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Acceleration of Amide Bond Rotation by Encapsulation in the Hydrophobic Interior of a Water-Soluble Supramolecular Assembly (open access)

Acceleration of Amide Bond Rotation by Encapsulation in the Hydrophobic Interior of a Water-Soluble Supramolecular Assembly

The hydrophobic interior cavity of a self-assembled supramolecular assembly exploits the hydrophobic effect for the encapsulation of tertiary amides. Variable temperature 1H NMR experiments reveal that the free energy barrier for rotation around the C-N amide bond is lowered by up to 3.6 kcal/mol upon encapsulation. The hydrophobic cavity of the assembly is able to stabilize the less polar transition state of the amide rotation process. Carbon-13 labeling studies showed that the {sup 13}C NMR carbonyl resonance increases with temperature for the encapsulated amides which suggests that the assembly is able to favor a twisted for of the amide.
Date: April 8, 2008
Creator: Pluth, Michael D.; Bergman, Robert G. & Raymond, Kenneth N.
Object Type: Article
System: The UNT Digital Library
The Altus Times (Altus, Okla.), Vol. 109, No. 266, Ed. 1 Tuesday, April 8, 2008 (open access)

The Altus Times (Altus, Okla.), Vol. 109, No. 266, Ed. 1 Tuesday, April 8, 2008

Daily newspaper from Altus, Oklahoma that includes local, state, and national news along with advertising.
Date: April 8, 2008
Creator: Bush, Michael
Object Type: Newspaper
System: The Gateway to Oklahoma History
Anode Sheath Switching in a Carbon Nanotube Arc Plasma (open access)

Anode Sheath Switching in a Carbon Nanotube Arc Plasma

The anode ablation rate is investigated as a function of anode diameter for a carbon nanotube arc plasma. It is found that anomalously high ablation occurs for small anode diameters. This result is explained by the formation of a positive anode sheath. The increased ablation rate due to this positive anode sheath could imply greater production rate for carbon nanotubes.
Date: April 8, 2008
Creator: Abe Fetterman, Yevgeny Raitses, and Michael Keidar
Object Type: Report
System: The UNT Digital Library
Application of RAM to Facility/Laboratory Design (open access)

Application of RAM to Facility/Laboratory Design

None
Date: April 8, 2008
Creator: Mohammadi, Kazem
Object Type: Article
System: The UNT Digital Library
The Baytown Sun (Baytown, Tex.), Vol. 88, No. 99, Ed. 1 Tuesday, April 8, 2008 (open access)

The Baytown Sun (Baytown, Tex.), Vol. 88, No. 99, Ed. 1 Tuesday, April 8, 2008

Daily newspaper from Baytown, Texas that includes local, state, and national news along with advertising.
Date: April 8, 2008
Creator: Clements, Clifford E.
Object Type: Newspaper
System: The Portal to Texas History
The Boerne Star (Boerne, Tex.), Vol. 102, No. 29, Ed. 1 Tuesday, April 8, 2008 (open access)

The Boerne Star (Boerne, Tex.), Vol. 102, No. 29, Ed. 1 Tuesday, April 8, 2008

Semiweekly newspaper from Boerne, Texas that includes local, state, and national news along with advertising.
Date: April 8, 2008
Creator: Cartwright, Brian
Object Type: Newspaper
System: The Portal to Texas History
The Committee on Foreign Investment in the United States (CFIUS) (open access)

The Committee on Foreign Investment in the United States (CFIUS)

This report contains a background introduction on the Committee on Foreign Investment (CFIUS) in the United States.
Date: April 8, 2008
Creator: Jackson, James K.
Object Type: Report
System: The UNT Digital Library
Conformal Gauge Mediation and Light Gravitino of Mass m_{3/2} < O(10) eV (open access)

Conformal Gauge Mediation and Light Gravitino of Mass m_{3/2} < O(10) eV

We discuss a class of gauge mediated supersymmetry breaking models with conformal invariance above the messenger mass scale (conformal gauge mediation). The spectrum of the supersymmetric particles including the gravitino is uniquely determined by the messenger mass. When the conformal fixed point is strongly interacting, it predicts a light gravitino of mass m{sub 3/2} &lt; O(10) eV, which is attractive since such a light gravitino causes no problem in cosmology.
Date: April 8, 2008
Creator: Ibe, M.; Nakayama, Y. & Yanagida, T. T.
Object Type: Report
System: The UNT Digital Library
Customers give DART an 'A' (open access)

Customers give DART an 'A'

News release about a customer survey that shows high levels of satisfaction with DART services.
Date: April 8, 2008
Creator: Lyons, Morgan
Object Type: Text
System: The Portal to Texas History
The Early Optical Brightening in the GRB 071010B (open access)

The Early Optical Brightening in the GRB 071010B

We report the detection of early (60-230 s) optical emission of the gamma-ray burst afterglow of GRB071010B. No significant correlation with the prompt {gamma}-ray emission was found. Our high time-resolution data combining with other measurements within 2 days after the burst indicate that GRB071010B is composed of a weak early brightening ({alpha} {approx} 0.6), probably caused by the peak frequency passing through the optical wavelengths, followed by a decay ({alpha} {approx} -0.51), attributed to continuous energy injection by patchy jets.
Date: April 8, 2008
Creator: Wang, J. H.; Schwamb, M. E.; Huang, K. Y.; Wen, C. Y.; Zhang, Z. W.; Wang, S. Y. et al.
Object Type: Article
System: The UNT Digital Library
The Economic impact of ME/CFS: Individual and societal costs (open access)

The Economic impact of ME/CFS: Individual and societal costs

This article discusses the economic impact of Myalgic Encephalopathy and Chronic Fatigue Syndrome by examining the direct and indirect costs to the individual and to society.
Date: April 8, 2008
Creator: Jason, Leonard A.; Benton, Mary C.; Valentine, Lisa M.; Johnson, Abra & Torres-Harding, Susan
Object Type: Article
System: The UNT Digital Library

Ensemble: 2008-04-08 – Flute Choir

Access: Use of this item is restricted to the UNT Community
Ensemble concert presented at the UNT College of Music Concert Hall.
Date: April 8, 2008
Creator: University of North Texas. Flute Choir.
Object Type: Sound
System: The UNT Digital Library
European Union–U.S. Trade and Investment Relations: Key Issues (open access)

European Union–U.S. Trade and Investment Relations: Key Issues

None
Date: April 8, 2008
Creator: Aheam, Raymond J.; Fischer, John W.; Goldfarb, Charles B.; Hanrahan, Charles E.; Eubanks, Walter W. & Rubin, Janice E.
Object Type: Report
System: The UNT Digital Library
The Exon-Florio National Security Test for Foreign Investment (open access)

The Exon-Florio National Security Test for Foreign Investment

This report covers the recent background of the Exon-Florio provision with special regards to issues faced in the 112th Congress. The Exon-Florio provision grants the President the authority to block proposed or pending foreign acquisitions of "persons engaged in interstate commerce in the United States" that threaten to impair the national security.
Date: April 8, 2008
Creator: Jackson, James K.
Object Type: Report
System: The UNT Digital Library
Exponential Growth, Superradiance, and Tunability of a Seeded Free Electron Laser (open access)

Exponential Growth, Superradiance, and Tunability of a Seeded Free Electron Laser

None
Date: April 8, 2008
Creator: Wu, Juhao; /SLAC; Murphy, James B.; Wang, Xijie; /Brookhaven; Wang, Kelin et al.
Object Type: Article
System: The UNT Digital Library
The Express-Star (Chickasha, Okla.), Ed. 1 Tuesday, April 8, 2008 (open access)

The Express-Star (Chickasha, Okla.), Ed. 1 Tuesday, April 8, 2008

Daily newspaper from Chickasha, Oklahoma that includes local, state, and national news along with advertising.
Date: April 8, 2008
Creator: Wilson, Chris
Object Type: Newspaper
System: The Gateway to Oklahoma History
The Federal Minimum Wage and American Samoa (open access)

The Federal Minimum Wage and American Samoa

This report discusses the federal minimum wage in American Samoa. Under the Fair Labor Standards Act (FLSA), the minimum wage for the islands is fixed by a commission established by the Secretary of Labor. The minimum wage for fish processing is currently $3.26 an hour. Were Congress to extend the general (federal) minimum wage to American Samoa (and raise it to $7.25 an hour, as is currently proposed), the fish processing industry might absorb the increase, change the way it processes tuna, or migrate to other low-wage countries.
Date: April 8, 2008
Creator: Whittaker, William G.
Object Type: Report
System: The UNT Digital Library
Former NFL Players: Disabilities, Benefits, and Related Issues (open access)

Former NFL Players: Disabilities, Benefits, and Related Issues

This report discusses professional football players' injuries and health conditions that might have long-term consequences for their health.
Date: April 8, 2008
Creator: Halchin, L. Elaine
Object Type: Report
System: The UNT Digital Library
Greensheet (Houston, Tex.), Vol. 39, No. 109, Ed. 1 Tuesday, April 8, 2008 (open access)

Greensheet (Houston, Tex.), Vol. 39, No. 109, Ed. 1 Tuesday, April 8, 2008

Free weekly newspaper that includes business and classified advertising.
Date: April 8, 2008
Creator: unknown
Object Type: Newspaper
System: The Portal to Texas History
Greensheet (Houston, Tex.), Vol. 39, No. 110, Ed. 1 Tuesday, April 8, 2008 (open access)

Greensheet (Houston, Tex.), Vol. 39, No. 110, Ed. 1 Tuesday, April 8, 2008

Free weekly newspaper that includes business and classified advertising.
Date: April 8, 2008
Creator: unknown
Object Type: Newspaper
System: The Portal to Texas History
HAZARD ANALYSIS SOFTWARE (open access)

HAZARD ANALYSIS SOFTWARE

Washington Safety Management Solutions, LLC developed web-based software to improve the efficiency and consistency of hazard identification and analysis, control selection and classification, and to standardize analysis reporting at Savannah River Site. In the new nuclear age, information technology provides methods to improve the efficiency of the documented safety analysis development process which includes hazard analysis activities. This software provides a web interface that interacts with a relational database to support analysis, record data, and to ensure reporting consistency. A team of subject matter experts participated in a series of meetings to review the associated processes and procedures for requirements and standard practices. Through these meetings, a set of software requirements were developed and compiled into a requirements traceability matrix from which software could be developed. The software was tested to ensure compliance with the requirements. Training was provided to the hazard analysis leads. Hazard analysis teams using the software have verified its operability. The software has been classified as NQA-1, Level D, as it supports the analysis team but does not perform the analysis. The software can be transported to other sites with alternate risk schemes. The software is being used to support the development of 14 hazard analyses. …
Date: April 8, 2008
Creator: Sommer, S & Tinh Tran, T
Object Type: Article
System: The UNT Digital Library
Iraq: Reconciliation and Benchmarks (open access)

Iraq: Reconciliation and Benchmarks

None
Date: April 8, 2008
Creator: unknown
Object Type: Report
System: The UNT Digital Library
Liability of Interactive Computer Service for Violating the Fair Housing Act (open access)

Liability of Interactive Computer Service for Violating the Fair Housing Act

None
Date: April 8, 2008
Creator: Cohen, Henry
Object Type: Report
System: The UNT Digital Library
Mine Safety: Additional Guidance and Oversight of Mines' Emergency Response Plans Would Improve the Safety of Underground Coal Miners (open access)

Mine Safety: Additional Guidance and Oversight of Mines' Emergency Response Plans Would Improve the Safety of Underground Coal Miners

A letter report issued by the Government Accountability Office with an abstract that begins "In 2006, several mining tragedies led the Congress to pass the Mine Improvement and New Emergency Response Act of 2006 (MINER Act). The law required underground coal mine operators to develop emergency response plans that contain several components designed to improve accident preparedness and response, including providing a refuge of air to miners trapped underground after an accident and wireless communications systems. The Mine Safety and Health Administration (MSHA) is responsible for approving the plans and ensuring their implementation. GAO examined (1) the effectiveness of the approval process, (2) the status of implementation of the plans, and (3) MSHA's efforts to enforce and oversee implementation. To address these questions, GAO reviewed a nonprobability sample of emergency response plans, analyzed MSHA data, and interviewed MSHA officials and members of the mining community."
Date: April 8, 2008
Creator: United States. Government Accountability Office.
Object Type: Report
System: The UNT Digital Library