The radiolytic decomposition of tributyl phosphate has been show by burr to product gases, acids, and polymers. the acids that are formed can limit the usefulness of tributyl phosphate for the processing of radioactive materials. The study of acid formation on radiolysis therefor becomes important to us for the understanding of the mechanism of acid formation, the influence of added materials and the effect of the structure of organo- phosphorous compounds. Samples of purified esters have been irradiated in the ORNL cobalt source. Conclusions: (1) The formation of acid from tributyl phosphate during irradiation with cobalt gamma rays involves a mechanism that is not a primary step. Evidence has been obtained for a secondary reaction that is minimized by the presence of certain compounds. (2) Toluene acting as an inhibitor for radiolytic formation of acid may indicate the usefulness of an aromatic hydrocarbon diluent in processing. (3) The aromatic hydrocarbon, when phenyl, was not effective when it was part of the molecule. (4) First tests revealed that dibutyl butyl-phosphonate produced less acid the TBP and may warrant further consideration for process application.

For Co60 source at 15 meters, the air-scattered gamma dose rate predicted by theory is excerpted from ORNL-1575, pp. 167-203. This is compared with experimental measurements for the same source and comparable geometry reported by Convair in CVAC-170T. After applying an appropriate correction for ground scattering as estimated in Mart-55-16T (Convair), the two results are found to be in substantial agreement.

Report summarizing ongoing nuclear work performed by the ORNL for the United States Army.

From the questions which have been asked, I gather that I am expected to bring you the news of the latest exciting developments in desalination at the Oak Ridge National Laboratory. However, the agenda for this meeting does not include reports of unfinished investigations; moreover, although there are some new ideas afoot at Oak Ridge, they are aimed toward the very large stations which are somewhat beyond the scope of the more current interests represented here. So instead of presenting new developments, I would like today to talk about where to look for them--to give you some purely analytical considerations that assess the incentives we have to seed certain improvements in this or that portion of the equipment in a dual-purpose station.

Much of the shielding work carried out with the Bulk Shielding Reactor (BSR) has yielded data of particular interest for the design of swimming pool type reactors, However, it is often difficult for a reactor designer to locate such data since it may be recorded in a report primarily concerned with shielding problems. Therefore, this memorandum presents a bibliography of reports from the Bulk Shielding Facility arranged according to the application of data to the various aspects of reactor design.

Progress report of the Oak Ridge National Laboratory Biology Division providing updates on various projects, experiments, and other work. This report includes a summary of scholarly output from the division and departmental activities in cytology and genetics, mammalian genetics and development, microbial protection and recovery, mammalian recovery, pathology and physiology, general physiology, biochemistry, enzymology and photosynthesis, microbiology, plant biochemistry, and biophysics.

Semiannual Progress report of the Oak Ridge National Laboratory Chemistry Division providing updates on various projects, experiments, and other work in inorganic and physical chemistry, nuclear chemistry, organic chemistry, chemical physics, chemistry of separation processes, radiation chemistry, and reactor chemistry.

A qualitative theory for cake formation in ThO2 slurries is presented. The sphere formation which occurs in "Standard" slurry can be explained on the same basis. The irregular and unpredictable yield strength is easily fitted into the theory. On the basis of this theory, the writer has been led to the conclusion that only colloidally stable slurries, or slurries with crystallites or comminution-resistant particles which are large enough to overcome colloidal effects (probably larger than 0.1u) can be used with assurance in the ThO2 reactor system. This conclusion holds for 300 gm/kg slurries as well as for more concentrated mixtures.

Data are presented for all toroid runs which circulated aqueous thorium oxide slurries between Aug, 1054, and October, 1956. In addition, a tabulation of the properties of numerous thoria preparations is presented.

From abstract: "This report presents the progress in the laboratory development of a continuous solvent recovery process for the tributyl phosphate-diluent mixture used in the Purex Process. Investigations were made with 1/2" diameter pulse columns, using a nine foot sodium carbonate contacting column and a four foot water wash column."

This bibliography represents the first cumulative edit of the literature examined by the Radiation Shielding Information Center recently established at the Oak Ridge National Laboratory. Its two major sections consist of a list of documents by subject category and of an author index. The document list covers nine major subjects with a total of 118 categories; however, literature specimens have not yet been entered for all categories. If a document applies to more than one category, it is listed under each. The author index includes cross references to the categories under which each author's publications appear. Preceding the bibliography is a list of the subject categories, their corresponding category numbers and the pages on which they appear in the bibliography,

A general program has been written to plot curves on the Oracle curve plotter. A description of the code and complete instructions for preparation of input tapes and operation of the code are given. The code tape is available from the Mathematics Panel or from the author.

Resolution of the products of the reactions of DPN and ATP with ultraviolet light by techniques of partition paper chromatography is reported in this paper.

In analyzing stresses, deflections, and forces in piping and certain structural systems, it is useful to have a set of equations giving the deflections at any point of a curved beam in terms of the various loads acting on the beam. This technical report presents the deflection equations for a curved circular-arc beam of variable length. The cases treated include in-plane and out-of-plane bending due to forces and moments applied to the end of the beam in three principal directions, and uniformly distributed loads applied along the beam in these three directions. Deflections were calculated by the strain energy method using Castigliano's theorem.

Two revised Excer process flowsheets are presented for the production of UF4 from urnayl nitrate solution. In both, the uranium is sorbed on a cation-exchange resin and eluted with aqueous HF. In one, the resulting UO2F2 in dilute HF is mixed with dilute sulfuric or hydrochloric acid and electrolytically reduced in a cation-exchange-membrane cell, and the precipitated UF4·0.75H2O is dried and dehydrated to anhydrous UF4. A cost of 20¢ per pound of reduced uranium is estimated. In the other, ammonium fluoride is also added to the uranyl fluoride solution before the electrolytic reduction step, and the precipitate is UF4·04NH4F. A flowsheet for preparing UF4 from raw ore is also shown. The uranium is sorbed on an anion-exchange resin from a sulfuric acid leach liquor and eluted with dilute HCl. Ammonium fluoride and HF are added to the UO2Cl2-HCl solution before the uranyl ion is electrolytically reduced to precipitate UF4·0.4NH4F. Decontamination factors as high as 45 and 9 for gross beta and gamma activities and of 10 to 5000 for light metal impurities were obtained in the electrolytic reduction step.

The Aircraft Reactor Experiment (ARE)was successfully concluded in November of 1954, and a detailed report of the operation was published the following year. At that time it was thought that an extensive examination of the reactor and system components after disassembly was warranted. It was realized, of course, that the level of radioactivity of the components would necessitate extensive delays in the examinations. Since examination of a few critical ARE samples showed nothing unexpected, much of the planned hot-cell inspection was postponed and complete examination of all but a few specimens was indefinitely suspended. The few examinations that were completed are described in this report, along with a description of the disassembly of the ARE system. Diagrams of the fuel system, sodium system, and off-gas system are presented in Figs. 1, 2, and 3 for reference use in visualizing the disassembly process.

Report describing a set of high-precision routines for the IBM 7090 that perform efficiently the calculations most often required on axially symmetric magnetic systems. The routines compute the vector potential, field components, and the mixed gradient for current systems and for certain idealized distributions of magnetized matter. The programs for the current systems were developed from a set of six equations in elliptic integrals, which suffice when correlations are fully exploited for all the relevant properties of loops and solenoids.

Experimental work concerned with the development of an inexpensive composite fuel plate with a high burnup potential for application in a 500°C sodium environment as Core B of the Enrico Fermi Fast Breeder Reactor.

Quarterly report discussing progress on the Fast Ceramic Reactor Development Program, "an integrated analytical and experimental program directed toward the development of fast reactors employing ceramic fuels, with particular attention to mixed plutonium-uranium oxide" (p. 1).

Quarterly progress report discussing activities related to the Vallecitos Boiling Water Reactor (VBWR) and related facilities.

Report documenting ongoing research and developments at the Oak Ridge National Laboratory's Gas-Cooled Reactor Project.

Report issued by the Oak Ridge National Laboratory discussing quarterly progress of the Homogeneous Reactor Project. Progress of operations, design, development, and analysis is presented. This report includes tables, illustrations, and photographs.

Report documenting the ongoing research and developments of the Oak Ridge National Laboratory's Homogeneous Reactor Project.

From Summary: "The major objective of the run was the investigation of fuel stability. The reactor operated for long periods at the design power of 5 Mw with none of the usual indications of instability while the system pressure was kept at 1250 psig. Run 21 ended on January 22, so that the reason for an abrupt change in the mixing rate of fuel between the core and blanket could be investigated and a reactor steam-system valve could be repaired."