Although the standard model of particle physics agrees perfectly with experimental data, it is unlikely the final theory describing particles and their interactions. New phenomena has been searched in the jets and missing transverse energy topology. Such phenomena may be due to the pair production of leptoquarks decaying into a quark and a neutrino or the pair production of stops decaying into a charm and a neutralino which is assumed to be the lightest supersymmetric particle. These searches have been performed with the D0 detector at hadronic collider TeVatron with a center of mass energy of 1.96 TeV. This kind of search needs a good understanding of the jet energy calibration. The determination of the relative jet energy scale has allowed them to reduce the systematic uncertainties on the jet energy measurement when comparing the data and the simulation. Moreover a new method has been developed in order to correct simulated jets for the differences observed in the jet energy scale, the jet energy resolution and the jet reconstruction efficiency between the data and the simulation. The data analysis, performed with an integrated luminosity of 310 pb{sup -1}, has not observed any excess. This result is interpreted in terms of …

In order to better understand the fundamental components that govern catalytic activity, two-dimensional model platinum nanocatalyst arrays have been designed and fabricated. These catalysts arrays are meant to model the interplay of the metal and support important to industrial heterogeneous catalytic reactions. Photolithography and sub-lithographic techniques such as electron beam lithography, size reduction lithography and nanoimprint lithography have been employed to create these platinum nanoarrays. Both in-situ and ex-situ surface science techniques and catalytic reaction measurements were used to correlate the structural parameters of the system to catalytic activity.

Many chemical reactions utilize organometallic complexes as catalysts. These complexes find use in reactions as varied as bond activation, polymerization, and isomerization. This thesis outlines the construction of a new ultrafast laser system with an emphasis on the generation of tunable mid-infrared pulses, data collection, and data analysis.

The shrinking of IC devices has followed the Moore's Law for over three decades, which states that the density of transistors on integrated circuits will double about every two years. This great achievement is obtained via continuous advance in lithography technology. With the adoption of complicated resolution enhancement technologies, such as the phase shifting mask (PSM), the optical proximity correction (OPC), optical lithography with wavelength of 193 nm has enabled 45 nm printing by immersion method. However, this achievement comes together with the skyrocketing cost of masks, which makes the production of low volume application-specific IC (ASIC) impractical. In order to provide an economical lithography approach for low to medium volume advanced IC fabrication, a maskless ion beam lithography method, called Maskless Micro-ion-beam Reduction Lithography (MMRL), has been developed in the Lawrence Berkeley National Laboratory. The development of the prototype MMRL system has been described by Dr. Vinh Van Ngo in his Ph.D. thesis. But the resolution realized on the prototype MMRL system was far from the design expectation. In order to improve the resolution of the MMRL system, the ion optical system has been investigated. By integrating a field-free limiting aperture into the optical column, reducing the electromagnetic interference …

Sum frequency generation (SFG) surface vibrational spectroscopy was used to characterize interfaces pertinent to current surface engineering applications, such as thin film polymers and novel catalysts. An array of advanced surface science techniques like scanning probe microscopy (SPM), x-ray photoelectron spectroscopy (XPS), gas chromatography (GC) and electron microscopy were used to obtain experimental measurements complementary to SFG data elucidating polymer and catalyst surface composition, surface structure, and surface mechanical behavior. Experiments reported in this dissertation concentrate on three fundamental questions: (1) How does the interfacial molecular structure differ from that of the bulk in real world applications? (2) How do differences in chemical environment affect interface composition or conformation? (3) How do these changes correlate to properties such as mechanical or catalytic performance? The density, surface energy and bonding at a solid interface dramatically alter the polymer configuration, physics and mechanical properties such as surface glass transition, adhesion and hardness. The enhanced sensitivity of SFG at the buried interface is applied to three systems: a series of acrylates under compression, the compositions and segregation behavior of binary polymer polyolefin blends, and the changes in surface structure of a hydrogel as a function of hydration. In addition, a catalytically active thin …

This thesis presents the search for neutral Minimal Supersymmetric extension of Standard Model (MSSM) Higgs bosons decaying to tau pairs where one of the taus decays leptonically, and the other one hadronically. CDF Run II data with L{sub int} = 310 pb{sup -1} are used. There is no evidence of MSSM Higgs existence, which results in the upper limits on {sigma}(p{bar p} {yields} {phi}) x BR({phi} {yields} {tau}{tau}) in m{sub A} range between 115 and 250 GeV. These limits exclude some area in tan {beta} vs m{sub A} parameter space.

Superconducting high resolution fast-neutron calorimetric spectrometers based on {sup 6}LiF and TiB{sub 2} absorbers have been developed. These novel cryogenic spectrometers measure the temperature rise produced in exothermal (n, {alpha}) reactions with fast neutrons in {sup 6}Li and {sup 10}B-loaded materials with heat capacity C operating at temperatures T close to 0.1 K. Temperature variations on the order of 0.5 mK are measured with a Mo/Cu thin film multilayer operated in the transition region between its superconducting and its normal state. The advantage of calorimetry for high resolution spectroscopy is due to the small phonon excitation energies k{sub B}T on the order of {mu}eV that serve as signal carriers, resulting in an energy resolution {Delta}E {approx} (k{sub B}T{sup 2}C){sup 1/2}, which can be well below 10 keV. An energy resolution of 5.5 keV has been obtained with a Mo/Cu superconducting sensor and a TiB{sub 2} absorber using thermal neutrons from a {sup 252}Cf neutron source. This resolution is sufficient to observe the effect of recoil nuclei broadening in neutron spectra, which has been related to the lifetime of the first excited state in {sup 7}Li. Fast-neutron spectra obtained with a {sup 6}Li-enriched LiF absorber show an energy resolution of 16 …

Magnetic refrigeration is a promising technology that offers a potential for high energy efficiency. The giant magnetocaloric effect of the R{sub 5}(Si{sub x}, Ge{sub 1-x}){sub 4} alloys (where R=rare-earth and O {le} x {le} 1), which was discovered in 1997, make them perfect candidates for magnetic refrigeration applications. In this study the microstructures of Gd{sub 5}(Si{sub x}Ge{sub 1-x}){sub 4} alloys have been characterized using electron microscopy techniques, with the focus being on distinctive linear features first examined in 1999. These linear features have been observed in R{sub 5}(Si{sub x}, Ge{sub 1-x}){sub 4} alloys prepared from different rare-earths (Gd, Tb, Dy and Er) with different crystal structures (Gd{sub 5}Si{sub 4}-type orthorhombic, monoclinic and Gd{sub 5}Ge{sub 4}-type orthorhombic). Systematic scanning electron microscope studies revealed that these linear features are actually thin-plates, which grow along specific directions in the matrix material. The crystal structure of the thin-plates has been determined as hexagonal with lattice parameters a=b=8.53 {angstrom} and c=6.40 {angstrom} using selected area diffraction (SAD). Energy dispersive spectroscopy analysis, carried out in both scanning and transmission electron microscopes, showed that the features have a composition approximating to R{sub 5}(Si{sub x},Ge{sub 1-x}){sub 3}.phase. Orientation relationship between the matrix and the thin-plates has been calculated …

Applications augmented with adaptive capabilities are becoming common in parallel computing environments. For large-scale scientific applications, dynamic adjustments to a computationally-intensive part may lead to a large pay-off in facilitating efficient execution of the entire application while aiming at avoiding resource contention. Application-specific knowledge, often best revealed during the run-time, is required to initiate and time these adjustments. In particular, General Atomic and Molecular Electronic Structure System (GAMESS) is a program for ab initio quantum chemistry that places significant demands on the high-performance computing platforms. Certain electronic structure calculations are characterized by high consumption of a particular resource, such as CPU, main memory, or disk I/O. This may lead to resource contention among concurrent GAMESS jobs and other programs in the dynamically changing environment. Thus, it is desirable to improve GAMESS calculations by means of dynamic adaptations. In this thesis, we show how an application- or algorithm-specific knowledge may play a significant role in achieving this goal. The choice of implementation is facilitated by a module-driven middleware easily integrated with GAMESS that assesses resource consumption and invokes GAMESS adaptations to the system environment. We show that the throughput of GAMESS jobs may be improved greatly as a result of such …

Our explorations of rare-earth, transition metal intermetallics have resulted in the synthesis and characterization, and electronic structure investigation, as well as understanding the structure-bonding-property relationships. Our work has presented the following results: (1) Understanding the relationship between compositions and properties in LaFe{sub 13-x}Si{sub x} system: A detailed structural and theoretical investigation provided the understanding of the role of a third element on stabilizing the structure and controlling the transformation of cubic NaZn{sub 13}-type structures to the tetragonal derivative, as well as the relationship between the structures and properties. (2) Synthesis of new ternary rare-earth iron silicides RE{sub 2-x}Fe{sub 4}Si{sub 14-y} and proposed superstructure: This compound offers complex structural challenges such as fractional occupancies and their ordering in superstructure. (3) Electronic structure calculation of FeSi{sub 2}: This shows that the metal-semiconductor phase transition depends on the structure. The mechanism of band gap opening is described in terms of bonding and structural distortion. This result shows that the electronic structure calculations are an essential tool for understanding the relationship between structure and chemical bonding in these compounds. (4) Synthesis of new ternary rare-earth Zinc aluminides Tb{sub 3}Zn{sub 3.6}Al{sub 7.4}: Partially ordered structure of Tb{sub 3}Zn{sub 3.6}Al{sub 7.4} compound provides new insights into …

In recent years, semiconductor nanocrystal quantum dots havegarnered the spotlight as an important new class of biological labelingtool. Withoptical properties superior to conventional organicfluorophores from many aspects, such as high photostability andmultiplexing capability, quantum dots have been applied in a variety ofadvanced imaging applications. This dissertation research goes along withlarge amount of research efforts in this field, while focusing on thedesign and development of new nanoprobes from semiconductor nanocrystalsthat are aimed for useful imaging or sensing applications not possiblewith quantum dots alone. Specifically speaking, two strategies have beenapplied. In one, we have taken advantage of the increasing capability ofmanipulating the shape of semiconductor nanocrystals by developingsemiconductor quantum rods as fluorescent biological labels. In theother, we have assembled quantum dots and gold nanocrystals into discretenanostructures using DNA. The background information and synthesis,surface manipulation, property characterization and applications of thesenew nanoprobes in a few biological experiments are detailed in thedissertation.

Electroanalytical chemistry is often utilized in chemical analysis and Fundamental studies. Important advances have been made in these areas since the advent of chemically modified electrodes: the coating of an electrode with a chemical film in order to impart desirable, and ideally, predictable properties. These procedures enable the exploitation of unique reactivity patterns. This dissertation presents studies that investigate novel reaction mechanisms at self-assembled monolayers on gold. In particular, a unique electrochemical current amplification scheme is detailed that relies on a selective electrode to enable a reactivity pattern that results in regeneration of the analyte (redox recycling). This regenerating reaction can occur up to 250 times for each analyte molecule, leading to a notable enhancement in the observed current. The requirements of electrode selectivity and the resulting amplification and detection limit improvements are described with respect to the heterogeneous and homogeneous electron transfer rates that characterize the system. These studies revealed that the heterogeneous electrolysis of the analyte should ideally be electrochemically reversible, while that for the regenerating agent should be held to a low level. Moreover, the homogeneous reaction that recycles the analyte should occur at a rapid rate. The physical selectivity mechanism is also detailed with respect to …

The G0 (G-Zero) forward angle experiment completed in Hall C of the Thomas Jefferson National Accelerator Facility (TJNAF) has measured the parity violating asymmetries in elastic electron-proton scattering over a Q2 range of 0.12 < Q2 < 1.0 (GeV/c)2. A linear combination of the strange electric (GsE) and magnetic (GsM) form factors calculated from these asymmetries indicate a non-zero contribution of the strange quark to the charge and magnetization structure of the proton in the above kinematic range at a 89% confidence level. The results show a previously unmeasured Q2 dependence of the strange form factors. Combining the G0 results with previous parity violating experiments show that at Q2 = 0.1 (GeV/c)2 GsM = 0.62+-0.31 GsE = -0.013+-0.028 At intermediate Q2 of about 0.23 (GeV/c)2, a consistent value of GsM is seen compared to previous experiments, together with a measurement that may imply a negative value of GsE. For Q2 above 0.5 (GeV/c)2 a consistently positive value for the linear combination of the strange form factors is seen.

Our research focuses on taking advantage of the ability of scanning tunneling microscopy (STM) to operate at high-temperatures and high-pressures while still providing real-time atomic resolution images. We also utilize high-pressure x-ray photoelectron spectroscopy (HPXPS) to monitor systems under identical conditions thus giving us chemical information to compare and contrast with the structural and dynamic data provided by STM.

In order to understand the physical processes associated with fs-laser waveguide writing in glass, the effects of the laser repetition rate, the material composition and feature size were studied. The resulting material changes were observed by collecting Raman and fluorescence spectra with a confocal microscope. The guiding behavior of the waveguides was evaluated by measuring near field laser coupling profiles in combination with white light microscopy. Waveguides and Bragg gratings were fabricated in fused silica using pulse repetition rates from 1 kHz to 1 MHz and a wide range of scan speeds and pulse energies. Two types of fluorescence were detected in fused silica, depending on the fabrication conditions. Fluorescence from self trapped exciton (E{prime}{sub {delta}}) defects, centered at 550 nm, were dominant for conditions with low total doses, such as using a 1 kHz laser with a scan speed of 20 {micro}m/s and pulse energies less than 1 {micro}J. For higher doses a broad fluorescence band, centered at 650 nm, associated with non-bridging oxygen hole center (NBOHC) defects was observed. Far fewer NBOHC defects were formed with the 1 MHz laser than with the kHz lasers possibly due to annealing of the defects during writing. We also observed an …

This thesis presents two exclusive production processes in p{bar p} collisions at {radical}s = 1.96 TeV, using the Collider Detector Facility at Fermi National Accelerator Laboratory. An observation of exclusive e{sup +}e{sup -} production through {gamma}{gamma} {yields} e{sup +}e{sup -} is presented, as well as evidence for exclusive production of {gamma}{gamma} through gg {yields} {gamma}{gamma} (via a quark loop). The exclusive e{sup +}e{sup -} production observation is based on 16 candidate events, with a background estimate of 2.1{sub -0.3}{sup +0.7}. Each event has an e{sup +}e{sup -} pair (E{sub T} (e) &gt; 5 GeV, |{eta}(e)| &lt; 2) and nothing else observable in the CDF detector. The measured cross section is 1.6{sub -0.3}{sup +0.5}(stat) {+-} 0.3(sys) pb, while the predicted cross section is 1.711 {+-} 0.008 pb. The kinematic properties of the events are consistent with the predictions of the LPAIR Monte Carlo. The evidence for exclusive {gamma}{gamma} production consists of 3 candidate events, with a background estimate of 0.0{sub -0.0}{sup +0.2} events. Each event has two photons (E{sub T}{gamma}) &gt; 5 GeV, |{eta}({gamma})| &lt; 1 and nothing else observable in the CDF detector. The measured cross section for these events is 0.14{sub -0.04}{sup +0.14}(stat) {+-} (sys) pb. It agrees with …

The purpose of this study was to determine the effectiveness of and the subjects' overall satisfaction with the implementation of an internally created performance appraisal system. The system was implemented at a major technology consulting firm in the US. The subjects of this study were manager level employees of the firm. An employee survey conducted annually at the firm included questions relating to the implementation of the performance appraisal system. Eight years of managers' responses to six key questions in the Career Development category were analyzed. Managers' perceptions of their contribution to the firm, their understanding of what career paths are available to them, their understanding of the requirements for promotion, as well as their overall satisfaction with the implementation of the performance appraisal system were captured by this survey. Trend analysis indicates that managers at the firm perceived their career path knowledge improved and their understanding of promotion criteria improved as a result of the implementation. Overall satisfaction with the implementation did not improve enough to site confidence in managers' perceptions for the period immediately after the implementation; managers' responses to the actual implementation were disagreeable to neutral. Managers did not feel their impact on the organization improved as …

Educators can no longer simply look at student totals to distribute instructional dollars. Databased decision-making must be instituted to overcome achievement gaps between white and non-white students. In low-socioeconomic (SES) settings, districts must increase expenditure per pupil (EPP) as low-SES rates rise for all students as district administrators must be in a position to show product rather than process. It was attempted to determine if a positive or negative relationship existed between Anglo, Hispanic, and African-American student test scores and wealth factors on the Texas Assessment of Academic Skills tests in 2000 and 2002. Wealth factors studied included EPP and SES. Data analysis was carried out on 974 independent and consolidated school districts in Texas. Low-SES was found to be a negative predictor of higher test performance on standardized reading and mathematics tests. To varied degrees, low-SES affected all students from all ethnicities as well as affluent students. EPP was attributed with a positive effect on student test performance. Increases of $1,000 or more at one time produce performance increases from 0.20 to 0.40 points. In making specific recommendations, the researcher advises increasing expenditures low-SES districts, schools, and classrooms through the creation of specific district linear equations exhibited in this …

In this dissertation we study graph directed Markov systems (GDMS) and limit sets associated with these systems. Given a GDMS S, by the Hausdorff dimension spectrum of S we mean the set of all positive real numbers which are the Hausdorff dimension of the limit set generated by a subsystem of S. We say that S has full Hausdorff dimension spectrum (full HD spectrum), if the dimension spectrum is the interval [0, h], where h is the Hausdorff dimension of the limit set of S. We give necessary conditions for a finitely primitive conformal GDMS to have full HD spectrum. A GDMS is said to be regular if the Hausdorff dimension of its limit set is also the zero of the topological pressure function. We show that every number in the Hausdorff dimension spectrum is the Hausdorff dimension of a regular subsystem. In the particular case of a conformal iterated function system we show that the Hausdorff dimension spectrum is compact. We introduce several new systems: the nearest integer GDMS, the Gauss-like continued fraction system, and the Renyi-like continued fraction system. We prove that these systems have full HD spectrum. A special attention is given to the backward continued fraction …

For most of the past century, the positive outcome of grief in the West was characterized as the relinquishment of the bond to the deceased. Phrases such as "let go", "move on", and "get over it" were, and continue to be, common to the language of this pursuit. This 'breaking bonds' perspective does not take into account other means of grief resolution, nor does it consider historical or cultural findings. Consequently, reports of bereaved parents who indicate resolution of grief yet maintain a continued relationship with their deceased child were not given much attention until the 1990s. This research employed a Durkheimian approach, taking the social bond as the starting point of inquiry and examined continuing bonds of parents to their murdered children. How these bonds were related to the parents' attitudes of re-investing in life and their level of grief was measured. The relationship between the parents' level of grief and their life attitudes was also assessed. The sample consisted of 46 parents living in North Texas whose child had been murdered three or more years ago. A triangulated methodology was utilized and the data were collected by means of participant observation, unstructured interviews, and a mailed questionnaire which …

This study examines occupational aspiration and choice of traditional first-time college students utilizing longitudinal data from the Cooperative Institutional Research Program (CIRP). Focus is given to beliefs about the importance of family and money in relation to selection of an occupation that is classified as sex-typed. Change from one occupational category to another is also considered. The dissonance between students' beliefs about the importance of family and money as associated with their sex-typed occupational choice is explored. Understanding students' occupational plans that subsequently determine future prestige, wealth, and status is vital to higher educational professionals who facilitate students in their career selection and major. Therefore, environmental factors of satisfaction with career counseling and academic advising are examined. The U.S. Census Equal Employment Opportunity (EEO) data is applied in the classification of sex-typed occupations. Race and ethnicity is investigated to determine if the same gender patterns exist among cultural groups with regards to their occupational selection. The results indicate that students' occupational aspirations were influenced by their belief regarding the importance of family or money. In addition, their beliefs regarding family and money changed after four years of college with family increasing in importance. Strong beliefs that were, either concordant or …

Objective: Differences between biologic and non-biologic parents' acceptance and use of ordinary corporal punishment and use of explaining/reasoning as a disciplinary tool are examined from a sociobiological theoretical perspective. Method: Cross tabulations are used on data from a national survey conducted by the Gallup Organization in 1995. Results: Contrary to predictions, differences between biologic and non-biologic parents' acceptance of ordinary corporal punishment and the use of explaining/reasoning are not statistically significant. In addition, biologic parents are found to use ordinary corporal punishment significantly more often than non-biologic parents. Conclusions: The sociobiological theoretical perspective likely underestimates the influence of culture and social structure on parent-child interactions.

The primary objective of this thesis is to identify patterns of appearance among the flora and fauna of selected eighteenth-century New Spanish casta paintings. The objectives of the thesis are to determine what types of flora and fauna are present within selected casta paintings, whether the flora and fauna's provenance is Spanish or Mexican and whether there are any potential associations of particular flora and fauna with the races being depicted in the same composition. I focus my flora and fauna research on three sets of casta paintings produced between 1750 and 1800: Miguel Cabrera's 1763 series, José Joaquín Magón's 1770 casta paintings, and Andrés de Islas' 1774 sequence. Although the paintings fall into the same genre and within a period of a little over a decade, they nevertheless offer different visions of New Spain's natural bounty and include objects designed to satisfy Europe's interest in the exotic.

Johann Sebastian Bach's chorale preludes are varied and artistic not only in the treatment of chorale melodies, but also in the accompaniments of those chorale melodies. This study examines the accompaniments of Bach's long chorale preludes, focusing on identifying the various types and the characteristics that make them unique. This study investigates the two broad categories of accompaniments depending on whether the motives are chorale-derived or independent of the chorale. While the chorale prelude accompaniments in the first large group are closely related, the accompaniments of the chorale preludes in the second group stand independently and illustrate the vast range of Bach's compositional skill. Both groups demonstrate Bach's interest in expanding his predecessors' models, a trait that can be traced throughout all of Bach's compositional history.