Atomic Resolution Imaging with a sub-50 pm Electron Probe (open access)

Atomic Resolution Imaging with a sub-50 pm Electron Probe

Using a highly coherent focused electron probe in a 5th order aberration-corrected transmission electron microscope, we report on resolving a crystal spacing less than 50 pm. Based on the geometrical source size and residual coherent and incoherent axial lens aberrations, an electron probe is calculated, which is theoretically capable of resolving an ideal 47 pm spacing with 29percent contrast. Our experimental data show the 47 pm spacing of a Ge 114 crystal imaged with 11-18percent contrast at a 60-95percent confidence level, providing the first direct evidence for sub 50-pm resolution in ADF STEM imaging.
Date: March 2, 2009
Creator: Erni, Rolf P.; Rossell, Marta D.; Kisielowski, Christian & Dahmen, Ulrich
System: The UNT Digital Library
Cross-language search: The case of Google Language Tools (open access)

Cross-language search: The case of Google Language Tools

Article on cross-language searching and a case study of Google Language Tools, especially its cross-language search service.
Date: March 2, 2009
Creator: Chen, Jiangping & Bao, Yu
System: The UNT Digital Library
High-frequency surface acoustic wave propagation in nanaostructures characterized by coherent extreme ultraviolet beams (open access)

High-frequency surface acoustic wave propagation in nanaostructures characterized by coherent extreme ultraviolet beams

We study ultrahigh frequency surface acoustic wave propagation in nickel-on-sapphire nanostructures. The use of ultrafast, coherent, extreme ultraviolet beams allows us to extend optical measurements of propagation dynamics of surface acoustic waves to frequencies of nearly 50 GHz, corresponding to wavelengths as short as 125 nm. We repeat the measurement on a sequence of nanostructured samples to observe surface acoustic wave dispersion in a nanostructure series for the first time. These measurements are critical for accurate characterization of thin films using this technique.
Date: March 2, 2009
Creator: Siemens, M.; Li, Q.; Murnane, M.; Kapteyn, H.; Yang, R.; Anderson, E. et al.
System: The UNT Digital Library
HYDROGEN TECHNOLOGY RESEARCH AT THE SAVANNAH RIVER NATIONAL LABORATORY (open access)

HYDROGEN TECHNOLOGY RESEARCH AT THE SAVANNAH RIVER NATIONAL LABORATORY

The Savannah River National Laboratory (SRNL) is a U.S. Department of Energy research and development laboratory located at the Savannah River Site (SRS) near Aiken, South Carolina. SRNL has over 50 years of experience in developing and applying hydrogen technology, both through its national defense activities as well as through its recent activities with the DOE Hydrogen Programs. The hydrogen technical staff at SRNL comprises over 90 scientists, engineers and technologists, and it is believed to be the largest such staff in the U.S. SRNL has ongoing R&D initiatives in a variety of hydrogen storage areas, including metal hydrides, complex hydrides, chemical hydrides and carbon nanotubes. SRNL has over 25 years of experience in metal hydrides and solid-state hydrogen storage research, development and demonstration. As part of its defense mission at SRS, SRNL developed, designed, demonstrated and provides ongoing technical support for the largest hydrogen processing facility in the world based on the integrated use of metal hydrides for hydrogen storage, separation, and compression. The SRNL has been active in teaming with academic and industrial partners to advance hydrogen technology. A primary focus of SRNL's R&D has been hydrogen storage using metal and complex hydrides. SRNL and its Hydrogen Technology …
Date: March 2, 2009
Creator: Danko, E
System: The UNT Digital Library
The IceCube data acquisition system: Signal capture, digitization,and timestamping (open access)

The IceCube data acquisition system: Signal capture, digitization,and timestamping

IceCube is a km-scale neutrino observatory under construction at the South Pole with sensors both in the deep ice (InIce) and on the surface (IceTop). The sensors, called Digital Optical Modules (DOMs), detect, digitize and timestamp the signals from optical Cherenkov-radiation photons. The DOM Main Board (MB) data acquisition subsystem is connected to the central DAQ in the IceCube Laboratory (ICL) by a single twisted copper wire-pair and transmits packetized data on demand. Time calibration ismaintained throughout the array by regular transmission to the DOMs of precisely timed analog signals, synchronized to a central GPS-disciplined clock. The design goals and consequent features, functional capabilities, and initial performance of the DOM MB, and the operation of a combined array of DOMs as a system, are described here. Experience with the first InIce strings and the IceTop stations indicates that the system design and performance goals have been achieved.
Date: March 2, 2009
Creator: Collaboration, The IceCube & Matis, Howard
System: The UNT Digital Library
Measurement of quasi-ballistic heat transport across nanoscale interfaces using ultrafast coherent soft x-ray beams (open access)

Measurement of quasi-ballistic heat transport across nanoscale interfaces using ultrafast coherent soft x-ray beams

Understanding heat transport on nanoscale dimensions is important for fundamental advances in nanoscience, as well as for practical applications such as thermal management in nano-electronics, thermoelectric devices, photovoltaics, nanomanufacturing, as well as nanoparticle thermal therapy. Here we report the first time-resolved measurements of heat transport across nanostructured interfaces. We observe the transition from a diffusive to a ballistic thermal transport regime, with a corresponding increase in the interface resistivity for line widths smaller than the phonon mean free path in the substrate. Resistivities more than three times higher than the bulk value are measured for the smallest line widths of 65 nm. Our findings are relevant to the modeling and design of heat transport in nanoscale engineered systems, including nanoelectronics, photovoltaics and thermoelectric devices.
Date: March 2, 2009
Creator: Siemens, M.; Li, Q.; Yang, R.; Nelson, K.; Anderson, E.; Murnane, M. et al.
System: The UNT Digital Library
Observation of Two-source Interference in the Photoproduction Reaction AuAu --> AuAu rho 0 (open access)

Observation of Two-source Interference in the Photoproduction Reaction AuAu --> AuAu rho 0

In ultra-peripheral relativistic heavy-ion collisions, a photon from the electromagnetic field of one nucleus can fluctuate to a quark-antiquark pair and scatter from the other nucleus, emerging as a {rho}{sup 0}. The {rho}{sup 0} production occurs in two well-separated (median impact parameters of 20 and 40 fermi for the cases considered here) nuclei, so the system forms a 2-source interferometer. At low transverse momenta, the two amplitudes interfere destructively, suppressing {rho}{sup 0} production. Since the {rho}{sup 0} decays before the production amplitudes from the two sources can overlap, the two-pion system can only be described with an entangled non-local wave function, and is thus an example of the Einstein-Podolsky-Rosen paradox. We observe this suppression in 200 GeV per nucleon-pair gold-gold collisions. The interference is 87% {+-} 5%(stat.) {+-} 8% (syst.) of the expected level. This translates into a limit on decoherence due to wave function collapse or other factors, of 23% at the 90% confidence level.
Date: March 2, 2009
Creator: STAR Collaboration
System: The UNT Digital Library
Particle-In-Cell/Monte Carlo Simulation of Ion Back Bombardment in Photoinjectors (open access)

Particle-In-Cell/Monte Carlo Simulation of Ion Back Bombardment in Photoinjectors

In this paper, we report on studies of ion back bombardment in high average current dc and rf photoinjectors using a particle-in-cell/Monte Carlo method. Using H{sub 2} ion as an example, we observed that the ion density and energy deposition on the photocathode in rf guns are order of magnitude lower than that in a dc gun. A higher rf frequency helps mitigate the ion back bombardment of the cathode in rf guns.
Date: March 2, 2009
Creator: Qiang, Ji; Corlett, John & Staples, John
System: The UNT Digital Library
Sub-10 nm Platinum Nanocrystals with Size and Shape Control: Catalytic Study for Ethylene and Pyrrole Hydrogenation (open access)

Sub-10 nm Platinum Nanocrystals with Size and Shape Control: Catalytic Study for Ethylene and Pyrrole Hydrogenation

Platinum nanocubes and nanopolyhedra with tunable size from 5 to 9 nm were synthesized by controlling the reducing rate of metal precursor ions in a one-pot polyol synthesis. A two-stage process is proposed for the simultaneous control of size and shape. In the first stage, the oxidation state of the metal ion precursors determined the nucleation rate and consequently the number of nuclei. The reaction temperature controlled the shape in the second stage by regulation of the growth kinetics. These well-defined nanocrystals were loaded into MCF-17 mesoporous silica for examination of catalytic properties. Pt loadings and dispersions of the supported catalysts were determined by elemental analysis (ICP-MS) and H2 chemisorption isotherms, respectively. Ethylene hydrogenation rates over the Pt nanocrystals were independent of both size and shape and comparable to Pt single crystals. For pyrrole hydrogenation, the nanocubes enhanced ring-opening ability and thus showed a higher selectivity to n-butylamine as compared to nanopolyhedra.
Date: March 2, 2009
Creator: Tsung, Chia-Kuang; Kuhn, John N.; Huang, Wenyu; Aliaga, Cesar; Hung, Ling-I; Somorjai, Gabor A. et al.
System: The UNT Digital Library
X-ray Emission Spectroscopy to Study Ligand Valence Orbitals in Mn Coordination Complexes (open access)

X-ray Emission Spectroscopy to Study Ligand Valence Orbitals in Mn Coordination Complexes

We discuss a spectroscopic method to determine the character of chemical bonding and for the identification of metal ligands in coordination and bioinorganic chemistry. It is based on the analysis of satellite lines in X-ray emission spectra that arise from transitions between valence orbitals and the metal ion 1s level (valence-to-core XES). The spectra, in connection with calculations based on density functional theory (DFT), provide information that is complementary to other spectroscopic techniques, in particular X-ray absorption (XANES and EXAFS). The spectral shape is sensitive to protonation of ligands and allows ligands, which differ only slightly in atomic number (e.g., C, N, O...), to be distinguished. A theoretical discussion of the main spectral features is presented in terms of molecular orbitals for a series of Mn model systems: [Mn(H2O)6]2+, [Mn(H2O)5OH]+, [Mn(H2O)5NH2]+, and [Mn(H2O)5NH3]2+. An application of the method, with comparison between theory and experiment, is presented for the solvated Mn2+ ion in water and three Mn coordination complexes, namely [LMn(acac)N3]BPh4, [LMn(B2O3Ph2)(ClO4)], and [LMn(acac)N]BPh4, where L represents 1,4,7-trimethyl-1,4,7-triazacyclononane, acac stands for the 2,4-pentanedionate anion, and B2O3Ph2 represents the 1,3-diphenyl-1,3-dibora-2-oxapropane-1,3-diolato dianion.
Date: March 2, 2009
Creator: Smolentsev, Grigory; Soldatov, Alexander V; Messinger, Johannes; Merz, Kathrin; Weyhermuller, Thomas; Bergmann, Uwe et al.
System: The UNT Digital Library
Aerosols and clouds in chemical transport models and climate models. (open access)

Aerosols and clouds in chemical transport models and climate models.

Clouds exert major influences on both shortwave and longwave radiation as well as on the hydrological cycle. Accurate representation of clouds in climate models is a major unsolved problem because of high sensitivity of radiation and hydrology to cloud properties and processes, incomplete understanding of these processes, and the wide range of length scales over which these processes occur. Small changes in the amount, altitude, physical thickness, and/or microphysical properties of clouds due to human influences can exert changes in Earth's radiation budget that are comparable to the radiative forcing by anthropogenic greenhouse gases, thus either partly offsetting or enhancing the warming due to these gases. Because clouds form on aerosol particles, changes in the amount and/or composition of aerosols affect clouds in a variety of ways. The forcing of the radiation balance due to aerosol-cloud interactions (indirect aerosol effect) has large uncertainties because a variety of important processes are not well understood precluding their accurate representation in models.
Date: March 2, 2008
Creator: Lohmann,U. & Schwartz, S. E.
System: The UNT Digital Library
A Multigroup diffusion Solver Using Pseudo Transient Continuation for a Radiaiton-Hydrodynamic Code with Patch-Based AMR (open access)

A Multigroup diffusion Solver Using Pseudo Transient Continuation for a Radiaiton-Hydrodynamic Code with Patch-Based AMR

We present a scheme to solve the nonlinear multigroup radiation diffusion (MGD) equations. The method is incorporated into a massively parallel, multidimensional, Eulerian radiation-hydrodynamic code with adaptive mesh refinement (AMR). The patch-based AMR algorithm refines in both space and time creating a hierarchy of levels, coarsest to finest. The physics modules are time-advanced using operator splitting. On each level, separate 'level-solve' packages advance the modules. Our multigroup level-solve adapts an implicit procedure which leads to a two-step iterative scheme that alternates between elliptic solves for each group with intra-cell group coupling. For robustness, we introduce pseudo transient continuation ({Psi}tc). We analyze the magnitude of the {Psi}tc parameter to ensure positivity of the resulting linear system, diagonal dominance and convergence of the two-step scheme. For AMR, a level defines a subdomain for refinement. For diffusive processes such as MGD, the refined level uses Dirichet boundary data at the coarse-fine interface and the data is derived from the coarse level solution. After advancing on the fine level, an additional procedure, the sync-solve (SS), is required in order to enforce conservation. The MGD SS reduces to an elliptic solve on a combined grid for a system of G equations, where G is the …
Date: March 2, 2007
Creator: Shestakov, A I & Offner, S R
System: The UNT Digital Library
Distinguishing between Dirac and Majorana neutrinos withtwo-particle interferometry (open access)

Distinguishing between Dirac and Majorana neutrinos withtwo-particle interferometry

Two-particle interferometry, a second-order interferenceeffect, is explored as another possible tool to distinguish betweenmassive Dirac and Majorana neutrinos. A simple theoretical framework isdiscussed in the context of several gedanken experiments. The method canin principle provide both the mass scale and the quantum nature of theneutrino for a certain class of incoherent left-handed sourcecurrents.
Date: March 2, 2006
Creator: Gutierrez, Thomas D.
System: The UNT Digital Library
Rolling through a busy weekend: Plenty of places to wear hipster jewelry in Austin (open access)

Rolling through a busy weekend: Plenty of places to wear hipster jewelry in Austin

Article about roller derby, jewelry brands, hipster bars, and events around Austin, Texas.
Date: March 2, 2006
Creator: Scheidnes, Jean
System: The UNT Digital Library
The Structure of 12N using 11C + p resonance scattering (open access)

The Structure of 12N using 11C + p resonance scattering

The level structure of {sup 12}N has been investigated from 2.2 to 11.0 MeV in excitation energy using a {sup 11}C + p resonance interaction with thick targets and inverse kinematics. Excitation functions were fitted using an R-matrix approach. Sixteen levels in {sup 12}N were included in the analysis, several of them are new. Spin-parity assignments, excitation energies and widths are proposed for these levels. To fit the high energy part of the excitation function, imaginary phase shifts had to be added to the phase shifts generated by the hard sphere scattering.
Date: March 2, 2006
Creator: Perajarvi, K.; Chang, Bo Fu; Rogachev, G. V.; Chubarian, G.; Goldberg, V. Z.; Guo, Q. et al.
System: The UNT Digital Library
Type B Package Radioactive Material Contents Compliance (open access)

Type B Package Radioactive Material Contents Compliance

None
Date: March 2, 2006
Creator: Hensel, Steve J.; Watkins, R. W. & Smith, A. C.
System: The UNT Digital Library
An Analytical Solution for Slug-Tracer Tests in FracturedReservoirs (open access)

An Analytical Solution for Slug-Tracer Tests in FracturedReservoirs

The transport of chemicals or heat in fractured reservoirs is strongly affected by the fracture-matrix interfacial area. In a vapor-dominated geothermal reservoir, this area can be estimated by inert gas tracer tests, where gas diffusion between the fracture and matrix causes the tracer breakthrough curve (BTC) to have a long tail determined by the interfacial area. For water-saturated conditions, recent studies suggest that sorbing solute tracers can also generate strong tails in BTCs that may allow a determination of the fracture-matrix interfacial area. To theoretically explore such a useful phenomenon, this paper develops an analytical solution for BTCs in slug-tracer tests in a water-saturated fractured reservoir. The solution shows that increased sorption should have the same effect on BTCs as an increase of the diffusion coefficient. The solution is useful for understanding transport mechanisms, verifying numerical codes, and for identifying appropriate chemicals as tracers for the characterization of fractured reservoirs.
Date: March 2, 2005
Creator: Shan, Chao & Pruess, Karsten
System: The UNT Digital Library
Chemical Weapons Nonproliferation: Confronting New Technological Challenges (open access)

Chemical Weapons Nonproliferation: Confronting New Technological Challenges

None
Date: March 2, 2005
Creator: Nguyen, T
System: The UNT Digital Library
Design and performance evaluation of a coarse/fine precision motion control system (open access)

Design and performance evaluation of a coarse/fine precision motion control system

This abstract presents current collaborative work on the development of a stage system for accurate nanometer level positioning for scanning specimens spanning an area of 50 mm x 50 mm. The completed system employs a coarse/fine approach which comprises a short-range, six degree-of-freedom fine-motion platform (5 microns 200 micro-radians) carried by a long-range, two-axis X-Y coarse positioning system. Relative motion of the stage to a fixed metrology frame will be measured using a heterodyne laser in an eight-pass interferometer configuration. The final stage system will be housed in a vacuum environment and operated in a temperature-controlled laboratory. Results from a simple single coarse/fine axis system will be the design basis for the final multi-axis system. It is expected that initial stage performance evaluation will be presented at the conference.
Date: March 2, 2005
Creator: Yang, H.; Buice, E. S.; Smith, S. T.; Hocken, R. J.; Fagan, T. J.; Trumper, D. L. et al.
System: The UNT Digital Library
An Evaluation of the Difference Formulation for Photon Transport in a Two Level System (open access)

An Evaluation of the Difference Formulation for Photon Transport in a Two Level System

In this paper we extend the difference formulation for radiation transport to the case of a single atomic line. We examine the accuracy, performance and stability of the difference formulation within the framework of the Symbolic Implicit Monte Carlo method. The difference formulation, introduced for thermal radiation by some of the authors, has the unique property that the transport equation is written in terms that become small for thick systems. We find that the difference formulation has a significant advantage over the standard formulation for a thick system. The correct treatment of the line profile, however, requires that the difference formulation in the core of the line be mixed with the standard formulation in the wings, and this may limit the advantage of the method. We bypass this problem by using the gray approximation. We develop three Monte Carlo solution methods based on different degrees of implicitness for the treatment of the source terms, and we find only conditional stability unless the source terms are treated fully implicitly.
Date: March 2, 2005
Creator: Daffin, F C; McKinley, M S; Brooks, E D & Szoke, A
System: The UNT Digital Library
Simulation of Drift-Compression for Heavy-Ion Fusion (open access)

Simulation of Drift-Compression for Heavy-Ion Fusion

None
Date: March 2, 2005
Creator: Sharp, W. M.; Barnard, J. J.; Grote, D. P.; Celata, C. M. & Yu, S. S.
System: The UNT Digital Library
Characterization of Environmental Stability of Pulsed Laser Deposited Oxide Ceramic Coatings (open access)

Characterization of Environmental Stability of Pulsed Laser Deposited Oxide Ceramic Coatings

A systematic investigation of candidate hydrogen permeation materials applied to a substrate using Pulsed Laser Deposition has been performed. The investigation focused on application of leading permeation-resistant materials types (oxide, carbides, and metals) on a stainless steel substrate. and evaluation of the stability of the applied coatings. Type 304L stainless steel substrates were coated with aluminum oxide, chromium oxide, and aluminum. Characterization of the coating-substrate system adhesion was performed using scratch adhesion testing and microindentation. Coating stability and environmental susceptibility were evaluated for two conditions-air at 350 degrees Celsius and Ar-H2 at 350 degrees Celsius for up to 100 hours. Results from this study have shown the pulsed laser deposition process to be an extremely versatile technology that is capable of producing a sound coating/substrate system for a wide variety of coating materials.
Date: March 2, 2004
Creator: Adams, Thad M.
System: The UNT Digital Library
Chemical Kinetic Modeling of HMX and TATB Laser Ignition Tests (open access)

Chemical Kinetic Modeling of HMX and TATB Laser Ignition Tests

Recent laser ignition experiments on octahydro-1,3,5,7-tetranitro-1,3,5,7-terrazocine (HMX) and 1,3,5-triamino-2,4,6-trinitrobenzene (TATB) subjected to laser fluxes ranging from 10 to 800 W/cm{sup 2} produced ignition times from seconds to milliseconds. Global chemical kinetic thermal decomposition models for HMX and TATB have been developed to calculate times to thermal explosion for experiments in the seconds to days time frame. These models are applied to the laser ignition experimental data in this paper. Excellent agreement was obtained for TATB, while the calculated ignition times were longer than experiment for HMX at lower laser fluxes. At the temperatures produced in the laser experiments, HMX melts. Melting generally increases condensed phase reaction rates so faster rates were used for three of the HMX reaction rates. This improved agreement with experiments at the lower laser fluxes but yielded very fast ignition at high fluxes. The calculated times to ignition are in reasonable agreement with the laser ignition experiments, and this justifies the use of these models for estimating reaction times at impact and shock ''hot spot'' temperatures.
Date: March 2, 2004
Creator: Tarver, C M
System: The UNT Digital Library
Even parity theta-pentaquark and stable strange nuclear matter (open access)

Even parity theta-pentaquark and stable strange nuclear matter

The newly discovered exotic {Theta} baryon of mass 1540 MeV (and very small width) truly has a very low mass, if it is a pentaquark system of even parity. A schematic model in which the coherent interaction of u{bar s} and d{bar s} pairs leads to a very large residual (non-confining) attractive interaction is introduced. This collective vibrational model accounts for the mass and small decay width to the KN channel, but yields a significant coupling to the virtual K*N channel. The schematic model predicts an attractive {Theta}-nucleon interaction strong enough to bind a {Theta} particle to a nucleus in a state that is stable against decay via strong interactions. The discovery of {Theta}-nuclei could be a definitive proof that the {Theta} parity is even.
Date: March 2, 2004
Creator: Miller, Gerald A.
System: The UNT Digital Library