those mimetic descriptions are examples of ekphrasis in Spanish literature. Ekphrasis is both a literary and representational art. The mimetic dimension in Machado's poetry is ignored or misinterpreted by the critics of his poetics. This study written in Spanish investigates the use of ekphrasis in terms of Machado's poetic style. An analysis of Manuel Machado's ekphrastic poems will determine: ekphrastic poetry is a representational art; how visual and acoustic aspects of Machado's poems create enargeia; and the manifestation of ekphrasis in Spanish verse. In using Machado's poems, this project will contribute to future explorations of ekphrasis in Spanish literature.